Digital Commons Network^™

Characterization Of Iron Oxide Thin Films For Photoelectrochemical Hydrogen Production, Kyle Eustace Nelson George

UNLV Theses, Dissertations, Professional Papers, and Capstones

Solar energy is the most sustainable source of energy available. However, solar applications such as photovoltaic cells represent only a partial solution to weaning our dependence upon fossil fuels. Several methods of storing solar energy are currently being pursued, and chemical storage stands out as a promising option - combining design simplicity with high energy density, with hydrogen being particularly attractive because of its abundance and inherently clean nature. A monolithic Photoelectrochemical (PEC) device that produces hydrogen by electrolyzing water directly from sunlight has the benefit of utilizing "free" solar energy to drive the reaction.

Although α-Fe 2 O 3 …

Static High Pressure Ft-Ir Spectroscopic Studies Of Tatb, Brian F. Yulga

UNLV Theses, Dissertations, Professional Papers, and Capstones

Static high-pressure experiments utilizing diamond anvil cells (DACs) provide an alternative method to shockwave studies for extracting precise information on the physical and chemical properties of energetic materials. Due to mechanical restraints (e.g. small sample sizes and apertures), synchrotron radiation sources are ideal for probing the structure of materials at the molecular level. 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) is an insensitive (tertiary) high explosive (iHE) useful in military applications. Compared to other conventional iHEs, it is a safer and more stable energetic material. Its unique properties cause it to be of interest in the energetic materials research community. A series of Fourier-transform infrared …

Optimization Of The Microprecipitation Procedure For Nuclear Forensics Applications, Lyndsey Renee Kelly

UNLV Theses, Dissertations, Professional Papers, and Capstones

Microprecipitation has become one of the most widely used sample preparation techniques for alpha spectroscopy. Many factors during the precipitation process can affect the yield and energy resolution by adding unwanted mass to the sample. Current applications in nuclear forensics call for an optimization of energy resolution and yield in order to improve identification and quantify specific radionuclides. The purpose of this research is to determine the optimal parameters used for microprecipitation. The optimal solution temperature, precipitation time, carrier amount, and hydrofluoric acid amount are used to investigate the influence of varying the type of carrier, as well as, the …

Parametric Study Of Efficiency Measures For Home Energy Conservation In Las Vegas, Nevada, Todd M. France

UNLV Theses, Dissertations, Professional Papers, and Capstones

Pulte Homes, a production home builder and community developer partnering with the U.S. Department of Energy's Building America program, has collaborated with the Center for Energy Research at the University of Nevada, Las Vegas and NV Energy, the local electric utility, on an energy conservation project in the Las Vegas Valley.

This study entails four model homes at a new development in the Summerlin community of Las Vegas, Nevada, named Villa Trieste. The home models, ranging in floor plan area from 1,487 to 1,777 square feet, have been constructed under the Environments for Living program and are LEED (Leadership in …

Partial Ion Yield Sspectroscopy Around The Cl 2p And C 1s Ionization Thresholds In Cf3cl, D. Ceolin, Maria Novella Piancastelli, Wayne C. Stolte, Dennis W. Lindle

Chemistry and Biochemistry Faculty Research

We present a partial ion yield experiment on freon 13, CF₃Cl, excited in the vicinity of the C 1s and Cl 2p ionization thresholds. We have collected a large amount of cationic fragments and a few anionic fragments at both edges. We have observed a strong intensity dependence of Rydberg transitions with ion fragment size for the CF_nCl⁺ and CF_n⁺/F⁺ (n=0–3) series at both the Cl 2p and C 1s ionization edges. Selectivity in the fragmentation processes involving the C–Cl and C–F bonds are highlighted by the intensities of the C …

Yttrium And Hydrogen Superstructure And Correlation Of Lattice Expansion And Proton Conductivity In The Bazr0.9y0.1o2.95 Proton Conductor, A. Braun, A. Ovalle, V. Pomjakushin, A. Cervellino, S. Erat, Wayne C. Stolte, T. Graule

Chemistry and Biochemistry Faculty Research

Bragg reflections in Y-resonant x-ray diffractograms of BaZr_0.9Y_0.1O_2.95 (BZY10) reveal that Y is organized in a superstructure. Comparison with neutron diffraction superstructure reflections in protonated/deuterated BZY10 suggests that both superstructures are linked, and that protons move in the landscape imposed by the Y. The thermal lattice expansion decreases abruptly for protonated BZY10 at T≥648±20 K, coinciding with the onset of lateral proton diffusion and suggesting a correlation of structural changes and proton conductivity. The chemical shift in the Y L₁-shell x-ray absorption spectra reveals a reduction from Y³⁺ toward Y²⁺ upon …

Rebuilding After Disaster: Going Green From The Ground Up, U.S. Department Of Energy

Publications (E)

If you’re a leader in a community that has met with disaster and must be rebuilt, this guide is for you. It’s intended to show how communities—big or small—can incorporate green principles and technologies like energy efficiency and renewable energy into their rebuilding plans. The information in this guide is based on the real-life experiences of two U.S. Department of Energy (DOE) teams. One team worked with city leaders in New Orleans, Louisiana, after hurricanes Katrina and Rita in 2005, and the other assisted community leaders in Greensburg, Kansas, after a devastating tornado in 2007. Although the two communities are …

Ac Susceptibility And Heat Capacity Studies Of The Geometrically Frustrated Pyrochlores Terbium Titanium Tin Oxides And Holmium Titanates, Daniel Antonio

UNLV Theses, Dissertations, Professional Papers, and Capstones

Materials with a geometrically frustrated magnetic pyrochlore lattice have been of interest due to their unusual ground states. Tb 2 Ti 2 O 7 is known for having a spin liquid ground state which does not transition to a long-range ordered state down to at least 50 mK. Ho 2 Ti 2 O 7 has a macroscopically degenerate spin ice ground state which resembles that of the proton ordering in water ice. Heat Capacity measurements of Tb 2 Ti 2- x Sn x O 7 were done down to 0.36 K and AC magnetic susceptibility measurements of Ho 2- x …

Desert Varnish As An Indicator Of Modern-Day Air Pollution In Southern Nevada, Piotr Nowinski

UNLV Theses, Dissertations, Professional Papers, and Capstones

Rock varnish, often called desert varnish, is a slow-growing, manganese-rich coating that accumulates on exposed rock surfaces. The mechanism of varnish formation is not fully understood, however, most authors agree that varnishes derive their components from the atmosphere. The main goal of this study was to demonstrate the potential use of desert varnish as a passive environmental monitor of present and past atmospheric pollution. Analysis of varnishes is a new field that can potentially provide records of pre-anthropogenic levels of atmospheric metals and other environmental pollutants. To evaluate the potential of desert varnish as an environmental monitoring tool, the following …

Pedestrian Dynamics: Mathematical Theory And Evacuation Control, Pushkin Kachroo

Electrical & Computer Engineering Faculty Research

Homeland security, transportation, and city planning depend upon well-designed evacuation routes. You can’t wait until the day of to realize your plan won’t work. Designing successful evacuation plans requires an in-depth understanding of models and control designs for the problems of traffic flow, construction and road closures, and the intangible human factors. Pedestrian Dynamics: Mathematical Theory and Evacuation Control clearly delineates the derivation of mathematical models for pedestrian dynamics and how to use them to design feedback controls for evacuations. The book includes: * Mathematical models derived from basic principles * Mathematical analysis of the model * Details of past …

Efficient Clustering Techniques For Managing Large Datasets, Vasanth Nemala

UNLV Theses, Dissertations, Professional Papers, and Capstones

The result set produced by a search engine in response to the user query is very large. It is typically the responsibility of the user to browse the result set to identify relevant documents. Many tools have been developed to assist the user to identify the most relevant documents. One such a tool is clustering technique. In this method, the closely related documents are grouped based on their contents. Hence if a document turns out to be relevant, so are the rest of the documents in the cluster. So it would be easy for a user to sift through the …

Analytical Method Development For Determination Of Volatile Organic Compounds In Calcareous Desert Soil, Mary F. Turner

UNLV Theses, Dissertations, Professional Papers, and Capstones

Soil sample preservation for volatile organic compound analysis generally requires short sample holding times or preservation of the sample's chemical constituents with sodium bisulfate (NaHSO 4 ). Calcareous soils cannot be preserved using NaHSO4 because effervescence will promote the loss of analytes, and short holding times before analysis are not practical for remote sampling locations. An experimental approach was developed for determination of volatile organic compounds (VOCs) in soil that utilizes solid sorbents for sample preservation and solid-phase microextraction (SPME) sample preparation technique coupled with gas chromatography/mass spectrometry (GC/MS) for analysis. Solid sorbents are used to sequester readily extractable (vapor …

Systematic Analysis Of Identifying Key Dimensions Of Environmentally And Socially Responsible Hotels, Courtney Suess

UNLV Theses, Dissertations, Professional Papers, and Capstones

Development in Southeast Asia involves making good decisions for the future, so the idea that good planning can ignore sustainability is something of an oxymoron. Good development has to be sustainable and we have reached a point where the old ways of tourism development are intolerable. For example, hotels spring up without planning for the future. This short sightedness means natural endowments, like coastlines, erode and forests are cut down, chasing away the wildlife; or cultural history in the form of temples, historic buildings, and sacred places are destroyed. Ironically, tourism development is eradicating the very forms of product that …

Effects Of Plant Uptake And Micro-Topography On Chloride Transport In Arid Soils, Wenming Nie

UNLV Theses, Dissertations, Professional Papers, and Capstones

Chloride concentration profiles to depths of 1 m were evaluated on a young alluvial fan in Eldorado Valley, NV. It was found that chloride beneath plant canopies were 11 to 222 times higher than adjacent (1 - 2 m away) bare soil locations. Two-dimensional numerical simulations using HYDRUS 2D/3D model were used to further explore the impact of plants on chloride transport. The simulation results indicated that lateral flow driven by root uptake concentrated chloride toward root zones, leading to the accumulation of chloride under plant canopies. Results also suggest that locally micro-topography can have a substantial impact on chloride …

Evaluation Of Rapid Electric Battery Charging Techniques, Ronald Baroody

UNLV Theses, Dissertations, Professional Papers, and Capstones

Battery powered electric vehicles are gaining popularity worldwide. This is trend is driven by several factors including the need to reduce air and noise pollution, and dependence on fossil fuels. The main drawback of today's electric vehicle is its limited range, and the long time duration that is required to charge the electric batteries. This thesis addresses the latter problem.

In recent years, significant progress (through research and development) has been made to accelerate the charging time of the electric vehicle batteries through pulse charging rather than supplying continuous current and/or voltage. Some patented fast charging techniques demonstrated reduced charging …

Water Use And Natural Limits In The Las Vegas Valley: A History Of The Southern Nevada Water Authority, Christian Harrison

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis examines the history of the Southern Nevada Water Authority (SNWA) and how it has helped transform various aspects of southern Nevada's economy and environment. Prior to the establishment of the SNWA in 1991 the Las Vegas Metropolitan Area (LVMA) possessed several competing water providers whose opposition to one another adversely affected the management of water in the region. These water providers recognized this problem, came together, and negotiated the creation of a regional water agency, the SNWA. This organization, comprised of representatives from each of the LVMA's water providers has the power to institute policy across municipal boundaries. …

Relationships And Dropping Out: The Voice Of At-Risk Youth, Robert Thomas Henry

UNLV Theses, Dissertations, Professional Papers, and Capstones

The practice of retaining students in grade has been studied, researched, discussed, criticized and yet it continues. Dropping out of school prior to graduation has been studied, researched, discussed, written about and continues to be practiced by our youth. Policymakers are often provided quantitative data to consider as they explore, evaluate, and deliberate issues such as the practice of retention-in-grade to assure adherence to standards, or in response to the social, political, and educational problems created by youth who have dropped out from school.

Current studies and research into retention and dropping out fail to include the issues from the …

Controlled Functionalization Of Crystalline Polyolefins And Their Application In Soluble Polymer Support, Jihoon Shin

UNLV Theses, Dissertations, Professional Papers, and Capstones

Functionalization of polyolefins has been recognized as a useful methodology for the generation of new materials with a wide range of applications. Recently, crystalline or semi-crystalline polyolefins have drawn increasing attention in both industrial and academic fields as one of the most interesting engineering plastics, due to their remarkable physical and mechanical properties. This dissertation describes: (1) novel methods for the direct postfunctionalization of crystalline polyolefins to introduce functionality, (2) characterizations for the functionalized polymers to analyze their structures, molecular-weight properties, thermal properties, and hydrophilicity, and (3) an application of the modified crystalline polystyrene as a soluble polymer support for …

Examining Compressed Speech Listening Measure With College Students Who Are Visually Impaired Or Blind, William J. Marks

UNLV Theses, Dissertations, Professional Papers, and Capstones

Psychological assessments are a way of gaining some understanding of an individual in order to help make informed decisions (Sattler, 2001). These assessments offer potentially important and valuable information that can assist individuals with impaired vision in learning additional skills, improving deficient abilities, and in providing diagnostic information for future research. In addition, psychological assessments are frequently used to diagnosis a variety of psychological and learning disorders. Assessing individuals with impaired vision presents a variety of challenges from those encountered with the general population.

The current study provided an investigation into the relationship of the results of the compressed speech …

Statistical Inferences For Functions Of Parameters Of Several Pareto And Exponential Populations With Application In Data Traffic, Sumith Gunasekera

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this dissertation, we discuss the usability and applicability of three statistical inferential frameworks--namely, the Classical Method, which is sometimes referred to as the Conventional or the Frequentist Method, based on the approximate large sample approach, the Generalized Variable Method based on the exact generalized p -value approach, and the Bayesian Method based on prior densities--for solving existing problems in the area of parametric estimation. These inference procedures are discussed through Pareto and exponential distributions that are widely used to model positive random variables relevant to social, scientific, actuarial, insurance, finance, investments, banking, and many other types of observable phenomena. …

Zirconia-Magnesia Inert Matrix Fuel And Waste Form: Synthesis, Characterization And Chemical Performance In An Advanced Fuel Cycle, Kiel Steven Holliday

UNLV Theses, Dissertations, Professional Papers, and Capstones

There is a significant buildup in plutonium stockpiles throughout the world, because of spent nuclear fuel and the dismantling of weapons. The radiotoxicity of this material and proliferation risk has led to a desire for destroying excess plutonium. To do this effectively, it must be fissioned in a reactor as part of a uranium free fuel to eliminate the generation of more plutonium. This requires an inert matrix to volumetrically dilute the fissile plutonium. Zirconia-magnesia dual phase ceramic has been demonstrated to be a favorable material for this task. It is neutron transparent, zirconia is chemically robust, magnesia has good …

Improving Casino Profitability Through Effective Offer Packages, Ren Zhang

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of the this study is to investigate effective marketing techniques to attract potential customers in a particular demographic group, young people aged from 21 to 34, as a way of exploring the local market. This demographic group constitutes a dynamic part of the local population and is characterized by its unique financial conditions and spending preferences. The hypothesis is that with well-designed price bundling, the casinos can realize increased revenue through increased visits from the local young population. The marketing technique used in this study is to utilize offer packages which bundle promotional items and other hotel-provided services. …

Processes Of Disposition Development In K--5 Teachers, Deborah A. Obara

UNLV Theses, Dissertations, Professional Papers, and Capstones

Educators concur that teacher competency requires more than teaching knowledge and skills; competency requires appropriate professional dispositions. The development of professional dispositions is an expected outcome of teacher education programs. Since 2002, program accreditation has been contingent on documentation that prospective teachers have met national standards for dispositions. The body of educational research on disposition assessment has been growing. Research on disposition learning and development, however, has been impeded by the prevailing conceptualization of dispositions as fixed traits resistant to change. The present study conceptualized dispositions as malleable constructs within a theoretical framework that synthesized a cognitive model of thinking …

Mineralogy And Micromorphology Of An Atacama Desert Soil, Chile: A Model For Hyperarid Pedogenesis, Michael S. Howell

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Atacama Desert is the oldest and driest desert on Earth. Hyperarid soils in this desert are dominated by rare (or exclusive) salt minerals and assemblages. Previous research details salt origins and abundance, however pedogenic processes involved in salt distribution are not adequately explained. Therefore, the main goal of this investigation was to identify and document evidence for hyperarid pedogenesis (via salt mineralogy and soil micromorphology) at a field site, Oficina Ercilla, located ~80 km northeast of Antofagasta, Chile within the Central Depression and hyperarid core of the Atacama Desert. This study presents an interpretational model for hyperarid pedogenesis, which …

Two-Tank Indirect Thermal Storage Designs For Solar Parabolic Trough Power Plants, Joseph E. Kopp

UNLV Theses, Dissertations, Professional Papers, and Capstones

The performance of a solar thermal parabolic trough plant with thermal storage is dependent upon the arrangement of the heat exchangers that ultimately transfer energy from the sun into steam. The steam is utilized in a traditional Rankine cycle power plant. The most commercially accepted thermal storage design is an indirect two-tank molten salt storage system where molten salt interacts with the solar field heat transfer fluid (HTF) through a heat exchanger. The molten salt remains in a closed loop with the HTF and the HTF is the heat source for steam generation. An alternate indirect two tank molten salt …

Sequence And Chemostratigraphic Study Across The Basal Eureka Quartzite Unconformity In The Great Basin, Nevada: Implications For The Origin Of The Late Ordovician Carbon Isotope Excursion, Apostolos Paul Kosmidis

UNLV Theses, Dissertations, Professional Papers, and Capstones

The positive carbon isotope (δ 13 C) excursion from the late Middle Ordovician Copenhagen Formation that underlies the Eureka Quartzite in central Nevada has been hypothesized to record a global cooling event ∼10 Myr prior to the well-recognized Late Ordovician Hirnantian glaciation (∼443 Ma). However, direct evidence for pre-Hirnantian continental glaciation remains scarce, raising uncertainties in the relationship between the inferred eustatic sea-level fall and the origin of the positive δ 13 C excursion. Additionally, previous stratigraphic studies from southern Nevada and California suggest relative sea-level fall in excess of ∼ 150 meters, which exceeds estimates for younger glacial periods …

Standing In The Night, Karin Jane Millhouse

UNLV Theses, Dissertations, Professional Papers, and Capstones

Standing in the Night has been completed under the influence of phenomenology with its curious regard towards reality. Yet it makes no claims to be anything other than what it is: really, we're just making it all up as we go along.

Effects Of Similarity Metrics On Document Clustering, Rushikesh Veni

UNLV Theses, Dissertations, Professional Papers, and Capstones

Document clustering or unsupervised document classification is an automated process of grouping documents with similar content. A typical technique uses a similarity function to compare documents. In the literature, many similarity functions such as dot product or cosine measures are proposed for the comparison operator.

For the thesis, we evaluate the effects a similarity function may have on clustering. We start by representing a document and a query, both as a vector of high-dimensional space corresponding to the keywords followed by using an appropriate distance measure in k-means to compute similarity between the document vector and the query vector to …

Bending Of Woody Riparian Vegetation As A Function Of Hydraulic Flow Conditions, John O. Goreham

UNLV Theses, Dissertations, Professional Papers, and Capstones

Vegetation encroachment reduces channel conveyance capacity below design objectives and greatly increases the risk for loss of life and property damage in the case of large flood events. Given minimal knowledge of hydraulic roughness for shrubs and woody vegetation, accurate estimation of channel capacity and water surface elevation is difficult. The ability to predict a tree's bent, reduced height in the presence of flow permits more accurate prediction of hydraulic roughness and water surface elevation.

In this study, field tests were performed to elucidate tree bending properties, which in turn served as input parameters for a numerical algorithm designed to …

Biofeedback Assisted Relaxation Training Program To Decrease Test Anxiety In Nursing Students, Catherine Andrea Prato

UNLV Theses, Dissertations, Professional Papers, and Capstones

Nursing programs have been cited as being among the most stressful undergraduate programs. Students' knowledge and skills are consistently tested and monitored, and students may fail a course or be dropped from their nursing program if scores are not above a certain standard. Anxiety reactions are common to situations perceived as threatening; however, excessive anxiety may paralyze an individual and interfere with effective learning, functioning, and testing. Numerous studies have found increased anxiety causes physiological changes including increased respirations and heart rate, and decreased peripheral skin temperature. The purpose of this study was two fold. First test anxiety was measured …