Digital Commons Network^™

The Regioselective 3-Alkylation Of Piperidine, Richard Dunn Todd

Chemistry & Biochemistry Theses & Dissertations

The compounds: 3-allylpiperidine, 3-ethylpiperidine and 3-n-butylpiperidine have been synthesized by regioselectively alkylating the three position of piperidine. Piperidine was converted to N-chloropiperidine and then dehydrohalogenated to produce Δ¹-piperideine. The enamide anion was generated by adding solutions of Δ¹-piperideine to ethylmagnesium bromide or lithium diisopropylamide. Addition of alkylhalides produced 3-alkyl- Δ¹-piperideine which could be reduced or alkyllithiated to give 3-alkylpiperidines or 2,3-dialkylpiperidines respectively.

The yields of products were low and the reaction generated a continuum of mono- and di-alkylpiperidines and there was evidence that several dimeric piperideines were formed. The low yields were discussed in …

Aseptic Techniques Currently Used In Dental Hygiene Clinics Within Accredited Dental Hygiene Programs, Jan Shaner Greenlee

Dental Hygiene Theses & Dissertations

The purpose of this survey was to assess the aseptic techniques currently used in 197 accredited dental hygiene programs in the United States. A self-designed, 51-item questionnaire examined the aseptic techniques used in: (1) preparation of the dental hygiene clinic and unit, (2) instrument preparation, (3) preparation of the student practitioner, (4) preparation of the patient, (5) preparation of radiographic equipment, and (6) treatment of the hepatitis patient.

The questionnaire and a letter of transmittal were mailed to the clinical supervisor of each accredited dental hygiene program. Data were obtained from 173 returned questionnaires and analyzed via modal and percentage …

Ortho Cyclization Reactions Of Catecholamines, Robert Lee Hudkins

Chemistry & Biochemistry Theses & Dissertations

A study was undertaken to examine the potential for ortho cyclization associated with the synthesis of 1,2,3,4,-tetrahydroisoquinolines using the Pictet-Spengler reaction. Specif1cally, the condensation of the biogenic amines, dopamine, norepinephrine and epinephrine were carefully examined in light of current literature and the facility and extent of ortho cyclization in each case. The para isomers of these three biogenic amine condensation products were isolated and characterized, while only the ortho isomer derived from dopamine was found stable and could be isolated, and structurally identified. These studies demonstrate that a second cyclization product does, in fact, form in each instance and that …

Local Lp-Saturation Of Positive Linear Convolution Operators, J. J. Swetits, B. Wood

Mathematics & Statistics Faculty Publications

Local L_p-saturation of positive linear convolution operators is investigated. Results are obtained for two important classes of operators previously studied by Bojanic, DeVore, Korovkin and the authors.

An Update Of The Tidewater Apprenticeship Information Handbook, Claud R. Divers Iii

OTS Master's Level Projects & Papers

The problem of this study was to review the Tidewater Apprenticeship Information Handbook to update information about the apprentice program and employment outlooks for the various trade areas. This information was compiled for the use of guidance and vocational education personnel for local high schools and community colleges.

Implementing Competency-Based Vocational Education In The Area Of Clerk-Typist I At Arcadia High School, Ann White Handy

OTS Master's Level Projects & Papers

The basic objectives of this study were: 1. To determine methods for implementing competency-based vocational education in Clerk-Typist I; 2. To identify the competencies recommended from V-Tecs catalogs; 3. To create performance objectives that will clearly identify the task; 4. To determine the applicability of identified competencies to students at Arcadia High School.

Organic N-Chloramines: Chemistry And Toxicology, Frank E. Scully, Jr., Maxwell A. Bempong

Chemistry & Biochemistry Faculty Publications

The stability of aqueous solutions of organic N-chloramines, suspected of contaminating chlorinated water, has been studied. Two factors influence the decomposition of solutions of N-chloropiperidine and N-chlorodiethylamine: a spontaneous decomposition and photodecomposition. Since solutions of these compounds are relatively long-lived, a need for an analytical method for their identification is discussed. A new method is described which involves reaction of organic N-chloramines with arenesulfinic acid salts. The method gives high yields of stable arenesulfonamides. Several toxicological studies of N-chloropiperidine are described. The compound is mutagenic by Ames assay in Salmonella typhimurium strain TA 100 and does not require metabolic activation …

Smallest Cubic And Quartic Graphs With A Given Number Of Cutpoints And Bridges, Gary Chartrand, Farrokh Saba, John K. Cooper Jr., Frank Harary, Curtiss E. Wall

Mathematics & Statistics Faculty Publications

For positive integers b and c, with c even, satisfying the inequalities b+1≤c≤2b, the minimum order of a connected cubic graph with b bridges and c cutpoints is computed. Furthermore, the structure of all such smallest cubic graphs is determined. For each positive integer c, the minimum order of a quartic graph with c cutpoints is calculated. Moreover, the structure and number of all such smallest quartic graphs are determined.

Picosecond Laser Pulse Irradiation Of Crystalline Silicon, K. L. Merkle, H. Baumgart, R.H. Uebbing, F. Phillipp

Electrical & Computer Engineering Faculty Publications

Morphology changes introduced by picosecond laser pulses at λ = 532 nm and 355 nm in (111) and (100) silicon samples are studied by means of optical and high-voltage electron microscopy. Depending on energy fluence, orientation and wavelength, amorphous or highly defective regions may be created. From an analysis of damage thresholds and damage depth distributions it is concluded that melting and energy confinement precedes the formation of the structural changes.

An Evaluation Of Nutrient Sources To Onslow Bay, North Carolina, Larry P. Atkinson, Leonard J. Pietrafesa, Eileen E. Hofmann

CCPO Publications

Hydrographic and current meter data from Onslow Bay, North Carolina, were examined to determine the relative importance of various nutrient sources.

Upwelled Gulf Stream water is the major source of nutrients while rivers represent a minor, if not insignificant, source. In the summer during stratified conditions, the upwelled water penetrates across the shelf, but in the winter the upwelled water is restricted to the outer shelf. Nitrate flux across the 40 m isobath was calculated from continuous temperature and current records. Flux during the summer of 1976 was 2 μM m² sec^-1 which is considerably less than flux …

Unbounded Functions And Positive Linear-Operators, J. J. Swetits, B. Wood

Mathematics & Statistics Faculty Publications

The approximation of unbounded functions by positive linear operators under multiplier enlargement is investigated. It is shown that a very wide class of positive linear operators can be used to approximate functions with arbitrary growth on the real line. Estimates are given in terms of the usual quantities which appear in the Shisha-Mond theorem. Examples are provided.

Design And Analysis Of A Hybrid Thermoelectric Solar Collector, Kay Eddie Shaheen

Mechanical & Aerospace Engineering Theses & Dissertations

A conventional flat-plate collector is modified by imbedding thermoelectric power generators between the absorber plate and flow tubes in parallel finned-tube passes. As solar energy cascades through these generators a temperature differential between the hot and cold junctions of the device produces direct current electricity. Energy not converted to electric power is converted away for use in domestic space and/or water heating.

A parametric study is performed on the steady-state model via computer program in order to find values of design variables that maximize electric power production for purposes of driving pumps, fans, and ·controlling devices. The results of this …

Water Wave Refraction With Non-Linear Theory, Im Sang Oh

OES Theses and Dissertations

Two different kinds of wave refraction models are formulated in the present study using Stokes' third order wave theory. One type of model is utilized in a parametric study employing several different topographies. Wave trajectories obtained from this model, when obtained by using first and third order wave theory with and without the consideration of energy dissipation, show considerable differences. These differences are examined in more detail for a bottom of constant slope: (1) An approximate 10% difference occurs between the refraction coefficients obtained using the first and the third order wave theory. (2) Considerably different ray trajectories are detected …

Experimental Investigation Of A Rectangular Surface Thermal Plume, Li-Cheng Chu

Mechanical & Aerospace Engineering Theses & Dissertations

An experimental investigation of the three dimensional mean temperature distribution of a rectangular buoyant surface thermal plume has been conducted for a range of buoyancies, velocity ratios, Reynolds numbers, and for various turbulence generating screens in the crossflow. This study has been motivated by a concern about the applicability of laboratory model data for predicting prototype plume behavior.

A large scale model has been built to study a buoyant, rectangular surface thermal plume which enters at right angles to a constant temperature uniform crossflow of depth equal to that of the plume. A large water tank and flume with weir …

Algal Dynamics In A Cypress Stand In The Seasonally Flooded Great Dismal Swamp, Joseph A. Atchue Iii

Biological Sciences Theses & Dissertations

The dynamics of epiphytic algae and phytoplankton were studied at a cypress stand in the Great Dismal Swamp, Virginia. Mean epiphytic algal biomass was 19.9 g m^-2 and mean planktonic biomass was 3.4 g m^-2.Nutrient concentrations in the epiphytic algae and the litter were determined. The algae had mean concentrations of 1.67% and 0.18%. They were found to immobilize as much as 0.5 g N m^-2 and 0.06 g P m^-2. This suggests that the algae are important as nutrient conservers. The phytoplankton were composed primarily of Bacillariophyceae. They exhibited a more or less …

A Quantitative Description Of Migratory Behavior Of The Brown Shrimp (Penaeus Aztecus) With Applications In Fisheries Management, Anne Madolyn Babcock

OES Theses and Dissertations

A quantitative description of the migratory behavior of the brown shrimp, Penaeus aztecus, was established using the density approach. A theoretical time density was estimated by the proportion of catch and catch per boat hour NOAA-NMFS fisheries statistics collected in Pamlico Sound, the Neuse River, and Core Sound. A clear quantitative description of brown shrimp migratory timing is found in the time densities. The impact of various physical tactors on the progress of the fishery in time and space can be objectively evaluated by using the time density statistics as dependent variables in modeling efforts. The distributions also enable …

Synthesis Of Dihydroisoquinolines And Tetrahydroisoquinolines, John J. Schlager

Chemistry & Biochemistry Theses & Dissertations

Dihydroisoquinolines and tetrahydroisoquinolines are compounds which possess a variety of pharmacological activities. New easier methods of synthetic manipulations of these structures is of constant interest in the pharmaceutical industry.

This paper describes a new three step method of preparing 1-alkyl- and 1-aryl-tetrahydroisoquinolines from a tetrahydroisoquinoline. The synthesis involves the N-chlorination of tetrahydroisoquinoline followed by dehydrohalogenation with potassium superoxide. The reaction products are the dihydroisoquinolines. Overall yields range from 85-96%. The unsubstituted, 1-methyl-, and 1-phenyl-J,4-dihydroisoquinolines have been formed. Organometallation of the unsubstituted dihydroisoquinoline provides the 1-substituted tetrahydroisoquinoline. The 1-benzyl-, 1-n-butyl-, 1-ethyl-, 1-methyl-, and 1-phenyl-1,2,J,4-tetrahydroisoquinolines were prepared. The use of Grignard and …

A Direct Formulation And Computer-Implementation Of A Symbolic Network Analysis Algorithm, Timothy James Knerr

Electrical & Computer Engineering Theses & Dissertations

An algorithm for the symbolic analysis of linear, time-invariant, active or passive networks is presented. The algorithm incorporates the best features of earlier numerical and topological methods of symbolic analysis. A hybrid set of equations is formulated for a closed linear graph and arranged in matrix form. A numerical evalu­ation procedure for the determinant of this hybrid matrix results in an efficient method of symbolic analysis. A proof of the algorithm based on determinant evaluation by a permutation product expansion provides insight into relationships with other methods of symbolic analysis. A computer program implementation of the algorithm is described and …

Petroleum-Utilizing Bacteria: The Biological Line Defense Against Oil Pollution, Steven W. Sokolowski

Biological Sciences Theses & Dissertations

A silica gel-petroleum (SGP) medium was developed which is reliable, approximately the same cost as that of the corresponding agar-based petroleum medium, and can be made sufficiently firm to use in streaking or the spread-plate technique. Advantages of the medium include: the incorporation of all of the major ions of seawater in accordance with Dittmar's Law (the salinity of which can easily be varied from 0 to 35 parts per thousand); a wide workable pH range (5.5 to 11.6); negligable pH drift(~ 0.2 pH units after 166 days); the elimination of all but negligable amounts of syneresis, the ability to …

Effects Of The Dental Hygiene Curriculum On Student Creativity, Linda Kathryn Martin

Dental Hygiene Theses & Dissertations

This investigation examined the influence of the dental hygiene curriculum on student creativity throughout the two years of dental hygiene study. A secondary purpose was to determine if various accredited dental hygiene programs differentially affect creativity in students. Torrance Tests of Creative Thinking was used to measure creativity in students from three dental hygiene programs in Virginia. Data were organized according to a 3 X 4 factorial research design, using dental hygiene programs and academic semester levels as attribute independent variables. Fluency, Flexibility, Originality and Total scores of the Torrance Tests of Creative Thinking were the dependent variables.

Two-way analysis …

The Effect Of Kindergarten Entrance Age On School Success In Kindergarten And First Grade In Selected Portsmouth Private Schools, Mary Lindsey H. Hester

Theses and Dissertations in Early Childhood Education

This two-year study compared kindergarten children by age and sex on cognitive development, emotional adjustment, and social development. A similar comparison was made of the sample at the end of their first grade year.

The sample (N=57) consisted of the total kindergarten enrollments of two private schools in Portsmouth, Virginia. Those children who had entered kindergarten before their fifth birthday were defined as "younger," and the remaining sample, "older."

The tool for measuring cognitive development was the Metropolitan Readiness Test in kindergarten, and the Metropolitan Achievement Test in first grade. A self­ designed developmental rating sheet was used both years …

A Method Of Modeling Multirate Two-Dimensional Recursive Digital Filters Author, Albert P. Gerheim

Electrical & Computer Engineering Theses & Dissertations

This dissertation presents a method of modeling two dimensional sampled data systems with two sampling rates in each dimension. This methodology is applied to the problem of synthesizing two dimensional velocity filters using one dimensional prototypes and multirate concepts.

The modeling method includes the replacement of scalar z-transforms of signals by vectors of polynomials, and the replacement of scalar z-transforms of impulse responses by matrices of polynomials.

The synthesis of velocity filters is accomplished through the use of coordinate transformations in the z-transform domain which skew the ω₁ -ω₂ axes on the unit bidisc. The filters synthesized using …

Effects Of Multiple Scattering And Surface Albedo On The Photochemistry Of The Troposphere, Tommy Reinhold Robert Augustsson

Mechanical & Aerospace Engineering Theses & Dissertations

A one-dimensional photochemical model of the troposphere containing the species of the nitrogen, oxygen, carbon, hydrogen, and sulfur families has been developed and used to investigate the vertical profiles and the natural (including atmospheric chemical reactions) and anthropogenic sources and sinks of these species. The species continuity equations are solved numerically applying prescribed boundary conditions. The vertical flux is simulated by use of the parameterized eddy diffusion coefficients. Heterogeneous losses (e.g. rainout, gas-to-particle chemistry, and dry deposition), are parameterized to make calculated profiles consistent with measurements. The photochemical model is coupled to a radiative transfer model that calculates the radiation …

A Technique For The Isolation And Identification Of Aliphatic Amines In Water, Peter Alan Drew

Chemistry & Biochemistry Theses & Dissertations

Small, aliphatic amines added to a basic, aqueous solution (16.2 L) at a concentration of 100 parts per billion were isolated by sorption on a small column of macroreticular resin. The amines were eluted with diethyl ether; the eluate concentrated, and the compounds separated and identified by gas chromatography. The efficiency of the recovery of a-nines ranged from 5 to 28%.

A protocol for derivatizing pyrrolidine and n-pentylamine in ether with fluorinated acylating agents was developed. The method was found to be adequate for the detection of approximately 13 micrograms of &-nines in concentrated ether extract.

Environmental water samples …

Characteristics Of Sediment Transport In Overwash Surges, Paul Richardson Bowen

OES Theses and Dissertations

Sediment samples taken from a washover deposit were used to determine the mode of sediment transport within overwash surges. The determination of sediment transport mode is based on the concept of hydraulic equivalency of different density grains. Hydraulic equivalency may be based on settling velocities or entrainment velocities. Two individual mineral grains of different densities cannot have the same settling and entrainment velocities. If the settling velocities of each grain are similar, then the less dense grain must be physically larger to settle at the same rate as the smaller denser mineral. However, once both of these grains have made …

Games And Gaming Of The Stuart Aristocracy, Vicky Ann Sanderlin

History Theses & Dissertations

Games and gaming provide insight into the lives of the people of the past. This thesis analyzes the games and gaming patterns of the aristocracy of Stuart England. This examination of gaming concentrates on the place of leisure games in the world of the elite. The study focuses on games suitable for inclement weather and includes both children's and adult's games from the period.

This thesis addresses three basic questions: 1) who were the gamesters, 2) when and where did they game, and 3) what games did they play and how did they play them? Answers to these questions have …

Chemistry Of Organic N-Chloramines, Formation Of Arenesulfonamides By Derivatization Of Organic N-Chloramine With Sodium Arenesulfinate, Katherine F. Bowdring

Chemistry & Biochemistry Theses & Dissertations

Organic N-chloramines are recognized by-products of chlorinated water systems. Because of their chemistry, none have been isolated or identified.

This paper discusses a method for the derivatization of the organic N-chloramines based on a nucleophillic substitution mechanism. N-Chloro derivatives of amines of various structures were studied including primary and secondary aliphatic amines, as well as amino acids. The effect of the presence of other functional groups including aromatic and unsaturated systems was investigated.

Derivatization was done by three different methods, one involving derivatization of the pure N-chloramine, and two involving derivatizations of the N-chloramine generated in situ. Seventeen arenesulfonamides have …

High Performance Liquid Chromatographic Analysis Of Biogenic Amines, Thais Edwina Ahrendt Keegan

Chemistry & Biochemistry Theses & Dissertations

The objectives of this research were to develop a sensitive method for separation and quantitation of biogenic amines and to apply that procedure by monitoring neurochemical changes resulting from stimuli to the test system.

Primary aromatic amines were derivatized with o-phthalaldehyde-mercaptoethanol prior to chromatography, Separation of the fluorescent adduct was achieved using a μBondapak/ phenyl reversed-phase column and a two-step gradient of methanol:0.08 M acetic acid, pH J.O. Fluorescence was monitored using a J40 nm excitation energy and an emission filter which transmits radiation greater than 400 nm (50% T at 418 nanometers).

Following optimization of the chromatographic conditions, studies …

Growth And Recruitment Of Two Penaeids In The Bay Of St. Louis, Mississippi During 1979, Teresa C. Heaton

OES Theses and Dissertations

Juvenile brown (Penaeus aztecus, Ives) and white (Penaeus setiferus, Linnaeus) shrimp were collected from two stations of a nursery area in St. Louis Bay Mississippi, during May to October, 1979. Periods of shrimp recruitment and growth were determined to discern whether the concurrent environmental variables of salinity and temperature had an influence on shrimp abundance and yield. Growth estimates were obtained from length frequency measurements of trawl samples taken over a 24-h period per month from each station. An analysis of variance of length versus the variables of sex, month, station, time of day, salinity and …

Goertler Instability In Compressible Boundary Layers Along Curved Surfaces With Suction And Cooling, Alok K. Verma

Mechanical & Aerospace Engineering Theses & Dissertations

The Goertler instability of the laminar compressible boundary layer flows along concave surfaces is investigated. The linearized disturbance equations for the three-dimensional, counter-rotating streamwise vortices in two dimensional boundary layers are presented in an orthogonal curvilinear coordinates. The basic approximation of the disturbance equations, that includes the effect of the growth of the boundary layer, is considered and solved numerically. The effect of compressibility on critical stability limits, growth rates, and amplitude ratios of the vortices is evaluated for a range of Mach numbers for Oto 5. The effect of wall cooling and suction of the boundary layer on the …