Digital Commons Network^™

The Temporal And Spatial Distribution Of Hydrocarbons In Atmospheric Deposition From Stations Surrounding Lower Chesapeake Bay, David Benjamin Webber

OES Theses and Dissertations

Hydrocarbon concentrations were determined in bulk, wet, and dry deposition samples from urban and non-urban locations surrounding lower Chesapeake Bay. Mean hydrocarbon concentrations in bulk deposition samples were over three times greater at the urban station indicating a localized source. The major hydrocarbons present were n-alkanes, polycyclic aromatic hydrocarbons (PAH), and the unresolved complex mixture (UCM). The PAH and the UCM were an indication of significant anthropogenic inputs while the odd/even distribution of the n-alkanes was an indication of biogenic sources. These findings indicated seasonal trends of highest biogenic hydrocarbon inputs in the spring and summer months and highest anthropogenic …

The Regioselective 3-Alkylation Of Piperidine, Richard Dunn Todd

Chemistry & Biochemistry Theses & Dissertations

The compounds: 3-allylpiperidine, 3-ethylpiperidine and 3-n-butylpiperidine have been synthesized by regioselectively alkylating the three position of piperidine. Piperidine was converted to N-chloropiperidine and then dehydrohalogenated to produce Δ¹-piperideine. The enamide anion was generated by adding solutions of Δ¹-piperideine to ethylmagnesium bromide or lithium diisopropylamide. Addition of alkylhalides produced 3-alkyl- Δ¹-piperideine which could be reduced or alkyllithiated to give 3-alkylpiperidines or 2,3-dialkylpiperidines respectively.

The yields of products were low and the reaction generated a continuum of mono- and di-alkylpiperidines and there was evidence that several dimeric piperideines were formed. The low yields were discussed in …

A Comparison Of Recruitment Strategies Among Brachyuran Crustacean Megalopae Of The York River, Lower Chesapeake Bay And Adjacent Shelf Waters, David Franklin Johnson

OES Theses and Dissertations

Twenty-one stations forming a transect of the Pamunkey River, York River, lower Chesapeake Bay and adjacent coastal waters were sampled from July through September 1980. The megalopa stages of 11 brachyuran species were sampled. Vertical and horizontal distributions are described for each species in relation to salinity and water column stratification. The megalopae are assigned to three apparent recruitment strategies: retained estuarine, expelled estuarine and retained coastal megalopae. the megalopa stages of estuarine adults, such as Hexapanopeus angustifrons, Neopanope sayi, Panopeus herbstii and Pinnotheres ostreum, are retained in estuarine epibenthic waters, while Rhithropanopeus harrisii are retained in slightly shallower …

A Pattern Analysis Algorithm For Wind Ambiguity Removal, Jaime R. Tormos

Electrical & Computer Engineering Theses & Dissertations

Some remote sensing devices, such as satellite microwave scatterometers, produce sampled wind vectors that are accurate in speed and streamline direction, but have a directional ambiguity of 180°. The extraction of information from the two dimensional wind vectors is readily handled using pattern analysis techniques. It is shown that there is sufficient information in the spatial relationships of the generated windstream vectors to recognize the driving meteorological wind patterns. This then leads to the resolution of the wind ambiguity problem. This thesis presents the development of a pattern analysis algorithm that generates a measure of the raw data set that …

Blueprints For A Small Theatre, Thomas J. Gale

Institute for the Humanities Theses

The contemporary small theatre, considered by some to be the germ of a new American theatre, has long been plagued by artistic starvation, technical ineptitude, and administrative inefficiency. Despite its traditional shortcomings, the small theatre has the potential to develop into a vital and financially viable institution.

Through a synthesis of the published opinions of theatre professionals and direct observations gleaned from practical theatre experience, this study addresses the aesthetic and practical problems faced by many contemporary small theatres. Solutions to these problems are suggested through specific plans for the establishment of a small but expanded professional theatre company.

The …

A Laboratory Study Of Nongenetic Embryonic Adaptation To Salinity And Its Subsequent Effects Upon Larval Development Of The Grass Shrimp Palaemonetes Pugio Holthius, Paul Jay Anninos

OES Theses and Dissertations

Fertilized embryos of the grass shrimp Palamonetes pugio Holthuis (Decapoda; Caridea) were exposed to two levels of salinity [5 ppt (exposed) and 20 ppt (control)] during incubation to determine the extent to which embryonic adaptation influences subsequent larval development. Larval response to embryonic exposure was measured at three salinities (5 ppt, 10 ppt, and 20 ppt) as the fraction of larvae surviving to metamorphosis and the duration (in days) of larval development. The survival rate of larvae hatched from control, or non-adapted, embryos was significantly influenced by rearing salinity. The differences in survival of pre-adapted larvae (exposed group), however, were …

Ortho Cyclization Reactions Of Catecholamines, Robert Lee Hudkins

Chemistry & Biochemistry Theses & Dissertations

A study was undertaken to examine the potential for ortho cyclization associated with the synthesis of 1,2,3,4,-tetrahydroisoquinolines using the Pictet-Spengler reaction. Specif1cally, the condensation of the biogenic amines, dopamine, norepinephrine and epinephrine were carefully examined in light of current literature and the facility and extent of ortho cyclization in each case. The para isomers of these three biogenic amine condensation products were isolated and characterized, while only the ortho isomer derived from dopamine was found stable and could be isolated, and structurally identified. These studies demonstrate that a second cyclization product does, in fact, form in each instance and that …

Measuring Interpersonal Dependency In Adolescent Psychiatric Inpatients, Susan D. Schaffer

Ellmer School of Nursing Theses & Dissertations

The successful inpatient treatment of emotionally troubled adolescents must facilitate their achievement of developmentally appropriate independence while minimizing the maladaptive dependency that can be fostered by the hospitalization experience. Levels of interpersonal dependency were measured in seven adolescent psychiatric inpatients over a ninety day period. The Interpersonal Dependency Inventory by Hirschfeld, Klerman, Gough, Barrett, Korchin, & Chodoff was utilized. The individual therapist of each participant independently assessed the participant's response to hospitalization at forty-five and ninety days using a five point Leikert type scale. The study demonstrated no significant changes in dependency levels at forty-five and ninety days. The therapist's …

Aseptic Techniques Currently Used In Dental Hygiene Clinics Within Accredited Dental Hygiene Programs, Jan Shaner Greenlee

Dental Hygiene Theses & Dissertations

The purpose of this survey was to assess the aseptic techniques currently used in 197 accredited dental hygiene programs in the United States. A self-designed, 51-item questionnaire examined the aseptic techniques used in: (1) preparation of the dental hygiene clinic and unit, (2) instrument preparation, (3) preparation of the student practitioner, (4) preparation of the patient, (5) preparation of radiographic equipment, and (6) treatment of the hepatitis patient.

The questionnaire and a letter of transmittal were mailed to the clinical supervisor of each accredited dental hygiene program. Data were obtained from 173 returned questionnaires and analyzed via modal and percentage …

A Capacitance Wavestaff And Measurements Of Wave Height Decay In The Surf Zone, David L. Timpy

OES Theses and Dissertations

A wavestaff system utilizing capacitance was developed to measure wave heights in the surf zone. Data were used to test the assumption that wave height decays linearly across the surf zone. The instrument system consisted of two wavestaffs and housing which contained the needed electronic circuits and a data recorder. Acceptable frequency response for waves of period greater than two seconds could not be obtained if sensor wires were greater than 0.35 mm in diameter. The size used was 0.35 mm.

A Structural Analysis Of Phytoplankton In The Chesapeake Bay Plume And Adjacent Shelf Waters, Charles K. Rutledge

Biological Sciences Theses & Dissertations

Community structures of phytoplankton populations from the southern portion of the Chesapeake Bight were examined and associated to real and environmental spaces. The sampling design was specifically intended to examine the small scale three dimensional structure of the Chesapeake Bay plume as characterized by its phytoplankton populations. The phytoplankton were sampled at 101 stations, non-synoptically, over a five day period in mid-June, 1980.

Several multivariate numerical techniques were used to determine the relationships between the phytoplankton species distributions and pattern the low salinity plume distribution. A pattern of distribution which approximated the salinity plume resulted from several clustering procedures. Environmental …

Unbounded Functions And Positive Linear-Operators, J. J. Swetits, B. Wood

Mathematics & Statistics Faculty Publications

The approximation of unbounded functions by positive linear operators under multiplier enlargement is investigated. It is shown that a very wide class of positive linear operators can be used to approximate functions with arbitrary growth on the real line. Estimates are given in terms of the usual quantities which appear in the Shisha-Mond theorem. Examples are provided.

An Update Of The Tidewater Apprenticeship Information Handbook, Claud R. Divers Iii

OTS Master's Level Projects & Papers

The problem of this study was to review the Tidewater Apprenticeship Information Handbook to update information about the apprentice program and employment outlooks for the various trade areas. This information was compiled for the use of guidance and vocational education personnel for local high schools and community colleges.

Organic N-Chloramines: Chemistry And Toxicology, Frank E. Scully, Jr., Maxwell A. Bempong

Chemistry & Biochemistry Faculty Publications

The stability of aqueous solutions of organic N-chloramines, suspected of contaminating chlorinated water, has been studied. Two factors influence the decomposition of solutions of N-chloropiperidine and N-chlorodiethylamine: a spontaneous decomposition and photodecomposition. Since solutions of these compounds are relatively long-lived, a need for an analytical method for their identification is discussed. A new method is described which involves reaction of organic N-chloramines with arenesulfinic acid salts. The method gives high yields of stable arenesulfonamides. Several toxicological studies of N-chloropiperidine are described. The compound is mutagenic by Ames assay in Salmonella typhimurium strain TA 100 and does not require metabolic activation …

Seeded Oscillatory Growth Of Si Over Sio² By Cw Laser Irradiation, G.K. Celler, L. E. Trimble, K.K. Ng, H.J. Leamy, H. Baumgart

Electrical & Computer Engineering Faculty Publications

Extensive seeded epitaxial growth of crystalline Si over SiO₂ was achieved by an oscillatory regrowth method applied to rectangular Si pads recessed into a thick SiO₂ film. Narrow (≃5 μm) via holes linked the pads with the bulk (100) Si substrate. Oriented single crystals propagated as far as 500 μm from the seeding area, following the long term advance of a scanned focused laser beam.

An Evaluation Of Nutrient Sources To Onslow Bay, North Carolina, Larry P. Atkinson, Leonard J. Pietrafesa, Eileen E. Hofmann

CCPO Publications

Hydrographic and current meter data from Onslow Bay, North Carolina, were examined to determine the relative importance of various nutrient sources.

Upwelled Gulf Stream water is the major source of nutrients while rivers represent a minor, if not insignificant, source. In the summer during stratified conditions, the upwelled water penetrates across the shelf, but in the winter the upwelled water is restricted to the outer shelf. Nitrate flux across the 40 m isobath was calculated from continuous temperature and current records. Flux during the summer of 1976 was 2 μM m² sec^-1 which is considerably less than flux …

Smallest Cubic And Quartic Graphs With A Given Number Of Cutpoints And Bridges, Gary Chartrand, Farrokh Saba, John K. Cooper Jr., Frank Harary, Curtiss E. Wall

Mathematics & Statistics Faculty Publications

For positive integers b and c, with c even, satisfying the inequalities b+1≤c≤2b, the minimum order of a connected cubic graph with b bridges and c cutpoints is computed. Furthermore, the structure of all such smallest cubic graphs is determined. For each positive integer c, the minimum order of a quartic graph with c cutpoints is calculated. Moreover, the structure and number of all such smallest quartic graphs are determined.

Local Lp-Saturation Of Positive Linear Convolution Operators, J. J. Swetits, B. Wood

Mathematics & Statistics Faculty Publications

Local L_p-saturation of positive linear convolution operators is investigated. Results are obtained for two important classes of operators previously studied by Bojanic, DeVore, Korovkin and the authors.

A Survey To Assess The Needs For Expanding The Child Care Program In The Vocational Occupational Home Economics Curriculum At Northampton High School, Martha L. White

OTS Master's Level Projects & Papers

The following objectives were applied to this study: 1. To find out what high schools are doing to provide young people with the knowledge and skills that will enable them to become effective parents; 2. To determine if there is an adequate number of day care programs provided here on the Eastern Shore to assist working parents within parents routes to work; 3. To determine if working parents would be interested in a day care program within or on the campus where parents work.

A Survey Of Business Education Graduates Of Accomack County For 1980-1981, Alma M. Davis

OTS Master's Level Projects & Papers

This study measured the effectiveness of student training in business education for those students enrolled in traditional classes as compared to those enrolled in the block program classes in Accomack County for 1980-1981.

A Study To Determine The Major Reasons For The Mass Exit Of Industrial Arts Teachers In The Chesapeake Public School System, Richard L. Macdonald

OTS Master's Level Projects & Papers

This study sought to answer the question of why so many vocational education teachers in the Chesapeake school district were seeking other careers.

Picosecond Laser Pulse Irradiation Of Crystalline Silicon, K. L. Merkle, H. Baumgart, R.H. Uebbing, F. Phillipp

Electrical & Computer Engineering Faculty Publications

Morphology changes introduced by picosecond laser pulses at λ = 532 nm and 355 nm in (111) and (100) silicon samples are studied by means of optical and high-voltage electron microscopy. Depending on energy fluence, orientation and wavelength, amorphous or highly defective regions may be created. From an analysis of damage thresholds and damage depth distributions it is concluded that melting and energy confinement precedes the formation of the structural changes.

Electrical And Structural Properties Of P-N Junctions In Cw Laser Annealed Silicon, M. Maier, D. Bimberg, G. Fernholz, H. Baumgart, F. Phillipp

Electrical & Computer Engineering Faculty Publications

Depth profiles of the electrical quality of ion implanted and cw laser annealed p-n junctions in silicon are obtained for the first time by secondary ion mass spectroscopy. A comparison with the crystallographic properties of the surface and the junction as observed by Nomarski optical microscopy as well as cross-sectional and plan view transmission electron microscopy is made. Samples containing slip dislocations show better insulation and a lower reverse bias current across the p-n junction as compared to samples with a perfect surface in agreement with current-voltage characteristics. Small dislocation loops located at the junction are found to degrade the …

A Quantitative Description Of Migratory Behavior Of The Brown Shrimp (Penaeus Aztecus) With Applications In Fisheries Management, Anne Madolyn Babcock

OES Theses and Dissertations

A quantitative description of the migratory behavior of the brown shrimp, Penaeus aztecus, was established using the density approach. A theoretical time density was estimated by the proportion of catch and catch per boat hour NOAA-NMFS fisheries statistics collected in Pamlico Sound, the Neuse River, and Core Sound. A clear quantitative description of brown shrimp migratory timing is found in the time densities. The impact of various physical tactors on the progress of the fishery in time and space can be objectively evaluated by using the time density statistics as dependent variables in modeling efforts. The distributions also enable …

"The Tide Of The Unconscious" Jung, Bosch And The Archetypes Of The Garden Of Earthly Delights, Andrea R. Peck

Institute for the Humanities Theses

Many scholars have discussed the meaning of Hieronymous Bosch's The Garden of Earthly Delights concluding that Bosch's works were of a conscious nature relating to the real world. By contrast, this study, using the theories of Carl Jung, fragments Bosch's work and sees the milieu of his art through the eyes of the collective unconscious. Accordingly, a number of explanations of Jungian ideas are presented with the view to better understanding Bosch: Jung's theory of the archetypes, his view of Christianity, his analysis of medieval alchemy, as well as matrix archetypes and symbolic forms relating to The Garden. Through this …

Experimental Investigation Of A Rectangular Surface Thermal Plume, Li-Cheng Chu

Mechanical & Aerospace Engineering Theses & Dissertations

An experimental investigation of the three dimensional mean temperature distribution of a rectangular buoyant surface thermal plume has been conducted for a range of buoyancies, velocity ratios, Reynolds numbers, and for various turbulence generating screens in the crossflow. This study has been motivated by a concern about the applicability of laboratory model data for predicting prototype plume behavior.

A large scale model has been built to study a buoyant, rectangular surface thermal plume which enters at right angles to a constant temperature uniform crossflow of depth equal to that of the plume. A large water tank and flume with weir …

Analysis Of Aerothermodynamic Environment Of A Titan Aerocapture Vehicle, Hsing Chow

Mechanical & Aerospace Engineering Theses & Dissertations

The extent of convective and rad1ative heating for a Titan entry vehicle is invest1gated. The flow in the shock layer is assumed to be axisymmtric, steady, viscous, and compressible. It is further assumed that the gas is in chemical and local thermodynamic equilibrium and tangent slab approximation is used for the rad1ative transport. The effect of slip boundary conditions on the body surface and at the shock wave are included in the analysis of high altitude entry conditions. The implicit finite difference technique is used to .solve the viscous shock layer equations for a 45-degree sphere cone at zero angle …

The Effects Of Copper On Skeletonema Costatum (Greville) Cleve, Susanne Sybille Jackman

Biological Sciences Theses & Dissertations

Copper levels and dominant phytoplankton species composition were examined from six sites in Kings Creek on Virginia's Eastern Shore from March to August 1980. Creek copper levels were determined by an APDCMIBK extraction procedure and ranged from 0.003 to 0.020 mg/1. Diatoms were the dominant phytoplankters with Skeletonema costatum (Greville) Cleve emerging as a major late summer species.

Subsequent laboratory studies involved 96-hour experiments using Skeletonema costatum (clone Skel) grown in enriched natural seawater. The water was collected from Kings Creek and enriched to Guillard and Ryther's (1962) f/2 media levels. Cupric sulfate was added to the experimental culture media …

Synthesis Of Dihydroisoquinolines And Tetrahydroisoquinolines, John J. Schlager

Chemistry & Biochemistry Theses & Dissertations

Dihydroisoquinolines and tetrahydroisoquinolines are compounds which possess a variety of pharmacological activities. New easier methods of synthetic manipulations of these structures is of constant interest in the pharmaceutical industry.

This paper describes a new three step method of preparing 1-alkyl- and 1-aryl-tetrahydroisoquinolines from a tetrahydroisoquinoline. The synthesis involves the N-chlorination of tetrahydroisoquinoline followed by dehydrohalogenation with potassium superoxide. The reaction products are the dihydroisoquinolines. Overall yields range from 85-96%. The unsubstituted, 1-methyl-, and 1-phenyl-J,4-dihydroisoquinolines have been formed. Organometallation of the unsubstituted dihydroisoquinoline provides the 1-substituted tetrahydroisoquinoline. The 1-benzyl-, 1-n-butyl-, 1-ethyl-, 1-methyl-, and 1-phenyl-1,2,J,4-tetrahydroisoquinolines were prepared. The use of Grignard and …

A Direct Formulation And Computer-Implementation Of A Symbolic Network Analysis Algorithm, Timothy James Knerr

Electrical & Computer Engineering Theses & Dissertations

An algorithm for the symbolic analysis of linear, time-invariant, active or passive networks is presented. The algorithm incorporates the best features of earlier numerical and topological methods of symbolic analysis. A hybrid set of equations is formulated for a closed linear graph and arranged in matrix form. A numerical evalu­ation procedure for the determinant of this hybrid matrix results in an efficient method of symbolic analysis. A proof of the algorithm based on determinant evaluation by a permutation product expansion provides insight into relationships with other methods of symbolic analysis. A computer program implementation of the algorithm is described and …