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Application Of Inverse Gas Chromatography In The Surface Characterization Of Diethanolamine Modified Polystyrene Based Polymer, Ayşegül Çi̇ğdem Adigüzel, Burak Korkmaz, Fati̇h Çakar, Bahi̇re Fi̇li̇z Şenkal, Özlem Cankurtaran
Application Of Inverse Gas Chromatography In The Surface Characterization Of Diethanolamine Modified Polystyrene Based Polymer, Ayşegül Çi̇ğdem Adigüzel, Burak Korkmaz, Fati̇h Çakar, Bahi̇re Fi̇li̇z Şenkal, Özlem Cankurtaran
Turkish Journal of Chemistry
In the present work, diethanol amine modified polystyrene based polymer (PVBC-Diethanol amine) was synthesized and characterized, then surface properties of the polymer were examined by inverse gas chromatography method at infinite dilution. The retention diagrams obtained based on the interaction of polar and nonpolar probes with the polymer were drawn over a temperature range from 30 to 55 °C. Through the diagrams, the dispersive component of the surface free energy, γSD of the polymer surface, and the specific enthalpy of adsorption, ΔHAS , of probes on the polymer were also calculated. Lewis acid, KA, and Lewis base, KD, parameters of …
Gc-Ms Analyses And Bioactivities Of Essential Oil Obtained From The Roots Ofchrysopogon Zizanioides (L.) Roberty Cultivated In Giresun, Turkey, Derya Efe, Mustafa Karaköse, Ayça Aktaş Karaçeli̇k, Bengü Ertan, Mehmet Emi̇n Şeker
Gc-Ms Analyses And Bioactivities Of Essential Oil Obtained From The Roots Ofchrysopogon Zizanioides (L.) Roberty Cultivated In Giresun, Turkey, Derya Efe, Mustafa Karaköse, Ayça Aktaş Karaçeli̇k, Bengü Ertan, Mehmet Emi̇n Şeker
Turkish Journal of Chemistry
The essential oils (EOs) constituents have trade importance due to their bioactivities. In this research, the essential oil of the roots of Chrysopogon zizanioides (L.) Roberty cultivated in Giresun was obtained by hydrodistillation. Then, the chemical composition and biological activities of Chrysopogon zizanioides root essential oil (CEO) were studied. Thirty compounds were identified by gas chromatography-mass spectrometry (GC-MS) and the major compounds were determined as isobutyl-angelate (11.15%), α-muurolene (10.56%), α-cedrene (8.42%), α-patchoulene (8.10%), and ethylene brassylate (7.49%). The antimicrobial effect of CEO was investigated against pathogenic bacteria and fungus. Minimal inhibition concentration (MIC) was determined 31.25 μg/mL against C. albicans …
Investigation Of Pzt-5h And Pzt-8 Type Piezoelectric Effect On Cycling Stability On Si-Mwcnt Containing Anode Materials, Mehbare Doğrusöz, Muhammed Taha Demi̇rkan, Rezan Demi̇r Çakan
Investigation Of Pzt-5h And Pzt-8 Type Piezoelectric Effect On Cycling Stability On Si-Mwcnt Containing Anode Materials, Mehbare Doğrusöz, Muhammed Taha Demi̇rkan, Rezan Demi̇r Çakan
Turkish Journal of Chemistry
Silicon (Si) containing materials cannot be used in commercial lithium ion batteries due to the mechanical stress problem triggered by volume expansion during cycling. The high-volume change causes mechanical instability of Si anode materials during charging/discharging, resulting fast capacity fading. It is thought that piezoelectric materials can be a solution for the volume expansion problem because of their ability to generate electric field when pressure is applied on them. For this purpose, PZT-8 and PZT-5H type piezoelectric materials were mixed with silicon and multiwalled carbon nanotube (MWCNT) to obtain anode composites and tested electrochemically versus lithium metal. The piezoelectiric effect …
Chemical Composition And Biological Activities Of Essential Oils Of Two New Chemotypes Of Glebionis Cass., Hüseyi̇n Servi̇
Chemical Composition And Biological Activities Of Essential Oils Of Two New Chemotypes Of Glebionis Cass., Hüseyi̇n Servi̇
Turkish Journal of Chemistry
This paper includes the result of the first study of the chemical composition, antioxidant, antiinflammatory, and antidiabetic activities of the essential oils of Glebionis coronaria (L.) Cass. ex Spach and Glebionis segetum (L.) Fourr. from Turkey. In the current study, nine and twenty-eight constituents were determined in the essential oils of aerial parts of G. coronaria (GCE) (92.1%) and G. segetum (GSE) (90.0%), respectively. The main components were capillin (65.9%) in GCE, capillene (53.4%) in GSE. The essential oil compositions were evaluated and compared with previous researches. In the current study, the plants are classified as chemotypes of Glebionis species. …
Pyridine Substituted Bodipys: Synthesis, Characterization And Cholinesterease,α-Glucosidase Inhibitory, Dna Hydrolytic Cleavage Effects, Burak Barut, Hüseyi̇n Baş, Zekeri̇ya Biyiklioğlu
Pyridine Substituted Bodipys: Synthesis, Characterization And Cholinesterease,α-Glucosidase Inhibitory, Dna Hydrolytic Cleavage Effects, Burak Barut, Hüseyi̇n Baş, Zekeri̇ya Biyiklioğlu
Turkish Journal of Chemistry
In this study, the synthesis of new monostyryl (BDPY-2) and distyryl BODIPY dyes (BDPY-4, BDPY-5) containing pyridine groups has been reported for the first time. The acetylcholinesterase from Electrophorus electricus (AChE), butyrylcholinesterase from equine serum (BuChE), α-glucosidase from Saccharomyces cerevisiae and DNA hydrolytic cleavage actions of BDPY-2, BDPY-4, BDPY- 5 were investigated using various techniques. The results indicated that the compounds had varying inhibition properties against AChE, BuChE, and α-glucosidase. BDPY-4 was the most potent compound on AChE with IC50 of 54.78 ± 4.51 μM, and Lineweaver-Burk plots indicated that the compound is bound to a site other than the …
Characterization Of Extracts From Papaver Rhoeas And Potential Valorization Of Theseextracts In Dyeing Applications, Mohand Ouidir Boussoum, Rachida Ouldmokhtar, Abdelkader Ali Nehari, Beatrice George
Characterization Of Extracts From Papaver Rhoeas And Potential Valorization Of Theseextracts In Dyeing Applications, Mohand Ouidir Boussoum, Rachida Ouldmokhtar, Abdelkader Ali Nehari, Beatrice George
Turkish Journal of Chemistry
The aim of our work is to study the dyeing properties of extracts from natural sources such as Papaver rhoeas by modifying the conditions of the dyeing process, choosing other substrates that could be pretreated by innovative and environmentally friendly processes. The results obtained show a fairly high fixation of the extracts on the natural and artificial fibers. The use of mordants allowed the dye to be better fixed on the dyed fibers and to give several shades to the fabric. The rate of essential oil contained in Papaver rhoeas was considered important by the Clevenger process. Screening of extractive …
Enhancement Of Dispersion Stability Of Inorganic Additives Via Poly(Sodium-4-Styrenesulfonate) Treatment Geared To Hydrogel Applications, Fi̇li̇z Boran, Merve Okutan
Enhancement Of Dispersion Stability Of Inorganic Additives Via Poly(Sodium-4-Styrenesulfonate) Treatment Geared To Hydrogel Applications, Fi̇li̇z Boran, Merve Okutan
Turkish Journal of Chemistry
This study reports the preparation of poly(sodium-4-styrene sulfonate) (PSS) treated bentonite and clinoptilolite to prevent the agglomeration and sedimentation of these inorganic fillers during the preparation of hydrogel. For this purpose PSS treated fillers were prepared by using various techniques (dip and dry, hydrothermal, one-step ball milling and ultrasonication methods). The most suitable technique for preparing these PSS treated inorganic fillers (abbreviated as BP-dip and CP-dip) was the dip and dry method. BP-dip and CP-dip based polyvinyl alcohol/polyvinylpyrrolidone (PVA/PVP) composite hydrogels were prepared using the freeze/ thawing method after the addition of one of BP-dip and CP-dip inorganic fillers in …
Effect Of Current Density On The Microstructure And Morphology Of The Electrodepositednickel Coatings, Amel Boukhouiete, Saliha Boumendjel, Nour-El-Houda Sobhi
Effect Of Current Density On The Microstructure And Morphology Of The Electrodepositednickel Coatings, Amel Boukhouiete, Saliha Boumendjel, Nour-El-Houda Sobhi
Turkish Journal of Chemistry
The aim of this research work was to study the effect of deposition current density on microstructure and surface morphology of electrodeposited nickel coatings. For this purpose, nickel deposits have been synthesized by direct current from Watts bath without additive, to limit the incorporation of pollutants resulting from surface adsorption or electro-activity of these compounds. Nickel deposits have been investigated by scanning electron microscopy and X-ray diffraction. Cyclic voltammetry was also used to gain information on the general behavior of the deposition. The optimum conditions of deposition were established and the influence of current density on the grain size, surface …
Dft (Density Functional Theory) Studies On Cycloisomerization Of 15-Memberedtriazatriacetylenic Macrocycle, Mansooreh Movahedi, Nader Zabarjad Hiraz, Ali Ezabadi, Marjaneh Samadizadeh, Mohamad Reza Talei Bavil Olyai
Dft (Density Functional Theory) Studies On Cycloisomerization Of 15-Memberedtriazatriacetylenic Macrocycle, Mansooreh Movahedi, Nader Zabarjad Hiraz, Ali Ezabadi, Marjaneh Samadizadeh, Mohamad Reza Talei Bavil Olyai
Turkish Journal of Chemistry
The mechanism as well the stereochemistry of cascade cycloisomerization of 15-membered triazatriacetylenic macrocycle was investigated theoretically by using M062X/6-31+G(d,p) and M062X/LANL2DZ calculations. The results showed that the mechanism and outcome of the reaction depended on the absence and presence of a transition metal catalyst. So that, in thermal-induced condition, the reaction had to experience several suprafacial concerted reactions including Ene-reaction (ΔG#=35.38 kcal/mol), Diels-Alder cycloaddition (ΔG# = 17.16 kcal/mol), and sigmatropic H-shift rearrangement (ΔG# = 56.21 kcal/mol) to produce diastereoselective fused cis-tetracyclic aromatic bearing a pyrrole moiety by following kinetic considerations. Also, the [2+2+2] cycloaddition mechanism was neglected in thermal?induced conditions …
Cytotoxic And Apoptotic Effects Of Hypericum Androsaemum On Prostate Adenocarcinoma(Pc-3) And Hepatocellular Carcinoma (Hep G2) Cell Lines With Identification Of Secondarymetabolites By Lc-Hrms, Nurdan Yazici Bektaş, Ezgi̇ Ersoy, Mehmet Boğa, Tuğçe Boran, Ercan Çinar, Gül Özhan, Ahmet Ceyhan Gören, Esra Eroğlu Özkan
Cytotoxic And Apoptotic Effects Of Hypericum Androsaemum On Prostate Adenocarcinoma(Pc-3) And Hepatocellular Carcinoma (Hep G2) Cell Lines With Identification Of Secondarymetabolites By Lc-Hrms, Nurdan Yazici Bektaş, Ezgi̇ Ersoy, Mehmet Boğa, Tuğçe Boran, Ercan Çinar, Gül Özhan, Ahmet Ceyhan Gören, Esra Eroğlu Özkan
Turkish Journal of Chemistry
The study aims to determine the secondary metabolites of Hypericum androsaemum L. extracts by liquid chromatographyhigh resolution mass spectrometry (LC-HRMS), and investigate the antioxidant and cytotoxic activities of the plant. Cytotoxic activity was evaluated by MTT assay, and apoptosis induction abilities on human prostate adenocarcinoma (PC-3), and hepatocellular carcinoma (Hep G2) cell lines. Accordingly, major secondary metabolites were found as hederagenin (762 ± 70.10 μg/g) in the leaves dichloromethane (LD), herniarin (167 ± 1.50 μg/g) in fruit dichloromethane (FD), (-)-epicatechin (6538 ± 235.36 μg/g) in the leaves methanol (LM), (-)-epigallocatechin gallate (758 ± 20.46 μg/g) in the fruit methanol (FM), …
Synthesis Of Imidazo-1,4-Oxazinone Derivatives And Investigation Of Reaction Mechanism, Volkan Taşdemi̇r
Synthesis Of Imidazo-1,4-Oxazinone Derivatives And Investigation Of Reaction Mechanism, Volkan Taşdemi̇r
Turkish Journal of Chemistry
In this study, nine different C-2 aroyl imidazole derivatives were synthesized in a one pot reaction with two steps, and the reduction reactions of these derivatives with NaBH4 were carried out under mild conditions. Substitution reaction of obtained imidazo methanol derivatives with chloroacetylchloride reagent and ring reaction of substitution products were investigated. It was determined that 1,4-imidazoxazinone derivative was obtained as a result of the cyclization reaction. The intermediate products obtained during the cyclization reaction were isolated, and the path of the reaction under different conditions was discussed.
Supramolecular Solvents: A Review Of A Modern Innovation In Liquid-Phase Microextraction Technique, Muhammad Saqaf Jagirani, Mustafa Soylak
Supramolecular Solvents: A Review Of A Modern Innovation In Liquid-Phase Microextraction Technique, Muhammad Saqaf Jagirani, Mustafa Soylak
Turkish Journal of Chemistry
Supramolecular solvents (SUPRASs) have rapidly gained more attention as a potential substitute to organic solvents in the sample preparation and preconcentration process. The essential properties of SUPRAS solvents (e.g., multiple binding sites, different polarity microenvironments, the opportunity to tailor their properties, etc.) these qualities offer numerous opportunities to advance innovative sample preparation and pretreatment platforms compared to the traditional solvents. Among these qualities, certain importance is placed on theoretical and practical knowledge. That has assisted in making significant developments in SUPRAS that advance our understanding of the processes behind SUPRA'S formation. The SUPRA-solute interactions that drive extractions are explored in …
Glucosamine Derived Hydrothermal Carbon Electrodes For Aqueous Electrolyte Energy Storage Systems, Burcu Ünal, Rezan Demi̇r Çakan
Glucosamine Derived Hydrothermal Carbon Electrodes For Aqueous Electrolyte Energy Storage Systems, Burcu Ünal, Rezan Demi̇r Çakan
Turkish Journal of Chemistry
Nitrogen-doped porous hard carbons are synthesized by hydrothermal carbonization method (HTC) using glucosamine as biosource and treated at different carbonization temperatures in nitrogen environment (500, 750, 1000 °C). The electrochemical performances of hard carbons electrode materials for aqueous electrolyte sodium ion batteries are examined to observe the effect of two different voltage ranges (-0.8-0.0) V and (0.0-0.8) V in 1.0 M Na2SO4 aqueous electrolyte. The best electrochemical performances are acquired for the 1000 °C treated glucosamine (GA-1000) porous carbon sample that provides ~96 F/g capacitance value in the negative voltage range (between -0.8 and 0.0) V. The sodium diffusion coefficient …
Study On Potential Applications And Toxicity Analysis Of Green Synthesized Nanoparticles, Rajni Garg, Priya Rani, Rishav Garg, Nnabuk Okon Eddy
Study On Potential Applications And Toxicity Analysis Of Green Synthesized Nanoparticles, Rajni Garg, Priya Rani, Rishav Garg, Nnabuk Okon Eddy
Turkish Journal of Chemistry
Nanomaterials have garnered the significant interest of scientists owing to their technological as well as medical applications. In particular, metal and metal oxide nanoparticles have gained prominence because of their enhanced performance as compared to their bulk counterparts. Metal-supported nanomaterials are anticipated to make major contributions to solving today's most challenging issues, like energy harvesting and environmental remediation. The incorporation of nanoparticles into sensors has significantly enhanced their precision and selectivity. With the advent of green chemistry, green synthetic techniques have been prioritized for the synthesis of single and multicomponent nanomaterials. In the current review, we have addressed the multidimensional …
Cyclodextrin-Active Natural Compounds In Food Applications: A Review Of Antibacterial, Bingren Tian, Yumei Liu
Cyclodextrin-Active Natural Compounds In Food Applications: A Review Of Antibacterial, Bingren Tian, Yumei Liu
Turkish Journal of Chemistry
Many natural compounds have excellent activity against different bacteria. However, their food use to inhibit the bacteria is often limited by poor water solubility, or instability to light, heat, oxygen, and other environmental factors. Cyclodextrin combines with these natural compounds could not only overcome these shortcomings, but also increase the antibacterial ability of active compounds. This review focuses on the following aspects of active natural compounds in cyclodextrin-based food: the preparation, food applications, and their possible antibacterial mechanisms of different systems. Both cyclodextrin and its derivatives are able to selectively combine with different guest molecules, such as terpenes, phenols and …
One-Pot Synthesis Of Graphene Hydrogel-Anchored Cobalt-Copper Nanoparticles And Their Catalysis In Hydrogen Generation From Ammonia Borane, Ibtihel Zaier, Önder Meti̇n
One-Pot Synthesis Of Graphene Hydrogel-Anchored Cobalt-Copper Nanoparticles And Their Catalysis In Hydrogen Generation From Ammonia Borane, Ibtihel Zaier, Önder Meti̇n
Turkish Journal of Chemistry
We reported a facile one-pot synthesis of bimetallic CoCu nanoparticles (NPs) anchored on graphene hydrogel (GH-CoCu) as catalysts in hydrogen generation from the hydrolysis of ammonia borane (HAB). The presented novel one-pot method composed of the reduction of the mixture of graphene oxide, cobalt(II), and copper(II) acetate tetrahydrates by aqueous ethylene glycol solution in a teflon-coated stainless-steel reactor at 180 °C. The structure of the yielded GH-CoCu nanocatalysts was characterized by TEM, SEM, XRD, XPS, and ICP-MS. This is the first example of both the synthesis of bimetallic CoCu NPs anchored on GH and the testing of a hydrothermally prepared …
Green Dehydrogenation Of Dimethylamine Borane Catalyzed By Cheaply Copper(0) Nanocatalysts Without Any Stabilizer At Nearly Room Temperature, Ali̇ Özdemi̇r, Si̇bel Duman
Green Dehydrogenation Of Dimethylamine Borane Catalyzed By Cheaply Copper(0) Nanocatalysts Without Any Stabilizer At Nearly Room Temperature, Ali̇ Özdemi̇r, Si̇bel Duman
Turkish Journal of Chemistry
In this work, the findings of the work on the green dehydrogenation behavior of molten dimethylamine borane (DMAB) catalyzed by the precatalyst copper(II) acetylacetonate (Cu(acac)2) in solvent-free medium (green) at near room temperature (nRT, 30.0+0.1°C) were reported. Herein, a complete study has been presented, which includes the following steps: (i) synthesis and catalytic activity of Cu(0) NCats in solvent-free medium, (ii) determination of activation energy for Cu(0) NCats catalyzed green dehydrogenation of DMAB, (iii) demonstration of catalytic lifetime of Cu(0) NCats, (iv) test of isolability and reusability of Cu(0) NCats, (v) poisoning experiments using carbon disulfide on a per-active-copper-atom basis, …
Antiinflammatory Photodynamic Therapy Potential Of Polyoxyethylene-Substituted Perylene Diimide, Nitrocatechol, And Azo Dye, Özgül Hakli, Kasim Ocakoğlu, Furkan Ayaz
Antiinflammatory Photodynamic Therapy Potential Of Polyoxyethylene-Substituted Perylene Diimide, Nitrocatechol, And Azo Dye, Özgül Hakli, Kasim Ocakoğlu, Furkan Ayaz
Turkish Journal of Chemistry
Photodynamic therapy (PDT) applications enable light-controlled activation of drug candidates instead of their constitutive activities to prevent undesired side effects associated with their constant activities. A specific wavelength of light is utilized to enable electron mobility in the chemical structure, which results in differential activities that may alter cell viability and cellular functions. Canonical photodynamic therapy applications mostly focus on cytotoxicity-based antimicrobial and anticancer properties of the PDT agents. In this study, we focused on subtoxic concentrations of three different molecules containing polyoxyethylene group and examined their antiinflammatory activities on stimulated mammalian macrophages. Stimulated macrophages produce proinflammatory cytokines TNF and …
Structural, Surface Morphological, Optical And Electrical Properties Of Inxsey Thin Films, An Absorber Layer For Photovoltaic Cells Fabricated By M-Cbd Method Using Different Variables, Fati̇h Ünal, Serkan Demi̇r, Hasan Mammadov
Structural, Surface Morphological, Optical And Electrical Properties Of Inxsey Thin Films, An Absorber Layer For Photovoltaic Cells Fabricated By M-Cbd Method Using Different Variables, Fati̇h Ünal, Serkan Demi̇r, Hasan Mammadov
Turkish Journal of Chemistry
Mixed-phased InxSey thin film containing InSe, In2Se3 and In6Se7 phases was prepared by M-CBD method and characterized by X-ray diffraction, AFM, optical spectroscopy and J-V measurements. Structural, optical and electrical conductance properties were modified by annealing the films at different temperatures. Optical and morphological properties were also investigated dependently on temperature and concentration of cationic precursor solution. It has been observed with annealing that, the compositions of the phases changed, particle sizes increased, energy band gaps decreased and electrical conductivity increased. The photoconductivity of thin film was revealed by J-V measurements and slightly increased by annealing. From temperature-dependent J-V measurements, …
Novel Surfactant Stabilized Plga Cisplatin Nanoparticles For Drug Delivery Applications, Samra Umar, Manzar Zahra, Muhammad Akhter, Amir Waseem
Novel Surfactant Stabilized Plga Cisplatin Nanoparticles For Drug Delivery Applications, Samra Umar, Manzar Zahra, Muhammad Akhter, Amir Waseem
Turkish Journal of Chemistry
In the current study, cisplatin loaded (Poly(lactic-co-glycolicacid)) (PLGA) stabilized with 4-phenylphenacylbromide based surfactants nanoparticles were developed for drug delivery applications. For the course of this study four new 4-phenylphenacylbromide based compounds abbreviated as PA(C2)3, PA(C8)3, PAC16 and PAC18 have been synthesized by the reaction of 4-phenylphenacylbromide with various long chain amines. The new surfactants were characterized with 1H and 13C NMR and FTIR spectroscopy. The critical micelle concentration (CMC) of newly synthesized surfactants are in the range of 0.024-0.091 mM. The newly synthesized surfactants have been incorporated in PLGA based nanoparticles and are used for drug encapsulation and delivery of …
Determination Of Characterization, Antibacterial And Drug Release Properties Of Poss-Based Film Synthesized With Sol-Gel Technique, İdi̇l Karaca Açari, Süleyman Köytepe, Burhan Ateş, İsmet Yilmaz, Turgay Seçki̇n
Determination Of Characterization, Antibacterial And Drug Release Properties Of Poss-Based Film Synthesized With Sol-Gel Technique, İdi̇l Karaca Açari, Süleyman Köytepe, Burhan Ateş, İsmet Yilmaz, Turgay Seçki̇n
Turkish Journal of Chemistry
In the study, antibacterial film synthesis was aimed using sol-gel technique from POSS structure with various functional groups. For this purpose, antibacterial properties have been acquired by metronidazole to the films to be synthesized. The films obtained were coated on glass surface samples by dip coating method. Antibacterial activities of surface coated glass samples were observed in E.coli and S. aureus bacteria. Metronidazole release studies in the film samples were followed by UV spectrophotometer. It was observed that drug release reached 68.90% at the end of the 24th h. As a result, it is thought that the synthesized film will …
Study Of The Effectiveness Of A Presoaking Process For Reducing The Additives Migration From Babies Toys, Mohand Ouidir Boussoum, Aicha Kentaoui, Beatrice George, Stephane Dumarcay, Ahmed Boucherit, Hassiba Laribi Habchi
Study Of The Effectiveness Of A Presoaking Process For Reducing The Additives Migration From Babies Toys, Mohand Ouidir Boussoum, Aicha Kentaoui, Beatrice George, Stephane Dumarcay, Ahmed Boucherit, Hassiba Laribi Habchi
Turkish Journal of Chemistry
This research aims to study a process of steeping in the n-heptane, used for reducing the migration of additives contained initially in toys for babies plasticized with di-octylphtalate (DOP) based on poly (vinyl chloride) (PVC) and stabilized with epoxidized sunflower oil (ESO). Two formulations were carried out at different levels of DOP plasticizers (15% and 45%). The migration tests were conducted in the synthetic saliva in the absence and in the presence of α-amylase with or without agitation at 37° C for 1, 3, and 6 h. The migration phenomenon was studied on the basis of preliminary studies based on …
Microwave Irradiated Synthesis Of Schiff Bases Of 4-(Arylideneamino)-5-Alkyl-2,4-Dihydro-1,2,4-Triazole-3-Thione Containing 1,2,4-Triazole Segment, Mahdi Shirmohammadi, Saeid Souzangarzadeh, Dadkhoda Ghazanfari, Mohsen Ghodratbeigi, Mohammad Reza Akhgar
Microwave Irradiated Synthesis Of Schiff Bases Of 4-(Arylideneamino)-5-Alkyl-2,4-Dihydro-1,2,4-Triazole-3-Thione Containing 1,2,4-Triazole Segment, Mahdi Shirmohammadi, Saeid Souzangarzadeh, Dadkhoda Ghazanfari, Mohsen Ghodratbeigi, Mohammad Reza Akhgar
Turkish Journal of Chemistry
Novel compounds based on the 1,2,4-triazole skeleton were synthesized. A class of 4-amino-5-alkyl-4H-1,2,4-triazole-3- thione created by reaction of thiocarbohydrazide with long-chain aliphatic carboxylic acids, and then the Schiff bases were obtained in the media of heat and microwave waves, in the presence and the absence of a catalyst. Their chemical structures were assayed by elemental analysis, also device spectroscopic methods.
Puerarin-Coated Gold Nanoparticles (Pue-Aunps) Synthesized Via Green Synthetic Route: A New Colorimetric Probe For The Detection Of Ciprofloxacin, Tasneem Zehra, Faiqa Ahsan, Muhammad Ali Versiani, Sana Wahid, Sajid Jahangir, Muhammad Raza Shah
Puerarin-Coated Gold Nanoparticles (Pue-Aunps) Synthesized Via Green Synthetic Route: A New Colorimetric Probe For The Detection Of Ciprofloxacin, Tasneem Zehra, Faiqa Ahsan, Muhammad Ali Versiani, Sana Wahid, Sajid Jahangir, Muhammad Raza Shah
Turkish Journal of Chemistry
Puerarin-coated gold nanoparticles (PUE-AuNPs) synthesized via green synthetic route, a new colorimetric sensor, efficiently detected the ciprofloxacin (CP) in tap water and cow milk samples. The PUE-AuNPs were characterized by UV-visible, FTIR, AFM, and DLS techniques and were found to be spherical with an average size of approximately 19-20 nm. FTIR spectrum confirms that functional groups such as -OH, -C=O, -CO and -C=C were responsible for the reduction of gold (III) chloride trihydrate. These functional groups acted as capping agents to form AuNPs. The PUE-AuNPs sensor was proved to be selective and sensitive for the detection of CP through colorimetric …
The Hydrothermal Synthesis Of Blue-Emitting Boron-Doped Cqds And Its Application For Improving The Photovoltaic Parameters Of Organic Solar Cell, Tuğbahan Yilmaz
The Hydrothermal Synthesis Of Blue-Emitting Boron-Doped Cqds And Its Application For Improving The Photovoltaic Parameters Of Organic Solar Cell, Tuğbahan Yilmaz
Turkish Journal of Chemistry
In this work, boron-doped CQDs (B-CQDs) were synthesized by using boric acid, urea, and citric acid via hydrothermal method to use as a novel additive material for poly(3-hexylthiophene-2,5-diyl) (P3HT):[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) based organic solar cells. The OSCs with an inverted device structure were fabricated on titanium dioxide (TiO2) thin film. It was showed the crystallinity, morphological and optical properties of P3HT:PCBM films improved after B-CQDs additive. The best performance was obtained to be a 39.65% of FF, a 546 mV of Voc, an 8.606 mA cm-2 of Jsc after 3 vol.% B-CQDs addition in P3HT:PCBM blend. The power …
The Removal Of Chromium (Vi) From Tannery Waste Using Spirulina Sp. Immobilized Silica Gel, Nais Pinta Adetya, Uma Fadzilia Arifin, Emiliana Anggriyani
The Removal Of Chromium (Vi) From Tannery Waste Using Spirulina Sp. Immobilized Silica Gel, Nais Pinta Adetya, Uma Fadzilia Arifin, Emiliana Anggriyani
Turkish Journal of Chemistry
The use of microalgae biomass is an alternative solution to the problem of environmental pollution due to heavy metals, one of which is Cr metal in leather tanning liquid waste. However, the ability of biomass to adsorb heavy metals has limitations. Therefore, the algal biomass is immobilized with silica gel in order to obtain a stable structure. This research aims to study the absorption efficiency of Cr (VI) metal by the biomass of Spirulina sp. which is immobilized with silica gel from the tannery liquid waste. The preparation stages in this study were adsorbent preparation, immobilization of biomass with silica …
Synthesis, Characterization, Cox1/2 Inhibition And Molecular Modeling Studies On Novel 2-Thio-Diarylimidazoles, Zafer Şahi̇n, Meli̇ke Kalkan, Barkin Berk, Leyla Yurttaş, Ceysu Bender, Sevde Nur Bi̇lteki̇n Kaleli̇, Şeref Demi̇rayak
Synthesis, Characterization, Cox1/2 Inhibition And Molecular Modeling Studies On Novel 2-Thio-Diarylimidazoles, Zafer Şahi̇n, Meli̇ke Kalkan, Barkin Berk, Leyla Yurttaş, Ceysu Bender, Sevde Nur Bi̇lteki̇n Kaleli̇, Şeref Demi̇rayak
Turkish Journal of Chemistry
Heterocyclic compounds with diaryl substituents have been a milestone approach for selective cyclooxygenase 2 (COX 2) inhibition by bioisosteric replacements and modifications. It is also known that thiazole derivatives have different pharmacological activities. In this study, nine novel 2-[(1,5-diphenyl-1H-imidazole-2-yl)thio]-N-(thiazole-2-yl)acetamide derivatives (Compound 1-9) were synthesized via the reaction of 1,5-disubstitued phenyl-imidazole-2-thiole and N-thiazole acetamide. The inhibitory effects of COX-1 and COX-2 enzymes were tested for the synthesized compounds. Enzyme-ligand interactions of the most active compound on COX subtypes were elucidated by molecular modeling studies. The percent inhibitory effect for compound 1, which is the naked derivative among all the compounds, was …
A Flame Retardant-Hardener For Epoxy Resins: Synthesis, Structural, And Dft Studies Of The [Cu(H2nc2h4nh2)2 (H2o)Cl]Cl Complex, Borys Mykhalichko, Helen Lavrenyuk, Oleg Mykhalichko
A Flame Retardant-Hardener For Epoxy Resins: Synthesis, Structural, And Dft Studies Of The [Cu(H2nc2h4nh2)2 (H2o)Cl]Cl Complex, Borys Mykhalichko, Helen Lavrenyuk, Oleg Mykhalichko
Turkish Journal of Chemistry
The aqua-bis(ethylenediamine)-chloro-copper(II) chloride complex, [Cu(en)2 (H2O)(Cl)]Cl (1), was synthesized by direct interaction of CuCl2×2H2O with pepa (pepa is a polyethylenepolyamine containing ethylenediamine (en)). The crystalline complex 1 was characterized by IR spectra and structurally studied. Crystals of this complex consist of the [Cu(en)2(H2O)(Cl)] + discrete cations, whose Cu2+ ion is chelated by two en molecules. The Cu(II) coordination polyhedron has the shape of an elongated square bipyramid, in which four nitrogen atoms of the -NH2 groups of en molecules form the base of this bipyramid, and the oxygen atom of the water molecule and Cl- are in its apical positions. …
Novel Vic-Dioximes: Synthesis, Structure Characterization, And Antimicrobial Activity Evaluation, Dumitru Ureche, Ion Bulhac, Alexandru Ciocarlan, Daniel Roshca, Lucian Lupascu, Paulina Bourosh
Novel Vic-Dioximes: Synthesis, Structure Characterization, And Antimicrobial Activity Evaluation, Dumitru Ureche, Ion Bulhac, Alexandru Ciocarlan, Daniel Roshca, Lucian Lupascu, Paulina Bourosh
Turkish Journal of Chemistry
The vic-dioximes are compounds with various industrial uses and scientific applications. Many coordination compounds have been synthesized based on vic-dioximes. This study presents the synthesis and full characterization of two vic-dioximes based on dichloroglyoxime, p-aminobenzoic acid, and p-aminotoluene. Their structures were proved by IR, 1H, 13C and 15N NMR spectral analysis, and single crystal X-ray diffraction. One of the reported vic-dioximes, bis(di-p-aminotoluene)glyoxime mono-p-aminotoluene trihydrate showed good to moderate antimicrobial activity against both nonpathogenic gram-positive and gram-negative bacteria (Bacillus subtilis and Pseudomonas fluorescens), phytopathogenic (Xanthomonas campestris, Erwinia amylovora, E. carotovora) and the fungi (Candida utilis and Saccharomyces cerevisiae) at MIC - …
Preparation And Characterization Of Nano Mno-Cals As A Green Catalyst For Oxidation Of Styrene, Mahdi Arian, Hoda Mollabagher, Salman Taheri, Ali Zamanian, Seyed Amir Hossein Seyed Mousavi
Preparation And Characterization Of Nano Mno-Cals As A Green Catalyst For Oxidation Of Styrene, Mahdi Arian, Hoda Mollabagher, Salman Taheri, Ali Zamanian, Seyed Amir Hossein Seyed Mousavi
Turkish Journal of Chemistry
Hydrophilic nano MnO is shown to have significant stability in aqueous media for oxidation of styrene. Different catalysts have been used to synthesis styrene oxide, but MnO-CaL is considered the efficient and selective catalyst to produce styrene oxide. In general, this paper reported especial strategy for synthesis of novel nano MnO that stabilized with oleic acid in chloroform and changing nature of its stabilizer by exchanging oleic acid with lignosulfunate and displays its catalytic activity towards selective oxidation of styrene. The catalyst has shown good selectivity in oxidation of styrene by changing temperature. Finding the optimal conditions for reaction and …