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Complexes Of The 2,2'-Bisacylhydrazide Of 3,3'-Bipyridine And The Dipicolinic Acid Dihydrazide Ligand Systems, William Leo Johnson Iii

Chemistry & Biochemistry Theses & Dissertations

The copper(II) complexes of the picolinic acid bydrazide (PH), the dipicolinic acid dibydrazide (DPH), and the 2,2'-bisacylbydrazide of 3,3'-bipyridine (DAR) ligand systems have been prepared and have been characterized by infrared spectroscopy. Coordination has been proposed to occur between the terminal amine, the amide nitrogen, and the ring nitrogen in each of the respective complexes.

Evidence for the loss of the amide hydrogen upon complexation of PH, DPH, and DAH with copper(II) has been observed by the n.m.r. study of the zinc(II) complexes of the PH and DAH ligand systems. This is in support of the structures proposed above for …

Intervention Effects Of A Crisis-Resource Program In A Public School, Marcella A. Kerlin

Communication Disorders & Special Education Theses & Dissertations

No abstract.

Food And Feeding Of Fishes From Magothy Bay, Virginia, Joseph J. Kimmel

OES Theses and Dissertations

No abstract provided.

The Concept Of Authority In James Otis And Thomas Paine, Mark Allan Brown

History Theses & Dissertations

Abstract unavailable.

A Zooplankton Study Of Stumpy Lake, Virginia Beach, Virginia, Jose E. Hernandez

Biological Sciences Theses & Dissertations

A one year study was made of the zooplankton composition in Stumpy lake, a reservoir in the city of Virginia Beach, Virginia. Quantitative and qualitative -parameters were investigated under field conditions. The analysis of the data presents information on the monthly dynamics or the zooplankton and other fluctuations in the lake environment. It is the intention or this study to emphasize the seasonal changes in the zooplankton community and their relationship to the ecological factors responsible for these variations.

Computer-Aided Design Of Light Aircraft To Meet Certain Aerodynamic And Structural Requirements, Joanne Lynn Walsh

Mechanical & Aerospace Engineering Theses & Dissertations

Nonlinear mathematical programming techniques are applied to a particular aircraft design problem, that of determining the maximum range design for light aircraft subject to certain aerodynamic and structural requirements. Search techniques available in an existing nonlinear optimization computer program, AESOP, are applied to the design problem. Seven design variables are used to define the wing dimensions, the wing skin thickness, the cruise velocity, the amount of fuel carried, and the engine horsepower. The influence of different design requirements on the range is observed and discussed.

A Simulation Model Of Peromyscus Leucopus In An Area Of The Great Dismal Swamp, James E. Paschal Jr.

Biological Sciences Theses & Dissertations

A computer simulation model was developed to explain the population dynamics of the white-footed mouse (Peromyscus leucopus) in an area of the Great Dismal Swamp. The model was designed to provide an experimental base for future studies. The model indicates relationships between food availability, home range size, competition with Peromyscus nuttali habitat selection and reproduction.

White-footed mice were trapped in the Old Dismal Town site during each season from April, 1972 through March, 1973. The age-sex structure of the population was determined, and was compared with the simulated structure. Although there were significant discrepancies between the comparisons, the …

Investigation Of The Halocline Structure In Lower Chesapeake Bay, Samuel Bowen Heltzel

OES Theses and Dissertations

A portion of the Chesapeake Bay from 37°20’N latitude to the entrance was investigated to determine the halocline structure, the effects on this structure through the tidal sequence, and seasonal variations. A determination of the stage of slack water during which maximum extension of the halocline occurred was also made. This was accomplished by looking at the salinity distribution at the halocline upper limit, the mean depth to the halocline, and seasonal salinity contours drawn for tidal increments. By comparing salinity/depth gradients and salinity-depth vertical profiles, an attempt was made to relate seasonal and tidal variations to the halocline structure. …

A Seasonal Distributional Survey Of The Epiphytic Diatoms Of The Outer Banks Region Of North Carolina With Respect To Temperature And Salinity, Charles Welles Belin Jr.

OES Theses and Dissertations

This study was initiated to investigate epiphytic diatoms at selected stations along the North Carolina coast and bay region. The relationships between these organisms and the season of the year and salinity and temperature of the water in which they were found are considered. The special affinity between the epiphytic diatoms and their host plants is also discussed. The specific data were analyzed statistically via linear correlation coefficients, graphs of least squares-best fit, and multiple linear regression analysis.

From the statistical tests, it was found that the mean number of epiphytic diatoms shows a significant multiple linear regression with respect …

Governmental Elites In Three Virginia Counties: A Reappraisal Of The Turner Thesis, Harry Stuart Holman

History Theses & Dissertations

Abstract unavailable.

Numerical Study Of The Turbulent Boundary Layer In A Hypersonic Nozzle, Joan Patricia Gosink

Mechanical & Aerospace Engineering Theses & Dissertations

A numerical study of the turbulent boundary layer in a hypersonic nozzle is presented. The boundary layer equations are solved by a second order, implicit finite difference scheme developed at Langley Research Center. The technique is applicable to laminar, transitional or turbulent compressible or incompressible boundary layer flows for planar or axisymmetric geometries. A technique is presented for utilizing experimental data to start the finite difference solution.

Turbulent boundary-layer measurements on axisymmetric nozzle walls at Mach number 6 are presented and compared with numerical predictions obtained by starting the solution in the stagnation chamber and from a downstream experimental station. …

Effect Of Air Bubble Solution On Air-Sea Gas Exchange, Larry P. Atkinson

CCPO Publications

Recent data on ambient wave generated oceanic bubble spectra (Medwin, 1970) permit the calculation of the influence of bubble solution on air-sea gas exchange. Schulkin's formula is used to estimate the depth variation of bubbles, and a square law is used to estimate the increase of bubble volume with wind speed. Calculations indicate that bubble solution can be a very significant factor in gas exchange. Bubble solution enhances gas input and retards degassing of the water column. Preliminary data show a lag time of about 5 hours in the response of the water column to an atmospheric pressure change.

The Social Status Of Special Class Emr Adolescents Assigned Part-Time To Public School Regular Classes, Margaret E. Carter

Communication Disorders & Special Education Theses & Dissertations

No abstract.

John M. Daniel Editor Of The Richmond Examiner And Gadfly Of The Confederacy, Raymond K. Cooley

History Theses & Dissertations

Abstract unavailable.

Seismic Refraction Study Of Post-Pliocene Stratigraphy, Dismal Swamp, Virginia, William Brian Fraser

OES Theses and Dissertations

This study examines Pliocene-Pleistocene lithostratigraphy and the Yorktown unconformity within the Dismal Swamp by means of remote sensing analysis, Wyrobek-Gardner seismic refraction profiling and split-spoon coring. Pre-Sangamon fluvial/tidal channel deposits are not present and the Yorktown unconformity dips irregularly southeastward at 0.35 meters/kilometer (2 feet/mile) from a high at 4 meters above sea level to a low of -1 meter (+12 to -2 ft) below sea level. The marker velocity for the Yorktown Formation is 1600 mps (5250 fps) and regression of seismic depths of the Yorktown Formation with corresponding split-spoon depths yields a high correlation. Short line upper layer …

The Expression Of Despair In Three Hardy Novels, Brenda J. Casey

English Theses & Dissertations

No abstract.

Morphologic Time Series From A Submarine Sand Ridge On The South Virginia Coast, John F. Mchone Jr.

OES Theses and Dissertations

Submarine sand ridges several km long locally merge southward into the U. S. Atlantic coastline. Shallow (< 8m) observations of -such a ridge at False Cape, Virginia, favor a modern hydraulic origin. Time series maps show the ridge to be paralleled by a landward trough of approximately equal volume. Ridge flanks are usually steeper on the trough side.

Northeasterly winds and waves generate a coast-parallel current which funnels southward into the trough scouring it out and providing sediments for ridge aggradation. The current may be organized as a helical flow cell or cells. Bottom currents converge southward along the ridge crest causing landward transport of traction load along the crest. The trough current eventually breaches the confining ridge at the head of the trough, cutting saddles with steeper seaward slopes and producing outlying sediment fans.

The ridge and trough rest obliquely …

Air Bubbles In An Oceanic Mixed Layer: Effect On Gas Concentrations And Air-Sea Gas Exchange, Larry P. Atkinson

CCPO Publications

This thesis attempts to determine the effect of air bubbles that are entrapped into the surface layers of the ocean by breaking waves on gas concentrations in the ocean and gas exchange across the air-sea interface. N₂ and Ar data gathered during the Hudson-70 expedition produced indications of the magnitude and nature of the effect. A mathematical model is developed that equates the input of gas via bubble solution with the vertical eddy diffusion. Published values for bubble spectra and solution rates are used and assumptions are made concerning the effect of wind on bubble spectra. The model predicts …

The Urban Gestation: City Building In Wilmington, Delaware, Dennis Signorovitch

History Theses & Dissertations

Abstract unavailable.

The Synthesis And Characterization Of The 2,2'-Bisacylazide Of 3,3'-Bipyridine, Magdy Adly Guirguis El-Fayoumy

Chemistry & Biochemistry Theses & Dissertations

The primary objective of this research has been the synthesis and characterization of a new heterocyclic diacylazide, the 2,2'-bisacylazide of 3,3'-bipyridine 19. This heterocyclic diacylazide has been successfully synthesized from the phenanthrolin-5,6-dione 14, and examined with regard to its.thermal and photolytic decomposition.

Thermal decomposition of this disacylazide seems to go by a double-barreled Curtius rearrangement leading to a series of pyridonaphthyridinone (20) compounds such as 22 and 29.

An initial study of the photolysis of this bisacylazide has been initiated to examine the possible formation of nitrene-type intermediates.

The Contributions Of The W. K. Kellogg Foundation To Adult Education, Betty Lou Mitchell

Educational Leadership & Workforce Development Theses & Dissertations

No abstract.

Phytoplankton Distribution In Waters Off The Northeastern Coast Of The United States, Sharon H. Craft

Biological Sciences Theses & Dissertations

Abstract unavailable.

Ben Butler And The Occupation Of Norfolk, 1862-1865: A Reappraisal, Kenneth H. Schwartz

History Theses & Dissertations

Abstract unavailable.

A Numerical Technique For Solving Rigid Body Impact On An Incompressible, Viscous Medium, Cecil Thomas Chapman

Civil & Environmental Engineering Theses & Dissertations

A technique for solving rigid-body impact on a viscous, incompressible medium is presented. The numerical scheme is adapted from the Marker and Cell (MAC) method developed to solve problems involving time-dependent motion of a viscous, incompressible fluid in two-dimensional space. As the pressure end velocity fields are computed throughout the flow field, the solution gives the force and displacement time history of the rigid-body during the impact phase. In conjunction with this, through a system of marker particles, the changes in configuration of the viscous medium on impact can be studied. With a "movie frame" (incremental time) approach, computational experimentation …

Determination Of Nutrient Levels And Proposed Predictive Models For Phosphate In The Lafayette River, Norfolk, Virginia, John R. Montgomery

OES Theses and Dissertations

The Lafayette River, an Urban, well-mixed estuarine embayment, was sampled from October, 1970 to January, 1972 for phosphate, nitrate, nitrite, oxygen, water temperature and salinity. The mean values found for these samples were: oxygen saturation from 69% to 106% nitrate from 0 to 4 microgram-atoms per liter, and salinity from 13 ‰ to 24 ‰. The mouth of the Elizabeth River to Hampton Roads as also sampled from May, 1971 to August, 1971. The Lafayette and Elizabeth Rivers were also sampled over a 24 hour period in the summer of 1971 and the Lafayette River again in the winter of …

An Interdisciplinary Semantic Analysis Of Labels For "Emotional Disturbance", Mary Lou Green

Communication Disorders & Special Education Theses & Dissertations

A systematic pilot investigation of connotative differences in the meaning of commonly used labels for "emotional disturbance" was undertaken with psychiatrists, psychologists, social workers, elementary-education teachers, special-education teachers, and counselors in the Tidewater area of Virginia. The Semantic Differential technique de eloped by Osgood (1952) was selected as the method of investigation, and an instrument was prepared from a sample of the professional and nonprofessional populations through the use of a modified paper-and-pencil free association. A 35-scale instrument was developed from this procedure and administered to a sample of 100 graduate and undergraduate students at Old Dominion University, Norfolk, Virginia. …

Surface Water Turbidity In The Entrance To Chesapeake Bay, Virginia, James R. Melchor

OES Theses and Dissertations

Seasonal and spatial variations in the surface water turbidity across the entrance to Chesapeake Bay, Virginia, have been monitored with an optical transmissometer for one year. The data indicate a suspended-sediment gradient across the entrance with higher turbidity on the south side. This condition suggests that the flooding and ebbing tidal currents are influenced by Coriolis force. Clearer ocean water is introduced into the bay on the north side; whereas highly turbid water from the major drainage systems exits on the south side. A salinity gradient with18 0/00 on the south side of the bay and approximately 32 0/00 on …

An Investigation Of The Feasibility Of Computer Assisted Instruction (Cai) In The Elementary School, Jane Chavis

STEMPS Theses & Dissertations

No abstract provided.

A Physical Hydrographic Study Of The Lafayette River, E. Glenn White

OES Theses and Dissertations

A basic investigation of the physical ~properties, temperature, density and current velocity, in the Lafayette River is presented. Graphs of the observations indicata a difference in salinity, density and current velocity- distributions after moderate to heavy rains from the graphs during a dry period. The changes in distribution indicate a change in the classification of the estuary from a type B/C, partially mixed estuary, to a type D, sectionally homogeneous estuary. The estuary is predominantly a well-mixed or sectionally homogeneous estuary.

Changes in salinity, temperature, density and current velocity over tidal cycles are discussed as well as tidal height data. …

Political Concepts In The Novels Of Carson Mccullers, Ronald Flowe

English Theses & Dissertations

No abstract.