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Some Bioactive Organotin(Iv) Derivatives With 3,4-Dichlorophenylacetic Acid: Synthesis, Spectroscopic Properties, And X-Ray Structure Of [Sn_4(C_4h_9)_8(Oocch_2c_6h_3cl_2)_4o_2], Muhammad Adeel Saeed, Muhammad Khawar Rauf, . Imtiaz-Ud-Din, Amin Badshah, Muhammad Zaeem Akhtar, Bushra Mirza Jan 2010

Some Bioactive Organotin(Iv) Derivatives With 3,4-Dichlorophenylacetic Acid: Synthesis, Spectroscopic Properties, And X-Ray Structure Of [Sn_4(C_4h_9)_8(Oocch_2c_6h_3cl_2)_4o_2], Muhammad Adeel Saeed, Muhammad Khawar Rauf, . Imtiaz-Ud-Din, Amin Badshah, Muhammad Zaeem Akhtar, Bushra Mirza

Turkish Journal of Chemistry

Some bioactive organotin(IV) derivatives of 3,4-dichlorophenylacetic acid (HL) were synthesized by reacting the ligand acid with various di- or tri-organotin compounds (in suitable mole ratios) in the presence of triethylamine. The structural investigation was carried out via multinuclear (^1H, ^{13}C, and ^{119}Sn) NMR, IR spectroscopy, and X-ray crystallography. The crystal structure of 4 comprises a central Sn_2O_2 core with O atoms bonded to 2 dibutylbis(3,4-dichlorophenylacetato)tin(IV) units. All the Sn atoms of 4 are essentially 5-coordinated in distorted trigonal-bipyramidal geometry. Some of the compounds exhibited significant antibacterial and antifungal activity.


Study Of Seasonal Influences On Algal Biodiversity In The River Yarqon (Central Israel) By Bio-Indication And Canonical Correspondence Analysis (Cca), Sophia Barinova, Moti Tavassi Jan 2009

Study Of Seasonal Influences On Algal Biodiversity In The River Yarqon (Central Israel) By Bio-Indication And Canonical Correspondence Analysis (Cca), Sophia Barinova, Moti Tavassi

Turkish Journal of Botany

In our research conducted in the River Yarqon during 2003-2006, we identified 313 taxa of algae and cyanobacteria belonging to 8 taxonomical divisions. Out of these 313 taxa, 268 taxa (85.6%) were indicators of environmental conditions that characterised the river water as alkaline with medium mineralisation. In the rainy and dry seasons the algal taxonomic compositions were very different, with prevailing diatoms in the winter and cyabobacteria and greens in summer. Bio-indication shows that the taxonomic preference for the self-purification process was more intensive during the rainy season, while the low level of river water in the dry season stressed …


Productive Replication Of Malacosoma Neustria Nucleopolyhedrovirus (Manenpv) In Md203 Cell Line, İsmai̇l Demi̇r, Nurten Gürel, Remzi̇ye Nalçacioğlu, İkbal A. İnce, Zi̇hni̇ Demi̇rbağ Jan 2009

Productive Replication Of Malacosoma Neustria Nucleopolyhedrovirus (Manenpv) In Md203 Cell Line, İsmai̇l Demi̇r, Nurten Gürel, Remzi̇ye Nalçacioğlu, İkbal A. İnce, Zi̇hni̇ Demi̇rbağ

Turkish Journal of Biology

A plaque-purified genotypic variant, derived from a field isolate of the Malacosoma neustria nucleopolyhedrovirus (ManeNPV) from Turkey was characterized based on in vitro replication properties in a cell line, Md203 derived from Malacosoma disstria. The life cycle of ManeNPV was studied based on the cytopathic effects (CPEs), polyhedral inclusion body (PIB) formation, budded virus (BV) production, viral DNA replication and polyhedrin protein expression in ManeNPV-infected Md203 cells. Infection of Md203 cells with ManeNPV resulted in cytopathic effects within 24 and 36 h post infection and most cells detachted from the bottom of the culture plate on the fourth day. Typical …


Comparative Susceptibilities Of Six Insect Cell Lines To Infection By Malacosoma Neustria Nucleopolyhedrovirus (Manenpv), İsmai̇l Demi̇r, Nurten Gürel, Remzi̇ye Nalçacioğlu, Zi̇hni̇ Demi̇rbağ Jan 2009

Comparative Susceptibilities Of Six Insect Cell Lines To Infection By Malacosoma Neustria Nucleopolyhedrovirus (Manenpv), İsmai̇l Demi̇r, Nurten Gürel, Remzi̇ye Nalçacioğlu, Zi̇hni̇ Demi̇rbağ

Turkish Journal of Biology

In this study, 6 lepidopteran cell lines derived from Trichoplusia ni (Tn5), Lymantria dispar (LdElta), Bombyx mori (Bm-5), Spodoptera frugiperda (Sf21), Spodoptera exigua (Se-1), and Choristoneura fumiferana (Cf-124T) were investigated for susceptibility to Malacosoma neustria nucleopolyhedrovirus (ManeNPV) isolated in Turkey. Infection of Malacosoma disstria (Md203) cell line by ManeNPV was used as a control. In ManeNPV-Md203 infection, polyhedral inclusion bodies (PIBs) were detected at 36 h p.i. and observed in all infected cells by 120 h p.i., and the infectious virus titer increased 10^3-fold. At 24 h p.i., the efficient replication of viral DNA was detected. In this study, we …


Spectroscopic Characterisation And Biological Applications Of Organotin(Iv) Derivatives Of 3-(N-Naphthylaminocarbonyl)-2-Propenoic Acid, Sajjad Ahmad, Moazzam H. Bhatti, Saqib Ali, Fiaz Ahmed Jan 2006

Spectroscopic Characterisation And Biological Applications Of Organotin(Iv) Derivatives Of 3-(N-Naphthylaminocarbonyl)-2-Propenoic Acid, Sajjad Ahmad, Moazzam H. Bhatti, Saqib Ali, Fiaz Ahmed

Turkish Journal of Chemistry

In an effort to develop new organotin materials for investigation and biocidal evaluation, a series of compounds with the general formula R_{4 - n}SnL_n (where R = CH_3, n-C_4H_9, C_6H_5, C_6H_5CH_2 and L = 3-(N-naphthylaminocarbonyl)-2-propenoic acid) were synthesised, and characterised by elemental analysis, IR, multinuclear (^1H, ^{13}C and ^{119}Sn) NMR, ^{119m}Sn Mössbauer spectroscopy and mass spectrometry. The biological activity of these compounds against various bacteria and fungi was investigated. All of the compounds were active against the fungi tested with a few exceptions. These compounds also showed significant antibacterial activity. LD_{50} data show that the investigated compounds have significant toxicity.


Synthesis, Spectroscopic (Ft-Ir, ^1h, ^{13}C, Mass Spectrometry), And Biological Investigation Of Five-Coordinated Germanium-Substituted Tricyclohexyl Antimony Dipropionates: Crystal Structure Of Tricyclohexylantimony Dibromide, Muhammad Kaleem Khosa, Muhammad Mazhar, Saqib Ali, Kieran C. Molloy, Sarim Dastgir, Farkhanda Shaheen Jan 2006

Synthesis, Spectroscopic (Ft-Ir, ^1h, ^{13}C, Mass Spectrometry), And Biological Investigation Of Five-Coordinated Germanium-Substituted Tricyclohexyl Antimony Dipropionates: Crystal Structure Of Tricyclohexylantimony Dibromide, Muhammad Kaleem Khosa, Muhammad Mazhar, Saqib Ali, Kieran C. Molloy, Sarim Dastgir, Farkhanda Shaheen

Turkish Journal of Chemistry

A series of five-coordinated germanium-substituted tricyclohexylantimony dipropionates have been synthesized and characterized by different instrumental techniques, such as elemental analyses, FT-IR, multinuclear NMR (^1H, ^{13}C) and mass spectrometry. These compounds have also been screened against different microbes and they showed good activity against different bacteria that was comparable to the reference drugs. The crystal structure of the precursor (C_6H_{11})_3SbBr_2 is reported here, which showed that the antimony atom in an asymmetric unit exists in trigonal bipyramidal geometry, having space group C2/c with the monoclinic crystal system.


^{1}H, ^{13}C, ^{119}Sn Nmr, Mass, Mössbauer And Biological Studies Of Tri-,Di- And Chlorodiorganotin(Iv) Carboxylates, Hajra Masood, Saqib Ali, Mohummad Mazhar, Saira Shahzadi, Khadija Shahid Jan 2004

^{1}H, ^{13}C, ^{119}Sn Nmr, Mass, Mössbauer And Biological Studies Of Tri-,Di- And Chlorodiorganotin(Iv) Carboxylates, Hajra Masood, Saqib Ali, Mohummad Mazhar, Saira Shahzadi, Khadija Shahid

Turkish Journal of Chemistry

The reaction of 2-[(2,3-dimethylphenyl)amino]benzoic acid (HL) with tri- and diorganotin(IV) chlorides yielded complexes of the type R_{3}SnL and R_{2}SnL_{2} (R = n-C_{4}H_{9}, C_{6}H_{5}, C_{6}H_{5}CH_{2}, n-C_{8}H_{17}). The compounds R_{2}SnClL were obtained by a redistribution reaction between R_{2}SnL_{2} and R_{2}SnCl_{2}. All the compounds were characterized by CHN analysis, infrared, multinuclear NMR, mass and Mössbauer spectroscopy. The possible mode of carboxylate group bonding in solid as well as in solution is proposed on the basis of infrared, Mössbauer and NMR (^{1}H, ^{13}C, ^{119}Sn) spectroscopy.


Cover And Contents Jan 2004

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.


Geographic Variations And Taxonomic Status Of Miniopterus Schreibersi (Kuhl, 1819) In Turkey (Chiroptera: Vespertilionidae), İrfan Albayrak, Şule Coşkun Jan 2000

Geographic Variations And Taxonomic Status Of Miniopterus Schreibersi (Kuhl, 1819) In Turkey (Chiroptera: Vespertilionidae), İrfan Albayrak, Şule Coşkun

Turkish Journal of Zoology

This study is a taxonomical revision of 257 specimens of Miniopterus schreibersi (Kuhl, 1819) collected from Turkey between 1974 and 1994. A total of 30 external and cranial measurements and weights and the ages of the specimens were determined. Diagnostic characters, habitat, and measurements of subspecies were recorded. The specimens collected in Turkey were evaluated by comparison with the nominate form distributed nearby, Miniopterus schreibersi pallidus Thomas, 1907, and synonyms. It was determined that both the nominate form and Miniopterus schreibersi pallidus exist in Turkey.


Use Of Baculovirus As Expression Vector In Biotechnology, Zihni Demi̇rbağ, A. Osman Beldüz, İsmail Demi̇r Jan 1998

Use Of Baculovirus As Expression Vector In Biotechnology, Zihni Demi̇rbağ, A. Osman Beldüz, İsmail Demi̇r

Turkish Journal of Biology

Variuos viral, bacterial, plant and animal proteins which are important for medicinal, industrial and agricultural aspects, have been synhesized via expression vector systems have great importance in biotechnology. Baculoviruses, used as a good model system in molecular biology studies, a biological control agent in agriculture and an expression vector for synthesis of important proteins, opened up a significant period for recombinant DNA technology and protein production. Desired foreign genes, code for various products such as drug, toxin and nutrient substances, can be replaced with viral genes which are not essasial for replication of baculovirus in cell culture. Priority and advantages …


Kinetic Studies Of The Thermal Decomposition Of Di- And Tri-Organotin Derivatives Of 1-Nitroso-2-Naphthol, Saqib Ali, Moazzam H. Bhatti, Sohail Mahmood, Muhammad Mazhar, M. Saleem Khalid, Nazar Hussain Jan 1998

Kinetic Studies Of The Thermal Decomposition Of Di- And Tri-Organotin Derivatives Of 1-Nitroso-2-Naphthol, Saqib Ali, Moazzam H. Bhatti, Sohail Mahmood, Muhammad Mazhar, M. Saleem Khalid, Nazar Hussain

Turkish Journal of Chemistry

The di- and tri-organotin complexes of general formula R$_2$SnL$_2$ and R$_3$SnL where R = C$_4$H$_9$, C$_6$H$_5$, C$_6$H$_5$CH$_2$, C$_6$H$_{11}$ and L=1-nitroso-2-naphthol, were subjected to thermal decomposition by means of thermogravimetry (TG). The decomposition occurred in steps and the kinetics of every set of reactions were determined using the method described by Coats and Redfern. These results were analysed to establish the decomposition kinetics and hence to calculate activation energies. The activation energies were also determined by applying the method described by Horowitz, which yielded comparable results.