Digital Commons Network^™

Impact Of Advection Process In Simulating The Dynamics Of Diffusion-Controlled Irreversible Fast/Moderate/Slow Bimolecular-Reactive Systems, Maruti Mudunuru, Kalyana Nakshatrala

Society of Engineering Science 51st Annual Technical Meeting Archive

Diffusion-controlled bimolecular reactions arise in various branches of natural sciences [1], chemically reacting systems [2], and contaminant transport [3]. Based on the kinetics of the chemical reaction, they are broadly classified in to three categories: fast, moderate, and slow [4]. Herein, we are interested in the dynamics of a (fast/moderate/slow) bimolecular reaction given by the following stoichiometric relationship [5]: nA A + nB B −→ nC C In this discussion, we shall present a computational framework to simulate the dynamics of an irreversible bimolecular advection–diffusion–reaction (ADR) system within the context of low-order mixed finite element method. Most importantly, we shall …

Investigation And Modeling Of Uranium Polarization For The Electrorefining Of Scrap U-Mo Foils, Melissa Rose

Open Access Dissertations

A uranium molybdenum alloy fuel has been proposed to convert research and test reactors from highly enriched uranium to low enriched uranium to increase the proliferation resistance at such reactors. Pyroprocessing has been selected to recover uranium from the scrap produced in the manufacture of this novel fuel type. Electrorefining, the main separation process of pyroprocessing, is modeled through a novel approach using corrosion theory. To use corrosion theory, knowledge of uranium polarization and kinetic parameters such as Tafel constant, transfer coefficient and exchange current density are required. Uranium polarization was investigated at five temperatures and three scan rates in …

Simulations Of Diffusion Driven Phase Evolution In Heterogenous Solids, Subramanya Gautam Sadasiva

Open Access Dissertations

With reduction in size, ever greater operational demands are placed on electronics components at all levels of the device, starting from the transistor level to the level of the package and the solder interconnects. Concurrently, there has been a move to more complicated materials systems in order to meet health and environmental guidelines. These trends of reducing size, increasing loads have increased the necessity to understand the mechanisms of the failure. ^ As the length scales are reduced, it becomes increasingly important to consider interfacial and micro-structural effects that can be safely ignored at larger length scales owing to the …

Particle Swarms In Confining Geometries, Eric Robert Boomsma

Open Access Dissertations

The transport of micro- and nano-particles in subsurface fluid deposits is an area of increasing interest due to the rising use of these particles for consumer and industrial purposes. Subsurface particle transport is complicated by the presence of fractures and fracture networks which govern the paths that particles will be able to take. In this thesis, subsurface particle transport will be investigated using particle swarms; collections of hydro-dynamically interacting particles which exhibit group behavior. The effects of fluid viscosity, particle properties, fracture geometry, and fracture aperture on swarm behavior were experimentally investigated. ^ Swarm parameters were examined in time with …

Studies Of Systems With Nonholonomic Constraints: The Segway And The Chaplygin Sleigh, Joseph Troy Lee Tuttle

Open Access Theses

In this thesis, two systems with nonholonomic systems are investigated: the Segway and the Chaplygin sleigh. Using Lagrangian mechanics, the constrained nonlinear equations of motion for both systems are derived. By use of the nullspace of the constraint matrices, the unconstrained equations of motion can be obtained. For the Segway, these equations are linearized about a zero equilibrium state, placed into state space form and decoupled. A feedback controller is designed about the velocity and heading angle rate reference commands. To compare to the real data from the built Segway, measurement noise was also included in the model. Experimental data …

New Experimental And Theoretical Tools For Studying Protein Systems With Elements Of Structural Disorder, Tairan Yuwen

Open Access Dissertations

Disordered proteins are one class of proteins which do not possess well-folded three-dimensional structures as their native conformations. Many eukaryotic proteins have been found to be fully disordered or contain certain disordered regions. Disordered proteins usually display several characteristic properties, such as increased motional freedom and the conformational heterogeneity caused by that. The elements of structural disorder are commonly involved in many important biological functions and are implicated in many diseases. Therefore, the study of disordered proteins has become one of the most important research topics in recent years. This thesis presents results from three different research projects; the common …

Indoor Acoustic Mapping And Geolocation, Thomas Shyy

Open Access Theses

The Global Positioning System (GPS) is widely used in navigations of flights, vehicles and travelers nowadays. However, the signals are not always available and there are some cases where the receptions of the GPS signal can be lost because of the presence of urban canyons, buildings, tunnels and forests. Another down side for the GPS is that indoor positioning can be really difficult because of the greater signal interference from the indoor.

On the other hand, the concept of echolocation has also been used for positioning purposes. Echolocation offers a promising approach to improve the quality of life of people …

Tunable Impedance Matching Network Fundamental Limits And Pracitical Considerations, Wesley N. Allen

Open Access Dissertations

As wireless devices continue to increase in utility while decreasing in dimension, design of the RF front-end becomes more complex. It is common for a single handheld device to operate on a plethora of frequency bands, utilize multiple antennae, and be subjected to a variety of environments. One complexity in particular which arises from these factors is that of impedance mismatch. Recently, tunable impedance matching networks have begun to be implemented to address this problem. ^ This dissertation presents the first in-depth study on the frequency tuning range of tunable impedance matching networks. Both the fundamental limitations of ideal networks …

Epistemic Uncertainty Quantification In Scientific Models, Xiaoxiao Chen

Open Access Dissertations

In the field of uncertainty quantification (UQ), epistemic uncertainty often refers to the kind of uncertainty whose complete probabilistic description is not available, largely due to our lack of knowledge about the uncertainty. Quantification of the impacts of epistemic uncertainty is naturally difficult, because most of the existing stochastic tools rely on the specification of the probability distributions and thus do not readily apply to epistemic uncertainty. And there have been few studies and methods to deal with epistemic uncertainty. A recent work can be found in [J. Jakeman, M. Eldred, D. Xiu, Numerical approach for quantification of epistemic uncertainty, …

Determination Of Disulfide Bond Connecting Patterns Via Tandem Mass Spectrometry (Msn) And Biomolecular Ion/Radical Reactions, Kirt Lenroy Durand

Open Access Dissertations

Disulfide bond formation is one of the most common post translational modifications to occur in proteins and naturally occurring peptides. Disulfide bond formation plays a critical role in stabilizing their three-dimensional structure; therefore, it is very important to pinpoint the correct disulfide bond connecting pattern in order to fully understand the biological functions of these proteins and peptides. To fully characterize an analyte containing disulfide bonds, the sequence must first be known followed by the disulfide bond connecting pattern. This presents an analytical challenge as there are very few methodologies that can produce those essential pieces of information. The gold …

A Qualitative Study Of Problematic Reasonings Of Undergraduate Electrical Engineering Students In Continuous Time Signals And Systems Courses, Farrah Fayyaz

Open Access Dissertations

Continuous Time Signals and Systems is a core course in the undergraduate electrical engineering curriculum. The topics covered in this course are difficult to learn conceptually because a significant number of topics are abstract, disconnected from a student's daily life, and make extensive use of mathematical modeling and formulas. Engineering educators have put in significant effort to design effective educational strategies for this course; however, there remained a gap in qualitative understanding of students' reasonings associated with difficulties in conceptual learning of the course content. This study aims to fill this gap by identifying problematic reasonings of undergraduate electrical engineering …

Algorithm-Circuit Co-Design For Detecting Symptomatic Patterns In Biological Signals, Himanshu Markandeya

Open Access Dissertations

The advancement in scaled Silicon technology has accelerated the development of a wide range of applications in various fields including medical technology. It has immensely contributed to finding solutions for monitoring general health as well as alleviating intractable disorders in the form of implantable and wearable systems. This necessitates the development of energy efficient and functionally efficacious systems. This thesis has explored the algorithm-circuit co-design approach for developing an energy efficient epileptic seizure detection processor which could be used for implantable epilepsy prosthesis. Novel wavelet transform based algorithms are proposed for accurate detection of epileptic seizures. Energy efficient techniques at …

Capacity-Related Driver Behavior On Modern Roundabouts Built On High-Speed Roads, Shaikh Ahmad

Open Access Theses

The objective of this thesis was to investigate the factors that affect capacity-related driver behavior on modern roundabouts built on high-speed roads. The capacity of roundabouts is strongly affected by the behavior of drivers as represented by critical headway (critical gap) and follow-up headway (follow-up time). The effects of heavy vehicles (single-unit truck, bus, and semi-trailer) and area type (rural or urban) on roundabout capacity were investigated by comparing the critical headways for roundabouts located on high-speed and low-speed roads. The effects of nighttime conditions (in the presence of street lighting) were also considered. Data were collected using the Purdue …

Wi-Fi Real Time Location Systems, Benjamin A. Doll

Open Access Theses

This thesis objective was to determine the viability of utilizing an untrained Wi-Fi real time location system as a GPS alternative for indoor environments. Background research showed that GPS is rarely able to penetrate buildings to provide reliable location data. The benefit of having location information in a facility and how they might be used for disaster or emergency relief personnel and their resources motivated this research. A building was selected with a well-deployed Wi-Fi infrastructure and its untrained location feature was used to determine the distance between the specified test points and the system identified location. It was found …

Uncertainty, Irreversibility, And Investment In Secondgeneration Biofuels, Tanner Joseph Mccarty

Open Access Theses

The present study formalizes and quantifies the importance of uncertainty for investment in a corn-stover based cellulosic biofuel plant. Using a real options model we recover prices of gasoline that would trigger entry into the market and calculate the portion of that entry trigger price required to cover cost and the portion that corresponds to risk premium. We then discuss the effect of managerial flexibility on the entry risk premium and the prices of gasoline that would trigger mothballing, reactivation, and exit. Results show that the risk premium required by plants to enter the second-generation biofuel market is likely to …

Optimization Of Switch Virtual Keyboard By Using Computational Modelling, Xiao Zhang

Open Access Theses

In this thesis, I first reviewed some keyboard technologies used by people with motor difficulties, and described design elements that influence efficiency. I cast the design of a switch keyboard as an optimization problem, and arrangement of keys on such a keyboard as a Mixed Integer Programming problem. One significant variable in the MIP problem, the error rate, is related to several other variables. I treated modeling of the error rate as a parameter estimation problem, and used a data mining method. I designed HCI experiments to gather data for parameter estimation, using Bayesian logistic regression model. The empirical data …

Solar Sail Trajectory Design In The Earth-Moon Circular Restricted Three Body Problem, Ashwati Das

Open Access Theses

The quest to explore the Moon has helped resolve scientific questions, has spurred leaps in technology development, and has revealed Earth's celestial companion to be a gateway to other destinations. With a renewed focus on returning to the Moon in this decade, alternatives to chemical propulsion systems are becoming attractive methods to efficiently use scarce resources and support extended mission durations. Thus, an investigation is conducted to develop a general framework, that facilitates propellant-free Earth-Moon transfers by exploiting sail dynamics in combination with advantageous transfer options offered in the Earth-Moon circular restricted multi-body dynamical model. Both periodic orbits in the …

Observation Of Upsilon Suppression, Search For Long-Lived Particles, And Observation Of B0s → Micro + Micro-- At The Lhc With The Cms Experiment, Zhen Hu

Open Access Dissertations

The LHC centre-of-mass energy allows abundant ϒ production in lead-lead (PbPb) collisions. A detailed measurement of the bottomonium production will help to characterize the dense matter produced in heavy-ion collisions. The full spectroscopy of quarkonium states has been proposed as a possible thermometer for the QGP. The measurement reported in Chapter 3 is performed with data recorded by CMS during the first PbPb run at 2010 and the proton-proton (pp) run at 2011, both at sqrt s_NN = 2.76 TeV. The integrated luminosity corresponds to 7.28/µb for PbPb and 225/nb for ppcollisions. Using muons of transverse momentum ( …

Solid Amine-Boranes As High Performance Hypergolic Hybrid Rocket Fuels, Mark A. Pfeil

Open Access Dissertations

Hypergolic hybrid rockets have the potential of providing systems that are simple, reliable, have high performance, and allow for energy management. Such a propulsion system can be applied to fields that need a single tactical motor with flexible mission requirements of either high speed to target or extended loitering. They also provide the possibility for alternative fast response dynamic altitude control systems if ignition delays are sufficiently short. ^ Amines are the traditional fuel of choice when selecting a hypergolic combination as these tend to react readily with both nitric acid and dinitrogen tertroxide based oxidizers. It has been found …

Energy Analysis Of Cool, Medium, And Dark Roofs On Residential Buildings In The U.S., Michael A. Dunbar

Open Access Theses

This study reports an energy analysis of cool, medium, and dark roofs on residential buildings in the U.S. Three analyses were undertaken in this study: energy consumption, economic analysis, and an environmental analysis. The energy consumption reports the electricity and natural gas consumption of the simulations. The economic analysis uses tools such as simple payback period (SPP) and net present value (NPV) to determine the profitability of the cool roof and the medium roof. The variable change for each simulation model was the roof color. The default color was a dark roof and the results were focused on the changes …

Experimental Study Of Droplet Capable Conductivity Probe, Yikuan Yan

Open Access Theses

This research focus on experimentally studying the performance of the newly designed Droplet Capable Conductivity Probe (DCCP). ^ A literature review is performed to illustrate the development of current two-fluid model and interfacial area transport equation. Previous conductivity probe instrumentation is also reviewed. The limitations of current conductivity probe design are described and the necessity of developing DCCP is illustrated. ^ The concept of DCCP-2 and DCCP-4 are introduced and experiments are performed to benchmark the capability of DCCP-4.

The Weakness Of Winrar Encrypted Archives To Compression Side-Channel Attacks, Kristine Arthur-Durett

Open Access Theses

Arthur-Durett, Kristine MS, Purdue University, December 2014. The weakness of WinRAR encrypted archives to compression side-channel attacks. Major Professor: Eugene Spaff This paper explores the security of WinRAR encrypted archives. Previous works concerning potential attacks against encrypted archives are studied and evaluated for practical implementation. These attacks include passive actions examining the effects of compression ratios of archives and the fi contained, the study of temporary ar- tifacts and active man-in-the-middle attacks on communication between individuals. An extensive overview of the WinRAR software and the functions implemented within it is presented to aid in understanding the intricacies of attacks against …

Rapid Indirect Trajectory Optimization On Highly Parallel Computing Architectures, Thomas Antony

Open Access Theses

Trajectory optimization is a field which can benefit greatly from the advantages offered by parallel computing. The current state-of-the-art in trajectory optimization focuses on the use of direct optimization methods, such as the pseudo-spectral method. These methods are favored due to their ease of implementation and large convergence regions while indirect methods have largely been ignored in the literature in the past decade except for specific applications in astrodynamics. It has been shown that the shortcomings conventionally associated with indirect methods can be overcome by the use of a continuation method in which complex trajectory solutions are obtained by solving …

The Barriers To Adopting Composting Toilets Into Use In Urban And Suburban Locations In The United States, Julia Branstrator

Open Access Theses

The amount of fresh water available in the world is a finite resource. Large quantities of the fresh water are located in remote locations, while more accessible sources of fresh water are disproportionately distributed around the world. Some populations lack reliable access to clean water for daily life, making the routine use of potable water in toilets of upper-income countries a questionable practice in terms of resource responsibility, energy use, and sustainable infrastructure. The innovative nature of composting toilets offers potential solutions to the downfalls of conventional, waterborne toilets. However, the path to adoption of composting toilets has encountered barriers …

Dropwise Condensation Dynamics In Humid Air, Julian Eduardo Castillo Chaco

Open Access Theses

Dropwise condensation of atmospheric water vapor is important in multiple practical engineering applications. The roles of environmental factors and surface morphology/chemistry on the condensation dynamics need to be better understood to enable efficient water-harvesting, dehumidication, and other psychrometric processes. Systems and surfaces that promote faster condensation rates and self-shedding of condensate droplets could lead to improved mass transfer rates and higher water yields in harvesting applications. The thesis presents the design and construction of an experimental facility that allows visualization of the condensation process as a function of relative humidity. Dropwise condensation experiments are performed on a vertically oriented, hydrophobic …

Implementing The Caspie Coursebased Research Experience At The United States Military Academy: Affective Responses And Effects On Critical Thinking, Anthony Michael Chase

Open Access Theses

The Center for Authentic Science Practices in Education (CASPiE) pioneered a course-based research experience approach to teaching chemistry laboratory courses. The method had previously been studied in a variety of institutional settings. Recently, the United States Military Academy at West Point decided to develop CASPiE-style modules for the introductory honors chemistry course. This research setting presents clean experimental-control comparisons and a group of faculty who were completely new to the method. Equipping students with authentic research experiences early in their education is important regardless of the institution. However, cadets at a military academy must make decisions relatively early (the outset …

A Dynamic Stochastic Model For Converging Inbound Air Traffic, Jun Chen

Open Access Theses

Weather accounts for the majority of congestion in the National Airspace System which highlights the importance of addressing weather uncertainty to mitigate delays, and this paper presents an effort in this direction. Firstly, a new dynamic stochastic 0-1 Integer Programming (IP) model is proposed, which models the Single Airport Ground Holding Problem (SAGHP) with respect to uncertainty in the separation between flights instead of Airport Acceptance Rate (AAR) or landing capacity. Uncertainty in separation according to different weather conditions is represented through the scenario tree by using stochastic linear programming. Considering time separation constraints instead of AAR constraints, our model …

New Strategies To Reveal Protein Candidates In Protein-Protein Interactome Study, Meng-Chieh Chen

Open Access Theses

Comprehensive protein-protein interaction network analysis can help reveal protein functions in a system-wide manner. A reliable knowledgebase of interaction networks is not only important for selecting the candidates for drug therapies, but also for evaluating the disease risk. In current interaction databases, 322579 interactions comprised of 56460 proteins have been reported (statistical analysis from APID: Agile Protein Interaction DataAnalyzer; http://bioinfow.dep.usal.es/apid/index.htm). The huge datasets are contributed mainly by yeast -two -hybrid (Y2H) screening and affinity-purification followed by mass spectrometry (AP-MS). High false positive rates and failing to cover certain interaction categories are the limitations of these two methods. Here, we developed …

Nitrate Removal From Subsurface Drainage By Denitrifying Bioreactor, Erin Chichlowski

Open Access Theses

Denitrifying bioreactors are an edge-of-field best management practice that reduce nitrate in runoff and subsurface drainage waters with minimum surface foot print and management requirements. The objectives of this study included evaluating a 173 m3 wood chip bioreactor for nitrate reduction and removal rates, the effects on phosphorus, and the impacts of the bioreactor's physical characteristics on effective nitrate reduction During periods of flow, weekly water samples were collected for lab analysis of nitrate+nitrite (nitrate-N), total nitrogen (TN), soluble reactive phosphorus (SRP), and total phosphorus (TP) and measurements were made of water temperature, dissolved oxygen, pH, oxidation reduction potential, temperature, …

Impact Of License Selection On Open Source Software Quality, Benjamin J. Cotton

Open Access Theses

Open source software plays an important part in the modern world, powering businesses large and small. However, little work has been done to evaluate the quality of open source software. Two different license paradigms exist within the open source world, and this study examines the difference in software quality between them. In this thesis, the author uses technical debt as a measure of software quality. Eighty open source projects (40 from each paradigm) were downloaded from the popular open source hosting website SourceForge. Using complexity, code duplication, comments, and unit test coverage as inputs to the SonarQube technical debt model, …