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Full-Text Articles in Entire DC Network
Effect Of Row Spacing Under Maize-Soybean Relay Intercropping System On Yield, Competition, And Economic Returns, Muhammad Hayder Bin Khalid, Liang Cui, Ghulam Abbas, Muhammad Ali Raza, Adeel Anwar, Zaheer Ahmed, Abdul Waheed, Amjad Saeed, Waqas Ahmed, Muhammad Jawad Babar, Shakeel Ahmad, Rezwan Tariq, Muhammad Maroof Ajmal, Ali Ahsan Bajwa, Hülya Doğan
Effect Of Row Spacing Under Maize-Soybean Relay Intercropping System On Yield, Competition, And Economic Returns, Muhammad Hayder Bin Khalid, Liang Cui, Ghulam Abbas, Muhammad Ali Raza, Adeel Anwar, Zaheer Ahmed, Abdul Waheed, Amjad Saeed, Waqas Ahmed, Muhammad Jawad Babar, Shakeel Ahmad, Rezwan Tariq, Muhammad Maroof Ajmal, Ali Ahsan Bajwa, Hülya Doğan
Turkish Journal of Agriculture and Forestry
Interrow spacing of intercrop species directly affects yield and competition indices such as land equivalent ratio of intercropping. The objectives of this research were to analyze (i) the maize and soybean yields under different spatial arrangements in maize-soybean relay strip intercropping (MSR) and (ii) the interspecies competition to provide a basis for optimization of rowspacing in MSR. The field trial was conducted in 2011 and 2012 at the Research Farm of the Sichuan Agricultural University in Ya'an to determine the impacts of various interrow planting distances on yield and competition indices in cereal (maize crop)-legume (soybean crop) relay strip intercropping. …
Some Fractional Dirac Systems, Yüksel Yalçinkaya
Some Fractional Dirac Systems, Yüksel Yalçinkaya
Turkish Journal of Mathematics
In this work, including $\alpha\epsilon(0,1)$; we examined the Dirac system in the frame which includes$\ \alpha$ order right and left Reimann-Liouville fractional integrals and derivatives with exponential kernels, and the Dirac system which includes $\alpha$ order right and left Caputo fractional integrals and derivatives with exponential kernels. Furthermore, we have given some definitions and properties for discrete exponential kernels and their associated fractional sums and fractional differences, and we have studied discrete fractional Dirac systems.
Biharmonic Pnmcv Submanifolds In Euclidean 5-Space, Rüya Şen, Nuretti̇n Cenk Turgay
Biharmonic Pnmcv Submanifolds In Euclidean 5-Space, Rüya Şen, Nuretti̇n Cenk Turgay
Turkish Journal of Mathematics
In this article, we study 3-dimensional biconservative and biharmonic submanifolds of $\mathbb{E}^5$ with parallel normalized mean curvature vector (PNMCV). First, we prove that the principal curvartures and principal directions of biconservative PNMCV isometric immersions into $\mathbb{E}^5$ can be determined intrinsically. Then, we complete the proof of Chen's biharmonic conjecture for PNMCV submanifolds of $\mathbb{E}^5$.
An Inverse Problem Of Finding A Time-Dependent Coefficient In A Fractional Diffusion Equation, Durdimurod Durdiev, Dilshod Durdiev
An Inverse Problem Of Finding A Time-Dependent Coefficient In A Fractional Diffusion Equation, Durdimurod Durdiev, Dilshod Durdiev
Turkish Journal of Mathematics
This article is concerned with the study of unique solvability of an inverse coefficient problem of determining the coefficient at the lower term of a fractional diffusion equation. The direct problem is the initial-boundary problem for this equation with usual initial and homogeneous Dirichlet conditions. To determine the unknown coefficient, an overdetermination condition is given as the Neumann condition at the left end of the spatial interval. The theorems of existence and uniqueness of inverse problem solution are obtained. Furthermore, we propose a numerical algorithm based on a finite-difference scheme to accurately compute the inverse problem of simultaneously determining a …
Obituary Prof. Dr. Ercan Özcan, Aral Okay, Demi̇r Altiner, Gyorgy Less
Obituary Prof. Dr. Ercan Özcan, Aral Okay, Demi̇r Altiner, Gyorgy Less
Turkish Journal of Earth Sciences
No abstract provided.
The First Application Of The Luminescence Surface Exposure Dating Method On Active Fault Scarps In The Western Anatolia Extensional Province: The Manisa Fault As An Example, Mustafa Softa, Eren Şahi̇ner, Hasan Sözbi̇li̇r, Joel Qg Spencer, Mehmet Utku, Mehmet Fati̇h Büyüktopcu
The First Application Of The Luminescence Surface Exposure Dating Method On Active Fault Scarps In The Western Anatolia Extensional Province: The Manisa Fault As An Example, Mustafa Softa, Eren Şahi̇ner, Hasan Sözbi̇li̇r, Joel Qg Spencer, Mehmet Utku, Mehmet Fati̇h Büyüktopcu
Turkish Journal of Earth Sciences
While there has been significant research on the dating of paleoearthquakes using methods such as surface cosmogenic dating, and trench-based luminescence or radiocarbon dating, this paper focuses on implementing an alternative surface dating method using a fault scarp-based optically stimulated luminescence (OSL) dating approach. Hence for the first time, we investigated the Pleistocene to Holocene earthquake cycle of the Manisa Fault, one of the dip-slip active faults of the Western Anatolia extensional province, utilizing novel OSL surface exposure techniques. In this technique, OSL bleaching profiles on the fault surface are directly related to the exposure of the fresh fault scarps …
Lithological Mapping Of Ophiolitic Rocks From Southern Part Of The Sivas Basin (Turkey) Using Aster Imagery, Taner Eki̇ci̇
Lithological Mapping Of Ophiolitic Rocks From Southern Part Of The Sivas Basin (Turkey) Using Aster Imagery, Taner Eki̇ci̇
Turkish Journal of Earth Sciences
The east-west extended Sivas Basin in central-eastern Anatolia is a foreland basin that formed after the obduction of the Tethyan ophiolite during the late Cretaceous and is also a north-verging fold-and-thrust belt. The basement rocks of the basin represent mainly sedimentary (Mesozoic platform-type carbonates) and late Cretaceous Divriği ophiolitic complex. As the ophiolitic rocks are affected by intense tectonic processes, field-based mapping studies require long processes and costs. The study tests to reveal the lithological features of the ophiolitic complex outcropping around the Ulaş district of the Sivas Province using remote sensing methods and techniques. Due to arid climatic conditions …
New Geodetic Constraints On The Role Of Faults And Blocks Vs. Distribute Strain In The Nubia-Arabia-Eurasia Zone Of Active Plate Interactions, Semi̇h Ergi̇ntav, Michael Floyd, Demitris Paradissis, Hayrullah Karabulut, Philippe Vernant, Frederic Masson, Ivan Georgiev, Ali̇ Özgün Konca, Uğur Doğan, Robert King, Robert Reilinger
New Geodetic Constraints On The Role Of Faults And Blocks Vs. Distribute Strain In The Nubia-Arabia-Eurasia Zone Of Active Plate Interactions, Semi̇h Ergi̇ntav, Michael Floyd, Demitris Paradissis, Hayrullah Karabulut, Philippe Vernant, Frederic Masson, Ivan Georgiev, Ali̇ Özgün Konca, Uğur Doğan, Robert King, Robert Reilinger
Turkish Journal of Earth Sciences
We present a broad view of present-day motions and deformations derived from uniform processing of GNSS observations within the Nubia-Arabia-Eurasia zone of plate interaction. The new observations we present provide a ~29% increase in the number of velocity determinations, a reduction in average station spacing from ~76 km to ~39 km, and an improvement in velocity uncertainties (for < 1 mm/year), from 180 to 578 sites compared to our prior published solution (Reilinger et al., 2006). We use these new constraints to better evaluate the role of faults and blocks in controlling the character of continental deformation within the zone of plate interactions. Simple elastic block models show that internal deformation of the region occurs in large part on mapped, seismically active fault systems, indicating elastic behavior of the seismogenic crust (above ~15 km). For example, eastern central Anatolia, an area of > ~126,000 km2, bounded by the North and East Anatolian Faults exhibits internal velocity differences of < 0.5 mm/year, indicating strain rates of < ~1.5 nanostrain/year. Geodetically constrained fault slip rates obtained from this simplified approach are comparable to geologic rates, indicating that major faults have controlled the recent geologic evolution of the region (i.e. 5?10 Myr). The pattern of present-day deformation, including increasingly fast motions towards the Hellenic trench, and the roughly simultaneous opening of all the major Mediterranean basins in the early Miocene with the slowing of the Nubia-Eurasia convergence, support conceptual models that foundering and rollback of the subducted Nubian slab beneath the Aegean is the primary mechanism responsible for present-day motion and internal deformation of the Anatolian-Aegean region.
Paleoseismology Of The Ganos Segment; The Western Extend Of The North Anatolian Fault (Turkey), Murat Ersen Aksoy, Mustapha Meghraoui, Matthieu Ferry, Zi̇yadi̇n Çakir, Gülsen Uçarkuş, Taylan Sançar, Mehmet Uğur Altin
Paleoseismology Of The Ganos Segment; The Western Extend Of The North Anatolian Fault (Turkey), Murat Ersen Aksoy, Mustapha Meghraoui, Matthieu Ferry, Zi̇yadi̇n Çakir, Gülsen Uçarkuş, Taylan Sançar, Mehmet Uğur Altin
Turkish Journal of Earth Sciences
The Ganos fault that ruptured on 9 August 1912 (Mw: 7.4) is the westernmost inland segment of the North Anatolian fault (NAF). Here, the Ganos fault is bounded at its two tips with offshore faults segments, in the Sea of Marmara to the east and the Gulf of Saros to the west in the North Aegean Trough. Therefore, the paleoseismology of the 45-km-long inland fault is of importance to the seismic hazard analysis related to offshore active faults and in particular for the seismic gap in the Marmara Region. Earlier studies have established an earthquake chronology for the western and …
Paleoseismology Of The Sürgü And Çardak Faults - Splays Of The Eastern Anatolian Fault Zone, Türkiye, Musa Balkaya, Hüsnü Serdar Akyüz, Süha Özden
Paleoseismology Of The Sürgü And Çardak Faults - Splays Of The Eastern Anatolian Fault Zone, Türkiye, Musa Balkaya, Hüsnü Serdar Akyüz, Süha Özden
Turkish Journal of Earth Sciences
The sinistral East Anatolian Fault Zone (EAFZ) and the dextral North Anatolian Fault Zone (NAFZ) are two important strike-slip faults that delimit the boundaries of the Anatolian plate. The north-south directed compressional forces in eastern Türkiye trigger the westward escape of the Anatolian plate along these prominent structures. This study aims to reveal the earthquake history of the Sürgü and Çardak faults, which are important fault segments that splay from the EAFZ. In this context, overall, four paleoseismologic trenches were dug, two trenches on the Sürgü Fault and two trenches on the Çardak Fault. Along the Sürgü Fault, at least …
Land Subsidence Due To Natural Gas Extraction In The Thrace Basin (Nw Turkey) And Its Influence On The North Anatolian Fault Under The Marmara Sea, Tohid Nozadkhalil, Zi̇yadi̇n Çakir, Semi̇h Ergi̇ntav, Uğur Doğan, Thomas R. Walter
Land Subsidence Due To Natural Gas Extraction In The Thrace Basin (Nw Turkey) And Its Influence On The North Anatolian Fault Under The Marmara Sea, Tohid Nozadkhalil, Zi̇yadi̇n Çakir, Semi̇h Ergi̇ntav, Uğur Doğan, Thomas R. Walter
Turkish Journal of Earth Sciences
We map surface deformation in the Thrace region of Turkey using the Sentinel-1 Synthetic Aperture Radar (SAR) data. Interferometric Synthetic Aperture Radar (InSAR) time series analysis of the SAR data acquired between 2014 and 2020 on ascending and descending orbits reveals large-scale subsidence (~110 × 60 km) with rates reaching up to 10 ± 1.5 mm/yr. We relate this deformation to natural gas reservoir operations, such as gas exploitation and extraction activities that have been taking place in the region for decades, an inference being supported by the strong correlation between the InSAR time series and the variation in natural …
Alkyd Resins Produced From Bio-Based Resources For More Sustainable And Environmentally Friendly Coating Applications, Cemi̇l Dizman, Eli̇f Cerrahoğlu Kaçakgi̇l
Alkyd Resins Produced From Bio-Based Resources For More Sustainable And Environmentally Friendly Coating Applications, Cemi̇l Dizman, Eli̇f Cerrahoğlu Kaçakgi̇l
Turkish Journal of Chemistry
Recently, due to the depletion of natural resources and raising environmental and economic concerns regarding petroleum derivatives, the creation of novel ecologically friendly and sustainable materials made from bio-based and renewable resources is gaining popularity. Alkyd resins are synthetic resins in which both renewable (fatty acids, glycerol, oil, etc.) and nonrenewable (maleic anhydride, pentaerythritol, phthalic anhydride, etc.) raw materials are used in their production. Due to their superior performance (good aging, greater weather resistance and high heat resistance, outstanding gloss, etc.) over other resins, easy application, low cost, and varied use, in the coating and paint industries, they are commonly …
Effect Of Okra Bast Fillers On Biodegradation Properties Of Poly(Vinyl Alcohol) Composites, Gazi Md Arifuzzaman Khan, Nazi̇re Deni̇z Yilmaz
Effect Of Okra Bast Fillers On Biodegradation Properties Of Poly(Vinyl Alcohol) Composites, Gazi Md Arifuzzaman Khan, Nazi̇re Deni̇z Yilmaz
Turkish Journal of Chemistry
This paper focuses on the effect of okra bast fillers on biodegradation of poly(vinyl alcohol) composites. Fibers were obtained from okra plant stems via biological degumming and subjected to different chemical treatments such as scouring, alkalizing, maleic anhydride treatment, and vinyl acetate grafting. The fibers were ground and PVA-okra bast filler composites were produced at 20 wt% fiber load via the solution casting method. The obtained composites were tested in terms of mechanical properties and exposed to biodegradation in soil. Effects of okra bast filler addition and chemical treatments on changes in mass, breaking strength, elasticity modulus, and breaking elongation …
Effect Of Carbon Fiber Reinforcement On Dimensional Variations Of 3d Printed Polyamide-6 Composites: A Simulation Study, Ans Al Rashid, Hamid Ikram, Muammer Koç
Effect Of Carbon Fiber Reinforcement On Dimensional Variations Of 3d Printed Polyamide-6 Composites: A Simulation Study, Ans Al Rashid, Hamid Ikram, Muammer Koç
Turkish Journal of Chemistry
Due to material design and fabrication flexibility, additive manufacturing (AM) or 3D printing (3DP) processes and polymer composites have paved their way into several industrial sectors. The quality of 3D printed polymer composites is highly dependent on the reinforcement content of polymers and 3DP process parameters. Several experimental studies are performed to optimize the reinforcement contents and process parameters; however, exploring the numerical modeling and simulation techniques is vital to lower the research and development costs. In the study, the numerical simulations for the 3DP process were performed using Digimat® software for carbon fiber-reinforced polyamide-6 (PA6) composites fabricated via the …
Effect Of Calcium Carbonate Particle Size And Content On The Thermal Properties Of Pvc Foamed Layer Used For Coated Textiles, Mouna Stambouli, Walid Chaouch, Sondes Gargoubi, Riadh Zouari, Slah Msahli
Effect Of Calcium Carbonate Particle Size And Content On The Thermal Properties Of Pvc Foamed Layer Used For Coated Textiles, Mouna Stambouli, Walid Chaouch, Sondes Gargoubi, Riadh Zouari, Slah Msahli
Turkish Journal of Chemistry
The goal of this research is to see how the amount and particle size of calcium carbonate (CaCO$_{3}$) used in the foamed layer in use for PVC-coated textiles affects the thermal properties of the material. Two different particle sizes were used at various concentrations. The impact of different CaCO$_{3}$ loadings and particle sizes on the PVC foamed layer's thermal properties were examined. Thermogravimetry (TGA and DTG) and differential scanning calorimetry (DSC) measurements were utilized to investigate the thermal properties of the PVC foamed layer and the samples have been also characterized by FTIR spectroscopy. According to the findings, the thermal …
Electrically Assisted Solution Blow Spinning Of Pvdf/Tpu Nanofibrous Mats For Air Filtration Applications, Andinet Kumella Eticha, Ali̇ Toptaş, Yasi̇n Akgül, Ali̇ Kiliç
Electrically Assisted Solution Blow Spinning Of Pvdf/Tpu Nanofibrous Mats For Air Filtration Applications, Andinet Kumella Eticha, Ali̇ Toptaş, Yasi̇n Akgül, Ali̇ Kiliç
Turkish Journal of Chemistry
In this study, pure polyvinylidene fluoride (PVDF), pure thermoplastic polyurethane (TPU), and PVDF/TPU blend nanofibers (1:3, 2:2, 3:1 ratios) were produced via electrically assisted solution blow spinning for air filtration applications. Scanning electron microscopy (SEM) analysis was conducted to investigate the diameters and morphology of nanofibers. The filtration performance of nanofibrous mats was examined by air filtration test with challenging with 0.26 ± 0.07 μm salt particles. Moreover, the flexibility and strength of the samples were determined via tensile tests. Results showed that pure TPU nanofibers had better mechanical properties, while pure PVDF nanofibers showed better filtration performance. However, 3PVDF/1TPU …
Investigating The Effect Of Poly (Ε-Caprolactone) Nanofibers Scaffolds With Random, Unidirectionally, And Radially Aligned Morphologies On The Fibroblast Cell?S Attachment And Growth Behavior, Saeed Nezari, Mohammadamin Sarli, Ahmad Hivechi, Hajir Bahrami, Peiman B. Milan, Noorahmad Latifi, Fatemeh Latifi, Tayyeb Ghadimi, S. Mohammad Amin Haramshahi, Soheila Naderi Gharahgheshlagh
Investigating The Effect Of Poly (Ε-Caprolactone) Nanofibers Scaffolds With Random, Unidirectionally, And Radially Aligned Morphologies On The Fibroblast Cell?S Attachment And Growth Behavior, Saeed Nezari, Mohammadamin Sarli, Ahmad Hivechi, Hajir Bahrami, Peiman B. Milan, Noorahmad Latifi, Fatemeh Latifi, Tayyeb Ghadimi, S. Mohammad Amin Haramshahi, Soheila Naderi Gharahgheshlagh
Turkish Journal of Chemistry
In the last decade, significant progress in tissue engineering, repairing, and replacing organs has been achieved. The design and production of scaffolds for tissue engineering are one of the main areas which have attracted the researcher's interest. In this regard, electrospinning is one of the most popular methods of nanoscale scaffold similar to extracellular matrix production. This paper reports the fabrication of scaffolds consisting of radially aligned PCL nanofibers by utilizing a collector composed of a central point electrode and a peripheral ring electrode. The chemical and physical properties were compared using SEM, FTIR, XRD, and DSC experiments, as well …
Surface Modification Of Polypropylene Nonwoven With Chitosan, Tio$_{2}$, And Ag Nanoparticles For The Removal Of Acid Dye From Water, Aminoddin Haji, Mohsen Hadizadeh, Masoumeh Ferdosi
Surface Modification Of Polypropylene Nonwoven With Chitosan, Tio$_{2}$, And Ag Nanoparticles For The Removal Of Acid Dye From Water, Aminoddin Haji, Mohsen Hadizadeh, Masoumeh Ferdosi
Turkish Journal of Chemistry
In this study, polypropylene nonwoven was coated with chitosan after being activated by oxygen/argon low-pressure plasma. The chitosan-treated sample (PP-Ch) was coated with TiO$_{2}$ nanoparticles by a pad-dry method. Silver nanoparticles were in situ synthesized on the chitosan-TiO$_{2}$-coated sample by a chemical reduction method. The morphology of each of the samples mentioned above was evaluated by FESEM. The efficiency of each sample in the removal of C.I. Acid Brown 248 from aqueous media was evaluated. The PP-Ch sample removed 90% of the dye at pH=3. Coating the PP-Ch sample with TiO$_{2}$ and silver nanoparticles improved the dye removal efficiency under …
Removal Of Amoxicillin Via Chromatographic Monolithic Columns: Comparison Between Batch And Continuous Fixed Bed, Mustafa Deni̇z Ağlamaz, Koray Şarkaya, Deni̇z Türkmen, Mustafa Uçar, Adi̇l Deni̇zli̇
Removal Of Amoxicillin Via Chromatographic Monolithic Columns: Comparison Between Batch And Continuous Fixed Bed, Mustafa Deni̇z Ağlamaz, Koray Şarkaya, Deni̇z Türkmen, Mustafa Uçar, Adi̇l Deni̇zli̇
Turkish Journal of Chemistry
This study presented a hydrophobic interaction-based poly(HEMA-MATrp) monolithic chromatographic column (MCC) to remove amoxicillin from aqueous solutions. In addition to their porous structure, monolithic-filled columns offer superior properties without loss of performance, which is one of the points that make them unique. The specific surface area of the monolithic column synthesized by the bulk polymerization of 2-hydroxyethyl methacrylate and N-Methacryloyl-L-tryptophan. Also, poly(HEMAMATrp) MCC has been characterized via FTIR, SEM, and elemental analysis. According to BET analysis, the specific surface area of the poly(HEMA-MATrp) monolithic chromatographic column (MCC) is 14.2 mg/g. The adsorption and desorption of amoxicillin in an aqueous solution …
Evaluation Of Photochemically Cross-Linked Collagen/Gold Nanoparticle Composites As Potential Skin Tissue Scaffolds, Evri̇m Meri̇ç Yelkuvan, Özge Erdemli̇, Bengi̇ Yilmaz, Ömer Aktürk
Evaluation Of Photochemically Cross-Linked Collagen/Gold Nanoparticle Composites As Potential Skin Tissue Scaffolds, Evri̇m Meri̇ç Yelkuvan, Özge Erdemli̇, Bengi̇ Yilmaz, Ömer Aktürk
Turkish Journal of Chemistry
Collagen type I is the main structural unit in skin tissue and is therefore used preferentially in skin tissue scaffolds. However, collagen-based 3D scaffolds have weak aqueous stability and degradation profiles in their uncross-linked states and chemical cross-linking reagents arise toxicity concerns, which generally restrict the spectrum of their biomedical applicability. Here, the research goal is to photochemically cross-link collagen type I with rose bengal (RB) when subjected to green laser light and to investigate the effect of silk sericin-capped gold nanoparticles (S-AuNP) when incorporated into scaffolds on the cross-linking process and thus on the scaffold properties. All the collagen …
Polymeric Nanoparticle-Based Electrochemical Sensor For The Detection Of Ca 125, Ceren Türkcan, Si̇nan Akgöl
Polymeric Nanoparticle-Based Electrochemical Sensor For The Detection Of Ca 125, Ceren Türkcan, Si̇nan Akgöl
Turkish Journal of Chemistry
In this paper, Cys-graft-p(HEMA) nanomaterials and a new electrochemical method were developed for determination of CA 125. Cys-graft-p(HEMA) nanomaterials were synthesized with emulsion polymerization method and modified with grafting procedure. It was determined that Cys-graft-p(HEMA) nanomaterials had 50 nm dimension and spherical morphology, and per gram polymeric material contained 0.011 mmol L-cysteine. Electrode surface was prepared step by step for electrochemical analysis with optimization process. Linear determination range was determined as 5-400 U/mL (R= 0.9935). Detection limit (LOD) was calculated as 1.87 U/mL, and quantification limit (LOQ) was determined as 5.62 U/mL. The fabricated sensor system showed good repeatability, accuracy, …
Estimation Of The Work Of Adhesion Between Ito And Polymer Substrates: A Surface Thermodynamics Approach, Sali̇h Özbay
Estimation Of The Work Of Adhesion Between Ito And Polymer Substrates: A Surface Thermodynamics Approach, Sali̇h Özbay
Turkish Journal of Chemistry
Indium tin oxide (ITO) is one of the most widely used semiconductor among transparent conducting oxides (TCOs) due to their electrical conductivity and optical transparency properties. Since the development of low temperature deposition methods, coating of ITO on polymer substrates especially for use in flexible electronics has been a popular topic. The existence of adequate adhesion strength between ITO and polymer is critical in producing a successful film. Nowadays, polycarbonate (PC), poly(methyl methacrylate) (PMMA) and polyethyleneterephtalate (PET) are frequently used as substrates for such coatings. However, there may be other polymeric alternatives that have a potential to be used for …
Structure-Emission Relationship Of Some Coumarin Laser Dyes And Related Molecules: Prediction Of Radiative Energy Dissipation And The Intersystem Crossing Rate Constants, Msa Abdelmottaleb
Structure-Emission Relationship Of Some Coumarin Laser Dyes And Related Molecules: Prediction Of Radiative Energy Dissipation And The Intersystem Crossing Rate Constants, Msa Abdelmottaleb
Turkish Journal of Chemistry
Dye lasers are commonly used in optical investigation because their solutions in organic solvents deliver tunable, coherent emissions. They exhibit intense fluorescence owing to some specific spectroscopic characteristics. One drawback of the laser dyes is that it shows excessive triplet-state losses (TSLs.) The lack of theoretical predictions of fluorescence rates, intersystem crossing (ISC), and phosphorescence in laser dyes prompted us to report on the predicted rates of radiative and nonradiative transitions of some laser dyes. Structural engineering by some substituents influencing the simulated rates of coumarin laser dye derivatives for an efficient operation was investigated. The NH$_{2}$ functional group renders …
Synthesis And Kinetic Analysis Of Poly(N-Acryloylmorpholine) Brushes Via Surface Initiated Raft Polymerization, Esma Mutlutürk, Tuncer Çaykara
Synthesis And Kinetic Analysis Of Poly(N-Acryloylmorpholine) Brushes Via Surface Initiated Raft Polymerization, Esma Mutlutürk, Tuncer Çaykara
Turkish Journal of Chemistry
Polymer brushes are promising many applications as smart materials and biocompatible surfaces. Surface-initiated reversible addition-fragmentation chain transfer (RAFT) polymerization is one of the most effective techniques for synthesis of well-defined polymer brushes. Herein, a biocompatible, uniform and stable poly(N-acryloylmorpholine)-silicon hybrid system was achieved using surface-initiated RAFT polymerization. Evidence of a well-controlled surface-initiated RAFT polymerization was confirmed by a linear increase of number average molecular weight (M$_{n}$) with overall monomer conversions. Water contact angle, ellipsometry, X-ray photoelectron spectroscopy and atomic force microscopy verified the presence of poly(N-acryloylmorpholine) (poly(NAM)) on silicon wafers. The grafting density (σ) and the average distance between grafting …
Fabrication Of Dendritic Pdcu Alloy Supported On 3d N-Doped Hollow Graphene For Efficient Ethanol Electrooxidation, Zhijie Ji̇ang, Shuiyuan Fu, Wei Zhao, Xvtang Liu, Fei Wang, Mingyu Cui, Linyang Dong
Fabrication Of Dendritic Pdcu Alloy Supported On 3d N-Doped Hollow Graphene For Efficient Ethanol Electrooxidation, Zhijie Ji̇ang, Shuiyuan Fu, Wei Zhao, Xvtang Liu, Fei Wang, Mingyu Cui, Linyang Dong
Turkish Journal of Chemistry
Fabricating highly efficient Pd-based nanocatalysts with a well-defined structure is desired for the commercialization of direct ethanol fuel cell (DEFC). Herein, a series of hierarchical three-dimensional N-doped hollow graphene spheres (NHGS) supported dendritic PdCu alloy catalysts Pd$_{x}$Cu$_{(d)}$-NHGS (x: Cu/Pd theoretical molar ratio of 4, 2, and 1) are assembled by one-pot ascorbic acid reduction-immobilization method. Aiming to maximize the Pd utilization and realize the efficient ethanol electrooxidation, this novel electrocatalyst offers potent activity sites and promotes electron and ion kinetics simultaneously. Characterization indicates that the as-obtained Pd$_{4}$Cu$_{(d)}$ alloy nanoparticles with average sizes of approximately 55 nm are evenly dispersed on …
Investigation Of The Dehydration Of Ulexite Ore With Different Parameters And Modeling With Artificial Neural Network (Ann) Method, Mustafa Engi̇n Kocadaği̇stan
Investigation Of The Dehydration Of Ulexite Ore With Different Parameters And Modeling With Artificial Neural Network (Ann) Method, Mustafa Engi̇n Kocadaği̇stan
Turkish Journal of Chemistry
Study experiments were conducted considering the temperature, time, and sample weight parameters in order to model the dehydration by applying dehydration processes to ulexite ores. Data obtained from the dehydration processes of ulexite ore were compared with TG analyzes. It was observed as the result of the heat treatment that the fastest water removal was provided in the temperature range of 150-250 °C and it was very low in the range of 400-750 °C. In order to design the ANN method, 4 different models were proposed with the same parameters in the dehydration experiments and the network structure was determined. …
Effect Of Microfluidic Channel Integration Onto Gold Microelectrode On Its Redox Electrochemistry, Ahmet Uçar, Zahraa Ali Hajool, Hamed Ghorbanpoor, Reza Didarian, Fatma Doğan Güzel
Effect Of Microfluidic Channel Integration Onto Gold Microelectrode On Its Redox Electrochemistry, Ahmet Uçar, Zahraa Ali Hajool, Hamed Ghorbanpoor, Reza Didarian, Fatma Doğan Güzel
Turkish Journal of Chemistry
Microfluidic systems have attracted significant interest in recent years as they are extensively employed in lab-on-chip and organ-on-chip research. Their combination with electrochemical platforms offers many advantages, promising a high potential for sensing applications, still the microfluidic-channel integration onto electrodes might induce challenges related to changes in signal-tonoise ratios and mass transport conditions. In this study, we investigated the effect of microfluidic channel integration in redox behavior of thermally deposited gold thin film microelectrodes by voltammetric (CV and SWV) electrochemical measurements. Using different dimensions of PDMS microfluidic channels (i.e. widths of 50, 100, 250, and 500 μm) and a constant …
Enhanced Ionic Conductivity And Mechanical Strength In Nanocomposite Electrolytes With Nonlinear Polymer Architectures, Recep Bakar, Saeid Darvishi, Erkan Şenses
Enhanced Ionic Conductivity And Mechanical Strength In Nanocomposite Electrolytes With Nonlinear Polymer Architectures, Recep Bakar, Saeid Darvishi, Erkan Şenses
Turkish Journal of Chemistry
Solvent-free polymer-based electrolytes (SPEs) have gained significant attention to realize safer and flexible lithium-ion batteries. Among all polymers used for preparing SPEs electrolytes, poly(ethylene oxide), a biocompatible and biodegradable polymer, has been the most prevalent one mainly because of its high ionic conductivity in the molten state, the capability for the dissolution of a wide range of different lithium salts as well as its potential for the environmental health and safety. However, linear PEO is highly semicrystalline at room temperature and thus exhibits weak mechanical performance. Addition of nanoparticles enhances the mechanical strength and effectively decreases the crystallization of linear …
On Chip Microfluidic Separation Of Cyclotides, Reza Didarian, Aliakbar Ebrahimi, Hamed Ghorbanpoor, Hesam Bagheroghli, Fatma Doğan Güzel, Mohsen Farhadpour, Nasrin Lotfibakhshayesh, Hossein Hashempour, Hüseyi̇n Avci
On Chip Microfluidic Separation Of Cyclotides, Reza Didarian, Aliakbar Ebrahimi, Hamed Ghorbanpoor, Hesam Bagheroghli, Fatma Doğan Güzel, Mohsen Farhadpour, Nasrin Lotfibakhshayesh, Hossein Hashempour, Hüseyi̇n Avci
Turkish Journal of Chemistry
Cyclotides as a cyclic peptide produced by different groups of plants have been a very attractive field of research due to their exceptional properties in biological activities and drug design applications. The importance of cyclotides as new biological activities from nature caused to attract researchers to develop new separation systems. Recent growth and development on chip-based technology for separation and bioassay especially for anticancer having sparklingly advantages comparison with common traditional methods. In this study, the microfluidic separation of Vigno 1-5 cyclotides extracted from Viola ignobilis by using polar and nonpolar forces as a liquid-liquid interaction was investigated through modified …