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Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Facile One-Step Activated Glassy Carbon Electrode For Sensitive Tryptophan Sensing In Yogurt, Sevi̇lay Erdoğan Kablan, Ahmet Çeti̇nkaya, Si̇bel Özkan, Emi̇rhan Nemutlu

Turkish Journal of Chemistry

Activation of glassy carbon electrodes (GCEs) in tailored solution environments introduces oxygenated surface functionalities such as hydroxyl, carboxyl, and quinone groups. These modifications enhance electron‐transfer kinetics and strengthen interactions with target analytes, thereby improving electrochemical sensitivity. In this study, square-wave voltammetry was used, and the most suitable supporting electrolyte for tryptophan (TRP) analysis was a pH 3 Britton–Robinson buffer. The cyclic voltammetry potential range and number of cycles for the Act-GCE were obtained as 0–1.5 V and seven cycles, respectively. The activated electrode exhibited excellent analytical performance, with a linear response for TRP over 0.20–6.28 μM, a detection limit of …

Thiophene-Carbazole-Based Covalent Organic Polymer Electrodes For Electrochromic And Supercapacitor Applications, Si̇nem Altinişik

Turkish Journal of Chemistry

In this study, a thiophene-carbazole-based conjugated organic polymer was successfully synthesized on indium tin oxide (ITO)/glass and graphite sheet substrates using in situ oxidative polymerization. In terms of electrochromic properties, the electrodes exhibited significant color change from light yellow-green to dark gray in the potential range of 0 V to 1.2 V, with optical contrast ranging from 84.2% to 47.2% and coloring efficiency of 171.3 cm2/C. The prepared PCBP-Th_ITO/glass electrode also exhibited fast switching times (tb = 0.89 s and tc = 2.05 s) at 650 nm. Furthermore, 90% optical stability was maintained after 1000 cycles. In terms of energy …

Fabrication Of Cross-Linked Thiophene-Coumarin-Fluorene Donor–Acceptor Pentamer Thin Films For Electrochromic Devices Application, Ari̇fe Aktaş, Mert Akgün, Mücahi̇t Özdemi̇r, Sermet Koyuncu

Turkish Journal of Chemistry

Functionalized p-conjugated polymers have emerged as promising electrochromic materials due to their well-defined molecular structures, facile synthesis, and ability to form smooth and homogeneous thin films. Furthermore, surface cross-linking enhances the mechanical and environmental stability of these films while improving their durability during electrochemical operation. In this study, a unique band gap-tunable pentamer (FBP) was developed featuring a D-A-D-A-D configuration, which includes thiophene, coumarin, and fluorene. Cross-linked films (FBPX) were obtained using both spray and electrospray methods in the presence of tetrathiol-based crosslinkers and 366 nm light, thanks to the functionalizable allyl groups present in the FBP structure. UV–Vis analysis …

Samarium-Doped Ceria Catalysts For Boron-Aluminum Composite Propellants: Effect Of Synthesis Method, Di̇lara Güçtaş Gürel, Mehmet Ali̇ Faruk Öksüzömer

Turkish Journal of Chemistry

Solid propellants based on ammonium perchlorate (AP) are widely used in rocket and missile propulsion systems due to their high energy density and reliable combustion characteristics. Although aluminum (Al) is the conventional metal fuel in AP-based formulations, boron (B) has gained increasing attention as a partial or full substitute owing to its significantly higher volumetric energy density. However, the low combustion efficiency of boron particles remains a critical challenge, making the use of catalysts essential to enhance the thermal decomposition of AP and overall propellant-burning performance. In this study, samarium-doped ceria (SDC20) catalysts were synthesized by three different methods including …

Rapid Synthesis Of Agcu Bimetallic Nanodendrites With Enhanced Catalytic Activity For 4-Nitrophenol Reduction, Jun Liu, Hongguang Liao, Xuanyan Liu

Turkish Journal of Chemistry

Herein, AgCu nanodendrites were fabricated via a facile one-step displacement reaction at ambient temperature with Zn powder as the reducing agent. The morphology, structure, and composition of the products were systematically characterized by transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The results demonstrate that the structure and morphology of the catalysts are strongly dependent on the Ag/Cu molar ratio. The catalytic performance was evaluated by the reduction of 4-nitrophenol (4-NP) at room temperature, in comparison with monometallic Ag and Cu catalysts. The catalytic activity follows the order Ag1Cu1 > Ag1Cu3 > Ag3Cu1 > Ag > Cu. The optimized Ag1Cu1 catalyst achieves 98.6% …

Effects Of Washing, Oxidation, Carboxylation, And Hydrophobicity On The Antibacterial Activity Of Graphene Oxide And Reduced Graphene Oxide, Emi̇r Boztepe, Ceren Poyraz, Ruki̇ye Taşdemi̇r, Ebru Önem, Ümran Sofu, Keri̇m Yapici

Turkish Journal of Chemistry

In this study, the effects of number of washes, oxidation degree, carboxylation, and hydrothermal reduction temperature on the antibacterial activity of graphene oxide (GO) and reduced graphene oxide (rGO) nanomaterials were investigated. GO derivatives with different numbers of washes (1–5W) and oxidation levels (3X, 6X, and 9X), carboxylated GO (GO-COOH), and rGO samples obtained at different hydrothermal reduction temperatures (100, 140, and 180 °C) were characterized by X-ray diffraction, field-emission scanning electron microscopy, Fourier-transform infrared spectroscopy, zeta potential analysis, and Raman spectroscopy, and were subsequently evaluated for antibacterial activity against gram-positive Staphylococcus aureus (S. aureus) and gram-negative Escherichia coli (E. …

Cobalt-Substituted Hydroxyapatite As A Potential Basis Of Biomaterials: Synthesis, Crystal-Chemistry Properties And Antibacterial Activity, Maria M. Vlasova, Ksenia S. Stasenko, Evgeny Bulanov

Turkish Journal of Chemistry

This paper presents the results of the synthesis of solid solutions of cobalt-substituted hydroxyapatite of the composition Ca10-xCox(PO4)6(OH)2 by the solid-phase and solution method. The formation of only the composition of Ca9.5Co0.5(PO4)6(OH)2 has been reliably established, whereas an increase in the cobalt content, as well as an increase in the temperature of synthesis and calcination of the samples prepared in solution, leads to the formation of stable mixtures of calcium and cobalt phosphates. The crystal structure has been refined for Ca9.5Co0.5(PO4)6(OH)2 (a = 9.4121(28) Å, c = 6.8762(20) Å, V = 527.54(35) Å3; R-Bragg = 2.455%) under the assumption of …

The Effect Of Seedling Age On Nickel (Ni) Accumulation In Maize (Zea Mays L.), Tuba Göçergi̇l, Hava Şeyma İnci̇

Turkish Journal of Agriculture and Forestry

One of the most significant problems facing different ecosystems worldwide is the pollution of soil and water resources with heavy metals, which are harmful to biota. Metals are absorbed by plant roots through soil-plant interaction, leading to accumulation in plants. The plant's growth phase is one of the most important factors in heavy metal uptake and accumulation. Among heavy metal elements, nickel is one of the serious environmental pollutants and plant growth inhibitors due to its toxicity and persistent nature at high concentrations, as well as its bioaccumulation in ecosystems. This study aims to investigate how nickel accumulation in plant …

Species-Specific Metal Uptake Thresholds In Riparian Macrophytes: A Biological Framework For Ecological Risk Assessment, Reyhan Sağlam, Ferhat Gökbulak

Turkish Journal of Agriculture and Forestry

Anthropogenic pressures on freshwater ecosystems have increased metal contamination in riparian zones; however, biological thresholds that distinguish tolerable exposure from ecologically significant accumulation remain poorly defined. This study investigated species-specific thresholds for heavy metal uptake in riparian macrophytes to establish a biologically grounded framework for ecological risk assessment in impacted streams. A gradient encompassing five sites was used to sample four dominant macrophyte species: Typha latifolia, Phragmites australis, Lythrum salicaria, and Persicaria lapathifolia. Concentrations of cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), nickel (Ni), lead (Pb), and zinc (Zn) in aboveground plant biomass were examined in relation to their …

A Lightweight Multitask Adaptive Fusion Network With Channel Attention For Uav-Based Crop Detection And Classification, Xuanyu Yue, Zhenyu Wan

Turkish Journal of Agriculture and Forestry

Unmanned aerial vehicles (UAVs) have become essential tools in precision agriculture, facilitating large-scale monitoring of crop health, weed proliferation, and overall field conditions. However, conventional single-task recognition models encounter significant challenges when implemented on resource-constrained UAV platforms, particularly in detecting densely distributed small objects, managing scale variations, and addressing occlusions. To address these challenges, this paper proposes a channel attention-based adaptive fusion network (CNAF-Net) specifically designed for agricultural scenarios. CNAF-Net utilizes MobileNetV3 for hierarchical feature extraction and integrates a channel attention-guided adaptive fusion mechanism that dynamically combines multiscale features across detection, classification, and segmentation tasks. Experiments conducted on the WeedMap …

Genetic Inheritance Of Leaf Rolling As An Adaptive Trait For Fog Capture And Drought Tolerance In Wheat, Sabah Merrium, Zulfiqar Ali, Latifa Alhusnain, Muneera D.F. Alkahtani, Sadia Hakeem, Sajid Fiaz, Muhammad Ali Sher, Kotb A. Attia, Seung Hwan Yang, Muhammad Abu Bakar Saddique, Muhammad Hammad Nadeem Tahir

Turkish Journal of Agriculture and Forestry

Wheat is a primary source of sustenance for around 2 billion people worldwide; however, its production is threatened by the water scarcity associated with climate change. In the search for climate-smart wheat varieties, atmospheric moisture in the form of fog and dew is gaining attention as a sustainable, self-irrigating water source for crops. Leaf rolling (LR) is a well-known adaptive trait under water deficit conditions that supports fog moisture capture in wheat; however, little is known about its genetic potential and inheritance pattern, particularly given its high environmental influence. This study assesses the genetic heritability, combining ability, and diversity of …

Valorization Of Buttermilk As A Functional Ingredient In Yogurt Soup: Effects On Physicochemical Properties, Aroma Profile, Amino Acid Composition, And Bioactivities, Emi̇ne Maci̇t, Fatma Zehra Özyilmaz

Turkish Journal of Agriculture and Forestry

​In this study, the feasibility of using buttermilk as a functional ingredient in yogurt soup, a traditional fermented dairy product, was investigated with the aim of valorizing dairy industry by-products. Soup samples prepared with different buttermilk ratios (0%, 25%, 50%, 75%, and 100%) were evaluated for their physicochemical and sensory properties, aroma and amino acid profiles, antioxidant capacity, and antidiabetic activity. The incorporation of buttermilk resulted in statistically significant differences in total solids, ash, and titratable acidity (p < 0.01 and p < 0.05), while no significant changes were observed in fat, protein, or pH values. Increasing buttermilk levels led to higher L* and b* values and lower a* values. Sensory analysis showed that flavor scores increased with buttermilk content, with the highest score observed in the sample containing 100% buttermilk (T5). In the control sample, hexanoic acid, benzoic acid, acetic acid, methyl salicylate, and several ketones were identified as dominant aroma compounds, whereas buttermilk-enriched samples were characterized mainly by hexanoic acid, acetic acid, butanoic acid, ethyl acetate, higher alcohols, and ethanol. Increasing buttermilk content resulted in a higher proportion of alcohols and a reduction in acids, ketones, and aldehydes. Samples with higher buttermilk levels exhibited increased essential amino acid content, while functional amino acids such as γ-aminobutyric acid, β-aminoisobutyric acid, ethanolamine, proline, and alanine reached their highest levels in the T5 sample. The T5 sample showed a DPPH radical scavenging activity of 5.98%, whereas the highest α-amylase inhibition was observed in the control sample. Overall, the results indicate that buttermilk can be effectively used as a functional ingredient in yogurt soup formulations, improving nutritional quality and sensory characteristics.

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Turkish Journal of Medical Sciences

No abstract provided.

Effects Of A Virtual Reality-Based Nature Video Intervention On Sleep Quality And Mental Well-Being In Patients With Multiple Sclerosis: A Randomized Controlled Trial ​, Hati̇ce Yağci Karamanli, Nuray Bi̇ngöl

Turkish Journal of Medical Sciences

Background/aim: Sleep quality and mental health are negatively affected in many patients with multiple sclerosis (MS). The study was conducted to evaluate the effects of virtual reality (VR) on sleep quality and mental well-being.

Materials and methods: The study was designed as a randomized controlled trial. Data were collected from patients with MS who presented to a hospital in Türkiye. The study was completed by 21 participants in the experimental group and 22 participants in the control group. Participants in the experimental group watched nature videos using VR headsets for 6 weeks. Participants completed the Pittsburgh Sleep Quality Index (PSQI) …

Nonlinear Mode Crossing And Spontaneous Frequency Comb Generation In Driven Magnetic Nanodisks, Hasan Pi̇şki̇n

Turkish Journal of Physics

Nonlinear magnetization dynamics in confined nanostructures provide a rich platform for fundamental studies and advanced spintronic applications. Here, we investigate the driven dynamics of a perpendicularly magnetized permalloy nanodisk using high-resolution micromagnetic simulations. In the linear regime, geometric confinement quantizes the uniform precession into discrete radial standing spin-wave (SSW) modes. As the excitation amplitude increases, the fundamental Kittel mode exhibits a pronounced nonlinear frequency shift relative to the higher-order SSW modes, ultimately leading to a critical mode crossing associated with nonlinear resonance overlap and the breakdown of modal orthogonality. Time-domain analysis reveals that strong mode hybridization governs the ensuing dynamics, …

Stress–Strain Behavior Of The High-Entropy Cantor Alloy Crmnfeconi Using A Deep Neural Network Potential, Nguyen Le Hoai Phuong, Le Huu Nghia, Huynh Khanh Van, Vo Khuong Dien, Nguyen Thanh Tien

Turkish Journal of Physics

Machine learning interatomic potentials (MLIPs) provide an efficient approach to large-scale molecular dynamics simulations of high-entropy alloys. In this work, an MLIP trained on AIMD data was developed for the CrMnFeCoNi Cantor alloy and validated against DFT calculations. In addition, we compared MLIP results with those obtained using the classical modified embedded atom method (MEAM)-based interatomic potential for the CrMnFeCoNi Cantor alloy. The model achieved energy and force RMSEs of 7.39 x 10-6 meV/atom and 4.46 x 10-3 eV/A, respectively. Tensile simulations demonstrated that the MLIP accurately reproduced the stress–strain response, elastic constants, and deformation mechanisms observed in DFT calculations. …

Spacer-Mediated Gold Nanocube Arrays For Edge-Localized Excitonic Enhancement In Monolayer Mos2​, Abdullah Efe Yildiz, Emre Ozan Polat

Turkish Journal of Physics

Plasmonic nanostructures offer an effective route for enhancing light-matter interaction in atomically thin semiconductors, whose optical response is intrinsically limited by their subnanometer active thickness. Here, we numerically investigate excitonic enhancement in monolayer (ML) Molybdenum Disulfide (MoS2) coupled to size-tuned gold (Au) nanocube arrays separated by thin aluminum oxide (Al2O3) and hexagonal boron nitride (h-BN) spacer layers. By varying the nanocube side length, the localized surface plasmon resonance is tuned across the visible spectral range to modulate the A- and B-excitonic transitions of monolayer MoS2.We show that the nanocube-size-dependent spectral redshift can be further controlled through the spacer material and …

Theoretical Construction Of Light Hexaquarks And Their Substantiation By Seven-Dimensional Representation Of Su(2) Group, Mayank Joshi, Shuchi Bisht, Navjot Hothi, Manish Bisht

Turkish Journal of Physics

This manuscript presents a theoretical approach to constructing light hexaquarks using up and down quarks. These light exotic hexaquarks are shown to exhibit a seven-dimensional representation of the SU(2) isospin group. Additionally, the isospin septuplet is developed along with the quintet, triplet, and singlet representations for these light exotic hexaquarks. These particles are essentially mesonic in nature and also satisfy the requirements of the Kronecker product. Furthermore, the physical characteristics and weights of the respective states are intrinsically provided for these light hexaquarks.

Selective Citation: The Systematic Omission Of Established Regional Literature, İrem Eli̇tez

Turkish Journal of Earth Sciences

No abstract provided.

Integrated Assessment Of Groundwater Quality And Human Health Risks In A Semiarid Region Of Kemaliye (Türkiye), Veli̇ Keski̇n, Celaletti̇n Şi̇mşek

Turkish Journal of Earth Sciences

In this study, the hydrochemical characteristics, drinking water suitability, and potential human health risks of groundwater in the Karapınar region (Kemaliye, Erzincan, Türkiye), which has become a critical drinking water resource due to drought associated with climate change and the depletion of surface water resources, were investigated using an integrated multiparameter approach. Within the scope of the study, a total of 18 water samples, comprising 13 spring water samples and 5 groundwater samples obtained from wells, were collected during the dry season (October 2021) and analyzed for major ions, physicochemical parameters, nitrate, and trace elements. The suitability of the samples …

Editorial Note To The Article “Identification Of A Previously Unrecognized Listric Fault Beneath The Acıpayam Graben: Insights From Integrated Dinsar And Field Observations” [Turkish Journal Of Earth Sciences 35 (1) 2026 20-41], Orhan Tatar

Turkish Journal of Earth Sciences

No abstract provided.

Possible Fluid Contributions From Active Faults To Mercury Distribution In Surface Sediments Of The Gemlik Gulf And Health Risk Assessment, Erol Sari, M. Namik Çağatay, Tuğçe Nagi̇han Arslan Kaya, Zeynep Çeti̇n, Nuray Çağlar

Turkish Journal of Earth Sciences

The Gemlik Gulf, located in the eastern part of the Sea of Marmara (Türkiye), is recognized as a relatively contaminated marine environment, influenced by a variety of natural and anthropogenic inputs. A comprehensive geochemical study was performed to examine the distribution of total mercury (THg) in surface sediments and to elucidate the possible sources contributing to its accumulation. The analysis revealed that THg concentrations ranged from 485 to 6486 ng/g, with all measured values substantially exceeding the average shale background concentration of 400 ng/g, indicating significant enrichment. According to sediment quality guidelines, none of the samples exceeded the effects range …

Citation Scope And Scientific Relevance In An Event-Based Seismotectonic Study: Reply To The Comment By Elitez On Eski (2026), Semi̇h Eski̇

Turkish Journal of Earth Sciences

No abstract provided.

Challenges, Trends, And The Role Of Lstm In Ai-Based Predictive Maintenance Of Electrolyzers For Solar Hydrogen Systems: A Review, Yani Koerniawan Kuatno, Muhamad Zahim Sujod

Turkish Journal of Electrical Engineering and Computer Sciences

The transition toward low-carbon energy systems has increased interest in hydrogen as a clean energy carrier, with solar-driven water electrolysis emerging as a promising technology due to its high efficiency and compatibility with renewable energy sources. However, dynamic operating conditions and intermittent renewable input accelerate electrolyzer degradation, reducing reliability and system lifespan. Predictive maintenance (PdM), supported by artificial intelligence (AI), offers a data-driven approach to anticipate failures and improve operational durability. This review systematically investigates AI-based PdM approaches for electrolyzers, with an emphasis on long short-term memory (LSTM) networks and Internet of things (IoT) integration. Following PRISMA 2020 guidelines, 35 …

Dynamic Focal Loss Adjustment For Railway Defect Detection, Mehmet Koç, Ridvan Özdemi̇r, Ömer Gerek

Turkish Journal of Electrical Engineering and Computer Sciences

Railway infrastructure is critical to the safe and efficient operation of transportation systems, and the early detection of defects is essential for preventing catastrophic failures. Automated defect detection methods are therefore crucial for maintaining continuous safety while reducing maintenance costs. Although Focal Loss is widely used in object detection under class-imbalanced conditions, its fixed α parameter may limit its effectiveness in detecting rare defects. In this study, we propose an adaptive α-tuned Focal Loss approach that dynamically adjusts class weights based on average precision (AP) values. By iteratively optimizing α without relying on gradient-based optimization, the proposed method improves the …

Relative Rate Observer-Based Online Tuning Mechanism For Single-Input Interval Type-2 Fuzzy Pid Controllers, Oqba Aldreiei, Cenk Ulu, Mert Can Kurucu, Müjde Güzelkaya

Turkish Journal of Electrical Engineering and Computer Sciences

The characteristics of the footprint of uncertainty (FOU) in interval type-2 membership functions (IT2-MFs) are crucial to the performance and robustness of interval type-2 fuzzy controllers (IT2-FCs). However, existing IT2-FC design approaches mostly use fixed FOU structures. This study proposes an online membership function (MF) adjustment mechanism for a single-input interval type-2 fuzzy PID controller (SIT2-FPID)  that adjusts the FOU of the antecedent MFs and weights of the consequent MFs, respectively, to achieve high performance and robustness. The proposed online adjustment mechanism consists of a relative rate observer (RRO), a two-input rule-base adjustment system, and a first-order smoothing filter. The …

Cuip-X25: A Real-World Network Intrusion Dataset For Next-Generation Ai-Driven Security, Arshad Iqbal, Sohail Asghar

Turkish Journal of Electrical Engineering and Computer Sciences

The efficacy of artificial intelligence (AI) in intrusion detection systems (IDS) is critically dependent on high-fidelity training data. However, as detailed in the manuscript's literature review, existing benchmark datasets are predominantly synthetic, outdated, or imbalanced and fail to capture the complexity of the contemporary threat landscape. To bridge this gap, this study introduces CUIP-X25, a novel real-world cyber-attack dataset captured over a four-month period using a dionaea honeypot deployed on a public network. Unlike synthetic alternatives, this dataset provides an authentic representation of modern adversarial tactics, techniques, and procedures, encompassing 3.16 million real events across ten distinct attack categories, including …

Robust Load Frequency Control For Multiarea Electrical Power Systems Via Analytical Proportional-Integral-Derivative Plus Second Order Derivative Controller Design, Yavuz Güler, Mustafa Nalbantoğlu, Ibrahim Kaya

Turkish Journal of Electrical Engineering and Computer Sciences

This research presents a proportional-integral-derivative plus second order derivative (PIDD2) controller design based on the Direct Synthesis Method (DSM) for load frequency control (LFC) of interconnected power systems. The parameters of the proposed PIDD2 controller are determined using the DSM, which offers an analytical approach for tuning. The design approaches have been developed specifically for single, two, and three-area power systems, encompassing nonreheated and reheated thermal turbines. In the proposed design method, the best values of PIDD2 controller parameters were found by using a multicriteria objective function that includes the integral of absolute error (IAE) and settling time. In response …

Boundary Layer Sliding Mode Control Strategy For Variable-Speed Compressor In Deep Freezers: Experimental Validation Of Energy Efficiency And Freezing Capacity, Sertan Aksoy, Kami̇l Çeti̇n, Sezai̇ Taşkin

Turkish Journal of Electrical Engineering and Computer Sciences

This study presents the design and experimental validation of a nonlinear sliding mode controller developed for a deep freezer equipped with a variable-speed compressor. The proposed control strategy aims to minimize energy consumption while maintaining rapid and stable cooling performance under varying ambient conditions. A detailed thermal model of the deep freezer was established using an equivalent resistance–capacitance network representation, enabling precise analysis of temperature dynamics. The sliding mode-based control algorithm dynamically adjusts the compressor’s operating frequency according to temperature deviation, ambient conditions, and time-dependent factors, providing robust performance without requiring parameter retuning for different models. Beyond theoretical-based analysis, a …