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A Study Of The Photolysis Of O-Methyl Podocarpinitrile Oxide, Dianne Marie Hunter

Dissertations and Theses

The photolytic reaction of 0-methyl podocarpinitrile oxide to yield the δ-lactam (shown below) was studied under various conditions such as: solvent (hexane, methanol), mercury lamp wattage (lOOW, 450W), filter (Pyrex, Corex, Vycor), and additives (dichloromethane, hexafluorobenzene). The reactions were analyzed with IR, NMR and HPLC. Preparative medium pressure liquid chromatography and TLC were used in the δ-lactam isolation. The conditions resulting in the optimum yield of δ-lactam were determined. The photolytic stability of the δ-lactam under the conditions in which it was formed indicated that it was relatively stable only in hexane.

Selective Reflection Of Light At A Solid-Gas Interface And Its Application, Fumihide Takeda

Dissertations and Theses

In order to study the detailed spectral intensity distribution of light reflected from a solid-gas interface, the extinction theorem in optics is extended to include an absorbing medium and the thermal motion of the gas molecules near the interface. The theoretical spectral intensity distribution in the region of anomalous dispersion is found to be strongly modified compared to that predicted by existing theory. An important consequence of this theory in the line shapes of the reflected light is the possibility of using recently developed saturation spectroscopic techniques to study atoms and molecules near surfaces. In order to investigate the feasibility …

Effect Of Phenoxy Acids And Their Derivatives On The Ionic Permeability Of Bilayer Lipid Membranes, Malkanthi Paulis Illangasekare

Dissertations and Theses

It has been found that the herbicide 2,4-D has the ability to increase the rate of transport of positive ions of several kinds and inhibit the transport of negatively charged tetraphenylborate ions in lipid bilayer membranes. Only the neutral molecules of 2,4-D are transport active. The ionized 2,4-D molecules do not modify the transport of ions, and do not by themselves permeate through lipid membranes. The results suggest that the enhancement of transport of positively charged ions is dominated by the increase of the ion translocation rate constant. It has been shown that membrane transport of negatively charged tetraphenylborate ions …

Faculty Senate Monthly Packet November 1979, Portland State University Faculty Senate

Faculty Senate Monthly Packets

The November 1979 Monthly packet includes the November agenda and appendices and the Faculty Senate minutes and attachments from the meeting held October 1979.

Rare, Threatened And Endangered Vascular Plants In Oregon: An Interim Report, Jean L. Siddall, Kenton L. Chambers, David H. Wagner

Institute for Natural Resources Publications

This report on rare, threatened and endangered vascular plants in Oregon is a basic document in the process of inventorying the state's natural areas * Prerequisite to the orderly establishment of natural preserves for research and conservation in Oregon are (1) a classification of the ecological types, and (2) a listing of the special organisms, which should be represented in a comprehensive system of designated natural areas. The necessary ecological classification was published in the U.S. Forest Service Pacific Northwest Forest and Range Experiment Station document, "Research Natural Area Needs in the Pacific Northwest," by Dyrness et al. (1975). This …

Interference Suppression In Ho Fluorescence Detection, Thomas M. Hard, Robert J. O'Brien, T. B. Cook, G. A. Tsongas

Environmental Science and Management Faculty Publications and Presentations

In this Letter we report preliminary results on a sampling method that greatly reduces the above interferences relative to hydroxyl fluorescence.

A Geophysical Definition Of A Klamath Falls Graben Fault, Cynthis Ann Veen

Dissertations and Theses

Four geophysical methods, along with well logs and outcrop data, were used in determining the location of a fault situated on the campus of Oregon Institute of Technology, just north of Klamath Falls, Oregon. The fault displaces rocks of the Yonna Formation, of Pliocene age. Wells located northeast of the fault (on the upthrown side) produce cold water, and wells located southwest of the fault (on the downthrown side) produce hot water. The purpose of this investigation was to define the characteristics of the fault exposed behind a large water tank southeast of the OIT campus.

Copper Toxicity And Extracellular Release In Selenastrum Capricornutum, Michael Edwin Darling

Dissertations and Theses

Copper toxicity was investigated using the green alga, Selenastrum capricornutum. Two major areas were investigated: the forms of copper which are toxic to growth of the alga and factors that can change the concentration of free copper, Cu²⁺(aq), in the growth medium during the logarithmic growth of the organism. This research has shown that S. capricornutum is sensitive to the free Copper ion, Cu²⁺(aq), irrespective of the total copper concentration.

Brownian Motion In A Flowing Fluid, John D. Ramshaw

Physics Faculty Publications and Presentations

A phenomenological theory is developed for Brownian motion in a flowing incompressible fluid. The Brownian particles are regarded as an ideal gas subject to a position- and time-dependent force field that represents interactions with the host fluid. This approach immediately leads to deterministic partial differential equations of motion for the Brownian particles. These equations are then examined in the limit of large friction, in which they imply an expression for the diffusional mass flux of Brownian particles. This expression is a sum of terms representing concentration, forced, thermal, and pressure diffusion. Comparisons are made with earlier work, and with the …

Consciousness, Neurons, And Laughing Gas, Dody Michelson Orendurff

Dissertations and Theses

Psychological and physiological effects of nitrous oxide resemble those of eight other drug categories. Lipid solubility or hydrate microcrystal theories correlate behavioral measures with measurable parameters of the molecule N₂O. N₂O, a spindle poison, halts mitosis in metaphase, producing widespread physiological consequences. N₂O affects the microtubules of the spindle in a number of specific ways. Microtubules are utilized in other parts of eukaryotic cells, in a wide variety of functions. In neurons, microtubules build and maintain dendritic sensory processes. Since microtubules are built of two dissimilar proteins, constantly assemble and disassemble, and maintain a …

"The Urban Enigma: America's Urban Alternatives", Christopher L. Salter

Special Collections: Oregon Public Speakers

Presented with Brown, Harrison Scott, "Energy Resources."

"Energy Resources", Harrison Scott Brown

Special Collections: Oregon Public Speakers

With: Salter, C. L. The urban enigma.

The Geology And Geochemistry Of The North Fork Stock, Northeastern Oregon, David Joseph Matty

Dissertations and Theses

The North Fork stock is a composite intrusive body of Late Jurassic-Early Cretaceous age which outcrops in the Blue Mountains of northeastern Oregon. The upper 600 m of the intrusion are exposed over an area of approximately 36 km² along the canyon walls of the North Fork of the John Day River in Grant and Umatilla counties. The stock intrudes metasediments, metavolcanics, and metagabbros associated with the Permian-Triassic Elkhorn Ridge Argillite. Contact metamorphism of the Elkhorn Ridge Argillite is developed to the hornblende-hornfels facies throughout most of the exposed area of this unit in the study area. The contact …

1979 Commencement Program, Commencement

Commencement Archives 1970-79

The program for the Portland State University Spring commencement ceremony held June 10, 1979 at 3:00 p.m. at Memorial Coliseum, Portland, Oregon.

Faculty Senate Monthly Packet June 1979, Portland State University Faculty Senate

Faculty Senate Monthly Packets

The June 1979 Monthly packet includes the June agenda and appendices and the Faculty Senate minutes and attachments from the meeting held May 1979.

The Concentration And Speciation Of Sugars In Natural Waters, Minoo Shakerin Sweet

Dissertations and Theses

Due to the importance of carbohydrates in biological systems, many efforts have been made to develop a quantitative method for analysis of carbohydrates in natural waters. The low concentrations of dissolved sugars in natural waters require a sensitive analytical method. In this study, gas chromatography of alditol acetate derivatives of sugars was investigated for quantitative and qualitative analysis of individual dissolved sugars in natural waters. The alditol acetate derivatives of sugars give only one derivative for each sugar, yielding qualitative and quantitative results.

The detection limit was 25 nM for each sugar. Because of this very low detection limit, only …

Faculty Senate Monthly Packet May 1979, Portland State University Faculty Senate

Faculty Senate Monthly Packets

The May 1979 Monthly packet includes the May agenda and appendices and the Faculty Senate minutes and attachments from the meeting held April 1979.

Geology Of North Craters Of The Moon National Monument, Idaho, William C. Sidle

Dissertations and Theses

The purpose of the investigation was to map the geology of the north end of Craters of the Moon National Monument and surrounding area. A stratigraphic sequence of Late Paleozoic sedimentary and Tertiary volcanic rocks was compiles and the structures of these rocks and contact relationships with intrusions were delineated. Grade and facies of contact metamorphism were defined. The Snake River Plain basalts were also mapped. The sources of these flows were determined where possible. Preexisting structures and relationships of vents to earlier faulting were explored in ascertaining extensions of the Great Rift Zone into the Pioneer Mountains. Petrographic descriptions …

Faculty Senate Monthly Packet April 1979, Portland State University Faculty Senate

Faculty Senate Monthly Packets

The April 1979 Monthly packet includes the April agenda and appendices and the Faculty Senate minutes and attachments from the meeting held March 1979.

Portland State Perspective; March 1979, Portland State University

Portland State Perspective

A quarterly alumni newsletter. In this issue: storage and space problems at the library; degree opportunities expand; campaign against disco music.

Scattering Of Focused Beams By Tenuous Particles, S. Colak, Cavour W. Yeh, Lee W. Casperson

Electrical and Computer Engineering Faculty Publications and Presentations

This paper deals with the problem of the scattering of focused laser beams by tenuous particles using an iterative technique. The results are shown to be accurate provided that (a) the polarizability of the particle medium is small and (b) the phase shift of the central ray is less than 2. It was found that when the size of the incident beam waist is close to that of the scatterer, the scattered field deviates significantly from that for the incident plane wave case. Specific examples are given.

Comments On The Theory Of Dipolar Fluids, John D. Ramshaw

Physics Faculty Publications and Presentations

The theory of dipolar fluids posbulated by Chan, Mitchell and Ninham is commented upon.

Stratigraphy And Sedimentary Petrology Of The Northwest Quarter Of The Dutchman Butte Quadrangle, Southwest Oregon, Thomas Edward Koler

Dissertations and Theses

The study area lies in southwest Douglas County 5 kilometers south from Camas Valley and is accessible by state highway 42. The purpose of the study was to map the geology at a 1:31,250 scale, determine the stratigraphy, study the petrology of the formations, and determine the provenance within a tectonic setting.

The Structure And Stratigraphy Of The Columbia River Basalt In The Hood River Valley, Oregon, Susan Timm

Dissertations and Theses

The Hood River Valley, located 100 kilometers east of Portland, Oregon, is in the transition zone between two geologic provinces--the High Cascades and the Columbia Plateau. The entire valley is probably underlain by Columbia River Basalt, but it crops out only on steep hillsides and in stream valleys. The base of the basalt is not exposed in the thesis area. The basalt is overlain by Pliocene and Quaternary basalt and andesite, volcanic sediments and glacial debris.

The stratigraphy of the Columbia River Basalt is useful in determining the path of the basalt flows into western Oregon, in mapping the structure …

Structural Geology Of The Southeast Quarter Of The Dutchman Butte Quadrangle, Oregon, Gerald Lee Black

Dissertations and Theses

Field work in the southeast quarter of the Dutchman ·Butte Quadrangle, which lies within the Klamath Mountains geomorphic province of southwestern Oregon, was completed during the summers of 1973 and 1974. The objectives of the study were fourfold: (1) to produce a geologic map of the southeast quarter of the Dutchman Butte Quadrangle, (2) to determine the nature of the contact between the Dothan and Rogue formations, (3) to construct a stratigraphic column of the Dothan Formation in the area, and (4) to attempt to determine the nature of the deformation occurring in the area.

Faculty Senate Monthly Packet January 1979, Portland State University Faculty Senate

Faculty Senate Monthly Packets

The January 1979 Monthly packet includes the January agenda and appendices and the Faculty Senate minutes and attachments from the meeting held December 1978.

A Polarographic Study Of Fe(Ii) And Fe(Iii) Complexes With Catechol, Wen-Tang Shen

Dissertations and Theses

A study of the anodic polarography of catechol in 0.100 F sodium perchlorate is presented. A new wave is observed in alkaline solutions which is different from the simple oxidation wave of catechol to ortho-quinone observed by previous workers. The importance of buffer materials is discussed and a possible explanation of the new wave is suggested.

A study of the polarography behavior of Fe(II) and Fe(III) in the presence of catechol is reported. In the case of reduction of Fe(III) in the presence of catechol, two steps occur at about -1.5 and -1.8 volts (vs. SCE) at pH higher than …

Photogrammetric Digitizing System, Frank Richard Gorshe

Dissertations and Theses

The acquisition of terrain data from aerial photography using digital photogrammetric methods gives the engineer and planner an economical alternative to conventional ground surveys. This paper describes a complete photogrammetric digitizing system developed for the Portland District Army Corps of Engineers. The hardware of the system consists of a

Wild AlO first order stereoplotter interfaced to an Altec AC-74 coordinate digitizer which is interfaced to both a Hewlett Packard 9810A programmable calculator and a Digi-Data nine-track magnetic tape recorder. The software of the system consists of photogrammetric routines developed for online computation by the programmable calculator and a sophisticated FORTRAN …

The Cusp Catastrophe And The Laws Of Dialectics, Martin Zwick

Complex Systems Faculty Publications and Presentations

The three classical "laws" of dialectics of Hegel and Engels, ( 1) the transformation of quantity into quality, (2) the interpenetration of opposites, and (3) the negation of the negation, can be given precise meanings in terms of the Catastrophe Theory of Rene Thom and E. C. Zeeman. This suffices to counter the charge that dialectics is scholasticism or empty metaphysics, but does not support claims of universality for the dialectical principles, nor guarantee the validity of any particular application of these principles.

The Systhesis And Photolysis Of 1-Phenylcyclohexaneacetic Acid Azide, Jack P. Mourad

Dissertations and Theses

The aim of this research project was to study the possible synthesis of the morphine analog 3-oxo-5-phenylmorphan via the photochemical cyclization of the acyl azide of 1-phenylcyclohexaneacetic acid.