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Articles 931 - 960 of 6894
Full-Text Articles in Entire DC Network
Introduction To Confronting Teacher Preparation Epistemicide: Art, Poetry, And Teacher Resistance, Richard D. Sawyer, Daniel Ness
Introduction To Confronting Teacher Preparation Epistemicide: Art, Poetry, And Teacher Resistance, Richard D. Sawyer, Daniel Ness
Northwest Journal of Teacher Education
In this special issue, we present different perspectives from a documentary project on curricular epistemicide. We view curriculum epistemicide —the annihilation of curriculum—as an embodied process. It limits ways of knowing, questioning, and envisioning the world, and it constricts multiplicity and erases identity and culture. Authors within this volume responded to two requests: 1) they examined some form of epistemicide; and 2) they did not reinforce current systems of power and inequity. Throughout the issue, poetry and photography weave through theoretical papers and empirical studies. A range of methodologies are considered within the articles.
Confronting Curriculum Epistemicide: A Conversation With Editors Dan Ness & Rick Sawyer, Maika Yeigh, Richard D. Sawyer, Daniel Ness
Confronting Curriculum Epistemicide: A Conversation With Editors Dan Ness & Rick Sawyer, Maika Yeigh, Richard D. Sawyer, Daniel Ness
Northwest Journal of Teacher Education
As an entree into the Special Issue "Confronting Curriculum Epistemicide", NWJTE co-editor Maika Yeigh talk with editors Daniel Ness and Richard Sawyer to learn about their inspiration and goals of the Special Issue.
Disrupting The Hegemonic Practices Way Of Knowing: Moving Toward A Posthuman Perspective, Jordan Gonzalez, Brett Elizabeth Blake
Disrupting The Hegemonic Practices Way Of Knowing: Moving Toward A Posthuman Perspective, Jordan Gonzalez, Brett Elizabeth Blake
Northwest Journal of Teacher Education
No abstract provided.
Mathematics In The Woods: Exploring Low-Income Parents’ Perceptions Of And Involvement In Their Children’S Mathematical Learning, Lulu Sun
Northwest Journal of Teacher Education
This article features data from a three-day mathematics camping trip that offered parents and their children time and space to enjoy non-digital activities and mathematics-building tasks. Drawing upon data from a larger qualitative study of children and their parents, this article specifically focuses on 10 parents’ perceptions of their children’s mathematics learning, problem-solving, and wellbeing. Findings suggest that, although parents are interested in their children’s mathematics learning, they are most concerned with their children’s development of problem-solving abilities and social skills. Moreover, students’ own learning experience is important for their mathematics learning.
Cocm: Co-Occurrence-Based Consistency Matching In Domain-Adaptive Segmentation, Siyu Zhu, Yingjie Tian, Fenfen Zhou, Kunlong Bai, Xiaoyu Song
Cocm: Co-Occurrence-Based Consistency Matching In Domain-Adaptive Segmentation, Siyu Zhu, Yingjie Tian, Fenfen Zhou, Kunlong Bai, Xiaoyu Song
Electrical and Computer Engineering Faculty Publications and Presentations
This paper focuses on domain adaptation in a semantic segmentation task. Traditional methods regard the source domain and the target domain as a whole, and the image matching is determined by random seeds, leading to a low degree of consistency matching between domains and interfering with the reduction in the domain gap. Therefore, we designed a two-step, three-level cascaded domain consistency matching strategy—co-occurrence-based consistency matching (COCM)—in which the two steps are: Step 1, in which we design a matching strategy from the perspective of category existence and filter the sub-image set with the highest degree of matching from the image …
Climate Change Curricula In Alberta, Canada: An Intersectional Framing Analysis, Greg Lowan-Trudeau
Climate Change Curricula In Alberta, Canada: An Intersectional Framing Analysis, Greg Lowan-Trudeau
Northwest Journal of Teacher Education
This article is comprised of a climate change-focused framing analysis of proposed revisions to Alberta, Canada’s K-6 curriculum as an ideologically motivated manifestation of curricular epistemicide. Eisner’s three curricula—the explicit, implicit, and null—and scholarship related to intersectional climate and environmental justice, education, and communication provide the theoretical framework. This inquiry concludes with a critical discussion of and possible alternatives to the revised curriculum with further consideration of the implications for those involved with similar endeavours in other jurisdictions across Canada and around the world.
Applying Biomimetic Passive Dynamics To A Quadruped Robot Leg, Emma Krnacik
Applying Biomimetic Passive Dynamics To A Quadruped Robot Leg, Emma Krnacik
Dissertations and Theses
The study of synthetic nervous systems is an emerging field within biomimetic robotics as an alternative to more classic control techniques. As the modeling of these nervous systems becomes more accurate, it is important to note that the nervous system and physical system co-evolved and continue to operate in an interdependent fashion. Many legged robots, including the existing quadruped in the AARL, have leg systems that may have similar geometrical properties to that of a mammal, but have significantly different dynamic properties. This paper presents a method for designing a limb so that the passive dynamics more accurately represent that …
Investigating Small-Group Cognitive Engagement In General Chemistry Learning Activities Using Qualitative Content Analysis And The Icap Framework, Safaa Y. El-Mansy, Jack Barbera, Alissa J. Hartig
Investigating Small-Group Cognitive Engagement In General Chemistry Learning Activities Using Qualitative Content Analysis And The Icap Framework, Safaa Y. El-Mansy, Jack Barbera, Alissa J. Hartig
Chemistry Faculty Publications and Presentations
The level of students’ engagement during active learning activities conducted in small groups is important to understanding the effectiveness of these activities. The Interactive–Constructive–Active–Passive (ICAP) framework is a way to determine the cognitive engagement of these groups by analyzing the conversations that occur while student groups work on an activity. This study used qualitative content analysis and ICAP to investigate cognitive engagement during group activities in a General Chemistry course at the question level, a finer grain size than previously studied. The analysis determined the expected engagement based on question design and the observed engagement based on group conversations. Comparisons …
Response Of Soil Respiration To Changes In Soil Temperature And Water Table Level In Drained And Restored Peatlands Of The Southeastern United States, E. E. Swails, K. Krauss, Marcelo Ardón, A. L. Peralta, A. M. Helton, Jennifer L. Morse, Multiple Additional Authors
Response Of Soil Respiration To Changes In Soil Temperature And Water Table Level In Drained And Restored Peatlands Of The Southeastern United States, E. E. Swails, K. Krauss, Marcelo Ardón, A. L. Peralta, A. M. Helton, Jennifer L. Morse, Multiple Additional Authors
Environmental Science and Management Faculty Publications and Presentations
Background
Extensive drainage of peatlands in the southeastern United States coastal plain for the purposes of agriculture and timber harvesting has led to large releases of soil carbon as carbon dioxide (CO2) due to enhanced peat decomposition. Growth in mechanisms that provide financial incentives for reducing emissions from land use and land-use change could increase funding for hydrological restoration that reduces peat CO2 emissions from these ecosystems. Measuring soil respiration and physical drivers across a range of site characteristics and land use histories is valuable for understanding how CO2 emissions from peat decomposition may respond to raising water table levels. …
Most Recent Rupture On The Boulder Creek Fault Triggered Bedrock Landsliding In The Nooksack Watershed, Whatcom County, Washington, Abigail Catherine Underwood
Most Recent Rupture On The Boulder Creek Fault Triggered Bedrock Landsliding In The Nooksack Watershed, Whatcom County, Washington, Abigail Catherine Underwood
Dissertations and Theses
Catastrophic bedrock landslides with volumes ranging from 106 to 108 m3 contribute to rapid landscape evolution, often resulting in erosion rates that exceed the long-term average rates caused by tectonic uplift. Understanding the spatiotemporal trends of large bedrock landslides helps us understand previous drivers of landscape evolution as well as predict how the landscape will respond in the future. The Nooksack Watershed, Whatcom County, Washington, is particularly susceptible to large slope failures because of its high relief, seismic activity, local geology, and relatively abundant precipitation. Specifically, folded and faulted bedrock structures conducive to landsliding in addition to …
Collective Proving Activity In A Synchronous Online Environment, Tenchita Alzaga Elizondo
Collective Proving Activity In A Synchronous Online Environment, Tenchita Alzaga Elizondo
Dissertations and Theses
Given the well documented fact students often struggle with proof and proof-related activity for various reasons, more educators have shifted to incorporating pedagogies involving collaborative learning given their benefits to student learning. However, there is still surprisingly little research focused on the nature of students' collaborative proving activity. Moreover, the recent COVID-19 pandemic, and subsequent shift to remote learning, forced educators and students to adapt and learn how to work within a new learning environment. In this dissertation project, I investigate how students engage in collaborative proving activity in a synchronous online introduction to proofs course. In the first paper, …
Explaining Backlash: Social Hierarchy And Men’S Rejection Of Women’S Rights Reforms, Lindsay J. Benstead, Ragnhild L. Muriaas, Vibeke Wang
Explaining Backlash: Social Hierarchy And Men’S Rejection Of Women’S Rights Reforms, Lindsay J. Benstead, Ragnhild L. Muriaas, Vibeke Wang
Political Science Faculty Publications and Presentations
Governments promote gender-sensitive policies, yet little is known about why reform campaigns evoke backlash. Drawing on social position theory, we test whether marginalized (women’s organizations) or intrusive (Western donors) messengers cause resistance across public rights (quotas) and private rights (land reform). Using a framing experiment implemented among 1,704 Malawians, we find that females’ attitudes are unaffected by campaigns, while backlash occurs among patrilineal and matrilineal males. Backlash among men is more common for sensitive private rights (land reform) than public rights (quotas) and Western donors than women’s organizations, suggesting complex effects generally more consistent with the intrusiveness hypothesis.
Quantum Key-Length Extension, Joseph Jaeger, Fang Song, Stefano Tessaro
Quantum Key-Length Extension, Joseph Jaeger, Fang Song, Stefano Tessaro
Computer Science Faculty Publications and Presentations
Should quantum computers become available, they will reduce the effective key length of basic secret-key primitives, such as blockciphers. To address this we will either need to use blockciphers with inherently longer keys or develop key-length extension techniques to amplify the security of a blockcipher to use longer keys.
We consider the latter approach and revisit the FX and double encryption constructions. Classically, FX was proven to be a secure key-length extension technique, while double encryption fails to be more secure than single encryption due to a meet-in-the-middle attack. In this work we provide positive results, with concrete and tight …
Arts Course-Taking And Math Achievement In Us High Schools With Daniel Mackin Freeman, Daniel Mackin Freeman
Arts Course-Taking And Math Achievement In Us High Schools With Daniel Mackin Freeman, Daniel Mackin Freeman
PDXPLORES Podcast
In this episode of PDXPLORES, Daniel Mackin Freeman, a Ph. D. candidate in the sociology department at Portland State University, discusses the results of a study that asked if fine arts coursework is positively correlated to mathematics achievement in high schools at low, middle, and high socio-economic levels. Freeman and PSU sociology professor, Dara Shifrer recently publish the results of their study, "Arts for Whose Sake? Arts Course-taking and Math Achievement in US High Schools," online in Sociological Perspectives.
Click on the "Download" button to access the audio transcript.
The Consequential Role Of Aesthetics In Forest Fuels Reduction Propensities: Diverse Landowners’ Attitudes And Responses To Project Types, Risks, Costs, And Habitat Benefits, Robert G. Ribe, Max Nielsen-Pincus, Chris Enright, Bart R. Johnson, David Hulse
The Consequential Role Of Aesthetics In Forest Fuels Reduction Propensities: Diverse Landowners’ Attitudes And Responses To Project Types, Risks, Costs, And Habitat Benefits, Robert G. Ribe, Max Nielsen-Pincus, Chris Enright, Bart R. Johnson, David Hulse
Environmental Science and Management Faculty Publications and Presentations
Private landowners in the southern Willamette Valley of Oregon, USA were surveyed. The survey queried probabilities of implementing specific fuels reduction projects in extensive areas of specific forest types on their property. The projects were described in relation to the beginning and target forest types, the actions required, costs, and long-term maintenance. Forest types were first rated for scenic beauty and informed levels of wildfire risk reduction, scarce habitat production, and associated property rights risks. Propensities to perform each fuels reduction project were then obtained. These were adversely affected by disbelief in heightened wildfire risks or climate change, higher project …
Canonical Quantile Regression, Stephen Portnoy
Canonical Quantile Regression, Stephen Portnoy
Mathematics and Statistics Faculty Publications and Presentations
In using multiple regression methods for prediction, one often considers the linear combination of explanatory variables as an index. Seeking a single such index when here are multiple responses is rather more complicated. One classical approach is to use the coefficients from the leading Canonical Correlation. However, methods based on variances are unable to disaggregate responses by quantile effects, lack robustness, and rely on normal assumptions for inference. An alternative canonical regression quantile (CanRQ) approach seeks to find the linear combination of explanatory variables that best predicts the τ" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; line-height: …
A Multi-Modal Volumetric Microscope With Automated Sample Handling For Surveying Microbial Life In Liquid Samples, Nathan Oborny, Eugene Serabyn, J. Kent Wallace, Kurt Liewer, Manuel Bedrossian, Stephanie Rider, Chris Lindensmith, Jay Nadeau, Multiple Additional Authors
A Multi-Modal Volumetric Microscope With Automated Sample Handling For Surveying Microbial Life In Liquid Samples, Nathan Oborny, Eugene Serabyn, J. Kent Wallace, Kurt Liewer, Manuel Bedrossian, Stephanie Rider, Chris Lindensmith, Jay Nadeau, Multiple Additional Authors
Physics Faculty Publications and Presentations
In the study of microbial life, microscopy plays a unique role due to its ability to detect ordered structure, motility, and fluorescence signals. As such it has also recently gained attention in the context of searching for extant life on distant Solar System bodies bearing liquid water. In this paper we introduce a multimodal volumetric microscopy system for potential future spaceflight missions that combines digital holographic microscopy (DHM) and volume fluorescence imager (VFI), which are volumetric imaging methods that provide highresolution, high-throughput examination of liquid samples. DHM provides information on the absorption, morphology, and motility of imaged objects without requiring …
From Machine Learning To Deep Learning: A Comprehensive Study Of Alcohol And Drug Use Disorder, Banafsheh Rekabdar, David L. Albright, Haelim Jeong, Sameerah Talafha
From Machine Learning To Deep Learning: A Comprehensive Study Of Alcohol And Drug Use Disorder, Banafsheh Rekabdar, David L. Albright, Haelim Jeong, Sameerah Talafha
Computer Science Faculty Publications and Presentations
This study aims to train and validate machine learning and deep learning models to identify patients with risky alcohol and drug misuse in a Screening, Brief Intervention, and Referral to Treatment (SBIRT) program. An observational cohort of 6978 adults was admitted in the western region of Alabama at three medical facilities between January and December of 2019. Data were cleaned and pre-processed using data imputation techniques and an augmented sampling data method. The primary analysis involved the multi-class classification of alcohol and drug misuse. Our study shows that accurate identification of alcohol and drug use screening instrument scores was best …
Filling Critical Gaps In The Space-Time Record Of High Lava Plains And Co-Columbia River Basalt Group Rhyolite Volcanism, Vanessa Marie Swenton, Martin J. Streck, Daniel P. Miggins, William C. Mcintosh
Filling Critical Gaps In The Space-Time Record Of High Lava Plains And Co-Columbia River Basalt Group Rhyolite Volcanism, Vanessa Marie Swenton, Martin J. Streck, Daniel P. Miggins, William C. Mcintosh
Geology Faculty Publications and Presentations
Miocene rhyolitic volcanism of eastern Oregon, USA, can be divided into two main episodes. Mantle plume upwelling is thought to have generated Columbia River Basalt Group (CRBG) lavas and coeval >16.5−15 Ma silicic volcanism trending north−south from northeast Oregon to northern Nevada. Rhyolite volcanism of the 12−0 Ma High Lava Plains province has been ascribed to either buoyancy-driven westward plume spreading or to slab rollback and mantle convection spanning from southeast Oregon to Newberry Volcano to the west. The apparent ca. 15−12 Ma eruptive hiatus suggests that rhyolites of these provinces were a product of separate processes, yet this gap …
Speculative Realism And Systems Metaphysics, Martin Zwick
Speculative Realism And Systems Metaphysics, Martin Zwick
Complex Systems Faculty Publications and Presentations
Recent developments in Continental philosophy have included emergence of a school of “speculative realism” which rejects the human-centered orientation that has long dominated Continental thought, but also opposes naïve realism or positivism. Proponents of speculative realism differ on several issues, but most agree on the need for an object-oriented ontology. Speculative realists who draw upon Marxist thought identify realism with materialism, while others accord equal reality to objects that are non-material, even fictional. Several thinkers retain a focus on difference, a well-established theme in Continental thought. This paper looks at speculative realism from the perspective of the metaphysics of systems …
Viruses In Astrobiology, Ignacio De La Higuera, Ester Lázaro
Viruses In Astrobiology, Ignacio De La Higuera, Ester Lázaro
Biology Faculty Publications and Presentations
Viruses are the most abundant biological entities on Earth, and yet, they have not received enough consideration in astrobiology. Viruses are also extraordinarily diverse, which is evident in the types of relationships they establish with their host, their strategies to store and replicate their genetic information and the enormous diversity of genes they contain. A viral population, especially if it corresponds to a virus with an RNA genome, can contain an array of sequence variants that greatly exceeds what is present in most cell populations. The fact that viruses always need cellular resources to multiply means that they establish very …
River Discharge Mediates Extent Of Phytoplankton And Harmful Algal Bloom Habitat In The Columbia River Estuary (Usa) During North Pacific Marine Heat Waves, Taylor N. Dodrill, Yangdong Pan, Tawnya D. Peterson
River Discharge Mediates Extent Of Phytoplankton And Harmful Algal Bloom Habitat In The Columbia River Estuary (Usa) During North Pacific Marine Heat Waves, Taylor N. Dodrill, Yangdong Pan, Tawnya D. Peterson
Environmental Science and Management Faculty Publications and Presentations
Marine heat waves (MHWs) have been associated with extensive harmful algal blooms (HABs) in the northeast Pacifc Ocean, but the degree to which these large-scale oceanographic events are mirrored in nearshore environments has not been well established. We compared phytoplankton assemblages in the Lower Columbia River Estuary (LCRE) during two Pacifc MHWs that took place in 2015 and 2019, with observations from 2017, a year with no MHW. These data were paired with environmental data from the summers of 2015–2019 to characterize differences in estuarine conditions during MHWs that promote phytoplankton assemblage transitions and identify HAB-conducive conditions. Bloom densities of …
Herbicide-Resistance In Turf Systems: Insights And Options For Managing Complexity, Jennifer H. Allen, David Ervin, George Frisvold, James T. Brosnan, James D. Mccurdy, Rebecca G. Bowling, Aaron J. Patton, Matthew T. Elmore, Travis W. Gannon, Lambert B. Mccarty, Multiple Additional Authors
Herbicide-Resistance In Turf Systems: Insights And Options For Managing Complexity, Jennifer H. Allen, David Ervin, George Frisvold, James T. Brosnan, James D. Mccurdy, Rebecca G. Bowling, Aaron J. Patton, Matthew T. Elmore, Travis W. Gannon, Lambert B. Mccarty, Multiple Additional Authors
Public Administration Faculty Publications and Presentations
Due to complex interactions between social and ecological systems, herbicide resistance has classic features of a “wicked problem.” Herbicide-resistant (HR) Poa annua poses a risk to sustainably managing U.S. turfgrass systems, but there is scant knowledge to guide its management. Six focus groups were conducted throughout the United States to gain understanding of socio-economic barriers to adopting herbicide-resistance management practices. Professionals from major turfgrass sectors (golf courses, sports fields, lawn care, and seed/sod production) were recruited as focus-group participants. Discussions emphasized challenges of the weed management of turfgrass systems as compared to agronomic crops. This included greater time constraints for …
Towards More Equitable And Climate Resilient Communities With Jola Ajibade, Jola Ajibade
Towards More Equitable And Climate Resilient Communities With Jola Ajibade, Jola Ajibade
PDXPLORES Podcast
In this episode of PDXPLORES, Professor Jola Ajibade discusses research examining how cascading social and environmental hazards might impact communities in the Portland metro region and what policymakers and community members can do to mitigate the risks and promote a more just, livable, and sustainable urban future.
Click on the "Download" button to access the audio transcript.
In Favor Of Bringing Game Theory Into Urban Studies And Planning Curriculum: Reintroducing An Underused Method For The Next Generation Of Urban Scholars, Brian Mcdonald Gardner
In Favor Of Bringing Game Theory Into Urban Studies And Planning Curriculum: Reintroducing An Underused Method For The Next Generation Of Urban Scholars, Brian Mcdonald Gardner
Dissertations and Theses
By looking at some historical examples of Urban Studies literature and theory (and a detailed dive into Neil Smith's "Toward a theory of gentrification…") this thesis makes the case that Game Theory has valid insights to add to the foundation of Urban Studies and Planning and should be included in Masters and Doctorate level curriculums. As a discipline Game Theory has revolutionized multiple other fields, and can be used both mathematically and/or non-mathematically. It is postulated below that the inclusion of Game Theory would help scholars and practitioners arrive at better outcomes. This case is made by reviewing various areas …
Transient Vision Loss Associated With Prefilled Aflibercept Syringes: A Case Series And Analysis Of Injection Force, Daniel J. Lee, Brittni A. Scruggs, Erik J. Sánchez, Merina Thomas, Ambar Faridi
Transient Vision Loss Associated With Prefilled Aflibercept Syringes: A Case Series And Analysis Of Injection Force, Daniel J. Lee, Brittni A. Scruggs, Erik J. Sánchez, Merina Thomas, Ambar Faridi
Physics Faculty Publications and Presentations
Purpose
To describe cases of significant vision loss after intravitreal aflibercept administration using prefilled syringes (PFS) and to study the relationships among syringe design, injection speed, and injection force.
Design
Retrospective case series and experimental study.
Participants
Twelve patients who received intravitreal aflibercept via PFS.
Methods
All retina specialists (n = 13) at Oregon Health & Science University and the Veterans Affairs Portland Medical Center were queried in December 2020 to report episodes of significant vision loss after aflibercept PFS use. Chart review was completed for all affected patients. Using a commercially available force measuring system, injection force was measured …
Chemical Interactions And Cytotoxicity Of Terpene And Diluent Vaping Ingredients, Yanira Baldovinos, Alexandra Archer, James C. Salamanca, Robert M. Strongin, Christie Sayes
Chemical Interactions And Cytotoxicity Of Terpene And Diluent Vaping Ingredients, Yanira Baldovinos, Alexandra Archer, James C. Salamanca, Robert M. Strongin, Christie Sayes
Chemistry Faculty Publications and Presentations
Vaping devices have risen in popularity since their inception in 2007. The practice involves using a variety of commercially available devices. Internal heating systems in devices aerosolize e-liquid formulations of complex mixtures including an active ingredient (e.g., THC, CBD, and nicotine), diluents (or cutting agents), solvents, and flavoring agents (e.g., terpenes and aldehydes). The vaping toxicology literature consists of cytotoxicity studies of individual chemicals and commercial formulas. Because of the variation of e-liquid composition, there is a limited understanding of the toxicity of ingredient combinations. This study analyzed the cytotoxic effects after exposure to individual and binary mixtures of a …
Cascadia Subduction Zone Earthquake Vertical Ground Acceleration Investigation And Potential Impact On Bridges In The Pacific Northwest, Rachel Caroline Bassil
Cascadia Subduction Zone Earthquake Vertical Ground Acceleration Investigation And Potential Impact On Bridges In The Pacific Northwest, Rachel Caroline Bassil
Civil and Environmental Engineering Master's Project Reports
The effects of vertical ground accelerations during subduction zone earthquakes currently are not sufficiently understood. There are numerous case studies and evidence that effects of vertical ground accelerations can significantly impact the performance of bridges during a seismic event, but most previous research has been focused on shallow crustal earthquakes. Current bridge design codes provide little guidance for accounting for vertical ground accelerations in seismic design, in part because additional information is needed about the characteristics of vertical ground motions during Cascadia Subduction Zone (CSZ) earthquakes in the Pacific Northwest.
For this study, recorded seismic data from recent subduction zone …
Computational Investigation Into Heteroleptic Photoredox Catalysts Based On Nickel(Ii) Tris-Pyridinethiolate For Water Splitting Reactions, Avik Bhattacharjee, Dayalis S.V. Brown, Trent E. Ethridge, Kristine M. Halvorsen, Alejandra C. Acevedo Montano, Theresa M. Mccormick
Computational Investigation Into Heteroleptic Photoredox Catalysts Based On Nickel(Ii) Tris-Pyridinethiolate For Water Splitting Reactions, Avik Bhattacharjee, Dayalis S.V. Brown, Trent E. Ethridge, Kristine M. Halvorsen, Alejandra C. Acevedo Montano, Theresa M. Mccormick
Chemistry Faculty Publications and Presentations
This work demonstrates a strategy to fine-tune the efficiency of a photoredox water splitting Ni(II) tris-pyridinethiolate catalyst through heteroleptic ligand design using computational investigation of the catalytic mechanism. Density functional theory (DFT) calculations, supported by topology analyses using quantum theory of atoms in molecules (QTAIM), show that the introduction of electron donating (ED) −CH3 and electron withdrawing (EW) −CF3 groups on the thiopyridyl (PyS–) ligands of the same complex can tune the pKa and E0, simultaneously. Computational modeling of two heteroleptic nickel(II) tris-pyridinethiolate complexes with 2:1 and 1:2 ED and EW −CH3 and −CF3 …
Portland State Magazine, Portland State University. Office Of University Communications
Portland State Magazine, Portland State University. Office Of University Communications
Portland State Magazine
PSU’s alumni magazine, published 2-3 times a year. In this issue: Portland State mobilizes for the next era of climate action; with perseverance and a little help, it’s never too late to graduate; three scientists answer the question: How do you stay hopeful and motivated to make a difference with climate change?; Portland State researchers are investigating how to help the most vulnerable parents; opera retakes the stage with the “Merry Wives of Windsor”; a record-breaking steeplechase runner finds his way; remembering Charles Moose, Portland's first Black police chief, and more.