Digital Commons Network^™

Synthesis Of Highly-Strained Gem-Difluoro Compounds By Reaction Of Difluoromethylene With Cycloalkenes, Deyi Yang

Theses

Trans-Cyclooctene is thought to be more reactive than cis-cyclooctene due to its trans-structure. When cis or trans-clooctene reacts with difluormethylene (:CF₂), trans-9,9-difluorobicyclo[ 6,1,0] nonane was generated in much higher yield than cis-9,9-difluorobicyclo[6,1,0]nonane. [PhCF₃P⁺CF₂Br]Br^- was chosen to be the difluoromethylene precursor in this study. The reason was that the reaction condition for trans-cyclooctene and :CF₂ should be at low temperature. Only [PhCF₃P⁺CF₂Br]Br^- could generate CF₂ at lower temperature (e.g. room temperature). We succeeded in the synthesis of trans-9,9-difluorobicyclo[6,1,0]nonane and its cis isomer and …

Thermal Decomposition Of 1,1,2- Trichloroethane In Hydrogen In Tubular Flow Reactors At Atmospheric Pressure, Chen-Chung Yeh

Theses

The decomposition of 1,1,2-trichloroethane in a hydrogen gas bath was carried out at 1 atmosphere total pressure in three different surface to volume ratio flow reactors. Temperature ranged from 440 to 850 °C and the residence times studied were in the range 0.2 - 2.3 seconds. Application of the first order rate expression to this data yields a linear relationship for each temperature studied and thus global rate constants for loss of reactant were determined.

It was found that conversion of the reagent was a function of both temperature and residence time. The major products observed are 1, 2-dichloroethylene (CHClCHCl), …

Application Of Microwave Energy To Remediation Of Soils Contaminated With Chromium, Chih-Ju Jou

Theses

A process based upon microwave treatment has been developed to render soil non-hazardous after that soil had been classified as hazardous due to heavy metal contamination. It has been applied to chromium-contaminated soil. The object of the present regulations is to prevent damage to water supplies as a result of the leaching of heavy metal ions from the soils. This object is expressed in the standard test for leaching, namely, the EPA EP Leachate test. This process can be used to immobilize metal ions sufficiently to meet the aforementioned standard. The present standard is based upon acid leaching, and not …

Study Of An Analytical Method For Benzo(A)Pyrene Metabolites In Human Urine, Zheng Ouyang

Theses

A method developed by Becher and Bjorseth for analysis of PAH metabolites in urine was employed to investigate human exposure to benzo(a)pyrene (BaP) - an ubiquitous environmental carcinogen. Preliminary results are presented showing the relationship between exposure to BaP and urinary elimination. Although the correlation between the two variables is not statistically significant, there appears to be a positive association with selected exposure varibles such as smoking. The identification of an association may establish urinary BaP as a marker of exposure.

However, detailed study of the analytical procedure indicated that recoveries with this method were as low as 3-8% for …

Thermal Decomposition Of 1,1,1-Thrichloroethane-Methane-Oxygen Mixture In Tubular Flow Reactor, Yo-Ping Wu

Theses

The thermal decomposition of 1,1,1-trichloroethane in methane/oxygen mixtures and argon bath gas was carried out at 1 atmosphere total pressure in a tubular flow reactors. The thermal degradation of 1,1,1-trichloroethane and methane were analyzed systematically over temperature ranges from 500 to 800°C, with average residence times in the range of 0.05 to 2.5 seconds. Five reactants ratio sets in three different size flow reactors were studied.

It was found that the complete decay (99%) of the 1,1,1-trichloroethane at 1 second residence time occurs at about 600°C for all the reactants ratio sets. The major product for 1,1,1-trichloroethane decomposition are 1,1-dichloroethylene …

Organics In Ambient Air By Collection On Tenax, Thermal Desorption,And Capillary Chromatography With Parallel Fid/Ecd Analysis, Chih-Hsiang Liao

Theses

Volatile organics in ambient air were regularly collected on Tenax cartridges at high (10 ml/min) and low (5 ml/min) intake flows. These Tenax samples were analyzed by using a Tekmar Automatic Thermal Desorber and capillary GC system with parallel flame ionization (FID) and electron capture detectors (ECD). A series of quality assurance procedures has been established to improve and assure the accuracy and precision of sample collector and analysis. These procedures relate to performance of the Tekmar thermal desorber, recovery efficiency from the Tenax, and include studies on breakthrough and co-elution. The results demonstrate (1) that from ambient air data …

Determination Of Benzo(A)Pyrene Metabolites In The Bile Of Winter Flounder From The New York Bight, Xingmin Liu

Theses

A method for detecting the concentration of BaP Metabolites in fish tissues has been developed. The analytical procedure includes extraction of PAH and BaP Metabolites from fish bile, liver extract and muscle extract; reduction of metabolites to BaP using hydriodic acid; and subsequent analysis of the BaP by thin layer chromatography with fluorescence detection. The method is applied to tissues from fish collected from polluted as well as clean reference waters and experimental tanks with dilutions of treated industrial wastewater. Experimental results on one kind of bottom-dwelling fish, winter flounder, which comes from the Hudson-Raritan Estuary, NY, where the water …

Ph Parametric Pumping : An Examination Of Different Feed Locations For A Two And Three Column Process With The Same Flow Patterns And Ph Distribution, Roberta Rosty

Theses

PH parametric pumping is used to separate protein mixtures of hemoglobin and Albumin.

In this thesis, modifications to a two-column process, where the fluid stage flow pattern and the pH distributions were constant, were explored. These modifications consisted of: changes in the feed stream inlet and outlet locations, changes in the amount of feed itself, and an addition of another column and reservoir to the original two-column process. The results were obtained through computer simulation.

Results indicate that the batch or no-feed two and three column processes yield better separations of the two proteins than the same processes with feed …

Scanning Electron Microscopy And X-Ray Energy Dispersive Spectroscopic Analysis Of Selected Sorbent Materials, Elhamy Amin Sedhom

Theses

A previous study⁽¹⁾ showed that a combination of acidic and basic sorbents in a layered system is required to reduce to safe levels the contaminants present in the leachates emanating from industrial landfills. The sorbents used were fly ash, vermiculite, kaolinite, illite, zeolite, apautagite, bentonite, activated carbon and bauxite.

The purpose of this investigation is to study the physical properties, elemental composition and the distribution of the aforementioned solid sorbents. Properties of interest are particle size, shape and distribution and also the chemical composition and the distribution of the elements within the sample particles.

Scanning Electron Microscopy (SEM) and …

A Non-Invasive Technique For Burn Area Measurement, Jong-Daw Yu

Theses

The need for a reliable and accurate method for assessing the surface area of burn wounds currently exists in the branch of medicine involved with burn care and treatment. The percentage of the surface area is of critical importance in evaluating fluid replacement amounts and nutritional support during the 24 hours of postburn therapy. A noninvasive technique has been developed which facilitates the measurement of burn area. The method we shall describe is an inexpensive technique to measure the burn areas accurately.

Our imaging system is based on a technique known as structured light. Most structured light computer imaging systems, …

Rays And Beams Near The Shadow Boundary, Weixing Gao

Theses

Asymptotic techniques in wave propagation problems exhibit attractive features in computational aspects compared to numerical methods. However, they experience problems in complicated environments due to the transition regions associated with them. The transition region involving a shadow boundary in the downward refractive index profile has been investigated. The ray paths were determined solving the ray equation analytically. The Green's function due to a line source is constructed and evaluated using numerical integration (reference solution) and asymptotic techniques. Then, the field produced by the source, is synthesized, using superposition of beams generated from complex source point representation. The floating parameters such …

Reduced Complexity Receivers For Trellis Coded Modulations Via Punctured Trellis Codes, Bonchul Koo

Theses

We introduce a new concept, called matched punctured trellis encoding, that simplifies the complexity of Maximum Likelihood Sequence Estimation (MLSE) receivers for combined trellis encoding and modulations with memory. Matched punctured trellis encoding is applied to tamed frequency modulation (TFM) which is a bandwidth efficient correlative - FM scheme. TFM finds applications in satellite, microwave radio, and mobile communications.

Our approach is based on puncturing a rate - 1/2 matched convolutional code to obtain a rate - 2/3 mismatched code. A matched code is one that produces trellis coded modulations of minimum complexity. Puncturing these codes to obtain mismatched codes …

Characterization Of Activated Sludge Immobilized In Calcium Alginate Gel With Respect To Biodegradation Of 2-Chlorophenol And Benzene, Manjari Singh

Theses

Activated sludges acclimated with phenol and 2-chlorophenol in one case, and a mixture of benzene, toluene, and o, in and p-xylene in another case, were characterized for biodegradation of 2-chlorophenol and benzene, respectively. Activated sludge was obtained from the Parsippany-Troy Hills Water Pollution Control Plant (NJ).

For both cases colonies were isolated before acclimation, after acclimation, and at the end of biodegradation studies. Since the unacclimated group was the same in both cases, there were a total of five different groups for which characterization was carried out.

For all the five groups together, a total of 54 isolates were obtained …

Estimation Of Thermodynamic Properties Of Petroleum Fractions To Supplement The Aspen Simulator, Steven E. Sund

Theses

The objective of this study was to develop a method of estimating hydrocarbon pseudocomponent data in a format that is consistent with the ASPEN simulator. Although algorithms exist to estimate the pseudocomponent properties, no comprehensive program exists for the public version of ASPEN. A computer program was developed which will take a minimum of input data and can generate the necessary pure component properties for an ASPEN simulation. The program is meant to complement the ASPEN simulator, so the input is similar to ASPEN's input. The output can be incorporated directly into an ASPEN input or can be of the …

Mathematical Model Of A Continuous Sterilization System For Fermentation Media Containing Suspended Solids, Mark A. Leskowicz

Theses

A mathematical model has been developed for a continuous sterilization system where the role of suspended solids on the overall degree of sterilization achieved is taken into account. Evaluation of a "typical" commercial continuous sterilization system showed the role of suspended solids to have little effect on the overall sterilization obtained. For continuous sterilization systems operating in a total residence time of less than one minute, the role of solids may become important and should be evaluated.

Microwave Treatment Of Organic Contaminated Soil, Suning Fan

Theses

The development of microwave technology to treat hazardous wastes hasbeen in progress at NJIT for the past three years. The initial stagesof this program have focused on determining the' breadth of hazardouswaste problems that are amenable to microwave technology applications.Benchscale studies have shown the following processes are technicallypossible:

a. It is possible to steam strip organic volatiles from soil;

b. Volatiles can be destroyed by impact upon lossy so lids

c. Heavy metal ions can be immobilized in soil;

d. It is possible to regenerate GAC on-site.

e. It is possible to pyrolyze polyarmotic compounds in soil in-site,and, thereby, effect …

Recirculation Flow Bioreactor For The Synthesis Of Nitroxide And N-Oxide Pharmaceuticals, Douglas Lischick

Theses

An investigation of the properties of calcium alginate immobilized hog liver microsomes, rich in FAD-containing mixed function oxidase, was performed. Studies involving catalyst storage, immobilization of cofactors within the matrix, and alginate gel concentration were performed using a 1.8 ml mixed flow micro assay reactor. A recirculation flow reactor was designed and used for the biochemical production of 2,2,4,4-tetramethyl-1,3-oxazolidine-l-oxyl, a potentially useful MRI contrast agent.

The activity of the immobilized microsomes was found to increase over time when stored in CaCl₂ or in buffer at 4-8°C. The increase in activity is a result of the removal of inherent inhibitors …

Thermal Desorption Of Hazardous And Toxic Organic Compounds From Soil Matrices, Sarah Calandra

Theses

The purpose of this research project was to determine feasiblity to remove organic contaminants from various soil matrices by thermal desorption and gas purge. The volatization and gas purge of organic contaminants from the soil increases under the influence of heat and inert gas.

The work was done in two parts. First, under isothermal conditions, organic compounds were injected as a plug unto columns that contained real or simulated soil matrices. These columns were continuously purged with a carrier gas (nitrogen) and a gas chromatogragh equipped with Flame Ionization Detector but no added column other than the soil was used …

Investigation Of Benzo(A)Pyrene In Outdoor Air, Indoor Air And Personal Inhalation Air, Hsiu-Wen Chen

Theses

The assessment of human exposure to an environmental contaminant requires the measurement of the concentrations levels present in each pathway of possible contact.

This was an investigation of human exposure to an environmental pollutant, benzo(a)pyrene, in outdoor air, indoor air and personal inhalation air samples. The analytical procedure involved extraction by ultrasonic and separation by thin layer chromatography, and detection by fluorescence. The resulting data was used to develop a profile of indoor and outdoor human exposure to B(a)P during the year.

Modelling And Parameter Estimation In Clinical Electrooculography, Shengche Hsu

Theses

The Corneoretinal potential (CRP) was discovered in 1848. Its response to changes in light intensity can provide information relevant in the diagnosis of some retinal degenerative disorders. The indirectly measured CRP is referred to as electro-oculography (EOG). A system for automatic data acquisition and modelling, providing graphic presentation, data processing and file management, has been developed. A linear feedback model is proposed to represent the dynamics of the EOG signal. Model parameters are estimated by the nonlinear least-square method. The effect of measurement time on the reliability of parameter estimation is discussed.

An Interactive Graphics Capability For Numerical Design Optimization, Abbay P. Joshi

Theses

Hierarchical Object Oriented Program Software [HOOPS] is used here to develop an interactive graphical interface for the design optimization program CADOP5. A preprocessor provides the user with button menu options. Using various buttons like Variable Button, Obj Button, Parameter Button, etc. the user can interactively define problem variables, parameters and limits as well as interactively modify the behavior and the constraint functions. The post processor displays variable values for three consecutive design cycle in the form of bar charts. Objective function values are plotted against the number of design cycle. Using this information the user can determine if the solution …

Digital Image Restoration Using Power Spectrum Equalization Filtering Technique, Debdatta Sen

Theses

Digital deblurring of micro-circulatory images using both homomorphic and power spectrum equalization filtering are considered. An existing homomorphic filter was modified by changing filter parameters. This permitted an image with better contrast to be obtained. The power spectrum equalization approach consists of modeling and characterization of degradation and estimation of the power spectrum of the image using the Welch method. The restoration is considered from the point of view of spatial-frequency domain descriptions of images. Consideration is restricted to degradations arising from additive noise and spatially invariant linear blurring. The filter restores the power spectrum of the image to what …

Trellis Coded Partial-Response Channels, Kumari Yalamanchili

Theses

Binary partial-response channels with transfer functions (1+D), (1-D) and (1 — D²) are intersymbol-interference channels which find applications in baseband data communications and magnetic recording systems (tapes, discs, compact discs, etc.). In this thesis we develop a coding technique for improving the reliability of digital transmission over noisy partial-response channels with the above transfer functions. We do so by introducing a new concept, called matched encoding, which arises in the context of trellis coding for channels with memory.

We use inner and outer trellis coding of the partial-response channels. The inner codes called matched inner coset codes, are …

Methods Of Achieving High Speed On Data Flow Machines, Chung-Lin Yu

Theses

Simultaneity is a key to high speed and large computation. Assuming hardware components of a given speed, it is the only remaining consideration in achieving raw speed. Simultaneity can be shackled by dependencies, however, and years of hardware and software work have been devoted to understanding the types of dependencies and how they can be obeyed or removed from a computation.

In this thesis, the principles of the data flow machines and the structure of the data flow languages are illustrated. Various methods of achieving high speed are discussed. These methods include streams, Lenient Cons (I-structure), and dependence-driven computation, which …

Interpolation Search For Alphabetic Tables, Loizos Gabriel

Theses

One of the fastest search techniques for uniformly distributed sorted numerical tables is interpolation search. This divide and conquer technique accesses the most probable key rather than the middle key as in binary search and continues to search similarly the appropriate part of the table . In the previous work we proved a lg lg n average number of accesses for interpolation search.

The inefficiency of interpolation search for an alphabetic table is demonstrated by Burton and Lewis and a robust variation suggested by them to improve the efficiency. This inefficiency is expected since such tables are usually far from …

One-Dimensional Parametric Inverse Scattering For Lossless Dispersive Media, Frank Gangi

Theses

In this thesis, the effects of high frequency noise on a perturbational inversion algorithm for a stratified dispersive medium are investigated. It is shown that the perturbational algorithm becomes unstable under high frequency noise. The physical origin of this instability is discussed.

In order to enhance the robustness of the perturbational inverse scattering solution, a parametric inversion algorithm is implemented. The improvement by the use of a parametric inversion is given quantitatively by the profile-to-error ratio (PER). Examples of the two-pole and the three-pole reflection coefficients are compared and contrasted.

Thermal Decomposition Of Dichloromethane In Hydrogen/Oxygen/Argon Mixtures And In Pure Oxygen, Wen-Pin Ho

Theses

The thermal decomposition of Dichloromethane in hydrogen/oxygen mixtures and argon bath gas was carried out at 1 atmosphere total presure in tubular flow reactors of varied surface to volume (S/V) ratio. The thermal degradation of dichloromethane was analyzed systematically over temperature ranges from 610 to 820°C, with average residence times in range of 0.1 to 2.0 seconds. Five reaction sets in three different size flow reactors were studied.

It was found that the complete decay ( 99% ) of the dichloromethane at 1 second residence time occurs at about 810°C for all the reactants ratio sets. The major products for …

The Rate Of Vibrational Segregation In Particulate Materials, Yidan Lan

Theses

The rate of vibratory size segregation has been modeled in multi-component size systems as a process of mutual sorting between each size species. The concept of mutual sorting is introduced from which generalized expressions are derived for the rates of change of the local concentration of each size species. In a binary system, the expressions simplify to give the expected result that the segregation rates for the large and small particles are equal but of opposite sign. Also, in these systems, the segregation rate is described by measuring the rising speed of the interface between the small and large particles. …

Cascading Lzw Algorithm With Huffman Coding : A Variable To Variable Length Compression Algorithm, Ashish Khandubhai Mehta

Theses

Two common schemes in data compression are fixed to variable length coding and variable to fixed length coding. Higher compression is expected from the more flexible scheme of variable to variable length coding. In such a scheme a compression dictionary is used to transfer variable length string over the text alphabet into variable length strings over the coding alphabet. The compression is achieved due to matching longer more frequent text strings with shorter coding strings.

To obtain a variable to variable length coding we choose to cascade the LZW , variable to fixed , coding with the Huffman , fixed …

Experimental Evaluation Of J-Integral For Fiber Reinforced Concrete Subjected To Impact Loading, Piyushkumar Patel

Theses

This research presents an experimental Evaluation of J-Integral for Fiber Reinforced Concrete Subjected to Impact Loading. Three-point edge notched bend specimen were employed in evaluation of J-Integral using both the multi-specimen, and the single specimen techniques. In the multi-specimen technique three different notch lengths were employed for extracting the energetic fracture parameter J_Ic. In the single specimen technique, the method developed by Rice[13] was used to evaluate J_Ic at three different notch lengths.

Different proportions of fiber were employed in determining the J_Ic values. Experimental results from present study indicates that the J_Ic values calculated …