Digital Commons Network^™

Effects Of Confinement On Ionic Liquids And Deep Eutectic Solvents For The Design Of Catalytic Systems, Electrochemical Devices, And Separations, Andrew Drake

Theses and Dissertations--Chemical and Materials Engineering

Confinement of ionic liquids (ILs) and deep eutectic solvents (DESs) within mesoporous materials such as silica helps to control the local environment within the pores for applications such as catalysis, electrochemistry, and absorption. Silica thin films with 2.5 and 8 nm pores and micron-sized silica particles with pore diameters of 5.4 and 9 nm were synthesized to study the effect of nanoconfinement on ILs 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF₆]), 1-butyl-3-methylimidazolium chloride ([BMIM][Cl]), and DESs reline and ethaline (choline chloride and urea or ethylene glycol). Silica thin films with vertically aligned, well ordered, and accessible pores were synthesized via the evaporation-induced …

Together Now, Alfonso Zapata

Theses and Dissertations--English

Together Now is a collection of poems by Alfonso Zapata, with work written between 2021 and 2023 at the University of Kentucky. This thesis contains poems which examine the close relationship between families, art, and the histories each contain. These poems use these subjects in order to illustrate the emotional and physical impact communities have upon those who live in them; art can evolve a person, shape them in beautiful ways, and give us the ability to process tragedy together; on the other end of the spectrum, societal neglect, environmental crisis, and food insecurity can rip these communities apart potentially …

Kill On The Left Foot, Daniel Collins

Theses and Dissertations--English

This collection of essays and short stories represents experiences during and related to my military service as a Tactical Air Control Partyman in the United States Air Force. Recurrent themes in this collection involve patriotism, fatherhood, masculinity, trauma, and recovery. The work itself represents the study and practice of the elements of fiction and foundational concepts related to creative nonfiction.

Emerging Hues: Essays From The Teneral Stage, Lucy Jayes

Theses and Dissertations--English

This collection of essays features work created and revised over two years in the Masters of Fine Arts in Creative Writing Program. They reflect a period of intense evolution in the author’s life and delve into topics of modern-day motherhood and cycles of intimate partner violence.

The Reflexitve Fritz Lang: Meta-Cinematic And Genre Critiques In His American Films, Justin J. Roberts

Theses and Dissertations--English

Director Fritz Lang is best remembered and most celebrated for the films he made in Germany, including Metropolis (1927) and M (1931), between 1919 and 1933. But he spent over half of his career working in Hollywood. This dissertation is a reconsideration of his American films, focused on how Lang used various Hollywood genres to question and critique the way Hollywood films and genres functioned, as well as trends within those genres. This dissertation is a roughly chronological reading of twelve of Lang’s American films, sorted by genre. We can see how his thinking about the function of film and …

Conceive And Control: Cultural-Legal Narratives Of American Privacy And Reproductive Politics, Emily Naser-Hall

Theses and Dissertations--English

Law and literature share a foundation in narrative. The literary turn in legal scholarship recognizes that the law itself is a form of narrative, one that simultaneously reflects socio-cultural norms and creates social and political regulations with a complex matrix of power. Cultural narratives from the 1950s to the mid-1970s pertaining to reproductive politics, domesticity, and national identity both produce and are productive of legal rulings that govern and restrict private acts of sexuality and speech. The Supreme Court used cases concerning sex and reproduction to enumerate, explicate, and complicate the right to privacy, which appears nowhere in the U.S. …

Myth, Mockery, & Misery: An Evolution Of Disillusion In Modern-War Expression, Richard W. Halkyard

Theses and Dissertations--English

Industrialization in 19th-Century America yielded a regrettable by-product: the modernization of warfare. Mass armies, technological innovation, and unprecedented rates of industrial productivity prompted the creation of machines designed to inspire fear, increase destructive capability, and inflict mass-death. The modernization of warfare altered forever the way war was experienced and represented literarily. Authors who attempted to represent the Civil and Spanish-American Wars, as well as World War I, articulated modernized warfare with a disillusionment which stems from the tragically dehumanizing effects of mechanical violence on an industrial scale. Myth, Mockery, & Misery argues that as far back as 1862, romantic idealization …

Ovid's Caeneus As A Queer Hero: Understanding Gender And Gender Variance In The Ancient Mediterranean., Rj Palmer

Theses and Dissertations--Modern and Classical Languages, Literature and Cultures

Caeneus, as written in Ovid’s Metamorphoses, is a notable blend of ancient and Hellenistic versions of the myth. Ovid’s Caeneus can be understood as a transgender man, since he was assigned female at birth, but asks for his gender to be changed by the god Neptune, and goes on to live the rest of his life with the body, appearance, and social roles of a man. Ovid incorporates Caeneus’ trans identity with his use of grammatical gender endings for Caeneus, using masculine gender for Caeneus except when discussing his pre-transition childhood, or when the centaurs address him mockingly while fighting. …

Exploring The Molecular Basis Of Touch: A Comparative Analysis Of Gene Expression In Sensory Corpuscle-Rich And Corpuscle-Poor Skin Regions In The Duck, Thomas Hart

Theses and Dissertations--Biology

Cutaneous touch is facilitated by discrete cellular complexes composed of non-neuronal cells associated with mechanoreceptor neuron endings. The non-neuronal cells of these cutaneous end organ complexes (CEOCs) are believed to contribute to touch, but their role in touch sensation remains unclear. To better understand the function of CEOC cells, we sought to characterize the transcriptional profile of CEOC-rich tissue and identify genes expressed in CEOC cells. Bill skin of the tactile foraging Pekin duck (Anas platyrhynchos) is dense with CEOCs, specifically the avian analogs of mammalian Pacinian and Meissner corpuscles, while corpuscles in duck foot skin are scarce. Using RNA …

Field Tests Of A Uav-Compatible Spectrometer To Evaluate Its Suitability For Detailed Soil Radon Potential Mapping, Alexandria Briahnne Thomas

Theses and Dissertations--Earth and Environmental Sciences

As part of ongoing research on radionuclide mapping and radon hazard characterization, field tests were performed to evaluate the suitability and limitations of a UAV-compatible gamma spectrometer. To date, this data set includes completed stationary data collection, mobile ground collection, multi-level UAV flights over a known material transition, as well as redundant ground and multi-level UAV data collection over a relatively uniform area. Total counts were used as a measure of soil radionuclide levels for our data collected above background. Although our test sites were in regions underlain by bedrock with high indoor radon levels, uranium counts were barely above …

The Appalachian System Of Basins And Platforms As A Tectonostratigraphic Analogue To The Barents Sea Shelf: Where Arctic Meets The Appalachians, Gustavo De Aguiar Martins

Theses and Dissertations--Earth and Environmental Sciences

Divided between Norway and Russia, the Barents Sea shelf (BSS) is an ~1.4 million km² Arctic province, containing significant hydrocarbon accumulations. However, much of the area is frontier, and geologic data are often restricted or unavailable. One strategy to mitigate lack of geologic data is the use of analogues from well-known, mature basins. Even though there have been attempts to use analogues to study the geology of the BSS, such use is limited. Moreover, no analogue, to my knowledge, has been capable of addressing the regional tectonostratigraphic development of the shelf as a whole.

In this research, the Appalachian …

Discovery Of The Middle Mantle Transition Zone (Mmtz) And Its Geodynamic Significance, Yuping Wang

Theses and Dissertations--Earth and Environmental Sciences

Global mantle discontinuities and mantle transition zones are crucial to the earth’s evolution. By employing K-Means clustering, which belongs to cluster analysis in machine learning (ML), on shear velocity variation data, we generate heterogeneity percentage profiles for three different global tomographic models (Models S362WMANI+M, SEMUCB-WM1, and S40RTS). Key cluster percentage shifts, which are observed at around 400 km, 650 km, 1050 km, 1500 km, and 2700 km, suggest global mantle discontinuities at corresponding depths. All profiles also indicate a global discontinuity in the lower mantle between 2200 km and 2600 km. The middle mantle transition zone (MMTZ), bounded between 1050 …

Applications Of Digital Terrain Modeling To Address Problems In Geomorphology And Engineering Geology, Sarah Johnson

Theses and Dissertations--Earth and Environmental Sciences

This dissertation uses digital terrain modeling and computational methods to yield insight into three topics: 1) evaluating the influence of glacial topography on fluvial sediment transport in the Teton Range, WY, 2) integrating regional airborne lidar, UAV lidar, and structure from motion photogrammetry to characterize decadal-scale movement of slow-moving landslides in northern Kentucky, and 3) applying machine learning methods to surficial geologic mapping.

The role of topography as a boundary condition that controls the efficiency of fluvial erosion in the Teton Range, Wyoming, was investigated by using existing lidar data to delineate surficial geologic units, geometrically reconstruct the depth to …

Picturing The Future City: Digital Mediation And Creative Placemaking, Jessica Mccallum Breen

Theses and Dissertations--Geography

Creative placemaking is an arts-oriented community development policy that focuses on the potential for art, artists, and cultural organizations to generate social, economic, and cultural vibrancy in their communities and is a primary tool of culture-led (re)development practices (Markusen & Gwada, 2010). Despite the focus of creative placemakers on the local impacts of their work, creative placemaking is more than local, it is both translocal and transcalar. In this dissertation, I examine the role that digital mediation plays in creative placemaking and how it makes visible these translocal and transcalar connections. I begin by outlining a methodology for tracing replicated …

The Psycho-(Geo)Political Driving Forces Of Comfort Women Social Movements In South Korea, Jaeyeon Lee

Theses and Dissertations--Geography

"Comfort women" refers to the estimated 80,000 to 200,000 women who were forced to serve the Japanese imperial army sexually, physically, and mentally during WWII in and beyond the Asia-Pacific region. Since 1992, Korean activists have held the Wednesday Demonstration, which is the weekly protest in front of the Japanese Embassy in Seoul, to call for an official apology and legal compensation from the Japanese government. Since 2011, Korean activists have also installed comfort woman statues in and outside of South Korea.

This dissertation examines the psycho-political driving force behind the Wednesday Demonstration and comfort woman statue movements in South …

Property Protocols And The Spatial Relations Of Real Estate Technologies, Ian Spangler

Theses and Dissertations--Geography

The dissertation contributes to our understanding of the technologically mediated, professionally managed social relations of private property, and specifically, their consequences for housing and home. I analyze standards and protocols for real estate data transfer, such as the multiple listing service, arguing that these standards play an increasingly important role in how real estate capital authenticates property relations. Focusing on technologies that leverage these standards in order to manage, exchange, and marketize housing, I show how standards often derive from moral values grounded in rubrics of white upper-class masculinity and national border-making. In making this argument, I draw on interviews, …

‘A Category Of Their Own’: Quantitative Methods In The Use Of Pile-Sort Data In Perceptual Dialectology, Zachary Ty Gill

Theses and Dissertations--Linguistics

The purpose of this study is to investigate how Mississippi Gulf Coast Creoles perceive language differences in their home area. A pile-sort task was carried out in which respondents were given stacks of cards with local communities written on them and instructed to stack together the regions where people “talk the same.” Once the piles were made, the fieldworker discussed their sortings with the respondents. The stacks were analyzed by means of a hierarchal agglomerative cluster analysis and non-parametric multidimensional scaling with k-means cluster analysis overlays to extract the perceived dialect areas. The groupings reveal that respondent strategies are based …

Language Ideologies In Deep South Korea: Voices Of Jeollanamdo English Teachers, Ian Schneider

Theses and Dissertations--Linguistics

Language ideologies serve as shared beliefs and key frames that link language and society, mediating both macro-level social forces and micro-level interactions. Through this lens, this thesis compares the ideological perspectives and experiences of expatriate and local English teachers working in secondary-level schools in the rural province of Jeollanamdo, South Korea. Through thematic analysis of semi-structured interviews, this study argues for complexity and nuance in how language teachers from distinct backgrounds perceive and negotiate dominant English language ideologies in Korean society. Moreover, these ideological perspectives differ between teachers of local and expatriate backgrounds, or teachers working in urban and rural …

Rhyming Tactics In Korean Hip-Hop With Two Approaches Of English And Korean Syllable Structures, Gihyun Gal

Theses and Dissertations--Linguistics

Rhyming Tactics in Korean Hip-Hop with Two Approaches of English and Korean Syllable Structures

Today, Korean Hip-Hop (KHH) has been slowly moving beyond a localized pop culture through the internet and media. This study finds that rhyming patterns in KHH are much more complex than prior research suggests. Especially, this study focuses on an evolution of Korean Hip-Hop through the time such as since 1989 to 2015. Park (2016) discusses how Korean rappers think about using rhyming tactics as "[m]over, the concept of rhyming was not conceptualized as belonging to the Korean language by most of rappers. Even if rappers …

Perceptual Dialectology Of Tulsan Speakers Of English, Andrew Carter

Theses and Dissertations--Linguistics

The present study analyzes new interviews from fifteen Tulsan speakers of English and maps produced by draw-a-map tasks. The interviews and subsequent map tasks were conducted over the course of the winter of 2021 for the purpose of this thesis and have been analyzed for folk linguistic information about the perceptions of Tulsa and the rest of the state. The study finds that Tulsan speakers hold similar dialectal perceptions about both their own city and other locations as their fellow Oklahomans, and also provides evidence of a deteriorating faith among Tulsans in the existence of the northern-southern dialectal divide compared …

“Local, But Intelligent”: Language Ideologies In The Informant Biographies Of The Linguistic Atlas Project, Nicholas A. Passarelli

Theses and Dissertations--Linguistics

This thesis argues for the relevance of the Linguistic Atlas Project (LAP) for studies of language ideologies, indexicality, and enregisterment. The LAP represents the largest dialect survey of North American English to date, offering an abundance of historical linguistic data for research in dialectology, linguistic geography, and variation over space and time. Additionally, the LAP also contains additional sources of sociolinguistic data, including informant biographies — documents written by fieldworkers at the conclusion of the LAP interview that summarize an informant’s demographic profile, as well as their personality, speech, and caliber as an interviewee. Rife with subjective judgments from the …

Forum On “Conquest”: Past-Present Politics Of Coloniality In Cinema On Latin America, Stephen Jakob Turner

Theses and Dissertations--Hispanic Studies

My dissertation analyzes the representation of Spanish “Conquest” in film as a critical commentary on the cultural present. Chapter 1, “Directorial Discord: The Cultural Politics of Representation in Apocalypto (USA/Mexico/UK, 2006) and Retorno a Aztlán (Return to Aztlán, Mexico, 1991)” focuses on the representation of the (im)possibility of Indigenous heroic protagonism and futurity in the origins of “Conquest.” Chapter 2, “‘The World is Thus’: Resistance and the Power of Ambivalent Conversion in Gabriel Retes’s Nuevo Mundo (The New World; Mexico, 1976) and Roland Joffé’s The Mission (USA/Paraguay, 1986)” posits that the “Conquest” problematizes the myth of …

Truth In Horror: Cinematic Representations Of Social Violence In Spain, Latin America, And The United States, Kelly Ferguson

Theses and Dissertations--Hispanic Studies

My dissertation, Truth in Horror: Cinematic Representation of Social Violence in Spain, Latin American, and the Latinx United States, investigates the recent explosion of political horror films that straddle the past and present, reflecting both the current political moment and the polemic historical memories of state repression against racialized others and ideological dissidents. Chapter One, “Paranoid Horror and the Return of Franco,” studies four Spanish horror films, Tras el cristal (1986), Pa negre (2010), Mientras duermes (2011), and Musarañas (2014), all of which feature child protagonists that seek out truth about violent family secrets, but ultimately reject it as …

Taken: Slavery, Forced Migration, And Environment In The Early United States, Christopher L. Leadingham

Theses and Dissertations--History

This work examines the development and collapse of the slave trade in Kentucky. It pushes readers to think about the slave trade in an environmental context. The development of the slave trade in the state depended on the violent acquisition of Indigenous lands. The networks of credit and capital that settler colonists established—wealth concentrated in land, stock, crops, and people—fueled the development of a slave system west of the southern mountains. That system increasingly relied on the forced movement of enslaved people in and through Kentucky. The state’s legal system and other institutions worked to support slave trading companies especially …

'Grave Fears Of Collision' : James Beecher And The Administration Of Freedmen's Bureau Policy In Reconstruction South Carolina, Cameron Sauers

Theses and Dissertations--History

As an agent of the Freedmen’s Bureau and military officer, James Beecher embodied Federal power in the South Carolina Lowcountry. During Presidential Reconstruction, Beecher became a key administrator of Order No.15 that promised formerly enslaved peoples’s “40 acres and a mule” that formerly belonged to white plantation owners. Beecher, despite his antebellum abolitionist politics, was remarkably unsympathetic to freedpeople’s desire for independent landholding. Beecher believed that freedpeople were unfit for immediate citizenship and should sign labor contracts to return to plantations where they might be inculcated with Northern free labor values. Amid epidemic disease, famine, and white paramilitary violence, James …

"Any Changes, Eh?": Party Defection, Party Switching, And Shifting Allegiances In Antebellum America, 1830-1860, Jacob Wood

Theses and Dissertations--History

Political party ties hardened during the Second Party System period, most noticeably in the transition from the Federalist and Democratic-Republicans to the Democratic and Whig parties. “Any Changes, Eh?” argues that politically-minded Americans still found ways to leave their political parties and support another, even in the face of social and political ostracism. As party ties grew stronger, party defection shifted from direct to indirect methods to challenge political system. Sometimes these movements were permanent conversions, other times they were a protest vote only to make a point to their home party. Party defection took a variety of forms beyond …

The Kids Were Alt-Right: Radical Right Youth Activism And The Origins Of The White Power Movement, 1960-1980, Austin Zinkle

Theses and Dissertations--History

This dissertation explores the young people—primarily young men—involved and weaponized within the radical racist Right during the 1960s and 1970s in the United States. This project argues that young people were an active bedrock of support within racist and antisemitic organizations such as the American Nazi Party, the National Alliance, the Knights of the Ku Klux Klan, and others, and created a unique coalition that ultimately developed into a revolutionary racist Right and eventual white power movement by the 1980s. This dissertation makes a significant intervention in scholarship on the radical Right’s development over the past sixty years and serves …

Orphans, White Unity, And The Charleston Orphan House, 1860-1870, Ruth Poe White

Theses and Dissertations--History

This dissertation explores the ways the Charleston Orphan House, a nineteenth-century whites-only benevolent institution, promoted white unity in South Carolina between 1860 and 1870. Just as it had during the antebellum era, the Orphan Home knit together white society by providing poor white families a source of social security, middling white families a source for cheap labor in the form of indentured service, and elite whites an opportunity to display social prominence. Yet, maintaining this delicate balance throughout the siege of Charleston and the Home’s eventual evacuation to Orangeburg, South Carolina was no easy feat. The Chairman of the Board …

Enduring The Elements: Civil War Soldiers’ Struggles Against The Weather, Cameron Boutin

Theses and Dissertations--History

This dissertation is an environmental history that studies the variety of ways that soldiers in the American Civil War experienced the pressures of weather over the course of their military service. For the troops of the U.S. and Confederacy, the weather was more than simply a passive backdrop to their time in the military, but a central preoccupation. This dissertation analyzes how weather intersected with some of the most central experiences of soldiering – tent camping and winter quarters, marching, bivouacking, manning sentry posts and field fortifications, and fighting in battles. Life in Civil War armies consisted of all of …

From Displaced To Displacers: Scottish Crofters, First Nation Peoples And Commons Enclosure From The 1700s To The 1800s, Anna Herrington

Theses and Dissertations--History

In the 18^th and 19^th centuries, the enclosure of common systems shaped the displacement of people on a global scale whilst bringing the people---Scottish Highland crofters and Mi’kmaq First Nation Canadians from the margins where they have dwelled for centuries in historical scholarship to of the centre of not just their history, but our collective history. Both populations experienced attacks on their ties to their lands, resources, and culture through enclosure. The enclosure process lasted over two centuries and was interspersed with violent protest, proactive resistance, interspersed with periods of acceptance and determination against their forced removals. Investigating …