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Evaluating The Neotectonic Activities Of The Eastern Makran At The Northern Edge Of The Triple Junction In Southwest Pakistan, Waseem Khan, Ke Zhang, Hao Liang
Evaluating The Neotectonic Activities Of The Eastern Makran At The Northern Edge Of The Triple Junction In Southwest Pakistan, Waseem Khan, Ke Zhang, Hao Liang
Turkish Journal of Earth Sciences
A number of five GIS-based indices, such as stream slope (Ss), surface roughness (Sr), asymmetric factor (Af), hypsometry integral (Hi), and stream-length gradient (SL), were summarised to examine the intensity of the index of tectonic activity (IAT) in 43 subbasins of Hingol Basin at the northern edge of the triple junction in southwest Pakistan. In addition, tectonic influences were identified by knickpoints spatial distribution and field surveys. The majority of the indices are consistent and display roughly the same classifications. The uncertain results have a less substantial impact on the obtained results in most of the 43 subbasins. Using these …
Mineralogical And Geochemical Characteristics Of The Upper Cretaceous And Lower Paleocene Parts Of The Germav Formation: Southeastern Türkiye, Sema Teti̇ker
Turkish Journal of Earth Sciences
The mineralogical and chemical characteristics of Upper Cretaceous-Lower Paleocene claystone sediment samples taken from Mardin and Batman, located in southeastern Türkiye, were analyzed in the present study. The clay mineral paragenesis in the Upper Cretaceous units consisted of chlorite-smectite (C-S) and illite, whereas the Lower Paleocene unit consisted of chlorite-vermiculite (CV) and vermiculite minerals. Analyses conducted on clay samples indicated high levels of Al, Mg, Fe, Cr, V, Ni, and Zr. Low levels of alkali and alkaline earth elements (Mg, Na, Ca, K) in the clay-rich sediments suggest relatively high-grade weathering in the source area. The mineralogical compositions, major elemental …
An Experimental Investigation On The Discrete Poisson’S Upward Continuation Of Anomalous Gravity Field Data, Mehmet Si̇mav, Bi̇hter Erol, Muhammet Aki̇f Gülender, Serdar Erol
An Experimental Investigation On The Discrete Poisson’S Upward Continuation Of Anomalous Gravity Field Data, Mehmet Si̇mav, Bi̇hter Erol, Muhammet Aki̇f Gülender, Serdar Erol
Turkish Journal of Earth Sciences
The Poisson upward continuation of gravity field functionals, typically given on the Earth’s irregular topography with limited spatial extent, necessitates some proper treatments due to the theoretical requirements. This study reviews the Poisson theory and investigates a more rigorous methodology for the numerical solution of the spherical integral equation by addressing many issues such as spherical-Earth model implementation, far-zone effect, Poisson kernel modification, and suitable ground data reduction scheme. We first explore the far-zone effect and search for an optimal near-zone spherical cap radius above which the truncation error is negligible. We then compare different variants of remove-restore technique with …
Microfacies, Geometry And Growth Phases Of Microbial Mound In Gucheng Area, Southeastern Tarim Basin, China, Xu Chen, Iftikhar Satti, Yuwen Dong
Microfacies, Geometry And Growth Phases Of Microbial Mound In Gucheng Area, Southeastern Tarim Basin, China, Xu Chen, Iftikhar Satti, Yuwen Dong
Turkish Journal of Earth Sciences
Microbial mound is favorable carbonate reservoir for petroleum exploration, especially for the deep tight reservoirs in the Tarim petroliferous basin. Due to lack of effective research methods, it is difficult to analyze its unique sedimentary structure and evolution process. In this study, based on cores, thin-sections, logging, 3D seismic data and geochemical test data, the petrographic texture, microfacies, geometry and growth phases of microbial mound in Gucheng area, Southeastern Tarim Basin were investigated, which can be used to reconstruct dynamic evolution of the microbial mounds and discuss the controlling factors. The major results are as follows: (1) Gucheng area is …
Genesis Of Efficient Reservoirs In Mixed Sedimentary Setting: A Case Study Of Benxi Formation In The Gaoqiao Area, Ordos Basin, Shu Liu, Jinbu Li, Fengbo Jin, Haifeng Liu, Meng Wang, Yulin Cheng, Yulin Cheng, Xiaohong Zhong, Hao Lu
Genesis Of Efficient Reservoirs In Mixed Sedimentary Setting: A Case Study Of Benxi Formation In The Gaoqiao Area, Ordos Basin, Shu Liu, Jinbu Li, Fengbo Jin, Haifeng Liu, Meng Wang, Yulin Cheng, Yulin Cheng, Xiaohong Zhong, Hao Lu
Turkish Journal of Earth Sciences
The Benxi-Taiyuan Formation in the southern region of the Ordos Basin represents a typical mixed sedimentary system, which has witnessed recent breakthroughs in the exploration of tight sandstone gas within the Benxi Formation. However, the development patterns of reservoirs in this mixed sedimentary area remain unclear, influenced by the sedimentary model and the distribution scale of sedimentary sandstone bodies. This study investigates the paleogeomorphology, sedimentary model, sandstone body type, petrological characteristics, and pore structure of the Benxi Formation. Field profiles, drilling core observations, microscopic section analysis, scanning electron microscopy (SEM), high-pressure mercury injection (HPMI), and physical property analysis are employed. …
Dinsar Analysis And Geophysical Modeling Of 2022 November 23 Gölyaka-Düzce Earthquake, Şükrü Onur Karaca, Gülteki̇n Erten, Batuğhan Yikmaz, Seli̇m Özalp
Dinsar Analysis And Geophysical Modeling Of 2022 November 23 Gölyaka-Düzce Earthquake, Şükrü Onur Karaca, Gülteki̇n Erten, Batuğhan Yikmaz, Seli̇m Özalp
Turkish Journal of Earth Sciences
Numerous significant earthquakes have occurred along the North Anatolian Fault Zone (NAFZ), Türkiye’s most important fault zone. An earthquake with magnitude of Mw 6.0 occurred near the Gölyaka District of Düzce Province at 04:08 local time on November 23, 2022. According to the moment tensor solutions published by national and international seismology centers, the earthquake occurred at the northeast end of the Karadere segment within the NAFZ and was caused by a right-lateral strike-slip fault in the NW-SE direction. In this study, the differential interferometric synthetic aperture radar (InSAR) method was employed to analyze the deformation. Four Sentinel-1A complex datasets …
Landslide Susceptibility Assessment Of The Asi Watershed, Southern Türkiye, Senem Teki̇n, Adolfo Quesada Román, Tolga Çan
Landslide Susceptibility Assessment Of The Asi Watershed, Southern Türkiye, Senem Teki̇n, Adolfo Quesada Román, Tolga Çan
Turkish Journal of Earth Sciences
Landslides constitute recurrent natural hazards worldwide with greater socioeconomic impacts in low-income places. Landslide susceptibility studies are carried out to determine the potential for landslides to occur in a region, to predict possible risks in the future and to integrate this information into sustainable planning and management strategies. Slip-type landslides occur in limited areas of less than 1% of the Asi watershed in Southern Türkiye. Therefore, meaningful estimations cannot be made with classical statistical models. So, using the maximum entropy approach (MaxEnt), a technique for estimating based on a small number of observations, a landslide susceptibility assessment was constructed. The …
A New Species From Türkiye, Centaurea Turhanii (Cardueae, Asteraceae), Tuna Uysal, Meryem Bozkurt, Ergi̇n Hamzaoğlu
A New Species From Türkiye, Centaurea Turhanii (Cardueae, Asteraceae), Tuna Uysal, Meryem Bozkurt, Ergi̇n Hamzaoğlu
Turkish Journal of Botany
In this article, a new cornflower, Centaurea turhanii Uysal & Hamzaoğlu (Asteraceae) from Türkiye was described and reported. Morphological, karyological, and molecular analyses were used to reveal the taxonomic status of the new species with the species thought to be related to taxa. A modified determination key was submitted and its ecology and phenology were given.
A Phylogenetic Analysis And Delimitation Of Turanecio (Asteraceae: Senecioneae), Meryem Bozkurt, Tuna Uysal, Ergi̇n Hamzaoğlu
A Phylogenetic Analysis And Delimitation Of Turanecio (Asteraceae: Senecioneae), Meryem Bozkurt, Tuna Uysal, Ergi̇n Hamzaoğlu
Turkish Journal of Botany
Recently, Turanecio Hamzaoğlu was described as a new genus for the scientific world. Turanecio has been distributed as far as Asia, Iran, Caucasus, and Iraq. A phylogenetic analysis based on nrDNA and cpDNA gene regions was performed to determine the position of the genus within the subtribe Adenostylinae. Results from Bayesian and parsimony analyses of the nuclear and chloroplast DNA regions of the subtribe Senecioninae concordantly indicated that it is monophyletic and belongs to the Quadridentate group, with 4-lobed disc flowers. Nuclear DNA data revealed that some of the researched taxa should be transferred to Turanecio and some taxonomical classifications …
Investigation Of Earthquake Sequence And Stress Transfer In The Eastern Anatolia Fault Zone By Coulomb Stress Analysis, Hamdi̇ Alkan, Aydin Büyüksaraç, Özcan Bektaş
Investigation Of Earthquake Sequence And Stress Transfer In The Eastern Anatolia Fault Zone By Coulomb Stress Analysis, Hamdi̇ Alkan, Aydin Büyüksaraç, Özcan Bektaş
Turkish Journal of Earth Sciences
A devastating earthquake with a magnitude of (Mw = 7.7) occurred on February 06, 2023, in the Pazarcık segment of the Eastern Anatolian Fault Zone, which has not shown major earthquake activity for a long time. On the same day, another earthquake with a magnitude of (Mw = 7.6) occurred in Ekinözü-Elbistan (Kahramanmaraş) in the northwest. Three more earthquakes with magnitudes of Mw = 6.6, Mw = 5.9, and ML = 5.7 occurred on the same day, and significant damage, loss of life, and property occurred in 11 provinces and districts. A sixth earthquake occurred with Mw = 6.4 magnitude …
Preliminary Results Of The Great Kahramanmaraş 6 February 2023 Earthquakes (Mw 7.7 And 7.6) And 20 February 2023 Antakya Earthquake (Mw 6.4), Eastern Türkiye, Şule Gürboğa, Önder Kayadi̇bi̇, Hafi̇ze Akilli, Serap Arikan, Sevi̇lay Tan
Preliminary Results Of The Great Kahramanmaraş 6 February 2023 Earthquakes (Mw 7.7 And 7.6) And 20 February 2023 Antakya Earthquake (Mw 6.4), Eastern Türkiye, Şule Gürboğa, Önder Kayadi̇bi̇, Hafi̇ze Akilli, Serap Arikan, Sevi̇lay Tan
Turkish Journal of Earth Sciences
The first MW 7.7 and second MW 7.6 Kahramanmaraş earthquakes were the strongest tectonic events in Eastern Türkiye since the MW 7.9 Erzincan earthquake in 1939. The first and second events occurred on the Pazarcık and Çardak segments of the East Anatolian Fault System, respectively. A subsequent significant earthquake of MW 6.4 occurred in the Antakya fault zone. We summarize preliminary earthquake data and share our previous field observations to better understand the mechanism and provide scientific consequences for future investigations and layout planning. After combining the field observations, kinematic analysis of fault surfaces, investigations of orthophotos, characteristics of mainshocks, …
Surface Rupture During The 6th Of February 2023 Mw 7.6 Elbistan-Ekinözü (Kahramanmaraş) Earthquake: Implications For Fault Rupture Dynamics Along The Northern Branch Of East Anatolian Fault Zone, Mustafa Softa, Fi̇kret Koçbulut, Eli̇f Akgün, Ercan Aksoy, Hasan Sözbi̇li̇r, Orhan Tatar, Volkan Karabacak, Çağlar Özkaymak, Mehmet Utku, Özkan Cevdet Özdağ, Recep Çakir, Ahmet Demi̇r, Gökhan Arslan
Surface Rupture During The 6th Of February 2023 Mw 7.6 Elbistan-Ekinözü (Kahramanmaraş) Earthquake: Implications For Fault Rupture Dynamics Along The Northern Branch Of East Anatolian Fault Zone, Mustafa Softa, Fi̇kret Koçbulut, Eli̇f Akgün, Ercan Aksoy, Hasan Sözbi̇li̇r, Orhan Tatar, Volkan Karabacak, Çağlar Özkaymak, Mehmet Utku, Özkan Cevdet Özdağ, Recep Çakir, Ahmet Demi̇r, Gökhan Arslan
Turkish Journal of Earth Sciences
On the 6th of February 2023, Mw 7.7 Pazarcık (Kahramanmaraş) and Mw 7.6 Ekinözü (Kahramanmaraş) earthquakes that occurred in Türkiye are devastating earthquake series that filled the existing seismic gaps on East Anatolian Fault Zone on the same day. The first Mw 7.7 earthquake caught most people in their sleep and 9 h later, a second one was triggered, ending up with more than 50k death toll, widespread damage to buildings, and massive landslides. This study presents the surface rupture geometry and coseismic displacement characteristics determined with field observations immediately after February 6, 2023, Ekinözü (Kahramanmaraş, Türkiye) earthquake (Mw 7.6). …
Tepehan Rockslide: A Large-Scale Earthquake-Induced Geological Structure Formed By Mw:7.8 Kahramanmaraş (Pazarcık) Earthquake, Türkiye, Ökmen Sümer
Turkish Journal of Earth Sciences
Three devastating and powerful earthquakes hit the southeastern and eastern parts of Turkey and the northestern part of Syria in February of 2023, causing many earthquake-induced slope movements. One of these major mass movements is called the “Tepehan Rockslide”, which was formed by the first Mw: 7.8 earthquake on February 6th, 2023 at Pazarcık (Kahramanmaraş) located in the Altınözü district of Hatay province. The rockslide involved the movement of Middle Miocene basement rocks that consist of clayey limestone, marl, and fine-grained clastic sedimentary rocks. The morphogenetic evaluation of the structure reveals that the Tepehan Rockslide is a very rapidly developed …
Response Of Water Resources To The Kahramanmaraş Earthquakes (Mw 7.7 And Mw 7.6) That Occurred On February 6, 2023, On The East Anatolian Fault Zone (Türkiye), Celaletti̇n Şi̇mşek, Görkem Akinci, Okan Fistikoğlu, Kerem Canli, Hasan Sözbi̇li̇r, Azi̇ze Ayol, Efem Bi̇lgi̇ç
Response Of Water Resources To The Kahramanmaraş Earthquakes (Mw 7.7 And Mw 7.6) That Occurred On February 6, 2023, On The East Anatolian Fault Zone (Türkiye), Celaletti̇n Şi̇mşek, Görkem Akinci, Okan Fistikoğlu, Kerem Canli, Hasan Sözbi̇li̇r, Azi̇ze Ayol, Efem Bi̇lgi̇ç
Turkish Journal of Earth Sciences
On February 6, 2023, two destructive earthquakes of 7.7 MW and 7.6 MW occurred in Pazarcık (Kahramanmaraş) and Elbistan (Kahramanmaraş) at 04:17 and 13:24 hours, respectively. These earthquakes caused a surface rupture with a total length of 450 km in the region with an average displacement of 3 m between the Arabian and Anatolian plates. This study was conducted to investigate the physical deformation of the aquifer system and the current water quality characteristics in the affected region utilizing field observations and on-site analysis of water sources and tap water. The study revealed significant physical changes in the karstic springs …
Soil Liquefaction And Subsidence Disaster In İskenderun Related To The 6 February 2023 Pazarcık (Mw: 7.7) And 20 February Defne (Mw: 6.4) Earthquakes, Türkiye, Hüseyi̇n Öztürk, Craig A. Davis, İbrahi̇m Kuşku, Süleyman Dalğiç, Cem Kasapçi, Muharrem Alper Şengül
Soil Liquefaction And Subsidence Disaster In İskenderun Related To The 6 February 2023 Pazarcık (Mw: 7.7) And 20 February Defne (Mw: 6.4) Earthquakes, Türkiye, Hüseyi̇n Öztürk, Craig A. Davis, İbrahi̇m Kuşku, Süleyman Dalğiç, Cem Kasapçi, Muharrem Alper Şengül
Turkish Journal of Earth Sciences
The Mw 7.7 Pazarcık earthquake on February 06, 2023, struck southern Türkiye, causing typical liquefaction along the shores of İskenderun Bay. This liquefaction was characterized by lateral spreading, subsidence, and flooding. Subsidence-triggered sand ejecta, water flows, and opening cracks were identified in areas spanning approximately 2 km in length and 300 m in width. Based on coastal references such as lighthouses or harbor platforms, settlements of 0.8 m and lateral spreading of 0.4% were recorded along the coastal zone following the Pazarcık earthquake. According to camera recordings, liquefaction-related water and silty sand outflows occurred 29 min after the earthquake. The …
Lithography-Free Highly Sensitive Detection Of Glucose Based On Colloidal Spheres, Habibe Durmaz
Lithography-Free Highly Sensitive Detection Of Glucose Based On Colloidal Spheres, Habibe Durmaz
Turkish Journal of Physics
Diabetes has emerged as a global health crisis, with a substantial increase in prevalence and associated healthcare costs. The urgency for early diagnosis to prevent complications has fueled research into advanced biosensing technologies. Plasmonic sensors, leveraging localized surface plasmon resonance (LSPR), have gained prominence for their sensitivity. This study explores a metamaterial-based sensor platform comprising nanospheres fabricated through colloidal lithography. A comprehensive numerical and experimental analysis of the designed metamaterial-based perfect absorber is presented, focusing on the spectral response at the resonance frequency of 525 nm. Finite-difference time-domain (FDTD) simulations reveal the field and charge distributions, enabling a systematic exploration …
The Effect Of Parity, Breastfeeding History, And Duration On Clinical And Pathological Characteristics Of Breast Cancer Patients, Naziye Ak, Zeynep Tuz, Esra Aydin, Ferhat Ferhatoğlu, Murat Sari, Nail Paksoy, İzzet Doğan, Anıl Yildiz, Rian Di̇şçi̇, Pınar Mualla Sai̇p
The Effect Of Parity, Breastfeeding History, And Duration On Clinical And Pathological Characteristics Of Breast Cancer Patients, Naziye Ak, Zeynep Tuz, Esra Aydin, Ferhat Ferhatoğlu, Murat Sari, Nail Paksoy, İzzet Doğan, Anıl Yildiz, Rian Di̇şçi̇, Pınar Mualla Sai̇p
Turkish Journal of Medical Sciences
The study is aimed to determine the relationship between the delivery and breastfeeding history of the patients andthe clinicopathological properties of breast cancer.Materials and methods: A questionnaire was utilized for the study, which included the age of diagnosis, the number of children at thetime of diagnosis, the age of the children, and the breastfeeding period of each child.Results: The study included 828 patients. The median age at diagnosis was 47 years for parous women and 42 years for nonparouswomen (p < 0.001). The tumor size of the patients diagnosed within the breastfeeding period was significantly larger compared to theother patients. Estrogen and progesterone receptor positivity were lower in patients diagnosed during breastfeeding. Additionally, themean number of positive lymph nodes, dissected lymph nodes, and positive lymph node/dissected lymph node ratio in parous andbreastfed patients with a nonmetastatic disease were statistically significantly higher in multivariable analysis than those patients whowere nulliparous and have not breastfed.Conclusion: Breast cancer is seen at a later age in patients who are parous than those who have never given birth. Patients who areparous and have breastfed tend to present with a higher stage of the disease.
Comparison Of Nonlinear Models For Predicting Live Weight Growth Curves In Lambproduction Of Kıvırcık And Karacabey Merino, Vasfi̇ye Kader Esen, Orhan Karadağ, Cengi̇z Elmaci, Seli̇m Esen
Comparison Of Nonlinear Models For Predicting Live Weight Growth Curves In Lambproduction Of Kıvırcık And Karacabey Merino, Vasfi̇ye Kader Esen, Orhan Karadağ, Cengi̇z Elmaci, Seli̇m Esen
Turkish Journal of Veterinary & Animal Sciences
To achieve sustainable lamb production, it is crucial to determine the optimal slaughter age for maximum economic efficiencyand have a comprehensive understanding of breed characteristics. This study focuses on evaluating different nonlinear models todetermine the optimal slaughter age for Karacabey Merino and Kıvırcık lambs, renowned for their early development and superiormeat quality, respectively. The dataset comprised age-related live weight data from 98 lambs, including 36 female and 15 male Kıvırcıklambs, as well as 33 female and 14 male Karacabey Merino lambs. Six models, namely, negative exponential, Brody, Gompertz, logistic,Bertalanffy, and Richards were utilized to analyze the data. The model parameters …
Exploring The Photocatalytic And Photodynamic Effects Of Bodipy-Linked Titanium Dioxide Nanoparticles, Seda Demi̇rel Topel
Exploring The Photocatalytic And Photodynamic Effects Of Bodipy-Linked Titanium Dioxide Nanoparticles, Seda Demi̇rel Topel
Turkish Journal of Chemistry
This study aimed to investigate the photocatalytic and photodynamic actions of a 2,6-diiodinated-BODIPY (2,6-diI2-Bod) photosensitizer (PS) covalently linked to TiO2 nanoparticles (NPs). The TiO2 NPs were synthesized utilizing the hydrothermal technique, yielding an average particle size of 4–5 nm as ascertained by transmission electron microscopy and 6.4 nm as determined by dynamic light scattering measurements. The integration of the nonsoluble Bod PS to TiO2 NPs provided increased dispersibility in physiological media, making it more applicable to photodynamic therapy applications. Bod-TiO2 NPs exhibited moderate efficiency of 56.9% in singlet oxygen generation. Additionally, the photocatalytic behavior of the TiO2 NPs was evaluated …
Bromination And Conversion Of Tetrahydro-1h-Indene To Bisoxirane With A New Approach: Synthesis, Structural Characterization By Spectroscopic And Theoretical Methods, And Biological Analysis Supported By Dft And Docking, Raşi̇t Fi̇kret Yilmaz, Sultan Erkan, Sali̇h Ökten, Ahmet Tutar, Ertan Şahi̇n
Bromination And Conversion Of Tetrahydro-1h-Indene To Bisoxirane With A New Approach: Synthesis, Structural Characterization By Spectroscopic And Theoretical Methods, And Biological Analysis Supported By Dft And Docking, Raşi̇t Fi̇kret Yilmaz, Sultan Erkan, Sali̇h Ökten, Ahmet Tutar, Ertan Şahi̇n
Turkish Journal of Chemistry
In this study, a new method for synthesizing diepoxides is proposed. Tetrahydroindene 1 was brominated with NBS in the presence of LiClO4 and acetic acid, resulting in the formation of dibromodiacetate derivatives 2 and 3. Treatment of compounds 2 and 3 with NaOH in methanol produced a mixture of diepoxides 4 and 5. Additionally, direct bromination of tetrahydro-1H-indene yielded tetrabromo octahydroindene isomers 6 and 7. The structures of the compounds were characterized using spectroscopic techniques such as 1H NMR, 13C NMR, APT, COSY, and XRD. The new method provides an easy and selective route to access epoxides for the synthesis …
Accelerated Iron Valence Cycling In Fenton System Using Activated Hydrogen Enhanced By Mil-100(Fe) Modified By Nano-Pd0 Particle, Yun-Dong Wang, Yi-Jun Chen, Mei-Na Cheng, Xin Liu
Accelerated Iron Valence Cycling In Fenton System Using Activated Hydrogen Enhanced By Mil-100(Fe) Modified By Nano-Pd0 Particle, Yun-Dong Wang, Yi-Jun Chen, Mei-Na Cheng, Xin Liu
Turkish Journal of Chemistry
In this paper, a novel Fenton reaction system which was called MHACF-MIL-100(Fe) was constructed. In this system, based on active hydrogen-accelerated FeIII reduction, the hydroxyl radical was continuously produced with a trace amount of total iron. The MIL-100(Fe) modified with the nano-Pd0 particle could be used to activate the H2. Under normal temperature and pressure, the target organic pollutants, such as sulfamethazine and 4-chloro phenol, could be degraded fast. In the condition of initial aqueous solution pH 3, 2 g L–1 dosage of MIL-100(Fe) catalyst loaded with nano-Pd0, Pd/MIL-100(Fe), 20 mM 30 wt% hydrogen peroxide, 25 μM ferrous chloride and …
Polypyrrole Fabricated Laponite Rd Conductive Nanocomposites: Influence Of Grafting Efficiency On Structural And Conductive Properties, Shafiq Ur Rehman, Shaista Taimur, Asif Raza, Tariq Yasin
Polypyrrole Fabricated Laponite Rd Conductive Nanocomposites: Influence Of Grafting Efficiency On Structural And Conductive Properties, Shafiq Ur Rehman, Shaista Taimur, Asif Raza, Tariq Yasin
Turkish Journal of Chemistry
In the present work novel conductive organic-inorganic nanocomposites were produced by grafting of pyrrole monomer onto silanized Laponite RD utilizing emulsion graft polymerization. Influence of some important factors like concentration of monomer, initiator and surfactant were investigated on grafting efficiency. Grafting of polypyrrole chains onto modified Laponite RD was verified by Fourier transform infrared spectroscopy (FT-IR). Scanning electron microscope (SEM) revealed the spherical particles of nanocomposite with average diameter of 271.5 nm. XRD pattern showed that molecular framework of pure polypyrrole almost remains same in nanocomposite. Surface area and pore volume of Laponite RD, measured by Brunauer-Emmett-Teller (BET) analysis, was …
Phytochemical Investigation On The Aerial Parts Of Veratrum Versicolor F. Viride Nakai And Their Biological Activities, Seong Su Hong, Jae Yeon Lee, Yeon Woo Jeong, Ji Eun Lee, Yun-Hyeok Choi, Wonsik Jeong, Eun-Kyung Ahn, Chun Whan Choi, Il Ho Ahn, Joa Sub Oh
Phytochemical Investigation On The Aerial Parts Of Veratrum Versicolor F. Viride Nakai And Their Biological Activities, Seong Su Hong, Jae Yeon Lee, Yeon Woo Jeong, Ji Eun Lee, Yun-Hyeok Choi, Wonsik Jeong, Eun-Kyung Ahn, Chun Whan Choi, Il Ho Ahn, Joa Sub Oh
Turkish Journal of Chemistry
Veratrum spp. have traditionally been used in folk medicine to treat various pathologies. In this study, nine compounds, comprising one simple phenolic compound (1), three stilbenoids (2–4), and five flavonoids (5–9), were isolated from the aerial parts of Veratrum versicolor f. viride Nakai. The structures of these compounds were elucidated by spectroscopic analyses and comparison with reported data. Together, all reported compounds were isolated from V. versicolor f. viride for the first time in the study. Among them, two flavone aglycone tricetins (7 and 9) have never been isolated from the genus Veratrum or the family Melanthiaceae. The ethanol extract …
Optimum Pyrolysis Conditions To Prepare The Most Crystalline Boron Carbide Powder From Boric Acid–Mannitol Complex Ester, Abdullah Devri̇m Pekdemi̇r, Müşerref Önal, Yüksel Sarikaya
Optimum Pyrolysis Conditions To Prepare The Most Crystalline Boron Carbide Powder From Boric Acid–Mannitol Complex Ester, Abdullah Devri̇m Pekdemi̇r, Müşerref Önal, Yüksel Sarikaya
Turkish Journal of Chemistry
A weak acidic complex ester (CE) in solid form was prepared by a condensation reaction between very weak boric acid (BA: H3BO3) and (D)-mannitol (MA: C6H14O6) by the molar ratio of BA/MA = 2. A boron carbide (B4C) precursor was obtained from heating of the CE at 400 °C for 4 h. The precursor was pyrolyzed under argon flow in the interval of 1300–1550 °C for 4 h and at 1400 °C for 1–4 h, respectively. The materials were examined using several techniques such as X-ray diffraction analysis, thermal analysis, scanning electron microscopy, particle size distribution, and nitrogen adsorption/desorption. The …
Synthesis Of Silane- And Quaternary Ammonium-Bearing Copolymers And Application As A Coating Resin On Cotton Fabric, Ayşe Marti̇n, Nazgül Güler, İlknur Yerli̇, Hande Hançer, Tüli̇n Özbek, Tarik Eren
Synthesis Of Silane- And Quaternary Ammonium-Bearing Copolymers And Application As A Coating Resin On Cotton Fabric, Ayşe Marti̇n, Nazgül Güler, İlknur Yerli̇, Hande Hançer, Tüli̇n Özbek, Tarik Eren
Turkish Journal of Chemistry
In this study, silane and quaternary ammonium functional methacrylate monomers were synthesized and used to construct a copolymer using an emulsion polymerization technique to control the reaction rate. The copolymer was then designed using different ratios of silane and quaternary ammonium groups to investigate the relationship between the structure and properties. The presence of the ethoxy silane group in the copolymer series provided covalent bonding through the silanol group onto cotton fabric. The presence of cationic groups also helped to cover the fabric surface. After coating the cotton textile fabric, the resistance of the dye on the fabric surface to …
Poly(Vinyl Alcohol)/Zsm-5 Zeolite Mixed Matrix Membranes For Pervaporation Dehydration Of Ethanol And N-Propanol, Ji Ting Wang, Zhen Huang, Ya Tong Zhu, Si Ning Wang
Poly(Vinyl Alcohol)/Zsm-5 Zeolite Mixed Matrix Membranes For Pervaporation Dehydration Of Ethanol And N-Propanol, Ji Ting Wang, Zhen Huang, Ya Tong Zhu, Si Ning Wang
Turkish Journal of Chemistry
In this study, mixed matrix membranes (MMMs) composed of poly(vinyl alcohol) (PVA) and porous ZSM-5 zeolite are thoroughly investigated for concentrating alcohols of ethanol and n-propanol via dewatering pervaporation. The effects of the zeolite content (10–30 wt.%), feed composition (5–30 wt.% water), and feed temperature (50–90 °C) on the pervaporation flux/separation factor and component permeance/selectivity of these MMMs are examined in detail. These MMMs achieve higher separation efficiency and pervaporation flux than their pure PVA counterparts as expected, even if the dehydration results strongly depend on the pervaporation conditions. The disparity in pervaporation performances acquired for different alcohol solutions may …
Extraction/Transportation Of Co2+ Metal Ions With Bis(2-Ethylhexyl) Phosphate Dissolved In Kerosene Using A Multidropped Liquid Membrane Technique, Volkan Demi̇rel, Ramazan Donat
Extraction/Transportation Of Co2+ Metal Ions With Bis(2-Ethylhexyl) Phosphate Dissolved In Kerosene Using A Multidropped Liquid Membrane Technique, Volkan Demi̇rel, Ramazan Donat
Turkish Journal of Chemistry
The transport properties of Co2+ ions from the aqueous donor phase to aqueous acceptor phase with the recently developed multidroplet liquid membrane (MDLM) extraction system were studied. This system serves as a continuous process for the transportation of ions and requires fewer reagents for starting and conducting the procedure. Moreover, the procedure results in fewer waste chemicals and mixtures in comparison to traditional extraction methods. During extraction, bis(2-ethylhexyl) phosphate (D2EHPA) was used as a carrier material and 5% potassium thiocyanate (KSCN) solution was used to obtain a colored complex for UV-Vis detection. By means of several experiments, the optimum D2EHPA …
Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül
Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül
Turkish Journal of Chemistry
Technological devices are mostly manufactured by conductive and semiconductive materials. As advancement in the last decades, carbon nanomaterials have been explored in electrical/electronic technology due to their unique performances for manufacturing developing, and prudential miniaturized and flexible electrical/electronic devices. In the era of sustainable and clean carbon technology; renewable, alternative, biodegradable, and eco-friendly new carbon resources are required. Biomass could be the answer to offer inspiring carbon allotropes from nature to be suitable for developing electrical/electronic devices. In this article, deriving of the technological carbonaceous material from biomass, studies although they are very limited in the literature on obtaining the …