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Investigation Of Nickle As A Matrix Modifier In The Atomic Absorption Analysis Of Tin, Charles William Saunders

Chemistry & Biochemistry Theses & Dissertations

Nickel has been widely used as a matrix modifier in the flameless atomic absorption analysis of arsenic and selenium. Its utility as a modifier for tin has been investigated using Polarized Zeeman effect Graphite Furnace Atomic Absorption Spectroscopy. Peak area, peak shape, and appearance times were compared in modified and nonmodified standards using the system computer's internal integration and a detector/readout system with 18 msec resolution.

The addition of nickel at 600 mg/L increased the tin absorbance signal five-fold. The improved signal to noise ratio resulted in a two-fold increase in the sensitivity and a lower limit of detection. The …

Attitudes Of Special Education Students Towards Vocational Education Classes At Western Branch High School, Chesapeake, Virginia, Cynthia R. B. Sessoms

OTS Master's Level Projects & Papers

The purpose of this study was to determine special education students' attitudes towards vocational education classes. The following questions have provided guidance to the investigator in designing this study: 1) Is the decision to enroll in vocational education classes primarily made by the student(s)? 2) Are there external influences that affect special education students decisions to enroll in vocational classes from: a. peer pressures b. parental advice c. school guidance counselor d. special education teacher; 3) Has the student planned to enroll in a vocational education course in the future?

Deep Flow Variability In Central Drake Passage, John M. Klinck, Eileen E. Hofmann

CCPO Publications

A rotary empirical orthogonal function analysis of the currents measured in central Drake Passage during DRAKE 79 shows that the deep (2500 m) flow has the same spatial and temporal structure as the flow at 500 m, suggesting that current variability in this region penetrates to the bottom. However, comparison of the time amplitude of the corresponding modes indicates that the variability of the 2500 m flow resulting from north to south shifts in the location of the Polar Front lags that at 500 m by one to three days. This implies that the Polar Front slopes to the east …

Sediment Processing And Selective Feeding By Pectinaria Koreni (Polychaeta: Pectinariidae), Fred C. Dobbs, Teresa A. Scholly

OES Faculty Publications

Pectinaria (Lagis) koreni (Malmgren) is an abundant, deposit-feeding, infaunal inhabitant of shallow-water marine environments in northern Europe. Laboratory experiments were performed to quantify the polychaete's sediment processing in 2 distinct sediments, 1 fine-grained and high in combustibles, the other coarse-grained and low in combustibles. Gut passage time and time to pseudodefecation were predictable only in coarse-grained sediment. In both sediments, reworking rate increased with worm size and over time, although temporal patterns differed in the 2 sediments. The ratio of pseudodefecated sediment to defecated sediment did not differ significantly over time in either sediment, but the ratio was greater in …

On The Linear Relation Between Mb And Ms For Discrimination Between Explosions And Earthquakes, Ali A. Nowroozi

OES Faculty Publications

Summary. The statistical capability of the m_b :M_s, discriminant for the discrimination of earthquake and explosion populations is examined by application of discriminant functions to a group of 83 explosions and 72 earthquakes in Eurasia. Equations are derived for the probability that an event is an earthquake or an explosion. The positive sign of DIS in the decision index equation,

DIS, = 34.3383 - 11.9569 mb_i, + 7.1 161 M_si,

indicates that the event i is an earthquake. Its negative sign indicates that event i is an explosion. The probability of …

Nonadiabatic Theory Of Fine-Structure Branching Cross Sections For Na-He, Na-Ne, And Na-Ar Optical Collisions, Linda L. Vahala, P. S. Julienne, Mark D. Havey

Electrical & Computer Engineering Faculty Publications

The nonadiabatic close-coupled theory of atomic collisions in a radiation field is generalized to include electron spin and is used to consider the weak-field Na–rare-gas (RG) optical collision Na(²S_1/2)+RG+nhν μNa(²P_j)+RG+(n-1)hν. The effects of detuning and incident energy on the branching into the atomic Na 3p²P_3/2 and 3p²P_1/2 states are examined. The cross sections σ(j) are found to have a strong asymmetry between red and blue detuning as well as a complex threshold and resonance structure dependence on energy. A partial cross-section analysis …

In Situ Growth And Chemical Composition Of The Giant Kelp, Macrocystis Pyrifera: Response To Temporal Changes In Ambient Nutrient Availability, Richard C. Zimmerman, James N. Kremer

OES Faculty Publications

Temporal variations in growth of the giant kelp Macrocystis pyrifera were examined in relation to ambient nutrient availability and chemical composition of mature blades, the primary site of nutrient and carbohydrate storage in M. pyrifera. The effect of nutrient availability on growth was well approximated by a Monod rectangular hyperbola, with growth saturating at ambient nitrate concentra- tions between 1 and 2 FM. M. pyrlfera was unable to generate nutrient reserves that would last beyond 30 d. Nitrogen reserves were stored as free amino acids, and generally constituted about 10 % of total tissue nitrogen. Total nitrogen content was …

An Assessment Of Current Procedures And Practices For Placement Of Handicapped Students In Vocational Programs In Chesapeake, Virginia, Linda Denise Britt

OTS Master's Level Projects & Papers

The questions related to this study were: 1. What major pieces of legislation shaped and promoted new cooperation between special education and vocational education in serving the handicapped? 2. How can administrators, special educators, vocational educators, guidance counselors, and parents augment cooperation, support, and communication between each other? 3. What are some of the considerations that effect decisions for placement of handicapped students in a vocational program?

Factors Regulating Settlement And Microhabitat Use By Spiny Lobsters Panulirus Argus, William F. Herrnkind, Mark J. Butler Iv

Biological Sciences Faculty Publications

Clumps of highly-branched red algae Laurencia spp. serve as important settling habitat for postlarval spiny lobsters Panulirus argus and as residence for early benthic-stage juveniles. Given choice between the 2 most abundant macrophytes in Florida Bay, Laurencia spp. and the seagrass Thalassia testudinum, postlarval and juvenile lobsters chose Laurencia spp. Postlarvae apparently use intricate algal architecture as a cue for settlement, whereas juveniles use both architecture and food abundance in selecting habitat. In tethering experiments, predation on juvenile lobsters was very high on open sand, much reduced in algal clumps and seagrass, and lowest in dense algal meadows. Predation …

Tidal Circulation In Chesapeake Bay, Carl W. Fisher

OES Theses and Dissertations

This study is a comprehensive examination of the tidal circulation of Chesapeake Bay and its major tributaries. Tide and current data, which were observed in Chesapeake Bay by the National Ocean Service during the period from 1972 to 1983, are analyzed and used to construct charts that describe the tide and tidal current. Frictionally damped analytic models are used to: explain the tidal hydrodynamics of the observed tides, determine the location of the quasinodes and antinodes of the M₂ and K₁ tidal waves, explain the relationship of the tides and tidal currents, and determine if the tide in …

Estimation In Truncated Exponential Family Of Distributions, Laxman M. Hegde

Mathematics & Statistics Theses & Dissertations

Estimating the parameters of a truncated distribution is a well known problem in statistical inference. The non-existence of the maximum likelihood estimator (m.l.e.) with positive probability in certain truncated distributions is not well known. To mention a few results in the literature:

(i) Deemer and Votaw 1955 show that the maximum likelihood estimator does not exist in a truncated negative exponential distribution on 0,T , T > 0 known, whenever the sample mean x (GREATERTHEQ) T/2.

(ii) Broeder 1955 shows that the maximum likelihood estimator of the scale parameter of a truncated gamma distribution, with the shape parameter being known, becomes …

Faceting At The Silicon (100) Crystal-Melt Interface: Theory And Experiment, Uzi Landman, W.D. Luedtke, R.N. Barnett, C.L. Cleveland, M.W. Ribarsky, Emil Arnold, S. Ramesh, H. Baumgart, A. Martinez, B. Khan

Electrical & Computer Engineering Faculty Publications

Molecular-dynamics simulations and in situ experimental observations of the melting and equilibrium structure of the crystalline Si(100)-melt interface are described. The equilibrium interface is structured, exhibiting facets established on (111) planes.

Silicon-On-Insulator Technology By Crystallization On Quartz Substrates, Helmut Baumgart

Electrical & Computer Engineering Faculty Publications

The purpose of the novel zone-melting recrystallization process (ZMR) is to produce single crystalline Si films on Si02 of high crystalline perfection, which are suitable for device fabrication and subsequent industrial applications. However, silicon films grown on amorphous insulating substrates without seeding contain regularly spaced subgrain boundaries as their predominant growth defect and to a lesser degree twin boundaries and some grain boundaries. Detailed materials studies have revealed the core structure of these extended defects and the fundamental mechanisms responsible for subgrain boundary formation. The nature and origin of subgrain boundaries is reviewed and a model for polygonization of the …

Absorption Cross-Sections Of Sodium Diatomic Molecules, Zeng-Shevan Fong

Physics Theses & Dissertations

The absorption cross sections of sodium dimers were studied using a heat pipe over operating in the non-heat-pipe mode. Three wavelength regions were observed. They are in the red, the green-blue, and the near ultraviolet regions. The absorption cross section depends on the wavelength of the incident light. Representative peak values for the v"=0 progression in the red and green-blue regions are 2.59 A sup 2 (average value) and 11.77 A sup 2 (T_ave=624 K). The value for the C greater than X transitions is several tenths A sup 2. The cross sections were measured from absorption spectra …

Portrait Of The Scientific Journals In Germany: 1930-1936, Paul Eugene Gesling Jr.

Institute for the Humanities Theses

The focus of this .study is to note and measure any discernible changes within the character of scientific publications in Germany after the elevation of the National Socialists to power. To detect any such changes, a classification scheme was established to categorize formal papers appearing in six journals between 1930-1936. The results are subject to variance as the journals examined did not fare identically. Certain journals declined in output while others prospered. Suggestion~ of ideological tampering remain largely absent. Indeed, the wide latitude of interests expressed by these papers suggest a preference on the part of German scientists and editors …

Lineament Analysis And Tectonic Interpretation For The Central Tharsis Region, Mars, Robert C. Anderson

OES Theses and Dissertations

Lineament studies conducted for the Central Tharsis Region of Mars (JOON and JOOS latitude; 450w to 157.50W longitude) indicate two major events controlled the formation of the Tharsis Dome: 1) a pre-Tharsis fracture system consisting of North-West (3150) trending fractures; and 2) a Tharsian fracture system containing North-South (355°) and East-West (275°) trending fractures. The North-West (3150) trending fractures represent a crustal weakness zone which controlled the early formation of the Tharsis Dome. Analytical studies suggest four centers of uplift: 1) 6°N, 124°W; 2) 0.5°N, 114°W; 3) 5°S, 105°W; and 4) 7°S, 104°W. Each of these uplifting centers is associated …

Comparison Of An Improved Plankton Sampler To The Standard Conical Plankton Net, Ronald S. Schmidt

OES Theses and Dissertations

A comparison of field and tank tests between the standard conical plankton net and an improved version of a plankton sampler is presented. The improved sampler was shown to filter larger quantities of water than the standard net without having the filtration efficiency reduced below 85%. The improved sampler was also shown to capture an increased number of plankton per volume sampled, as a result of eliminating increased avoidance activity by zooplankton. It was not shown that. the improved sampler capture either larger maximum sizes of zooplankton or additional species.

Conodont Biostratigraphy Of The Cambrian-Ordovician Boundary Interval In The Northern Shenandoah Valley Of Virginia, U.S.A., Randall C. Orndorff

OES Theses and Dissertations

Conodonts collected from two measured sections in the northern Shenandoah Valley of Virginia indicate that locally the Cambrian-Ordovician boundary is within the upper part of the Conococheague Formation and that the Conococheague-Stonehenge formational contact as defined in this study, is diachronous in relation to the boundary. Using the generally accepted definition of the CambrianOrdovician boundary as at the base of the trilobite Missisguoia Zone or within the conodont Hirsutodontus hirsutus Subzone of the Cordylodus proavus Zone, it is found here that the boundary is 230 ft (70 m) below the formational contact at the Narrow Passage Creek section. Several North …

Design Of Multivariable Feedback Control Systems Via Spectral Assignment, Mohsen Marefat

Electrical & Computer Engineering Theses & Dissertations

During the past 15 year s significant advances have been made towards developing viable synthesis- techniques for multivariable feedback control systems. The entire aggregate of this theoretical work has been reviewed and consolidated. Diverse notations have been standardized into a single system. A two-step design philosophy for spectral assignment has been developed which first meets stability and time response requirements by assigning eigenvalues and eigenvector s and then provides for attainment of secondary objectives without significant deviation from the initial assignment. Finally, a computer-aided design package has been created to streamline the process of mathematical calculation and to allow users …

Depositional Environments Of Late Precambrian Sediments From Liberia, Sierra Leone, And Senegal, West Africa, Alfred W. Magee Iii

OES Theses and Dissertations

Field and hand sample descriptions were supplemented with petrographic and textural analyses derived from thin sections, and scanning electron microscopy (SEM) to determine environments of deposition for the late Precambrian Gibi Mountain Formation, Liberia, Tabe

Formation, Sierra Leone, and the basal Mali Group, Senegal, West Africa.

The Gibi Mountain Formation consists of a glaciomarine tillite, marine laminites with dropgrains, and shallow water arkoses. A shale facies remains unresolved in origin.

The Tabe Formation is composed of three members: Tibai, Dodo, and Taban. The Tibai Member contains a glaciomarine tillite deposited in a shallow shelf marine environment, marine laminites, and shallow …

High Performance Switching Circuits For Vlsi, Ali Reza Feizi

Electrical & Computer Engineering Theses & Dissertations

Interconnection topology and device performance are of major concern in the design of LSI/VLSI systems, Pass networks are very suitable in this regard because of low power consumption, high density, and simple interconnection topology. A special type of pass networks called Binary Tree Structured (BTS) pass networks uses almost minimum number of transistors for the design of switching circuits. An algorithmic procedure is developed here for BTS pass networks which is very efficient in terms of both execution time and memory space. Based on these networks, the necessary and sufficient conditions are derived for the design of multiple-output pass networks. …

Depositional Model For The Auriferous Gravels In The Payan Mining District Department Of Narino, Columbia, South America, Jim R. Garrett

OES Theses and Dissertations

Unlike placer deposits in arid and semi-arid environments where gold concentration is closely tied to the position of the bedrock, Payan placer deposits have no association with bedrock. Gold concentration values show highest gold concentrations occur at the contact of a coarse sand unit and its underlying gravel unit. Comparisons of the size and shape distributions of gold grain populations with their associated black sand populations indicate the gold and black sand were not deposited in hydraulic equilibrium. The mean size of each gold population is consistently coarser than the mean size of its associated black sand population despite the …

Social Support Networks: The Effects Of Sex And Personality Variables On Utilization Of Resources, S. Dee Treschuk

Psychology Theses & Dissertations

The purpose of the study was to evaluate the effects of sex and various personality characteristics on the utilization of social support resources for four types of problems (day to day problems, "most serious" problem, emotional and material problems). An interview format was used in order to assess actual events in peoples' lives. Chi-square tests were performed to determine significant differences. Gender differences were found in the use of specific network members for day to day problems. As predicted, females utilized the family more than males; and males named "no one" more than females. For emotional problems, females utilized "love" …

Attributions Of Martial Conflict Among College Students, Gary Franklin Sigler

Psychology Theses & Dissertations

A study of single college student attitudes toward conflict was conducted to determine the attributions (internal versus external) they make regarding marital conflict scenarios (of mild to moderate to extreme severity). Between group differences of persons from divorced versus non-divorced homes were predicted as I well as sex differences with men making more external and females making more internal attributions. As expected, female actors did score higher than male actors on internal attribution. And females from both groups did rate the scenarios as more serious than males from both groups, as indicated by their higher mean rating of seriousness. However, …

Solar-Assisted Heat Pumps For Low-Temperature Industrial Process Heat Applications, Kamran Fouladi-Semnani

Mechanical & Aerospace Engineering Theses & Dissertations

In recent years, solar energy has been investigated as an alternative to· the fossil fuel based systems for industrial process heat (IPH) applications. Published results in literature indicate that roughly seven percent of total U.S. IPH requirement is in the temperature range of 40-90 °C. The present study, sponsored by Tennessee Valley Authority (TVA), examines the potential of series solar-assisted heat pumps (SAHP) for low-temperature IPH spectrum in the TVA region.

A design method based on utilizability technique is employed to determine the long-term thermal performance of the SAHP system. The transient simulation methodology is also employed to determine the …

Investigation Of Eddy Population And Motion In The Southern International Ice Patrol Operations Area (40°-47°N By 40°-55°W), Frank J. Williams

OES Theses and Dissertations

A study of the eddy population in the Newfoundland Basin region over the period from November 1981 to December 1984 was conducted. The study was undertaken to demonstrate the importance and basic character of eddy motion in the area patrolled by the International Ice Patrol. This is a descriptive study and no rigorous mathematical solutions are attempted. Data was collected on the number of eddies in the area, their average duration and size, formation, migration and deterioration patterns and rotational velocity. Satellite infrared imagery maintained by National Weather Service and Naval Eastern Oceanographic Center, Canadian Forces METOC Center sea surface …

Leachate Monitoring In Naturally Saline Groundwater Chesapeake Landfill Chesapeake Virginia, T. Britt Mcmillan

OES Theses and Dissertations

Groundwater chemistry around the Chesapeake municipal landfill was monitored over a one year period. Ten sample sites as well as two surface water sites were used to monitor water quality. Two wells, one at 3 m and the other at 10 m were located at each site. Surface water samples were taken from the Elizabeth River, north of the landfill, and a tidal channel, west of the landfill. Seven groundwater sites were downgradient of the landfill and three sites were upgradient (control sites).

The landfill overlies a tidal marsh, approximately 100 m south of the intracoastal waterway (Elizabeth River). Dredge …

The Effectiveness Of Stimulation Therapy For The Cognitively Impaired Elderly, Sylvia H. Old

Community & Environmental Health Theses & Dissertations

The effectiveness of stimulation therapy for the cognitively impaired elderly living in an institution was assessed. Residents with varying degrees of cognitive impairment were treated with twenty, thirty-minute daily periods of reality orientation, reminiscence, resocialization, remotivation, and other stimulating therapies and were compared with a control group_ receiving no intervention. Treatment effects were assessed with a variety of instruments reflecting functioning across several domains. Included were ability to perform both basic self-care functions and activities of daily living, cognitive performance, affect, and satisfaction with the care received and the living environment in the nursing home. The experimental group was divided …

Algebraic Grid Generation Using Tensor Product B-Splines, Bonita Valerie Saunders

Mathematics & Statistics Theses & Dissertations

In general, finite difference methods are more successful if the accompanying grid has lines which are smooth and nearly orthogonal. This thesis discusses the development of an algorithm which produces such a grid when given the boundary description.

Topological considerations in structuring the grid generation mapping are discussed. In particular, this thesis examines the concept of the degree of a mapping and how it can be used to determine what requirements are necessary if a mapping is to produce a suitable grid.

The grid generation algorithm uses a mapping composed of bicubic B-splines. Boundary coefficients are chosen so that the …

The Oneida Community: Its Apologists And Its Critics, Nancy C. Morris

Institute for the Humanities Theses

This thesis examines the historical literature regarding the Oneida Community (1848-81) from the society's conceptual beginnings in the 1830s to the present time. After an overview of the antebellum communitarian movement in the United States, a detailed description of the Oneida Community, one of America's most prominent nineteenth-century utopian experiments, is presented.

Chapters III, IV, and V survey the body of literature pertinent to the Oneida Community and its founder and spiritual leader, John Humphrey Noyes, over the last 145 years. The writings of the Oneida apologists, a majority of whom were Oneida Community family members and their descendants, are …