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Paleoseismological Study Of The Active Faults Of Northern Cyprus, Hasan Elmaci, Şule Gürboğa, Seli̇m Özalp, Hasret Ozan Avci, Hakan Aydoğan, Ayhan Yavuzoğlu, Ali̇ Atalay Yüce, Meryem Kara, Ahmet Rasi̇mcan Öztürker
Paleoseismological Study Of The Active Faults Of Northern Cyprus, Hasan Elmaci, Şule Gürboğa, Seli̇m Özalp, Hasret Ozan Avci, Hakan Aydoğan, Ayhan Yavuzoğlu, Ali̇ Atalay Yüce, Meryem Kara, Ahmet Rasi̇mcan Öztürker
Turkish Journal of Earth Sciences
The tectonic framework of Northern Cyprus is presented in this study based on integrated fieldwork and paleoseismology. We identified multiple fault systems including the 214-km Dardere (Ovgos) Fault Zone (with seven segments), the Haspolat Transfer Fault, Mersinlik Fault, Yamaçköy Fault Zone, Boğazköy Fault, Alsancak Fault, and Geçitköy-Koruçam Fault Zone. Eleven paleoseismological trenches were excavated, with six yielding reliable results in terms of dating and stratigraphy. The results indicate recurrence intervals exceeding ~2500 years across different fault segments. The Dardere (Ovgos) Fault Zone shows the potential to generate earthquakes of up to Mw 7.80 with evidence of Holocene activity. The Haspolat …
Integrated Edge Detection Of Gravity Data And Seismicity Approach For Mapping Potential Faults In The Bolu Region, Hazel Deni̇z Toktay, Burçi̇n Di̇dem Tamtaş
Integrated Edge Detection Of Gravity Data And Seismicity Approach For Mapping Potential Faults In The Bolu Region, Hazel Deni̇z Toktay, Burçi̇n Di̇dem Tamtaş
Turkish Journal of Earth Sciences
The Bolu region, situated along the western–central segment of the North Anatolian Fault Zone (NAFZ), is characterized by a complex fault architecture in which multiple overlapping strike-slip segments and associated subsurface structures accommodate active crustal deformation. Although the principal fault strands of the NAFZ have been well mapped, several clusters of seismicity are observed in areas without clear surface fault expression, indicating the presence of subsurface or poorly expressed fault zones. In this study, we integrated edge detection methods with a seismicity approach to delineate active and buried structural features across the Bolu region. Bouguer gravity anomalies derived from the …
The Harmancık “Purple Jade”: A Unique Blueschist-Facies Metatrachyte With Significant Geoarchaeological Value, Gülteki̇n Topuz, Aral I. Okay, Constantinos Mavrogonatos, Osman Candan, Michael Brandl, Onur Bamyaci, Serap Ala Çeli̇k, Frederik Vingaard, Warren Thompson, Peter Christian Toft, Benjamin Dominguez Heredia, Tonny Bernt Thomsen, Lasse Vilien Sørensen
The Harmancık “Purple Jade”: A Unique Blueschist-Facies Metatrachyte With Significant Geoarchaeological Value, Gülteki̇n Topuz, Aral I. Okay, Constantinos Mavrogonatos, Osman Candan, Michael Brandl, Onur Bamyaci, Serap Ala Çeli̇k, Frederik Vingaard, Warren Thompson, Peter Christian Toft, Benjamin Dominguez Heredia, Tonny Bernt Thomsen, Lasse Vilien Sørensen
Turkish Journal of Earth Sciences
The so-called Harmancık “purple jade” from the Bursa region of northwestern Türkiye has attracted attention as a gemstone; however, its geological characteristics and provenance have long remained uncertain. This short communication presents new field observations along with mineralogical and petrological data concerning the provenance, metamorphic evolution, and geoarchaeological relevance of this unique rock type. The rock occurs as loose boulders scattered across cultivated fields in the villages of Akpınar, Kocapınar, and Gedikören, where it was previously interpreted either as part of Neogene sedimentary successions or as a high-pressure metamorphic rock affected by contact metamorphism. Our detailed mapping and field observations …
Efficient Edge Implementation Of Midasnet For Real-Time Depth Estimation In Indoor Robotics, Muhammed Yasi̇n Adiyaman, İsmai̇l Fai̇k Başkaya
Efficient Edge Implementation Of Midasnet For Real-Time Depth Estimation In Indoor Robotics, Muhammed Yasi̇n Adiyaman, İsmai̇l Fai̇k Başkaya
Turkish Journal of Electrical Engineering and Computer Sciences
Real-time depth estimation is crucial in many vision-related tasks, including autonomous driving, 3D reconstruction, robotics, and simultaneous localization and mapping. In recent years, many methods have been proposed to solve depth maps from images by utilizing different modality setups like monocular vision, binocular vision, or sensor fusion. However, for real-time deployment on edge devices, complex methods are not suitable due to latency constraints and limited computation capacity. For edge implementation, models should be simple, minimal in size, and hardware-friendly. Considering these factors, we implemented MiDaSNet, which works on the simplest setup of monocular vision and utilizes hardware-friendly convolutional neural network-based …
Unveiling The Diversity Within Salvia Caespitosa Sensu Lato (Lamiaceae): Three New “Hidden” Endemic Species From Türkiye, Ferhat Celep, Musa Doğan, Gali̇p Akaydin, Ahmet Kahraman, Ersi̇n Karabacak, Ömer Çeçen, Meti̇n Armağan, Chun-Lei Xiang, Bryan T. Drew
Unveiling The Diversity Within Salvia Caespitosa Sensu Lato (Lamiaceae): Three New “Hidden” Endemic Species From Türkiye, Ferhat Celep, Musa Doğan, Gali̇p Akaydin, Ahmet Kahraman, Ersi̇n Karabacak, Ömer Çeçen, Meti̇n Armağan, Chun-Lei Xiang, Bryan T. Drew
Turkish Journal of Botany
Documenting species, particularly those that are threatened or endangered, is fundamental to biodiversity conservation. However, many taxa remain scientifically unrecognized, being either undiscovered or unpublished. While some plants can be easily recognized as new species, other identifications are obscured by morphological, taxonomic, and nomenclatural complexity. Detecting cryptic or “hidden” species is therefore essential to understanding biodiversity and plant evolution. Our revisionary studies on Salvia demonstrate that the morphologically complex Salvia caespitosa is not a single species but instead comprises at least four distinct species, three with narrow distributions. This conclusion is supported by integrative evidence from extensive field studies, herbarium …
Evolutionary Neural Architecture Search: A Survey, Ferda Nur Özçeli̇k, Mehmet Önder Efe
Evolutionary Neural Architecture Search: A Survey, Ferda Nur Özçeli̇k, Mehmet Önder Efe
Turkish Journal of Electrical Engineering and Computer Sciences
Deep Neural Networks (DNNs) have achieved remarkable success across diverse machine learning applications, yet designing effective architectures remains a laborious, expert-driven process. Neural Architecture Search (NAS) was introduced to automate this process, with Evolutionary NAS (ENAS) emerging as one of the most effective and widely adopted NAS paradigms. This survey provides a comprehensive and systematic review of 164 ENAS studies published between 2020 and 2024, categorized according to the specific evolutionary algorithm employed as the search strategy. Unlike prior surveys—which either treat evolutionary methods at a high level or focus on general NAS pipelines—this study is, to the best of …
A Holistic Approach For Workforce Scheduling And Routing, Kerem Can Manalp, Ansel Kaplan Erol, Kutluhan Erol, Cem Evrendi̇lek
A Holistic Approach For Workforce Scheduling And Routing, Kerem Can Manalp, Ansel Kaplan Erol, Kutluhan Erol, Cem Evrendi̇lek
Turkish Journal of Electrical Engineering and Computer Sciences
The workforce scheduling and routing problem (WSRP) involves assigning tasks across multiple locations while accounting for varying travel times, service durations, time windows, and skill requirements in a wide range of industries, from healthcare to telecommunications. This paper presents a mixed-integer programming model for the WSRP that balances the trade-off between cost and customer satisfaction using a score-generation function and subsequently evaluates the trade-off between solution quality and computation time for several algorithms on well-known datasets. We demonstrate that our model effectively balances cost, service-level agreement satisfaction, and task priorities while providing high-quality solutions in a timely manner. Observing that …
Cnkg: Harnessing Large Language Models For Cognitive Neuroscience Knowledge Graph Construction, Ali Sarabadani, Kheirollah Rahsepar Fard, Hamid Dalvand
Cnkg: Harnessing Large Language Models For Cognitive Neuroscience Knowledge Graph Construction, Ali Sarabadani, Kheirollah Rahsepar Fard, Hamid Dalvand
Turkish Journal of Electrical Engineering and Computer Sciences
Textual resources are among the most valuable sources of information in cognitive neuroscience (CN) for understanding and investigating brain activity and cognitive processes. Extracting and constructing knowledge graphs (KGs) from these texts can facilitate medical research by providing deeper insights into neurological diseases and brain function. In recent years, the use of large language models (LLMs) in natural language processing (NLP) has become increasingly widespread, significantly enhancing the extraction of meaningful information from large volumes of text. This study proposes a novel approach for constructing and evaluating a specialized knowledge graph, termed the cognitive neuroscience knowledge graph (CNKG), from scientific …
Dual-Stream Bilstm Framework With Histogram-Based Shape Features For Household Load Forecasting, Chang Xu, Wong Jee Keen Raymond, Hazlee Azil Illias, Hazlie Mokhlis
Dual-Stream Bilstm Framework With Histogram-Based Shape Features For Household Load Forecasting, Chang Xu, Wong Jee Keen Raymond, Hazlee Azil Illias, Hazlie Mokhlis
Turkish Journal of Electrical Engineering and Computer Sciences
This study proposes a dual-stream BiLSTM framework for household load forecasting that integrates time-series dynamics with histogram-based daily shape features. Unlike existing models relying on weather or external data, the proposed method extracts intrinsic load-shape information directly from normalized daily curves. A multihead attention module fuses temporal and shape representations, enabling adaptive weighting of informative dimensions. Experiments on three real-world datasets show consistent improvements over the baseline BiLSTM, with up to 30.12%, 24.27%, and 19.03% reductions in MAE, RMSE, and SMAPE, respectively. The results highlight the framework’s robustness and efficiency for fine-grained load forecasting without external inputs.
Robust Variable-Gain Backstepping Control For Nonlinear Systems With Real-Time Application To Induction Motor, Fadi Alyoussef, İbrahi̇m Kaya, Ahmad Akrad, Rabia Sehab, Cristina Morel
Robust Variable-Gain Backstepping Control For Nonlinear Systems With Real-Time Application To Induction Motor, Fadi Alyoussef, İbrahi̇m Kaya, Ahmad Akrad, Rabia Sehab, Cristina Morel
Turkish Journal of Electrical Engineering and Computer Sciences
This study proposes a novel variable-gain mechanism with a minimal number of tuning parameters to enhance the performance of conventional backstepping controllers for nonlinear systems while avoiding singularity and peaking phenomena. The proposed approach is simple, computationally efficient, and well suited for real-time implementation without imposing a significant computational burden. Its effectiveness is validated through real-time experiments conducted using a dSPACE DS1104 controller board and a 7.5-kW induction motor (IM). Simulation results demonstrate that the proposed controller outperforms the conventional backstepping controller. Robustness analyses under variations in stator resistance, load inertia, and viscous friction coefficient reveal substantial reductions in the …
Enhancement Of Nested Hexagonal Fractal Antenna Performance For Multiband Wireless Applications, Abdelbasset Azzouz, Rachid Bouhmidi, Mohammed Chetioui, Redouane Berber, Ahmed Jamal Abdullah Al-Gburi
Enhancement Of Nested Hexagonal Fractal Antenna Performance For Multiband Wireless Applications, Abdelbasset Azzouz, Rachid Bouhmidi, Mohammed Chetioui, Redouane Berber, Ahmed Jamal Abdullah Al-Gburi
Turkish Journal of Electrical Engineering and Computer Sciences
This work focuses on developing a compact multiband antenna to meet the growing demand for versatile and efficient radiating structures in modern wireless communication systems. A hexagonal fractal antenna is proposed and analyzed for applications such as mobile communications, WLAN, industrial, scientific and medical (ISM) bands, Wi-Fi, satellite links, radar systems, and military communications. By iteratively modifying the antenna geometry with larger hexagonal elements, the design enhances multiband behavior and improves key performance parameters including gain, S11, voltage standing wave ratio (VSWR), and radiation characteristics. The antenna is modeled using high-frequency structure simulator (HFSS)® and fabricated on a low-cost 0.8 …
Parameter Optimization Of Dual-Qsg Based Pll For Real-Time Control Of Grid-Connected Ev Chargers, Gaurav Yadav, Sudhanshu Mittal, Vineet Kumar, Sombir Kundu, Praveen Bansal
Parameter Optimization Of Dual-Qsg Based Pll For Real-Time Control Of Grid-Connected Ev Chargers, Gaurav Yadav, Sudhanshu Mittal, Vineet Kumar, Sombir Kundu, Praveen Bansal
Turkish Journal of Electrical Engineering and Computer Sciences
Dual-Quadrature Signal Generator (D-QSG) based Phase lock loop (PLL) has been recently proposed to handle the nonideal grid voltage conditions. However, selecting the parameter for D-QSG based controller has been a great challenge, especially for higher-order systems. Inappropriate parameter selection tends to increase settling time both in terms of amplitude as well as harmonics attenuation. Hence, in the proposed work, the main focus is on parameter selection to achieve a faster response. Here, a fourth-order Quasi-Synchronous Generator has been realized by cascading the two nonidentical second order generalized integrators (NISOGIs). Furthermore, the parameters of both the NISOGIs are selected in …
Erratum To “Sgsc-Kko-Lstm: A Deeplearning Classifier Model For Smart Grid” [Turkish Journal Of Electrical Engineering & Computer Sciences 34 (2) 2026 185-213], Samaniba Imchen, Dushmanta Kumar Das
Erratum To “Sgsc-Kko-Lstm: A Deeplearning Classifier Model For Smart Grid” [Turkish Journal Of Electrical Engineering & Computer Sciences 34 (2) 2026 185-213], Samaniba Imchen, Dushmanta Kumar Das
Turkish Journal of Electrical Engineering and Computer Sciences
The first and second authors were incorrectly ordered in the article PDF due to a typesetting error. To rectify this oversight and ensure the accuracy of the published work, the author order have been corrected as follows: 1. Samaniba Imchen – First Author 2. Dushmanta Kumar Das – Second Author
A link to the original article can be found at: https://doi.org/10.55730/1300-0632.4170
Influence Of A New Nanoensemble Of Graphene Oxide And Indole-3-Acetic Acid On The Morphophysiological, Biochemical, And Ultrastructural Characteristics Of Upland Cotton (Gossypium Hirsutum L.), Nurlan Amrahov, Ulviyya Hasanova, Aliyeva Gunel, Aghazada Goncha, Fuad Rzayev, Eldar Gasimov, Aliyeva Solmaz, Lala Gahramanli, Elvin Ibrahimli, Ruhangiz Mammadova, Zarema Gakhramanova, Cem Bayram, Goncha Eyvazova, Si̇bel Hasanova, Ziyaddin Mammadov
Influence Of A New Nanoensemble Of Graphene Oxide And Indole-3-Acetic Acid On The Morphophysiological, Biochemical, And Ultrastructural Characteristics Of Upland Cotton (Gossypium Hirsutum L.), Nurlan Amrahov, Ulviyya Hasanova, Aliyeva Gunel, Aghazada Goncha, Fuad Rzayev, Eldar Gasimov, Aliyeva Solmaz, Lala Gahramanli, Elvin Ibrahimli, Ruhangiz Mammadova, Zarema Gakhramanova, Cem Bayram, Goncha Eyvazova, Si̇bel Hasanova, Ziyaddin Mammadov
Turkish Journal of Botany
The exogenous application of phytohormones plays a crucial role in the activation of adaptive mechanisms in plants under both normal and stress conditions. Therefore, the present study investigates the synthesis, characterization, and application of nanoensembles based on indole-3-acetic acid (IAA) and graphene oxide (GO) nanolayers. The surface of GO synthesized by the modified Hummer method was noncovalently functionalized with IAA molecules. The structure and morphological properties of the prepared materials were analyzed by Fourier transform infrared spectroscopy, X-ray diffraction, UV-Vis spectroscopy, and transmission electron microscopy. The IAA and IAA+GO nanoensemble enhanced the morphological parameters, lateral root formation, catalase and peroxidase …
Effects Of Calcium And Magnesium Ions On Wheat (Triticum Aestivum) Chromosome Structure Visualized Using Light And Scanning ElecTron Microscopes, Andi Salamah, Fitri Amalia Nurchasanah, Vycka Fikriyani Fairuz, Astari Dwiranti
Effects Of Calcium And Magnesium Ions On Wheat (Triticum Aestivum) Chromosome Structure Visualized Using Light And Scanning ElecTron Microscopes, Andi Salamah, Fitri Amalia Nurchasanah, Vycka Fikriyani Fairuz, Astari Dwiranti
Turkish Journal of Botany
Divalent cations, particularly calcium (Ca2+) and magnesium (Mg2+), are essential for maintaining chromosomal architecture, yet their roles in plants remain poorly characterized. This study investigated the effects of Ca2+ and Mg2+ on the chromosomal structure of wheat (Triticum aestivum, 2n = 6x = 42), a widely used model in plant cytogenetics. Root-tip chromosomes were isolated enzymatically and treated with BAPTA (a Ca2+-specific chelator), EDTA (a broad cation chelator), and buffer solutions containing either 5 mM Mg2+ (XBE5) or no Mg2+ (XBE). Chromosomes were stained with aceto-orcein for light microscopy and processed for scanning electron microscopy (SEM). Microscopic observations revealed that …
A Revenue-Driven Approach For Enhanced Task Utilization In Vehicular Cloud Computing, Ashish Singh Saluja, Satyabrata Das, Sanjib Kumar Nayak, Sohan Kumar Pande
A Revenue-Driven Approach For Enhanced Task Utilization In Vehicular Cloud Computing, Ashish Singh Saluja, Satyabrata Das, Sanjib Kumar Nayak, Sohan Kumar Pande
Turkish Journal of Electrical Engineering and Computer Sciences
Vehicular networks support intelligent transportation through vehicle-to-roadside Units (V2R) and vehicle-to-vehicle (V2V) communication but face challenges from dynamic topologies, limited RSU coverage, and bandwidth scarcity, which impact service delivery and revenue. RDA-ITU addresses these challenges by integrating V2R and V2V paradigms to maximize RSU revenue, enhance service availability, and improve system efficiency. It dynamically allocates services based on real-time network conditions and vehicle mobility, leveraging V2V relays to optimize both RSU-direct and cooperative communication. Through extensive simulations, RDA-ITU significantly outperforms four baselines: RBSM, VVMM-U, VVMM-LW, and VVMM-MA. It achieves 81.1% higher total revenue, 154.8% more completed requests, and 103.6% higher …
Class-Aligned Frequency Augmentation Using Variational Mode Decomposition Forfew-Shot Image Classification, Leila Boussaad
Class-Aligned Frequency Augmentation Using Variational Mode Decomposition Forfew-Shot Image Classification, Leila Boussaad
Turkish Journal of Electrical Engineering and Computer Sciences
Few-shot image classification benefits from data augmentation, yet most existing methods operate in pixel space with limited control over spectral semantics. We introduce a lightweight, frequency-guided augmentation strategy based on Variational Mode Decomposition (VMD). Our method constructs an offline, per-class ModeBank by decomposing downsampled luminance patches and retaining midband modes that encode class-specific texture patterns. During episodic training, VMD is never executed online: instead, for each support image, a same-class midband mode is selected and blended using PSNR-targeted scaling with a luminance energy cap, ensuring perceptual consistency. The augmentation is fast, reproducible, class-consistent, and integrates seamlessly into standard metric-based pipelines …
Scalefusion: Hierarchical Feature Aggregation For Unified Multiscale Object Detection, Ayşenur Yaylaci, Berru Kaya, Mehmet Kiliçarslan
Scalefusion: Hierarchical Feature Aggregation For Unified Multiscale Object Detection, Ayşenur Yaylaci, Berru Kaya, Mehmet Kiliçarslan
Turkish Journal of Electrical Engineering and Computer Sciences
Detecting objects across a wide range of scales, particularly small ones, remains a significant challenge in computer vision. Existing methods often improve small object detection at the cost of performance on larger objects or introduce significant computational overhead through external techniques like image slicing. This paper introduces ScaleFusion, a novel, unified, end-to-end object detection architecture designed to provide robust performance across all scales within a single model. The core of our approach is a hierarchical feature aggregation strategy structured like a tree. ScaleFusion processes an image by running a shared backbone network only on fine-grained patches at the lowest level …
Cover And Content
Turkish Journal of Electrical Engineering and Computer Sciences
No abstract provided.
Swindeitvit: A Soft Voting Vision Transformer Ensemble For Accurate And Explainable Solar Panel Fault Detection, Mahe Zabin
Turkish Journal of Electrical Engineering and Computer Sciences
Solar panels are becoming very essential in providing sustainable energy but they are usually affected by defects on the surface like dust, snow, bird droppings, physical damages and electrical faults which interfere with their performance. These faults must be identified accurately and in a timely manner to enhance energy efficiency, lower the maintenance cost, and supplement the traditional manual methods of inspection which are labor-intensive, time-consuming and subject to human errors in judgment. The most common methods, such as traditional CNNs and hybrid architectures tend to be less accurate, less explainable and cannot be properly evaluated to be deployed in …
Production, Purification, And Crystallization Of The Recombinant Her2 Tyrosine Kinase Domain (Her2-Tkd), Edanur Topalan, Hali̇li̇brahi̇m Çi̇ftçi̇, Hasan Demi̇rci̇
Production, Purification, And Crystallization Of The Recombinant Her2 Tyrosine Kinase Domain (Her2-Tkd), Edanur Topalan, Hali̇li̇brahi̇m Çi̇ftçi̇, Hasan Demi̇rci̇
Turkish Journal of Chemistry
The human epidermal growth factor receptor 2 tyrosine kinase domain (HER2-TKD) is an important therapeutic target in oncology. In this study, we developed a practical and cost-effective approach for producing soluble recombinant HER2-TKD in Escherichia coli as a basis for structure-based drug discovery. The gene encoding HER2-TKD was cloned into a pET28a(+) expression vector and expressed in E. coli. Since the protein was initially obtained as inclusion bodies, solubilization with 1.5% sarcosyl was applied to recover it in soluble form. The purified protein was obtained through size-exclusion chromatography, followed by tag removal using reverse affinity purification. Crystallization trials were performed …
Quantum Engineered Mxene–Graphene–Plasmonic Nanocomposites For Next-Generation Transparent And Flexible Space Photovoltaics, Arash Vaghef-Koodehi
Quantum Engineered Mxene–Graphene–Plasmonic Nanocomposites For Next-Generation Transparent And Flexible Space Photovoltaics, Arash Vaghef-Koodehi
Turkish Journal of Chemistry
This study presents a quantum‑engineered, tricomponent heterostructure comprising Ti3C2T MXene quantum dots (2–5 nm), single‑layer graphene, and plasmonic gold nanoparticles (15 ± 3 nm) uniformly embedded within electrospun polyacrylonitrile nanofibers. This integrated architecture demonstrates a remarkable combination of optical transparency (89.3 ± 1.1%) and power conversion efficiency (19.7 ± 0.4%) under AM0 solar illumination, representing 340% enhancement over state‑of‑the‑art transparent photovoltaic devices. A multiscale computational framework, bridging density functional theory and device‑level drift-diffusion modeling, identifies optimal interlayer spacing (3.4 ± 0.1 Å) as the key to achieving 89.3% charge‑transfer efficiency. Concurrently, localized surface plasmon resonances at 532 nm generate electromagnetic …
Efficient Heterogeneous Photo-Fenton Degradation Of Azo Dyes Using The Nanocomposite Mgfe2o4/Mos2, Zahra Zeinali, Leila Ershadi Afshar, Naz Chaibakhsh, Farnaz Isapour
Efficient Heterogeneous Photo-Fenton Degradation Of Azo Dyes Using The Nanocomposite Mgfe2o4/Mos2, Zahra Zeinali, Leila Ershadi Afshar, Naz Chaibakhsh, Farnaz Isapour
Turkish Journal of Chemistry
In the present work, a facile hydrothermal route was employed to synthesize the nanocomposite MgFe2O4/MoS2, which acted as a heterogeneous photo-Fenton catalyst for the degradation of a synthetic diazo dye, Acid Blue 113 (AB113). The nanocatalyst produced underwent analysis using multiple characterization techniques. The parameters influencing the oxidative reaction were statistically modeled and optimized using response surface methodology. Optimal degradation efficiency for AB113 (94.92%) was attained at pH 8.79 using 10 mg of MgFe2O4/MoS2 nanocatalyst, 1.6 mL of H2O2, and a reaction duration of 27 min. The synergistic effect resulting from the formation of electron-hole pairs renders the combined photocatalysis …
Electrochemical Biosensing Of Alpha-Fetoprotein Based On Carboxylated Multi-Walled Nanotube-Polyazur A (In Des)-Gold Nanoparticles, Merve Yilmaz Çilçar, Meli̇ke Bi̇lgi̇ Kamaç
Electrochemical Biosensing Of Alpha-Fetoprotein Based On Carboxylated Multi-Walled Nanotube-Polyazur A (In Des)-Gold Nanoparticles, Merve Yilmaz Çilçar, Meli̇ke Bi̇lgi̇ Kamaç
Turkish Journal of Chemistry
AFP, a cancer biomarker, is monitored during fetal development and in the serum of pregnant women. Sensitive and rapid monitoring of AFP is crucial for effective management. In this study, screen-printed carbon electrodes (SPCEs) modified with multi-walled carbon nanotubes (MWCNT-COOH), polyAzur A (PAA), which was prepared in a deep eutectic solution (DES), and gold nanoparticles (AuNP) were fabricated. AFP biosensors were developed for practical, sensitive, low-cost, and rapid detection of AFP. Optimizations of nanostructures (MWCNT-COOH, AuNP) and polymers (PAADES) were performed. The MWCNT-COOH, PAADES, and AuNP-modified SPCEs were characterized by FE-SEM-EDX, FTIR, and XRD techniques. The amounts of 6-MOH, APTES, …
[H]-Mediated Enhancement Of The Fenton Reaction Over A Pd/Uio-66(Zr)-F4 Catalyst, Juanhong Li, Suqin Wang, Xin Liu, Feng Liu
[H]-Mediated Enhancement Of The Fenton Reaction Over A Pd/Uio-66(Zr)-F4 Catalyst, Juanhong Li, Suqin Wang, Xin Liu, Feng Liu
Turkish Journal of Chemistry
A [H]-accelerated catalytic Fenton system was developed using Pd/UiO-66(Zr)-F4 as the catalyst. This system enabled the regeneration of Fe²⁺ and facilitated the continuous generation of both ·OH and 1O2 through [H]-mediated electron transfer at ambient temperature and pressure. Under the conditions of 0.2 g L−1 catalyst (Pd loading 0.516 wt%), 25 μM Fe2+, 60 mL min−1 H2 flow (as the [H] source), 20 mM H2O2, and pH 3, approximately 89% of carbamazepine (initial concentration 20 mg L−1) was degraded within 3 h using trace iron. However, the catalytic activity of Pd/UiO-66(Zr)-F4 gradually declined from 89% to 53% over six reaction …
Alcohol-Based Microextraction Of Rhodamine 6g From Soft Drink, Food, And Cosmetic Samples, Mustafa Soylak, Esra Yamaner, Özgür Özalp
Alcohol-Based Microextraction Of Rhodamine 6g From Soft Drink, Food, And Cosmetic Samples, Mustafa Soylak, Esra Yamaner, Özgür Özalp
Turkish Journal of Chemistry
By using alcohol-based solvent extraction without tetrahydrofuran, a liquid–liquid microextraction technique was developed for the separation–enrichment of trace levels of Rhodamine 6G from complex matrices, including soft drinks, food, cosmetics, hygiene products, and natural waters. Numerous experimental parameters were tuned, including pH, alcohol volume, ultrasonication time, and sample and eluent volume. The enrichment factor (EF), limit of detection (LOD), and limit of quantification (LOQ) were used to assess the analytical performance of the suggested approach. The LOD and LOQ were 6.92 ng mL−1 and 23 ng mL−1, respectively, and the EF was 14. Through the use of the standard addition …
A Nonenzymatic Electrochemical Glucose Sensor Depending On A Ninps/Co3o4/Functionalized Graphene Oxide-Modified Working Electrode, Sümeyra Pekmez, Muhammet Güler
A Nonenzymatic Electrochemical Glucose Sensor Depending On A Ninps/Co3o4/Functionalized Graphene Oxide-Modified Working Electrode, Sümeyra Pekmez, Muhammet Güler
Turkish Journal of Chemistry
In the present research, the aim was to develop a novel electrochemical enzyme-free glucose sensor dependent upon a nickel nanoparticles (NiNPs)/cobalt (II, III) oxide (Co3O4)/carboxylated graphene oxide (GO-COOH)-modified glassy carbon (GC) electrode. The electrocatalytic performance of the electrode was tested using various electrochemical methods such as amperometry and cyclic voltammetry (CV). The NiNPs@Co3O4/GO-COOH/GC electrode showed noticeably superior electrocatalytic behavior for glucose oxidation in 0.1 M NaOH media, ascribed to the good synergistic impact between NiNPs, Co3O4, and GO-COOH. The amperometric response of the NiNPs@Co3O4/GO-COOH/GC electrode to glucose exhibited two linear determination ranges at +0.55 V potential. The first one was …
Synthesis Of Two Hofmann-Type-Like Clathrates, Characterizations, And Investigation Of Their Structures, Spectroscopic And Theoretical Properties, Zari̇fe Si̇bel Şahi̇n, Zeki̇ Kartal
Synthesis Of Two Hofmann-Type-Like Clathrates, Characterizations, And Investigation Of Their Structures, Spectroscopic And Theoretical Properties, Zari̇fe Si̇bel Şahi̇n, Zeki̇ Kartal
Turkish Journal of Chemistry
This study concerns two Hofmann-type-like clathrates using 4-aminopyridine (4AP) as ligands and the transition metal atoms copper (Cu) and zinc (Zn). These clathrates have the structural features of heteronuclear tetracyanonickelate(II) and contain H2O and 4AP molecules as guest molecules, respectively. These two clathrates were characterized by infrared spectroscopy (IR), elemental analysis, and single crystal X-ray diffraction (SC-XRD) techniques. Based on elemental and spectral data, the structural formulae describing these clathrates were found to be [Cu(II)(4AP)4Ni(μ-CN)2(CN)2]·H2O (1) and [Zn(II)(4AP)4Ni(μ-CN)2(CN)2]·(4AP) (2). In addition, the values of some optical, electronic, and thermochemical properties of the two obtained clathrates calculated with the Gaussian 03 …