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An Overview Of Sodium-Ion Batteries As Next-Generation Sustainable Electrochemicaldevices Beyond The Traditional Lithium-Ion Framework, Gamzenur Özsi̇n
An Overview Of Sodium-Ion Batteries As Next-Generation Sustainable Electrochemicaldevices Beyond The Traditional Lithium-Ion Framework, Gamzenur Özsi̇n
Turkish Journal of Chemistry
The rise in the popularity of electric vehicles and portable devices has boosted the demand for rechargeable batteries, withlithium-ion (Li-ion) batteries favored for their superior energy and power density. However, supply strains and sustainability issues aredriving the search for alternatives. Postlithium technologies, particularly sodium-ion (Na-ion) batteries, are gaining attention for theirpromising potential and similarity to Li-ion technology. While efforts are still needed to enhance the energy and power density as wellas the cycle life of Na-ion batteries to replace Li-ion batteries, these energy storage devices present significant advantages in terms ofsustainability, theoretical capacity, and intrinsic safety features. Through this paper, …
Simultaneous Determination Of Sunset Yellow And Tartrazine In Real Samples On An N-Butylamine-Graphite/Polyaminophenol Composite Electrode, Mürşi̇de Ceren Afşar, Zekerya Dursun
Simultaneous Determination Of Sunset Yellow And Tartrazine In Real Samples On An N-Butylamine-Graphite/Polyaminophenol Composite Electrode, Mürşi̇de Ceren Afşar, Zekerya Dursun
Turkish Journal of Chemistry
A composite electrode was fabricated for simultaneous determination of sunset yellow (SY) and tartrazine (Tz) in foods andsyrup. It is based on n-butylamine intercalation into graphite and then dropped on a poly (4-aminophenol)/glassy carbon electrode(GCE). The electrode surface morphologies, chemistry, and electrical properties were identified by scanning electron microscopy(SEM), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy (RS), and electrochemical impedance spectroscopy (EIS). Thenew composite electrode significantly increased the electrochemical response of SY and Tz relative to a bare GCE. The peak currentof SY and Tz increased linearly depending on their concentrations from 0.006 μmol L–1 to 1.0 μmol L–1 (r = …
Enhancing Salt Tolerance And Yield Potential In Cotton: Insights From Physiological Responses, Genetic Variability, And Heterosis, Muhammad Mubashar Zafar, Abdul Razzaq, Zunaira Anwar, Aqsa Ijaz, Muhammad Zahid, Muhammad Shahid Iqbal, Ghulam Farid, Mahmoud F. Seleiman, Rana Qammar Uz Zaman, Abdur Rauf, Xuefei Jiang
Enhancing Salt Tolerance And Yield Potential In Cotton: Insights From Physiological Responses, Genetic Variability, And Heterosis, Muhammad Mubashar Zafar, Abdul Razzaq, Zunaira Anwar, Aqsa Ijaz, Muhammad Zahid, Muhammad Shahid Iqbal, Ghulam Farid, Mahmoud F. Seleiman, Rana Qammar Uz Zaman, Abdur Rauf, Xuefei Jiang
Turkish Journal of Agriculture and Forestry
Soil salinity is a growing global concern, necessitating the development of salt-tolerant cotton cultivars to enhance the utilization of salt-affected soils and boost crop productivity. Salt tolerance is regulated by a complex interplay of genetic and physiological factors involving multiple genes. To investigate the genetic basis of salt stress tolerance, eight parental genotypes (four lines and four testers) and their 16 hybrid combinations were evaluated under normal and salt stress conditions (15 dS m⁻¹). Data were collected on various traits including the plant height (PH), number of bolls per plant (NBP), boll weight (BW), lint percentage (LP), seed cotton yield …
Landslides Triggered By The 6 February 2023 Kahramanmaraş Earthquakes (Türkiye), Sultan Kocaman, Si̇nem Çeti̇nkaya, Nazli Tunar Özcan, Gi̇zem Karakaş, Veysel Emre Karakaş, Candan Gökçeoğlu
Landslides Triggered By The 6 February 2023 Kahramanmaraş Earthquakes (Türkiye), Sultan Kocaman, Si̇nem Çeti̇nkaya, Nazli Tunar Özcan, Gi̇zem Karakaş, Veysel Emre Karakaş, Candan Gökçeoğlu
Turkish Journal of Earth Sciences
On February 6th, 2023, a sequence of devastating earthquakes hit the south and southeastern part of Türkiye. Numerous secondary hazards were triggered in the region, including thousands of landslides. This study investigated the landslides triggered by the 6 February 2023 Kahramanmaras Earthquakes. On the February 7th, the General Directorate of Mapping, Türkiye initiated several aerial photogrammetric flights and continued for several days. Although the adverse meteorological conditions affected the image quality, valuable data with a nominal resolution of 25 cm could be produced over an area of 108,627 km2. By comparing post-earthquake aerial orthophotos with pre-earthquake imagery stored in archives, …
Imaging Fault Geometries In The Upper Crust Using High-Resolution Earthquakehypocenters In The Germencik Geothermal Field, Western Türkiye, Onur Tan
Turkish Journal of Earth Sciences
The Germencik geothermal field with 240 °C fluid temperature is one of the most important energy production areas located at the westernmost end of the Büyük Menderes Graben (western Türkiye). The northern boundary faults of the graben have a dip angle larger than 50° and have listric characteristics. In this brief study, the earthquake activity between 2007 - 2024 in the Germencik geothermal field is improved with the double-difference inversion method to image the deep normal fault planes down to 20 km of the crust. Considering the steeply southward dipping boundary faults in the graben, probable listric normal faults in …
Geological Characterization Of The Breccia Corallina (Marmor Sagarium) Quarries In Northwest Asia Minor, Murat Yilmaz, Hakan Elçi̇, Serdar Akgündüz, Ati̇ye Tuğrul, Göksel Dursun
Geological Characterization Of The Breccia Corallina (Marmor Sagarium) Quarries In Northwest Asia Minor, Murat Yilmaz, Hakan Elçi̇, Serdar Akgündüz, Ati̇ye Tuğrul, Göksel Dursun
Turkish Journal of Earth Sciences
The province of Bilecik is one of the leading block stone production regions in Northwest Asia Minor, where natural stone quarrying has been carried out since ancient times. Natural stones with different patterns have been produced in the block stone quarries in this region. The natural stones produced from this region were used in Italy and Istanbul during the Roman period and in the construction of many historical buildings in Istanbul during the Ottoman period. The best known of these natural stones is Breccia Corallina (Marmor Sagarium), a brecciated limestone with ivory-colored clasts and coral red cement. In this study, …
Mineralogy And Geochemistry Of Copper Slags From The Roman Imperial Period:Implications For The Type And Technology Of Smelting Furnaces Indereköy Ancient Copper Mine (Thrace Region, Türkiye), Yi̇ği̇t Kurt
Turkish Journal of Earth Sciences
The Strandja Mountains in the northwestern part of Turkey host porphyry and skarn type mineralizations and ancient slag heaps, which are the residues of ancient metallurgical processes. Ancient smelting furnaces were established near the skarn type mineralization zones and the ores were processed. Charcoal were used as fuel in these furnaces. Tenorite mineral was detected in the mineralogical analyses of the slags by XRD and it was determined that the furnaces were heated above 1000 °C. When the distribution of SiO2 in the slags was examined according to different end members, it was determined that the melting temperatures were in …
Geochronological And Isotopic Data From The Adakitic Dodurga Pluton (Central Pontides, N Türkiye): New Insights For The Geodynamic Evolution Of The Northern Neotethys, Okay Çi̇men, Mehmet Ali̇ Gücer, Antonio Simonetti, Fati̇h Karaoğlan
Geochronological And Isotopic Data From The Adakitic Dodurga Pluton (Central Pontides, N Türkiye): New Insights For The Geodynamic Evolution Of The Northern Neotethys, Okay Çi̇men, Mehmet Ali̇ Gücer, Antonio Simonetti, Fati̇h Karaoğlan
Turkish Journal of Earth Sciences
The Dodurga Pluton is located within the Central Pontides (northern Türkiye) and, has a SW-NE elongation, and consists of granodiorite and dacite porphyry. Previous studies have suggested that this pluton is Triassic in age, and its whole-rock geochemical systematics are consistent with those from adakitic magmatic occurrences rather than the classic arc granitoid suite. This study reports the first time in-situ/whole-rock radiogenic isotopic (Sr, Nd and Pb) and mica/amphibole Ar-Ar age data to evaluate better its petrogenetic-geodynamic evolution and chemical nature of mantle source(s). Unlike previous data, combined new in-situ zircon U-Pb yield Late Cretaceous crystallization ages of 84.2±0.9 Ma …
Kinematics And Age Of The Afyon Zone In The Akhisar Region, Western Türkiye, Tali̇p Güngör, İsmai̇l İşi̇ntek, Erhan Akay, Cüneyt Akal, Altuğ Hasözbek, Ahmed Erbi̇l, Axel Gerdes
Kinematics And Age Of The Afyon Zone In The Akhisar Region, Western Türkiye, Tali̇p Güngör, İsmai̇l İşi̇ntek, Erhan Akay, Cüneyt Akal, Altuğ Hasözbek, Ahmed Erbi̇l, Axel Gerdes
Turkish Journal of Earth Sciences
In western Anatolia, to the south of the İzmir-Ankara Suture, Menderes Massif, Cycladic Blueschists, Afyon Zone and Bornova Mélange form the main tectonic belts from structurally bottom to top. In the Akhisar region, the Akhisar Nappe consists of Hasköy Formation, below, and Görenez Limestone, above. The Hasköy Formation is composed of a metaclastic sequence with metarhyolite intercalations (237.4 ± 1.1 Ma, zircon LA-ICP-MS) and recrystallized limestone lenses, and it gradually passes upward into late Norian-Early Jurassic Görenez Limestone. New radiogenic data from metarhyolites of the Hasköy Formation and fossil determinations from recrystallized limestones of the Görenez Limestone show that the …
Characterization And Provenance Analysis Of The Architectural Building Stones At Thestratonikeia Theater In Yatağan, Muğla, Southwest Türkiye, With Determination Of Itsconstruction History Through Osl, Tamer Koralay, Eren Şahi̇ner, Bi̇lal Söğüt, Tunç Sezgi̇n, Yusuf Kağan Kadioğlu
Characterization And Provenance Analysis Of The Architectural Building Stones At Thestratonikeia Theater In Yatağan, Muğla, Southwest Türkiye, With Determination Of Itsconstruction History Through Osl, Tamer Koralay, Eren Şahi̇ner, Bi̇lal Söğüt, Tunç Sezgi̇n, Yusuf Kağan Kadioğlu
Turkish Journal of Earth Sciences
Stratonikeia, a city in the interior of the Caria region, is located at Eskihisar settlement within the borders of Yatağan town of Muğla city. The ancient city’s foundation dates back to 5000 BC, making it one of the oldest settlements in southwest Turkey. It is strategically located between the Inner Aegean and Eastern Mediterranean regions. Due to its location, the city has always been important during its history. The Greek type of theater, which is the main topic of this paper, is one of the most remarkable structures known to date from the Hellenistic period and is made of marble …
The Role Of Α-Inequalities In Examining The Singular Version Of The Big Bang Model, Samane Ijadi, S. Mansour Vaezpour, Mehdi Shabibi, Shahram Rezapour
The Role Of Α-Inequalities In Examining The Singular Version Of The Big Bang Model, Samane Ijadi, S. Mansour Vaezpour, Mehdi Shabibi, Shahram Rezapour
Turkish Journal of Mathematics
In this article, by extending Friedmann's equation, we propose a singular fractional differential system for the Big Bang model. In this model, the rate of increase in the size of the universe tends to infinity at time near to zero and causes the emergence of a singular differential equation,which physically justifies the near-infinity energy of the universe in the near-zero volume of the universe in the early moments of the Big Bang. Then, we investigate this type of strong singular boundary value problem, by using $\alpha$-inequalities. In the sequel, some examples, describe the main results. Moreover, we present numerical and …
Asymptotic Behavior Of The Kirchhoff Index For Square Lattice With Boundary Conditions, Fati̇h Ecevi̇t, Arzu Boysal
Asymptotic Behavior Of The Kirchhoff Index For Square Lattice With Boundary Conditions, Fati̇h Ecevi̇t, Arzu Boysal
Turkish Journal of Mathematics
We determine leading asymptotic behavior of the Kirchhoff index for the square lattice under free, cylindrical and toroidal boundary conditions. Our results provide correct forms of the eleven false theorems/results published in the following papers: L. Ye, On the Kirchhoff index of some toroidal lattices, Linear Multilinear Algebra, 59:6 (2011), 645--650; J.-B. Liu, X.-F. Pan, J. Cao, X. Huang, The Kirchhoff index of toroidal meshes and variant networks, Math. Probl. Eng., Article ID 286876, 8 pages (2014); J.-B. Liu, X.-F. Pan, A unified approach to the asymptotic topological indices of various lattices, Appl. Math. Comput., 270 (2015), 62--73.
Properties Of Frontier, Exterior And Border In Picture Topological Spaces, Shanmugasundharam Durga, Lakshmanadas Vidyarani, Mandarasalam Vigneshwaran, Tomasz Witczak
Properties Of Frontier, Exterior And Border In Picture Topological Spaces, Shanmugasundharam Durga, Lakshmanadas Vidyarani, Mandarasalam Vigneshwaran, Tomasz Witczak
Turkish Journal of Mathematics
The paper is dedicated to picture sets. They are crisp version of Cuong's picture fuzzy sets (just like intuitionistic sets introduced by Coker are crisp version of intuitionistic fuzzy sets). We have already defined several basic topological notions in this framework and we have analyzed its algebra. Now we continue our research. We introduce the notions of border, frontier and exterior. Many properties are studied. Moreover, we point out that there are some important differences between classical and non-classical approach.
Inverse Ordered Semigroups, Michael Tsingelis
Inverse Ordered Semigroups, Michael Tsingelis
Turkish Journal of Mathematics
Ένα στοιχείο x μιας διατεταγμένης ημιομάδας [[EQUATION]] ονομάζεται αντίστροφο στοιχείο του [[EQUATION]]if [[EQUATION]]και [[EQUATION]]. Μια αντίστροφη διατεταγμένη ημιομάδα είναι μια διατεταγμένη ημιομάδα S για την οποία κάθε στοιχείο του S έχει ένα αντίστροφο στοιχείο και τα αντίστροφα στοιχεία οποιουδήποτε στοιχείου του S βρίσκονται στην ίδια συνδεδεμένη συνιστώσα του διαγράμματος Hasse της σχέσης τάξης του. Παρουσιάζουμε ιδιότητες που ικανοποιούνται από αντίστροφα διατεταγμένες ημιομάδες και χαρακτηρίζουμε αντίστροφα διατεταγμένες ημιομάδες με βάση την έννοια της κανονικότητας των διατεταγμένων ημιομάδων, το σύνολο των αδυναμιών τους και τις σχέσεις του Green. Επίσης αποδεικνύουμε ότι η αντιστρεψιμότητα των διατεταγμένων ημιομάδων διατηρείται από ομομορφισμούς.
On Minimal Hypersurfaces In Euclidean Spaces And Riemannian Manifolds, Josef Mikeš, Sergey Stepanov, Irina Tsyganok
On Minimal Hypersurfaces In Euclidean Spaces And Riemannian Manifolds, Josef Mikeš, Sergey Stepanov, Irina Tsyganok
Turkish Journal of Mathematics
In this paper, we present the conditions under which minimal and stable minimal hypersurfaces are as hyperplanes in Euclidean spaces ands a totally geodesic submanifolds in Riemannian manifolds.
A Novel Mu-Metal Based Weak Magnetic Energy Harvester For Self-Powered Monitoring Of Power Grid Assets, Arsalan Habib Khawaja, Hassan Pervaiz, Dongsheng Cai, Jian Li, Qi Huang
A Novel Mu-Metal Based Weak Magnetic Energy Harvester For Self-Powered Monitoring Of Power Grid Assets, Arsalan Habib Khawaja, Hassan Pervaiz, Dongsheng Cai, Jian Li, Qi Huang
Turkish Journal of Electrical Engineering and Computer Sciences
This paper presents a novel magnetic field driven contactless energy harvester with improved flux concentration capabilities for potential utilization in Power system monitoring where stray magnetic field is abundant and readily available. The designed harvester employs multilayered Mu-Metal based cone shaped core to maximize magnetic flux density. To achieve the final design, this work investigates magnetic flux concentration ability of various geometries and material properties in magnetic flux conditions typical to overhead 11 kV power distribution circuits. Impact of layers in core-coil region of harvesting coil on magnetic flux concentration is evaluated by means of Finite Element analysis. Resultantly, the …
Advanced Prediction Of Events And Temporal Expressions In Medical Text Using The Jena Api: Integrating Ontologies And Deep Learning, Hafida Tiaiba, Lyazid Sabri, Okba Kazar
Advanced Prediction Of Events And Temporal Expressions In Medical Text Using The Jena Api: Integrating Ontologies And Deep Learning, Hafida Tiaiba, Lyazid Sabri, Okba Kazar
Turkish Journal of Electrical Engineering and Computer Sciences
The automatic recognition of medical concepts and temporal expressions in narrative clinical text enhances the utility of electronic health records (EHRs) and supports clinical decision-making and research. However, challenges arise due to the complexity of medical language, ambiguity of terms, and variability in expression. To address these issues, the use of medical ontologies significantly improves data management in healthcare. A novel approach integrates various medical ontologies covering drugs, symptoms, diseases, anatomy, disease drivers, and food, and with convolutional neural networks (CNNs) -including Standard, Transposed, and Separable convolution models (CONSEPTR)- to extract both medical events (e.g., clinical departments, treatments, problems) and …
Machine Learning Models Approach For The Quantitative Classification Of Ferricyanide Compound Using Electrochemical Detection With Cpe-Fe3o4nps, Süleyman Aşir, Nemah Abu Shama, Najya Maroof Saleem, Devri̇m Kayali, Kami̇l Di̇mi̇li̇ler
Machine Learning Models Approach For The Quantitative Classification Of Ferricyanide Compound Using Electrochemical Detection With Cpe-Fe3o4nps, Süleyman Aşir, Nemah Abu Shama, Najya Maroof Saleem, Devri̇m Kayali, Kami̇l Di̇mi̇li̇ler
Turkish Journal of Electrical Engineering and Computer Sciences
Most common electrochemical analysis techniques used to evaluate enzymes, proteins, and heavy metals over a wide potential range include electrochemical impedance EIS, differential pulse voltammetry DPV, and square wave voltammetry SQWV. Machine leaning algorithms MLA are employed to classify the Potassium ferricyaniyde K3Fe(CN)6 concentrations using a modified carbon paste electrode CPE embedded with iron (II, III) oxide (Fe3O4) NPs. The CV, DPV, and SQWV voltametric data collected from all K3Fe(CN)6 concentrations were used as input data to the machine learning algorithms. Signaling current of K3Fe(CN)6 concentrations improved at Fe3O4 modified with nanoparticles NPs CPE in a comparison with the unmodified …
Balancing Anarchy And Efficiency: Partial Team Formations And Learning In Potential Games, Muhammed Sayin
Balancing Anarchy And Efficiency: Partial Team Formations And Learning In Potential Games, Muhammed Sayin
Turkish Journal of Electrical Engineering and Computer Sciences
Non-cooperative multi-agent learning, focusing on individual rationality (anarchy), often falls short in achieving system-wide efficiency in potential games, a class of games with applications in decentralized control and optimization. On the other hand, cooperative approaches prioritize system efficiency but often via global coordination, which could be impractical, e.g., for large-scale and less controlled environments. To address this dilemma, we propose a novel framework that introduces partial team formations, allowing team members with shared objectives to coordinate their actions while maintaining team-wise rationality for improved system-wide efficiency without the burden of global coordination. We model such interactions as a multi-team game …
Local Dynamic Analysis Of The Covid-19 Mathematical Model Based On Discrete-Time Predator-Prey Population Model, Fi̇gen Kangalgi̇l, Ni̇lüfer Topsakal, Özge Kuzucu
Local Dynamic Analysis Of The Covid-19 Mathematical Model Based On Discrete-Time Predator-Prey Population Model, Fi̇gen Kangalgi̇l, Ni̇lüfer Topsakal, Özge Kuzucu
Turkish Journal of Mathematics
In this article, the local dynamics of a discrete-time Covid-19 pandemic model based on the Lotka Volterra model with topological classifications, bifurcation analysis and chaos control are investigated. It is shown that under some parametric conditions, the discrete-time Covid-19 pandemic model has two equilibrium points. With linear stability theory, local dynamics are investigated with topological classifications about the equilibrium points of the discrete-time Covid-19 epidemic model. In addition, the existence of a Neimark-Sacker bifurcation at the internal equilibrium point is proved and this bifurcation is analysed using explicit criteria. Furthermore, the chaos in the discrete Covid-19 pandemic model is also …
Generalization Of Dual Numbers And Dual Euclidean 3-Space, Şükran Duygu Soylu, Harun Bariş Çolakoğlu, Mustafa Özdemi̇r
Generalization Of Dual Numbers And Dual Euclidean 3-Space, Şükran Duygu Soylu, Harun Bariş Çolakoğlu, Mustafa Özdemi̇r
Turkish Journal of Mathematics
In this study, we consider the generalized dual numbers and determine their algebraic and geometric properties. Then we generalize the well-known D3 module and introduce the generalized dual Euclidean 3-space with its scalar product and norm. After determining the conditions for being a unit generalized dual Euclidean vector, we derive the generalized Euclidean Study map, which states that there is a bijective correspondence between directed lines of the space and the elements of the unit generalized dual Euclidean sphere. Finally, we define the dual Euclidean angle between two generalized dual Euclidean vectors.
A Content-Based Recommender System For The Uav Caching In The Field Of Entertainment In Fog Computing, Elham Darbanian, Mohsen Nickray
A Content-Based Recommender System For The Uav Caching In The Field Of Entertainment In Fog Computing, Elham Darbanian, Mohsen Nickray
Turkish Journal of Electrical Engineering and Computer Sciences
The Unmanned Aerial Vehicle (UAV) can be used as good flying base stations to cache popular content and follow a user mobility pattern, to help them in a suitable services. Conventional edge caching algorithms often prioritize cache contents with higher popularity. Nevertheless, the cache capacity of mobile devices is restricted, and diverse clients may have expansive varieties in content inclination designs. In this manner, the performance and effectiveness of the cache will be so constrained without great strategies. The composition of recommender system and edge caching is considered as a new research topic, which is used to reduce cost and …
Estimates Of The Numerical Radius Utilizing Various Function Properties, Vuk Stojiljkovic, Mehmet Gürdal
Estimates Of The Numerical Radius Utilizing Various Function Properties, Vuk Stojiljkovic, Mehmet Gürdal
Turkish Journal of Mathematics
Numerous inequalities of the vector and numerical radius types have been found. We achieved several extensions of the well-known numerical radius type inequalities by using the function [[EQUATION]] described in the publication by Stojiljkovi\'{c} and Dragomir in [30] and convexity characteristics with standard operator theory approaches. In particular, the following integral type numerical radius inequality has been obtained, that is [[EQUATION]]
Nearly Toric Varieties Of Type A, Mahi̇r Bi̇len Can, Nestor Fernando Diaz Morera
Nearly Toric Varieties Of Type A, Mahi̇r Bi̇len Can, Nestor Fernando Diaz Morera
Turkish Journal of Mathematics
A notion of a nearly toric variety is introduced. The examples of nearly toric varieties in the context of Schubert varieties are discussed. In particular, combinatorial characterizations of the smooth and singular nearly toric Schubert varieties are found. Furthermore, the counts and generating series are determined. Additionally, a connection between Dyck paths and a certain family of nearly toric Schubert varieties is established.
Differentiation Of Mullus Barbatus And Mullus Surmuletus (Perciformes, Mullidae) From Turkish Waters Of The Mediterranean Sea Using Otolith Shape Analyses, Semra Saygin
Turkish Journal of Zoology
Red mullet (Mullus barbatus) and surmullet (Mullus surmuletus) are valuable components of the commercial fishery industry in the Mediterranean Sea in Türkiye. To date, morphological and genetic characteristics have been used to distinguish these species. This study aimed to determine whether it was possible to distinguish between the two species using the morphometric features of their sagittal otoliths. Sagittal otoliths were subjected to elliptic Fourier analysis, wavelet analysis, and analysis of otolith shape indices for 117 specimens from the Mediterranean Sea coast of Türkiye (Mullus barbatus: 53 individuals; Mullus surmuletus: 64 individuals). Overall, canonical discriminant analysis (CDA) demonstrated strong discrimination …
Analysis And Optimization Of The Adsorption Of Lead Ions On A New Material Based On Silica Synthesized From Blast Furnace Slag, Toufik Chouchane, Ouahida Khireddine, Sabiha Chouchane, Mohamed Tayeb Abedghars, Hazem Meradi
Analysis And Optimization Of The Adsorption Of Lead Ions On A New Material Based On Silica Synthesized From Blast Furnace Slag, Toufik Chouchane, Ouahida Khireddine, Sabiha Chouchane, Mohamed Tayeb Abedghars, Hazem Meradi
Turkish Journal of Chemistry
A novel silica-based material (SBM), synthesized from chemically, thermally, and mechanically treated blast furnace slag (TBFS), was examined for its batch-mode lead adsorption capacity, based on various parameters. Physico-chemical examinations revealed that the formulation of the new material (SBM) consists mainly of silica, which represents 81.79% of its total composition. After modification, the measured specific surface area changed significantly, from 275.8 to 480.13 m2/g, with a point of zero charge (PZC) of approximately 3.4 on the pH scale. The experiment revealed that the driving factors (contact time, stirring speed, solution pH, temperature, and initial concentration) greatly influenced the improvement of …
Understanding Ammonia's Role In Mitigating Concentration Polarization In Anion-Exchange Membrane Electrodialysis, Abdallah Timmaoui, Mahmoud Ferhat, Nesri̇ne Souad Ferhat, Ahmed Hamdi
Understanding Ammonia's Role In Mitigating Concentration Polarization In Anion-Exchange Membrane Electrodialysis, Abdallah Timmaoui, Mahmoud Ferhat, Nesri̇ne Souad Ferhat, Ahmed Hamdi
Turkish Journal of Chemistry
In processes such as electrodialysis, the applied electrical potential is constrained by concentration polarization at the membrane/solution interface. This polarization, which intensifies at higher current densities, impedes ion transport efficiency and may lead to problems such as salt precipitation, membrane degradation, and increased energy consumption. Therefore, understanding concentration polarization is essential for enhancing membrane performance, improving efficiency, and reducing operational costs. This study investigates the impact of ammonia buffer (NH₄⁺/NH₃) on sulfate ion transport through anion-exchange membranes, with a particular focus on limiting current density and concentration polarization under constant current conditions. Our findings demonstrate that ammonia effectively eliminates concentration …
Synthesis, Characterization, And Investigation Of Photochemical And In Vitro Properties Of Novel Zn(Ii) Phthalocyanine, Yasemi̇n Bayğu Yildiz, Ni̇lgün Kabay, Burak Yildiz, İpek Ömeroğlu, Mahmut Durmuş, E. Riza Karagür, Hakan Akça, Çağri Ergi̇n, Yaşar Gök
Synthesis, Characterization, And Investigation Of Photochemical And In Vitro Properties Of Novel Zn(Ii) Phthalocyanine, Yasemi̇n Bayğu Yildiz, Ni̇lgün Kabay, Burak Yildiz, İpek Ömeroğlu, Mahmut Durmuş, E. Riza Karagür, Hakan Akça, Çağri Ergi̇n, Yaşar Gök
Turkish Journal of Chemistry
In our work, a new non-peripheral zinc(II) phthalocyanine bearing octa carboxylic acid ethyl ester derivative substituted triazole attached propylmercaptothiobenzylmercapto derivative was synthesized by the tetramerization reaction of phthalonitrile. The photochemical in vitro photodynamic activity of zinc(II) phthalocyanine (ZnPc-I), such as human non-small cell lung carcinoma cell lines, was investigated in this study. The singlet oxygen generation property of novel zinc(II) phthalocyanine (ZnPc-I) was also examined due to the significantly high singlet oxygen quantum yield of ZnPc-I (ΦΔ = 0.66). The antiproliferative effects of ZnPc-I were also investigated on A549 and H1299 cell lines, our results demonstrate that the ZnPc-I has …
Preparation Of Manganese-Doped Carbon Quantum Dots@Halloysite Nanotubes Composites Films For Advanced Uv Shielding Properties, Xiao Zhang, Bin Wang
Preparation Of Manganese-Doped Carbon Quantum Dots@Halloysite Nanotubes Composites Films For Advanced Uv Shielding Properties, Xiao Zhang, Bin Wang
Turkish Journal of Chemistry
The development of Ultraviolet (UV) shielding materials are of great importance to protect human's health concerns and prevent the degradation of organic matters. However, the synthesis of highly efficient UV shielding polymer nanocomposites is currently limited by the agglomeration of inorganic anti-UV nanoparticles (NPs) within the polymer matrix and limited absorption spectrum of UV shielding agents. In this study, highly effective manganese doped carbon quantum dots@halloysite nanotubes composites (Mn-CDs@HNTs/PAS) were successfully synthesized by loading manganese doped carbon quantum dot (Mn-CDs) into UV shielding effective halloysite nanotubes (HNTs) via solvothermal method, followed by polymerization modification. The results show that inorganic NPs …