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Tissue Engineering And The Effect Of Volumetric Muscle Loss On Muscle Performance, Alex Pemberton Dec 2021

Tissue Engineering And The Effect Of Volumetric Muscle Loss On Muscle Performance, Alex Pemberton

Biomedical Engineering Undergraduate Honors Theses

Trauma, for so many people, creates life altering injuries. One of the major injuries that results from trauma is volumetric muscle loss (VML), which is the loss of muscle tissue that cannot be naturally regenerated and results in chronic loss of function. When a small amount of damage is done to a muscle, but the underlying extracellular matrix of the cell is still intact, the muscle can regenerate much of its volume and function. If the injury damages the extracellular matrix, the injury site is instead filled with scar tissue, which cannot regenerate muscle mass or function. Seen widely in …


Palmer Amaranth [Amaranthus Palmeri (S.) Wats.] Resistance To S-Metolachlor In The Mid-Southern Us And S-Metolachlor Dissipation In Soil, Koffi Badou Jeremie Kouame Dec 2021

Palmer Amaranth [Amaranthus Palmeri (S.) Wats.] Resistance To S-Metolachlor In The Mid-Southern Us And S-Metolachlor Dissipation In Soil, Koffi Badou Jeremie Kouame

Graduate Theses and Dissertations

Palmer amaranth [Amaranthus palmeri (S.) Wats.] presents both a high genetic diversity and propensity to evolve resistance to herbicides of several sites-of-action which have made it one of the worst weeds in US agriculture. In Arkansas, Palmer amaranth is resistant to herbicides of seven sites-of-action, which are 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS) inhibitor, acetolactate synthase inhibitors, microtubule inhibitors, protoporphyrinogen oxidase inhibitors, very long chain fatty acid inhibitors, glutamine synthetase inhibitors, and hydroxyphenylpyruvate dioxygenase inhibitors. Sustainable management requires a better understanding of its biology and that of herbicide environmental fate. This research had five objectives: 1) characterize the current status of Palmer amaranth …


Sigesn Light-Emitting Devices: From Optical To Electrical Injection, Yiyin Zhou Dec 2021

Sigesn Light-Emitting Devices: From Optical To Electrical Injection, Yiyin Zhou

Graduate Theses and Dissertations

Si photonics is a fast-developing technology that impacts many applications such as data centers, 5G, Lidar, and biological/chemical sensing. One of the merits of Si photonics is to integrate electronic and photonic components on a single chip to form a complex functional system that features compact, low-cost, high-performance, and reliability. Among all building blocks, the monolithic integration of lasers on Si encountered substantial challenges. Si and Ge, conventional epitaxial material on Si, are incompetent for light emission due to the indirect bandgap. The current solution compromises the hybrid integration of III-V lasers, which requires growing on separate smaller size substrates …


Diversifying Woolf’S Room: Private Spaces And Creativity In The Works Of Willa Cather, Kate Chopin, Gayl Jones, And Alice Walker, Ebtesam M. Alawfi Dec 2021

Diversifying Woolf’S Room: Private Spaces And Creativity In The Works Of Willa Cather, Kate Chopin, Gayl Jones, And Alice Walker, Ebtesam M. Alawfi

Graduate Theses and Dissertations

There is a divergence between Woolf’s vision of private physical spaces necessary for creating art and that of some feminists of color such as Alice Walker, Ortiz Cofer, and Gloria Anzaldua. Both Woolf and these contemporary scholars agree on the importance of physical spaces for female artists. However, they disagree on the nature of these spaces. Woolf’s private physical space is a room with a lock on the door whereas these writers’ room is the kitchen table, the bus, or the welfare line. Walker and like-minded writers challenge the narrowness of Woolf’s room because her locked room is a luxury …


New Titanate Bioceramic Nanomaterials For Drug Delivery And Controlled Release, Seaab Imad Sahib Dec 2021

New Titanate Bioceramic Nanomaterials For Drug Delivery And Controlled Release, Seaab Imad Sahib

Graduate Theses and Dissertations

Nanomaterials have attracted much attention for biomedical applications due to their unique characteristics that are proven to be potential in cell sensing, drug delivery, biological membrane penetration, biocompatibility, and tissue adhesion. The outcomes of this dissertation presented in chapter III-V mainly discuss new approaches in drug delivery, cellular uptake improvement, and neuronal regeneration and protection using a well-optimized titanium-based nanomaterial. In particular, Chapter III summarizes the impact of two different versions of the titanate nanowires on ameliorating the delivery of the antimicrobial and anticancer drug in vitro. Those drugs were loaded on the surface of the fabricated nanowires and characterized …


Cover Crop Effects On Near-Surface Soil Aggregate Stability In The Southern Mississippi Valley Loess (Mlra 134), Chandler M. Arel Dec 2021

Cover Crop Effects On Near-Surface Soil Aggregate Stability In The Southern Mississippi Valley Loess (Mlra 134), Chandler M. Arel

Crop, Soil and Environmental Sciences Undergraduate Honors Theses

Intensive agricultural cultivation within major land resource area (MLRA) 134, the Southern Mississippi Valley Loess, has led to soil erosion, soil compaction, and the overall destabilization of near-surface soil aggregates. The use of cover crops during the agricultural offseason has been shown to help alleviate soil compaction and provide stabilizing effects against soil erosion, which are particularly important as the silty soils of MLRA 134 have a large erosion potential. This study evaluated the effects of cover crop and no-cover crop treatment on silt-loam soils within MLRA 134. Treatments were implemented during Fall 2018 and Fall 2019 and consisted of …


Adverse Childhood Experiences And Social Determinants Of Health In Relation To Pediatric Intensive Care Unit Admissions, Kasey Davis Dec 2021

Adverse Childhood Experiences And Social Determinants Of Health In Relation To Pediatric Intensive Care Unit Admissions, Kasey Davis

The Eleanor Mann School of Nursing Undergraduate Honors Theses

This literature review was conducted in order to examine the correlation between adverse childhood experiences (ACEs), social determinants of health and pediatric intensive care unit (PICU) admissions. Oftentimes, those admitted as patients in the PICU come from homes in which social determinants of health, such as poverty and lack of access to healthcare, and ACEs, such as abuse and neglect, are prevalent. Systematic studies of existing literature and experience in the hospital setting revealed the ways in which these conditions often cause children to reach such poor health conditions that they must be admitted to the PICU. In order to …


Implementing 2nd Milk’S Use Of The World Health Organization Standardized Growth Charts To Better Track The Growth And Development Of The Malnourished And Orphaned Infants In Their Supplemental Nutrition Program In Malawi, Allie Wycoff Dec 2021

Implementing 2nd Milk’S Use Of The World Health Organization Standardized Growth Charts To Better Track The Growth And Development Of The Malnourished And Orphaned Infants In Their Supplemental Nutrition Program In Malawi, Allie Wycoff

The Eleanor Mann School of Nursing Undergraduate Honors Theses

This article considers the history and implications of the World Health Organization (WHO) standardized growth charts as well as the significant impact that growth chart utilization may have on 2ndMilk’s ability to understand and track the nutritional status of the malnourished orphaned infants in their formula program. Specifically, this literature review examines whether or not the WHO growth charts are a meaningful tool for 2ndMilk to adopt into their monthly baby assessments. The WHO growth charts are calibrated to express an accepted international “norm” for what an adequately nourished child looks like. In a recent service-learning …


Effects Of Abstinence-Based Sexual Education Compared To Evidence-Based Sexual Education In K-12 Schools, Lily Probst Dec 2021

Effects Of Abstinence-Based Sexual Education Compared To Evidence-Based Sexual Education In K-12 Schools, Lily Probst

The Eleanor Mann School of Nursing Undergraduate Honors Theses

Background: Historically, sexual education in the United States has been abstinence-based (ABSE), meaning that sexual education is centered around encouraging adolescents to abstain from sexual activity outside of wedlock. On the other hand, evidence-based sexual education (EBSE) includes abstinence in its curriculum but does not emphasize it, instead highlighting contraception and prevention strategies. Additionally, EBSE teaches adolescents about healthy relationships, attitudes towards sexuality, gender roles, and provides resources for sexual and reproductive health services. Supplying adolescents in K-12 schools with access to evidence-based sexual education may not only decrease teen pregnancy rates and incidence of sexually transmitted infections (STIs) but …


Bullying Experiences Among Families And Children With Autism Spectrum Disorder, Developmental Delay, Or Varying Ethnicities, Emma Humphrey Dec 2021

Bullying Experiences Among Families And Children With Autism Spectrum Disorder, Developmental Delay, Or Varying Ethnicities, Emma Humphrey

The Eleanor Mann School of Nursing Undergraduate Honors Theses

Bullying perpetration in schools is a significant problem within the United States that has shown to increase mental health issues and adverse outcomes in children. The purpose of this extended literature review is to evaluate the significance of bullying in children with developmental delay (autism spectrum disorder) and majority and minority ethnic groups. The review of literature analyzes implications of bullying within these vulnerable populations and the family factors associated with peer victimization. An analysis from twenty peer-reviewed chosen articles reflects heightened levels of bullying, mental health problems, and negative experiences of all researched populations. The increased amount of victimization …


An Exploration Of Effective Patient Education With An Emphasis On Concussion, Kayla M. Ruopp Dec 2021

An Exploration Of Effective Patient Education With An Emphasis On Concussion, Kayla M. Ruopp

Health, Human Performance and Recreation Undergraduate Honors Theses

Concussion is a prevalent healthcare issue in the US, with approximately 1.6-3.8 million sports and recreation-related concussions each year in all ages. A concussion can be defined as a traumatic brain injury caused by biomechanical forces. When an athlete sustains a concussion, a physiologic cascade of events occurs. The most common signs and symptoms of a concussion include: loss of balance, disorientation, headache and confusion. Concussion assessments are important in order to determine the presence of an impairment and there are a multitude of tests that clinicians can use in order to isolate each type of damage. Studies have shown …


The Relationship Between Gestational Diabetes And Stress: A Literature Review, Morgan Mcgrath Dec 2021

The Relationship Between Gestational Diabetes And Stress: A Literature Review, Morgan Mcgrath

The Eleanor Mann School of Nursing Undergraduate Honors Theses

The incidence of gestational diabetes has been increasing over the past ten to twenty years. The purpose of this literature review is to gather existing literature to examine the relationship between gestational diabetes and oxidative stress. Twenty peer-reviewed articles from two databases were selected to be examined in this review. From these studies, it was found that oxidative stress was higher in women who were diagnosed with gestational diabetes, and supplementation with vitamins and minerals was beneficial in decreasing stress in these women. While these studies can help healthcare providers in educating women who have been diagnosed, more research should …


Site-Specific Effects Of Lysine Acetylation On Aminoacyl-Trna Synthetase, Hao Chen Dec 2021

Site-Specific Effects Of Lysine Acetylation On Aminoacyl-Trna Synthetase, Hao Chen

Graduate Theses and Dissertations

Aminoacyl-tRNA synthetases (AARSs) are an ancient and highly conserved family of enzymes which can catalyze a two-steps aminoacylation reaction to charge tRNAs with their cognate amino acids, thus playing crucial roles in ribosomal protein synthesis. Naturally, the accurate amino acids and tRNA recognition of these synthetases are essential to the fidelity of translation process. To assure the correct recognition, some of these synthetases have evolved with an editing function to help remove the mischarged tRNAs. In addition to these functions, AARSs are also involved in various biological processes ranging from transcription to translation. Currently, a series of proteomic studies have …


Canine Microwear In Relation To Diet In Sumatran Primates And African Great Apes, Putu Pujiantari Dec 2021

Canine Microwear In Relation To Diet In Sumatran Primates And African Great Apes, Putu Pujiantari

Graduate Theses and Dissertations

This thesis considers canine microwear in relation to diet in five Sumatran primates (Pongo abelii, Hylobates lar, Hylobates agilis, Presbytis thomasi, and Macaca fascicularis) and two African great apes (Pan paniscus and Pan troglodytes schweinfurthii) using both microwear texture analysis and microwear feature analysis techniques. Statistical results for texture analysis show that there are significant differences in scale of maximum and heterogeneity. This indicates that some species have large pits on their canine surfaces, having these dominated by deep features at coarse scale yet have a slight microwear heterogeneity. For feature analysis, all variables show statistically significant variation. Variance in …


Adapting Animals: Nineteenth-Century British Literature, Science, And Media, Kristen Layne Figgins Dec 2021

Adapting Animals: Nineteenth-Century British Literature, Science, And Media, Kristen Layne Figgins

Graduate Theses and Dissertations

In the nineteenth century, Charles Darwin and other proponents of evolutionary theory provided a theoretical framework for discussing the question of humanity’s place in the world. These nascent theories emphasized the shared animal nature of humans and the nonhuman creatures who had once occupied a distinctly lower place on the chain of being. My dissertation addresses the question of how nineteenth-century scientific attitudes about animals were reflected in the literature of the period. By examining culture-texts from the nineteenth century, it is clear that literature was an active participant in extending scientific knowledge, often by playing with the blending categorical …


The Role Of Sex: An Analysis Of U.S. Attitudes Toward Climate Change, Chloe Riggs Dec 2021

The Role Of Sex: An Analysis Of U.S. Attitudes Toward Climate Change, Chloe Riggs

Graduate Theses and Dissertations

This study analyzes the intersection of sex, environmental risk perception of climate change, and feminism. More specifically, with a sample size of 8,280 respondents from the American National Election Studies (ANES) 2020 Times Series Study, this research examines the relationship between pro-environmental attitudes and sympathy for feminism, controlling for sex, as well as if a measure of sympathy for feminism influences pro-environmental attitudes, controlling for demographic (age, education, race, sex, and income) and political preference (political ideology and party affiliation) variables. Previous literature strongly supports a sex gap in risk perception, a pattern known as the White Male Effect (WME) …


Greenhouse Tomatoes: Process Simulation, Juan Gabriel Marin Jr. Dec 2021

Greenhouse Tomatoes: Process Simulation, Juan Gabriel Marin Jr.

Graduate Theses and Dissertations

Growing population demand and challenges brought on by climate change have spurred the need for more resilient fruit and vegetable supply chains. One agricultural technology of significant interest is the use of greenhouses for food production. Greenhouses create a stable and adaptable environment for crops such as tomatoes to grow year-round. Fresh tomatoes are the second most consumed vegetable per capita in U.S. diets, currently averaging 20.7 pounds. The growing consumption of fresh tomatoes has been the result of increasing cultural diversity in the United States.

To meet the growing demand, Venlo-type greenhouses have been frequently used by growers. It …


Data Analytics For Sustainable Food And Agriculture Systems, Megan Lord Reavis Dec 2021

Data Analytics For Sustainable Food And Agriculture Systems, Megan Lord Reavis

Graduate Theses and Dissertations

The increasing concentration of anthropogenic greenhouse gases in the atmosphere is altering the climate, posing a serious threat to global agriculture and food security. Agriculture and food production contribute a quarter of all GHG emissions produced, so there is a critical need to limit emissions in this area while increasing food production to feed the anticipated 10 billion people by 2050. To address the needs of the future, data-driven solutions are needed to guide decision-making and provide support for actionable climate mitigation and survival strategies. Research efforts must be focused on analyzing problems on multiple scales, identifying new ways to …


Investigation Of Optical And Structural Properties Of Gesn Heterostructures, Oluwatobi Gabriel Olorunsola Dec 2021

Investigation Of Optical And Structural Properties Of Gesn Heterostructures, Oluwatobi Gabriel Olorunsola

Graduate Theses and Dissertations

Silicon (Si)-based optoelectronics have gained traction due to its primed versatility at developing light-based technologies. Si, however, features indirect bandgap characteristics and suffers relegated optical properties compared to its III-V counterparts. III-Vs have also been hybridized to Si platforms but the resulting technologies are expensive and incompatible with standard complementary-metal-oxide-semiconductor processes. Germanium (Ge), on the other hand, have been engineered to behave like direct bandgap material through tensile strain interventions but are well short of attaining extensive wavelength coverage. To create a competitive material that evades these challenges, transitional amounts of Sn can be incorporated into Ge matrix to form …


Engineering Fluorescently Labeled Human Fibroblast Growth Factor One Mutants And Characterizing Their Photophysics Properties Towards Designing Fret Assays, Mamello Mohale Dec 2021

Engineering Fluorescently Labeled Human Fibroblast Growth Factor One Mutants And Characterizing Their Photophysics Properties Towards Designing Fret Assays, Mamello Mohale

Graduate Theses and Dissertations

Human fibroblast growth factor one (hFGF1) belongs to a family of 22 FGF members produced by fibroblast cells. Cell signaling during physiological processes of angiogenesis and wound healing occurs when hFGF1 binds to its receptor (FGFR). However, when heterogenous homeostasis is not maintained, fibroblast cells exhibit excessive proliferation which can lead to a myriad of cancers. smFRET is an ultrasensitive distant dependent (1-10 nm) technique capable of resolving such heterogeneity in structural dynamics and binding affinities (Kd). Therefore, we successfully designed and characterized fluorescently labeled hFGF1 tracers which span the visible light region of the electromagnetic spectrum for use in …


Cover Crop Effects On Infiltration, Aggregate Stability, And Water Retention On Loessial And Alluvial Soils Of The Lower Mississippi River Valley, Shelby G. Lebeau Dec 2021

Cover Crop Effects On Infiltration, Aggregate Stability, And Water Retention On Loessial And Alluvial Soils Of The Lower Mississippi River Valley, Shelby G. Lebeau

Graduate Theses and Dissertations

Cover crops are a widely considered practice to improve soil health in the form of erosion control, organic matter additions, and improving water-holding capacity. Despite the well-documented benefits, little is known about the effect of cover crops on soils in the Lower Mississippi River Valley (LMRV), an area historically dominated by intensive cultivated agriculture, with soils prone to erosion, and unsustainable aquifer withdrawals for irrigation. The main objective of this study was to evaluate the effects of cover crops [with cover crops (CC) and without cover crops (NCC)] on near-surface soil physical/chemical- and infiltration-related properties, aggregate stability, and water retention. …


Does Whispering Improve Children’S Memory? Comparing Auditory Vigilance And Salience Hypotheses, Christina M. Barnes Dec 2021

Does Whispering Improve Children’S Memory? Comparing Auditory Vigilance And Salience Hypotheses, Christina M. Barnes

Graduate Theses and Dissertations

Oral communication is one of the primary tools children use to learn new information and speech registers can deliver additional meaning to the words someone uses. Cirillo’s (2004) vigilance hypothesis states “Whispering can affect the psychobiological state of recipients, and in particular raise their auditory vigilance” (Cirillo, 2004, p. 76). Building on this theory, the current study investigates the role of whispering and children’s memory by examining a whispering vigilance, whispering salience which focused on the changes between normal and whisper registers, and combined vigilance and salience hypotheses to determine if whispering contributes to the recall of information. Using video …


Evaluation Of Nitrous Oxide Emissions From Furrow-Irrigated Rice On A Silt-Loam Soil In Arkansas, Jordan M. Slayden Dec 2021

Evaluation Of Nitrous Oxide Emissions From Furrow-Irrigated Rice On A Silt-Loam Soil In Arkansas, Jordan M. Slayden

Graduate Theses and Dissertations

As the number one rice (Oryza sativa)-producing state in the United States, Arkansas also ranks fourth as the largest user of groundwater. Recently, due to the development of drought- resistant hybrid cultivars, the furrow-irrigated rice production system has become an increasingly popular alternative to traditional flood-irrigated production with respect to conserving groundwater and maintaining yield. However, other environmental parameters, like greenhouse gas emissions, specifically nitrous oxide (N2O), have yet to be evaluated under furrow-irrigated rice. The objectives of this study were to i) evaluate the effects of site position (i.e., up-, mid-, and down-slope) and tillage treatment [i.e., conventional tillage …


Optimization Of Nitrogen Removal Rate In One-Stage Reactor Through Partial Nitrification Anammox Process During Direct Treatment Of Poultry Litter Wastewater, Yiting Xiao Dec 2021

Optimization Of Nitrogen Removal Rate In One-Stage Reactor Through Partial Nitrification Anammox Process During Direct Treatment Of Poultry Litter Wastewater, Yiting Xiao

Graduate Theses and Dissertations

Anammox is an increasingly common process used for the treatment of reject water and even mainstream wastewater due to its low oxygen demand. However, anammox is not commonly utilized in the direct treatment of poultry litter because of the high organic content, which would inhibit the anammox process. Thus, this project is aimed at optimizing the nitrogen removal rate through partial nitrification anammox process (PN/A) to treat synthetic poultry litter wastewater. Nitrogen removal efficiencies will therefore be improved through optimizing the combination of three operating parameters including hydraulic retention time (HRT), dissolved oxygen (DO) concentration, and carbon to nitrogen (C/N) …


Enzymatic Degradation Of Microcystin-Lr By Microcystinase (Mlra), Faisal Alqhtani Dec 2021

Enzymatic Degradation Of Microcystin-Lr By Microcystinase (Mlra), Faisal Alqhtani

Graduate Theses and Dissertations

Microcystin-LR (MC-LR) is affecting the water supply worldwide. Hence, a way to eliminate this toxin is an essential target. In this study, successful cloning of the mlrA gene and producing MlrA enzyme that can degrade the cyclic MC-LR to linearized MC-LR was done. MlrA protein was expressed in Escherichia coli BL-21 (E. coli). Also, enhancing the MlrA yield by adding nickel to LB media was a success in producing more MlrA enzyme from the same volume. Even though the enzyme showed no activity after adding Ni, the enzyme was expressed at a higher yield. Furthermore, it was to investigate adding …


Just Benjamin, Paige R. Murphy Dec 2021

Just Benjamin, Paige R. Murphy

Graduate Theses and Dissertations

This documentary short film is about a now 30-year-old transgender man telling his story of growing up queer in a small Arkansas town, from being outed as a lesbian in high school, to ultimately being accepted as a trans man by members of his military and biological families. Benjamin “Benji” Davis grew up in the small town of Friendship, Arkansas, enlisted in the U.S. Army shortly after high school and served for six years, then came back to Arkansas and primarily lived in Little Rock until he moved to Denver, Colorado this fall. The documentary is structured linearly both with …


Winter Cover Crop Mixes: Effects On Strip-Tilled Plasticulture And No-Till Watermelon Production In Arkansas, Alden Neil Hotz Dec 2021

Winter Cover Crop Mixes: Effects On Strip-Tilled Plasticulture And No-Till Watermelon Production In Arkansas, Alden Neil Hotz

Graduate Theses and Dissertations

Watermelon, Citrullus lanatus (Thunb.) Matsum. & Nakai, producers in Arkansas grow watermelons in either plasticulture or bare-ground systems. Both systems can benefit from the use of winter cover crops for weed control and to supply nitrogen (N) to the watermelon crop. Currently, the use of cover crops in watermelon production in AR is mostly limited to either cereal rye (Secale cereale L.) or winter wheat (Triticum aestivum L). The objective of this research is to evaluate the potential benefits of growing a mix of a legume and grass cover crops before watermelon production in both a strip-till plasticulture and a …


An Assessment Of The Neurovascular Structures Of The Trigeminal Nerve And Their Relationship To Diet In Primates, Caitlin Yoakum Dec 2021

An Assessment Of The Neurovascular Structures Of The Trigeminal Nerve And Their Relationship To Diet In Primates, Caitlin Yoakum

Graduate Theses and Dissertations

The inferior alveolar nerve (IAN) enters the mandible via the mental foramen, supplies nervous sensation to the mandibular teeth as it travels through the mandibular canal, and exits the mandibular foramen to send information to the brain to maintain chewing cycles and protect the teeth from damage. Although bony canals and foramina have been shown to form around soft-tissue structures, there are some examples (e.g., the hypoglossal nerve/canal) where the nervous structures do not comprise most of the canal/foramina space. It is important to know the size of nerves because it has been established that larger nerves convey more information …


Deciphering Chemomechanical Couplings In Proteins Using Microsecond-Level Molecular Dynamics Simulations, Vivek Govind Kumar Dec 2021

Deciphering Chemomechanical Couplings In Proteins Using Microsecond-Level Molecular Dynamics Simulations, Vivek Govind Kumar

Graduate Theses and Dissertations

All-atom molecular dynamics (MD) simulations combine the high temporal resolution of experimental methods like smFRET and spatial resolution of methods like x-ray crystallography, to provide a detailed dynamic picture of biomolecular processes. Here, microsecond-level atomistic MD simulations have been used to characterize chemomechanical couplings in human fibroblast growth factor 1 (hFGF1) and the spike proteins of SARS CoV-1 and SARS-CoV-2. hFGF1 is a globular signaling protein that is involved in several physiological processes ranging from cell proliferation to wound healing. Experimental studies have previously described the low proteolytic and thermal stability of hFGF1, in addition to the stabilizing role of …


Incorporation Of Zinc In Pre-Alloyed Cuin[Zn]S2/Zns Quantum Dots, Jean Carlos Morales Orocu Dec 2021

Incorporation Of Zinc In Pre-Alloyed Cuin[Zn]S2/Zns Quantum Dots, Jean Carlos Morales Orocu

Graduate Theses and Dissertations

Since the early 2000s heavy-metal-free quantum dots (QDs) such as CuInS2/ZnS have attempted to replace CdSe, their heavy-metal-containing counterparts. CuInS2/ZnS is synthesized in a two-step process that involves the fabrication of CuInS2 (CIS) nanocrystals (NCs) followed by the addition of zinc precursors. Instead of the usual core/shell architecture often exhibited by binary QDs, coating CIS QDs results in alloyed and/or partially alloyed cation-exchange (CATEX) QDs. The effect that zinc has on the properties of CIS NCs was studied by incorporating zinc during the first step of the synthesis. Different In:Cu:Zn ratios were employed in this study, maintaining a constant 4:1 …