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The Chemistry Of Sulfonyl Fluorides: Sf5 And/Or So2f Containing Compounds As Precursors To Sulfonic Acids, Robin Joyce Terjeson

Dissertations and Theses

Sulfonyl fluoride systems and their derivatives, RS0₂F, where R represents hydrocarbon/fluorocarbon moieties continue to be of considerable interest. The incorporation of the sulfonyl fluoride group (S0₂F) into molecular systems can lead to compounds that are useful as ion-exchange resins, surface active agents, fuel cell electrolytes, and strong sulfonic acids/salts.

Interest in preparing SF₅ containing sulfonyl fluorides led to the synthesis of the ᵝ-sultone, SF₅CHCF₂0S0₂, and its rearranged product. Hydrolysis of the sultone gave SF₅CH₂S0₂F which led to the sulfonic acid and salt, SF …

Analytically Reduced Form Of Multicenter Integrals From Gaussian Transforms, Jack C. Straton

Physics Faculty Publications and Presentations

In a previous paper the analytically reduced form was found for the general class of integrals containing multicenter products of ls hydrogenic orbitals, Coulomb or Yukawa potentials, and plane waves. The method consisted of combining all angular dependence within a single quadratic form by means of a three-dimensional Fourier transform and a one-dimensional Feynman transform for each term in the product and an additional integral transformation to move the resulting denominator into an exponential to be summed with the vector products in the plane waves. This quadratic form was then diagonalized with respect to the (introduced) momentum integrals and diagonalized …

Land Information System: Strategies For Local Governments In Oregon, Oregon. State Map Advisory Council

Center for Urban Studies Publications and Reports

The purpose of this report is to disseminate the findings and recommendations from the deliberations of the Oregon Land Records Committee (OLRC) of the State Map Advisory Council (SMAC). The OLRC consists of state and local government officials and professionals, and representation from utilities and private sector firms involved in the maintenance and use of land records and geographic information systems (GIS) for the analysis of data about land. These individuals have given freely of their time and experience in furtherance of the mission and goals of the OLRC.

This report is directed to professionals and public officials in local …

Fluorinated Esters: Synthesis And Identification, Jilla Schaff

Dissertations and Theses

Reactions of different alcohols with 2-hydroxy - 1- trifluoromethyl -1,2,2-trifluoroethanesulfonic acid sultone F₃CCFCF₂OSO₂ were studied. Six new esters were prepared: C₆F₅OC(O)CF(CF₃)SO₂F, CH₃CH₂OC(O)CF(CF₃)SO₂F, CF₃CH₂OC(O)CF(CF₃)SO₂F, (CF₃)₂CHOC(O)CF(CF₃)SO₂F, CH2=CHCH₂OC(O)CF(CF₃)SO₂F, (CH₂OC(O)CF(CF₃)SO₂F)₂. Analytical data, infrared, nmr and mass spectra are presented supporting the proposed structures for these new compounds.

Study Of Photolytic Interference On Ho Measurements By Lif-Fage, Carmen Ivette Martinez

Dissertations and Theses

For many years there has been a great interest among the scientific community in the study of the hydroxyl radical, HO. This interest stems from the fundamental role played by this molecule in the photochemistry of the atmosphere, mainly as a cleansing agent of environmental pollutants. Knowing the concentration of the radical would enable scientists to corroborate current atmospheric models and to predict future trends in the atmosphere. Even though there is a great interest in the determination of atmospheric concentrations of this molecule, the task has been very difficult. This is mainly due to the lack of a method …

Resource Allocation Patterns At U.S. Community Colleges: An Evaluation Of Priorities, Efficiency And The Historical Mission 1981-82 Through 1986-87, Douglas B. Morrison

Dissertations and Theses

Over a six-year period, this study compares the demonstrated priorities and efficiency of 328 U.S. community colleges to the historical mission of community colleges which includes the goals of unrestricted student access, service to many students, and the delivery of comprehensive, high-quality, low-cost educational programs. Sample data was provided by NACUBO for 328 institutions (out of a U.S. population of 770) reporting in both 1981-82 and 1986-87. The study compares the 1986-87 resource allocation patterns for each institution to the 1981-82 patterns for that same institution. Measurements include the level, mix, and rate of change in F.T.E. student enrollments, square …

An Analysis Of The Effect Of State Regulation Of Commercial Income Tax Preparers On The Quality Of Income Tax Returns, Jeanie Grace Sumner

Dissertations and Theses

Occupational regulation of many professions has grown in magnitude and complexity in the past fifty years. Statutes relating to occupational regulation are often implemented by state legislatures without sufficient quantitative analysis.

Prior studies have analyzed the need for regulation to protect consumers. Some research has been published which addresses the differences in the quality of services offered by regulated and unregulated professions. Due to lack of data, the effect of state regulation on commercial income tax preparers has not been quantified.

Recently data from the 1979 cycle of the Taxpayer Compliance Measurement Program (TCMP) has been made available by the …

Fluorinated [Beta]-Sultones As Precursors To Fluorinated Sulfonic Acids, And New Fluorosulfonyl Containing Monomers/Polymers, Javid Mohtasham

Dissertations and Theses

Sulfur trioxide (SO₃) adds to fluoroolefins of the form RCF=CF₂, (where R = F, SF₅, CF₃, CF₃OCF₂, CF₂=CF(CF₂)₂, CF₃(CF₂)₃O, CF₃O(CF₂)₂OCF₂, or CH₂ClCHClCH₂), yielding the fluorinated [beta]-sultones, RCFCF₂OSO₂. In the case of CF₃(CF₂)₃OCF=CF₂, a reverse addition occurs, giving the sultone, CF₃(CF₂)₃CF₂2OCFCF₂SO₂O. The fluoro [beta]-sultones are capable of undergoing different reactions, such as rearrangement, hydrolysis, esterification, and polymerization. These reactions, will result in the formation of compounds containing the fluorosulfonyl grouping (SO₂F); it is this group that yields the corresponding sulfonic acid upon base/acid treatment.

The addition of sodium bisulfite to CF₃CF= CF₂ and CF₃(CF₂)₄CF=CF₂ in the presence of (C₆H₅CO)₂O₂ and Na₂B₄O₇·10H₂O …

Organizational Inducements And Social Motives: A Game Theoretic Analysis, Richard G. Davis

Dissertations and Theses

Game theory was used to analyze compensation systems based on individual and group incentives. Payoff formulas were developed for these incentives assuming different preferences for individual and social outcomes. Two levels of contributions were considered: (1) Defection. The minimum acceptable level of contributions, and (2) Cooperation. A level of discretionary contributions above the minimum. The discretionary contributions associated with cooperation were represented as a cost to the individual.

A classification scheme for uniform n-person games was developed using the approach of Rappaport and Guyer (1966) for 2 x 2 games. This classification scheme defines the natural outcome (cooperation or defection) …

Relationships Between Teacher Perceptions Of Principal Support And Teacher Allocation Of Time, Betty Hutchinson Flad

Dissertations and Theses

The purpose of this study was to investigate teacher allocation of time and to examine if that allocation of time was related to teacher perceptions of principal behaviors and school policies. The study emerged from a review of the time-on-task literature and the principal effectiveness literature which suggested that teacher allocation of time might be related to principal behaviors and school policies. Three research questions were posed: (1) How do teachers allocate time to teaching responsibilities? (2) What perceptions do teachers have of principal behaviors and school policies at their schools? (3) Is there a relationship between teacher perceptions of …

Chemical Modification Of Skeletal Muscle Sarcoplasmic Reticulum Vesicles: A Study Of Calcium Permeability, Janice F. Stuart

Dissertations and Theses

Skeletal muscle contains an internal membrane system called the sarcoplasmic reticulum (SR) whose function is to regulate the Ca²⁺ concentration of the myoplasm. Ca²⁺ is transported into the SR from the myoplasm via a Ca²⁺ dependent ATPase thus lowering the myoplasmic Ca²⁺ concentration. Ca²⁺ exits from the SR via a Ca²⁺ releqse pathway resultingin the increase of myoplasmic Ca²⁺. Muscles contract when the myoplasmic Ca²⁺ concentration is > 5 uM and relax when the Ca²⁺ concentration is lowered below 1 uM. The Ca²⁺ dependent ATPase has been extensively studied but …

Ultrashort Pulse Production In Synchronously Pumped Mode-Locked Dye Laser Systems, Duncan Leo Macfarlane

Dissertations and Theses

The concern of this dissertation is the understanding and improvement of a class of lasers that is responsible for some of the shortest optical pulses available today. In particular, we seek ways to produce from synchronously pumped mode-locked dye laser systems, shorter pulses of higher intensity with improved pulse-to-pulse consistency. Specific topics.that are discussed herein include the study of the role of the pump pulse in synchronously pumped mode-locked lasers, the study of the pulse shaping and shortening due to an intracavity saturable absorber, and the study of a fundamental pulse train instability associated with these lasers.

The Market For Convention Facilities, Philipp Degens, M. Hossein Haeri, James G. Strathman

Center for Urban Studies Publications and Reports

Conventions, trade shows and meetings represent an industry of considerable size in the United States. In a 1984 survey, the International Association of Convention and Visitors Bureaus estimated a total of 20.5 billion dollars of annual expenditure generated by 54.3 million delegates nationwide. Despite its economic importance, the industry has received little analytical attention in the literature on tourism. In this paper we develop and estimate a model of demand for metropolitan convention facilities. Our results suggest that metropolitan convention activity is sensitive to both cost and attraction-related factors.

A Fractal Analysis Of Diffusion Limited Aggregation, Cliff Myers

Dissertations and Theses

A modified Witten-Sander algorithm was devised for the diffusion-limited aggregation process. The simulation and analysis were performed on a personal computer. The fractal dimension was determined by using various forms of a two-point density correlation function and by the radius of gyration. The results of computing the correlation function with square and circular windows were analyzed. The correlation function was further modified to include the edge from analysis and those results were compared to the fractal dimensions obtained from the whole aggregate. The fractal dimensions of 1.67 ± .01 and 1.75 ± .08 agree with the accepted values. Animation of …

A Lagrangian For A System Of Two Dyons, Rainer Georg Thierauf

Dissertations and Theses

Maxwell's equations for the electromagnetic field are symmetrized by introducing magnetic charges into the formalism of electrodynamics. The symmetrized equations are solved for the fields and potentials of point particles. Those potentials, some of which are found to be singular along a line, are used to formulate the Lagrangian for a system of two dyons (particles with both electric and magnetic charge). The equations of motion are derived from the Lagrangian. It is shown that the dimensionality constants k and k*, which were introduced to define the units of the electromagnetic fields, have to be equal in order to avoid …

Geographic Information Systems: Research Issues, Kenneth Dueker

Center for Urban Studies Publications and Reports

GIS research has evolved by trial and error. We need to think more systematically about GIS research. New technology and societal needs are important determinants of issues that govern GIS research strategies. URISA has a stake in fostering GIS research, particularly research that is appliications driven.

Roughness-Induced Resonance For Molecular Fluorescence Near A Corrugated Metallic Surface, P.T. Leung, Young Sik Kim, Thomas F. George

Physics Faculty Publications and Presentations

Based on a dynamical energy-transfer theory for the molecular decay rate near a rough metallic surface, a new resonance structure is predicted which is mediated by the roughness and which is absent in the static image theory. The implication of this new resonance structure to other phenomena, such as electron-energy-loss spectrum and cross coupling in thin films, is pointed out.

Dynamics Of Intermediate-Size Stream Outlets, Northern Oregon Coast, Ellen Eberhardt

Dissertations and Theses

This study measured and evaluated the relation of coastal foredune morphology to stream beach outlets, and investigated the processes associated with the stream outlet. Intermediate-size streams were studied, and defined as those that flow across the beach most of the year but have no tidal influence. Fifty-four of these streams were found along the northern Oregon coast between the Columbia River and Yaquina Bay. Crescent Lake Outlet, Saltair Creek and Daley Lake Outlet were chosen as study streams for further investigation.

Portland State Magazine, Portland State University. Office Of University Communications

Portland State Magazine

PSU’s alumni magazine, published quarterly. In this issue: Predicting presidential performance is the subject of the day for professors Jim Heath and David Smeltzer; paint brush to canvas has become light pen to video terminal in one Art Department office; advanced degrees in science and engineering are the focus of far-reaching plans at Portland State; a professor and a student from PSU heads up an experimental needle exchange program; and more.

Analysis Of Ferredoxin And Flavodoxin In Anabaena And Trichodesmium Using Fast Protein Liquid Chromatography, Karen Lorraine Jones

Dissertations and Theses

Iron is an essential nutrient for growth of photosynthetic microorganisms such as cyanobacteria and algae. Iron is required for proteins involved in the important processes of carbon and nitrogen assimilation. Low concentrations of iron in cultures or natural waters can lead to iron limitation which affects many aspects of algal metabolism. In natural waters, iron limitation can have effects on the patterns and rates of primary productivity.

The cellular content of certain proteins can be affected by media iron concentrations. Methods have been used that assay components of the cell as an indirect measure of iron nutritional status. For example, …

Portland State Magazine, Portland State University. Office Of University Communications

Portland State Magazine

PSU’s alumni magazine, published quarterly. In this issue: Making improvements in our justice system is more than an academic exercise for PSU’s Administration of Justice; using a new fitness test, PSU researchers are finding safer ways for the elderly to exercise; History Professor Gordon Dodds writes a book on the first 50 years at Portland State; and more.

A Geochemical Study Of The Eagle Creek Formation In The Columbia River Gorge, Oregon, Rachel Ann Carlin

Dissertations and Theses

The Early Miocene Eagle Creek Formation, a series of volcanic mudflows and debris flows, is exposed in the Columbia River Gorge about 64 kilometers east of Portland, Oregon. Eighty-seven samples were analyzed using instrumental neutron activation analysis for trace element concentrations. Eleven samples were analyzed by Dr. Peter Hooper at Washington State University using X-ray Fluorescence for major element chemistry. These data were used to determine that the Eagle Creek Formation compositionally ranges from andesite to dacite.

The Decay And Formation Of One-Dimensional Nonconservative Shocks, Marek Elźanowski, Marcelo Epstein

Mathematics and Statistics Faculty Publications and Presentations

The method of singular surfaces is used to obtain explicit conditions under which a one-dimensional acceleration wave develops into a shock when some dissipation mechanism is present. The conditions which secure the initial growth of the strong shock wave propagating into an undeformed nonlinear and dissipative medium are also derived. The analysis is pre- sented for a single balance law, one-dimensional elasticity, and the non- linear Maxwellian continuum.

Geochemical Stratigraphy Of The Dooley Rhyolite Breccia And Tertiary Basalts In The Dooley Mountain Quadrangle, Oregon, David Neale Whitson

Dissertations and Theses

The Dooley Rhyolite Breccia in northeast Oregon was erupted between 12 and 16 million years ago, from central vents and linear feeder dikes within the Dooley Mountain quadrangle. The peraluminous, high-silica rhyolites of the formation were erupted over an irregular highland of eroded pre-Tertiary metamorphic rocks locally overlain by intracanyon, Eocene Clarno-type basalt flow(s). The Dooley Rhyolite Braccia is exposed in a tectonically disrupted, north-south trending graben across the Elkhorn Range. The formation is variable in thickness with maximum thickness exceeding 660 meters in the south and 600 meters in the north half of the quadrangle. Volumetrically the formation is …

Implementing Ray Tracing Algorithm In Parallel Environment, Tjah Jadi

Dissertations and Theses

Ray tracing is a very popular rendering algorithm in the field of computer graphics because it can generate highly-realistic images from three-dimensional models. Unfortunately, the computational cost is very expensive. To speed up the rendering process we present both static and dynamic scheduling (balancing) strategies for a multiprocessor system. Hence, the load balancing among the processors is the most important problem in parallel processing. The implementation of the algorithm is based on a modified octree structure.

The Mechanism Of Intrusion Of The Inyo Dike, Long Valley Caldera, California, Ze'ev Reches, Jonathan H. Fink

Geology Faculty Publications and Presentations

We analyze the intrusion of the 11-km-long lnyo Dike at the margins of Long Valley caldera, eastern California. The dike trends N07°W and is divided into at least three segments which are rotated by as much as 25° with respect to the main trend. The dike seems affected primarily by the regional stress field of right-lateral shear of the western United States and by the local thermal conditions of the crust; the dike seems unaffected by the preexisting caldera margins and Sierra-Nevada frontal fault system. The high heat flow in Long Valley caldera implies that crustal rocks below 3-4.5 km …

Portland State Magazine, Portland State University. Office Of University Communications

Portland State Magazine

PSU’s alumni magazine, published quarterly. In this issue: Under the direction of Lee Casperson, PSU’s laser research lab is affecting the way the world uses lasers; helping crime labs identify skeletal remains has become a fascinating sideline for anthropologist Ann Bennett; conservative investing lessened the blow of October’s Black Monday for alumnus Richard Huson and his clients; the University’s 35 Advisory Councils are creating new bonds between PSU and the community; and more.

Faculty Senate Monthly Packet May 1988, Portland State University Faculty Senate

Faculty Senate Monthly Packets

The May 1988 Monthly packet includes the May agenda and appendices and the Faculty Senate minutes and attachments from the meeting held April 1988.

Spontaneous Coherent Pulsations In Standing-Wave Laser Oscillators, Lee W. Casperson

Electrical and Computer Engineering Faculty Publications and Presentations

Spontaneous pulsation phenomena in xenon lasers are now well known, and related effects have been observed with other laser types. Most theoretical analyses of such pulsations are formulated for unidirectional ring lasers, whereas most experiments involve standing-wave resonator geometries. Described here are rigorous semiclassical models governing the spontaneous pulsation instability in standing-wave laser oscillators. The standing-wave results are more complex and closer to experimental observations than the ring results for operation in the Lambdip region near line center.

Spectral Behavior And Pulse Train Instabilities Of A Synchronously Pumped Mode-Locked Dye Laser, Duncan Leo Macfarlane, Lee W. Casperson, Anthony A. Tovar

Electrical and Computer Engineering Faculty Publications and Presentations

The pulse-train envelope of a synchronously pumped mode-locked dye laser has been experimentally studied as a function of cavity length detuning. When a bandwidth-limiting birefringent tuning filter is included and the cavity is adjusted to the length that yields optimally short (˜2-psec) pulse, there is a slow (≤800 kHz), erratic amplitude modulation that provides a 20% variation in pulse energies. As the cavity length is detuned on the order of one part in 10⁴, the modulation vanishes, but the individual pulse lengths increade dramtically. Further detuning results in a clean periodic envelope with a 20% modulation depth and a˜5-μsec period. …