Digital Commons Network^™

Analysis And Applications Of Ftir Systems, Gunjan Navin Doshi

Theses

Fourier Transform Infrared Spectroscopy (FTIR) is a dynamical instrumental technique used in industry for measuring high quality infrared spectra. Over the last 25 years, the increased demand for having an efficient real-time quantitative measurement technique has led to extensive research and development in the field of FTIR Spectroscopy. Through the use of FTIR, sensitivity has increased, size of the smallest sample that can be analyzed has been reduced, and the number of new applications has exploded. In this thesis, an attempt is made to study the principles, theory, instrumentation and applications of FTIR Spectrometry. We survey the working of spectrometer, …

Improving The Run Time Of The Decomposition Algorithm For Fault Tolerant Clos Interconnection Networks Through Swap Re-Ordering, Andrea Laura Mcmakin

Theses

Clos interconnection networks, used in data networks and computing systems, can contain extra switches to be used in faulty conditions. The speed of such fault tolerant Clos interconnection networks is improved through the use these switches in no-fault situations. The network can be represented by a matrix, which is then decomposed using an algorithm, and the switch settings are thus assigned.

The original decomposition algorithm consisted of four element swaps in the following order: wild swap, simple swap, next simple swap, and successive swap. However, by re-arranging these swaps with the simple swap first, followed by the next simple and …

Competition Of Copper, Lead, And Cadmium Adsorption To Goethite, Chris A. Christophi

Theses

Competition of copper, lead, and cadmium adsorption on goethite depends on metal ion and oxide surface characteristics. Goethite was characterized via X-ray diffraction, potentiometric titrations, site density determination, particle size analysis, and optical microscopy. In this thesis, a hypothesis was tested that electronegativity is the most important factor in metal affinities and adsorption competition to goethite.

Metal affinity and site density for the goethite surface were assessed by performing adsorption edges and isotherms. Based on the results of these experiments, competition studies were designed to observe adsorption and displacement of the competing metals by limiting the number of available sites …

Requirement Elicitation And Knowledge Management Utilizing Relational Database, Client Server And Internet Technologies, Umang J. Dave

Theses

The first step in any project is a statement of requirements. Requirements specification is an inevitable part of any successful project. However, the "rush" to convert concepts to products often proves as a big hindrance in the development process of any requirements set. This, in turn, hampers the ability to produce the concept and manage knowledge as originally envisioned.

The goal of the thesis is to foster understanding among the different communities affected by the development of the given system. The thesis is based on the principle that the requirements elicitation process for complex system is fundamentally a conversation among …

Process Modeling Using Proslcse On Web-Enabled Platform, Orcan Ali Enunlu

Theses

Process modeling is a relatively complex task that needs to be addressed from a different point of view. The classical approach would be to design the model, to send it for evaluation, then to return feedback to the developing team, and to reevaluate the model with the feedback received from the parties involved.

However, it is our understanding that the steps taken during the process modeling could benefit from the advantages that the Internet offers. To demonstrate the usefulness of Internet in process modeling, I have taken an existing tool, ProSLCSE, and implemented it with Java so that it can …

Nanofiltration With Organic Solvents And Its Possible Applications To Organic Syntheses, Jose Antonio Whu

Theses

Experimental results on the nanofiltration (NF) separation behavior of three different solvent- compatible membranes are presented for three organic solutes of molecular weights 351, 826 and 1355 in methanol; the manufacturer-specified molecular weight cut-offs (MWCO) of the membranes are 250, 400 and 700. Membranes were primarily tested at 440 psig, at different concentrations of the solutes in methanol; the effect of varying the applied pressure was also briefly explored. The solvent permeation flux and the solute rejection were time dependent for an extended initial period; the membranes had to be compacted to achieve steady-state results. Furthermore, the manufacturer-specified MWCO was …

Determination Of Electron Donors In The Reductive Dechlorination Of Tetrachloroethene, Samantha L. Marasigan-Bernal

Theses

Several substrates, namely fatty acids and alcohols, were used to enhance the reductive microbial dechlorination of PCE to ethene. All of the microcosms amended with the volatile fatty acids (butyrate, succinate, lactate, formate, butyrate/formate mixture and butyrate/succinate mixture) demonstrated complete reductive dechlorination of PCE to ethane. The cultures amended with the butyrate/succinate mixture was the quickest to completely dechlorinate PCE to ethene (49 days). Those amended with butyrate, succinate, formate and the butyrate/formate mixture exhibited complete reductive, dechlorination at 77 days. Microcosms amended with lactate exhibited complete reductive dechlorination at 160 days.

The microcosms amended with the alcohols (ethanol, propanol, …

Measurement Of The Baroreceptor Sensitivity Index (Brsi) In The Frequency Domains, Tanvir Raquib

Theses

Time domain analysis for calculating the Baroreceptor Sensitivity Index (BRSI) did not always provide an accurate result. It also had another limitation in that it could not show the influence of the autonomic nervous system for different subjects. The correlation coefficient is a mechanism that was used to either accept or reject the BRSI values in the time domain but the correlation coefficient values changed drastically depending on how many sample points were selected for the calculation.

On the other hand, frequency domain analysis for the BRSI calculation was relatively easier and provided more accurate information compared to the time …

Supercritical Fluid Extraction (Sfe) And High Performance Liquid Chromotography (Hplc) Analysis Of Polycyclic Aromatic Hydrocarbon (Pah) Contaminated Soil, Marie Renee Gargas

Theses

Methods for the extraction and analysis of polycyclic aromatic hydrocarbons (PAHs) from contaminated soil were evaluated for use in a treatability study. Candidate procedures were selected from EPA SW-846 (Third Edition) methods. Soxhlet extraction (3540B) was selected to determine initial PAH concentrations. Supercritical fluid extraction with carbon dioxide (SFE: 3561) and high performance liquid chromatography (HPLC: 8310) were evaluated for use as the extraction and analysis methods. Experimental soil was obtained from a petroleum product refinery site; a Certified Reference Material (CRM) was also studied.

Experiments focused on determining concentrations of anthracene, chrysene, fluoranthene, phenanthrene, and pyrene in untreated experimental …

The Feasibility Of Transferring Clean Technology From The United States To China : A Case Study From The Paper Industry, He Ning

Theses

In their pursuit of economic development, many developing countries are causing pollution at an alarming rate. One solution to the problem is the use of clean technology. Some developed countries have created various manufacture technologies which result in pollution prevention. There is a need for the transfer of clean technology from the developed countries to developing countries. It is beneficial to study the feasibility of such transfer.

The manufacturing processes of the paper industry are selected for this study. An investigation and comparison was conducted in order to evaluate the feasibility of clean technology transfer from the United States to …

Development And Field Testing Of Pulse Introduction Membrane Extraction (Pime) For Measurement Of Ground Water Contamination, Anthony San Juan

Theses

VOCs are a class of aromatic and aliphatic compounds with a variety of functional groups, and are in general detrimental to human health even at trace levels. Conventional analysis of VOCs in groundwater usually involves sampling at site followed by laboratory analysis. This results in long turn around times, high cost and also errors associated with sample preservation during transportation and storage. In order to address these problems, a field portable instrument referred to as Pulse Introduction Membrane Extraction (PIME) has been developed for monitoring trace level halogenated organic contaminants in ground water. A membrane extraction approach has been used, …

Analytical And Experimental Study Of Investment Casting With Laser Stereolithography Models, Wen-Long Yao

Dissertations

This dissertation presents an analytical and experimental investigation of ceramic shell cracking during the burnout process in investment casting with internally webbed laser stereolithography (SLA) patterns. Included in the consideration are the cracking temperature of the ceramic shell, the web link buckling temperature, and the glass transition temperature of the epoxy resin. The hypothesis is that shell cracking will occur when the cracking temperature is lower than the glass transition temperature and the web buckling temperature.

An analytical and experimental study has been conducted, with the cross-sectional area, the span length of the web structure, and the shell thickness being …

A Combined Simulated Annealing And Tabu Search Strategy To Solve Network Design Problem With Two Classes Of Users, Qifeng Zeng

Dissertations

A methodology to solve a transportation network design problem (TCNDP) with two classes of users (passenger cars and trucks) is developed. Given an existing highway system, with a capital investment budget constraint, the methodology selects the best links to be expanded by an extra lane by considering one of three types of traffic operations: exclusive for passenger cars, exclusive for trucks, and for both passenger cars and trucks such that the network total user equilibrium (UE) travel time is minimized.

The problem is formulated as an NP-hard combinatorial nonlinear integer programming problem. The classical branch and bound methodology for the …

Space-Time Reduced Rank Methods And Cfar Signal Detection Algorithms With Applications To Hprf Radar, Tareq F. Ayoub

Dissertations

In radar applications, the statistical properties (covariance matrix) of the interference are typically unknown a priori and are estimated from a dataset with limited sample support. Often, the limited sample support leads to numerically ill-conditioned radar detectors. Under such circumstances, classical interference cancellation methods such as sample matrix inversion (SMI) do not perform satisfactorily. In these cases, innovative reduced-rank space-time adaptive processing (STAP) techniques outperform full-rank techniques. The high pulse repetition frequency (HPRF) radar problem is analyzed and it is shown that it is in the class of adaptive radar with limited sample support. Reduced-rank methods are studied for the …

Removal Of Volatile Organic Compound (Voc) Vapors In Biotrickling Filters : Process Modeling And Validation With Chlorinated Aromatic Compounds, Christos J. Mpanias

Dissertations

This study dealt with the removal of vapors of volatile organic compounds from airstreams in biotrickling filters (BTFs). A detailed general model was developed for describing the process under steady-state conditions. The model accounts for mass transfer between phases (air, liquid, biofilm) and biodegradation of pollutants in the biofilm. It also accounts for potential kinetic interactions among pollutants as well as potential process limitations by oxygen availability.

The general model was experimentally validated using mono-chlorobenzene (m-CB) and ortho-dichlorobenzene (o-DCB) as model compounds either alone or in mixture with each other. Before BTF experiments were undertaken, a systematic kinetic study was …

Robust Fuzzyclustering For Object Recognition And Classification Of Relational Data, Sumit Sen

Dissertations

Prototype based fuzzy clustering algorithms have unique ability to partition the data while detecting multiple clusters simultaneously. However since real data is often contaminated with noise, the clustering methods need to be made robust to be useful in practice. This dissertation focuses on robust detection of multiple clusters from noisy range images for object recognition. Dave's noise clustering (NC) method has been shown to make prototype-based fuzzy clustering techniques robust. In this work, NC is generalized and the new NC membership is shown to be a product of fuzzy c-means (FCM) membership and robust M-estimator weight (or possibilistic membership). Thus …

The Intelligent Browser For Texpros, Chih-Ying Wang

Dissertations

Browsing is a technique, which helps users to formulate their query and retrieve information in the information retrieval system. This technique provides users with capabilities of understanding their information needs and gaining system knowledge during the course of the browsing and thus it eases the users' burden when issuing queries. The basic components of the browser provides an underlying structure which allows users to navigate and a browsing process controller which provides users with the needed assistance during each browsing session.

In this dissertation, a new infrastructure (OP-Net), transformed from the existing object network is proposed. Each object in the …

Modelling Of In-Situ Bioremediation With Emphasis On Inhibitory Kinetics And Biomass Growth, Dilip Kumar Mandal

Dissertations

This thesis was motivated by the need for better engineering tools to predict the extent of contaminant plume migration in the saturated zone. The principal result was a mathematical model analogous to a catalytic packed-bed reactor, in which the subsurface was considered to be composed (conceptually) of soil aggregates (the "catalyst" particles, in which biodegradation, diffusion, and sorption take place), and a mobile phase (groundwater) passing around the aggregates, in which convection, axial diffusion, and mass transfer from the aggregates take place.

The modelling emphasis was on a more detailed exposition of the biokinetics of the system (including an inhibitory …

Knowledge-Based Document Filing For Texpros, Xien Fan

Dissertations

This dissertation presents a knowledge-based document filing system for TEXPROS. The requirements of a. personal document processing system are investigated. In order for the system to be used in various application domains, a flexible, dynamic modeling approach is employed by getting the user involved in document modeling. The office documents are described using a dual-model which consists of a document type hierarchy and a folder organization. The document type hierarchy is used to capture the layout, logical and conceptual structures of documents. The folder organization, which is defined by the user, emulates the real world structure for organizing and storing …

Effects Of Shore-Parallel Structures On Meiofauna In The Intertidal Foreshore Of A Sandy Estuarine Beach, Raritan Bay, New Jersey, Usa, Valerie L. Spalding

Theses

Field investigations conducted at three sites on the intertidal sandy foreshore at Cliffwood Beach and Keyport Harbor, Raritan Bay, New Jersey reveal the relationship between meiofaunal density, wave and beach characteristics at sites where bulkheads and seawalls are present and at an adjacent site where they are not.

Wave characteristics were gathered at 2 hz over the tidal cycle with a pressure transducer. Three replicate core samples, to a depth of 0. 10 m, were gathered at four sampling stations across the foreshore at low tide to determine meiofaunal density. A fourth core sample was used to determine grain size, …

Petri Net Modeling And Performance Analysis Of Can Fieldbus, Ji-Qiong Zhou

Theses

The CAN FB (Controller Area Network FieldBus) has been in existence for ten years. It supports automated manufacturing and process control environments to interconnect intelligent devices such as valves, sensors, and actuators. CAN FieldBus has a high bit rate and the ability to detect errors. It is immune to noise and resistant to shock, vibration, and heat. Two recently introduced mechanisms, Distributed Priority Queue (DPQ) and Priority Promotion (PP) enable CAN FieldBus networks to share out the system bandwidth and grant ail upper bound on the transmission times so as to meet the requirements in real-time communications. Modeling and analysis …

The Importance Of Liability For The Redevelopment Of Brownfields : The Developers View, Daniel F. Chachakis

Theses

The thousands of former industrial properties lying vacant in New Jersey are an economic challenge for all areas of government. If these properties are, or are perceived to be, contaminated then they are labeled Brownfields. An important question is whether the threat of liability for contamination by prior owners is a current cause behind the failure of developers to acquire and redevelop Brownfields in the State of New Jersey.

The goal of this work was to discover if there is a link between liability and the developer's decision making process. How important is the liability factor? Fifty-seven variables were examined …

Radiative Properties Of Silicon, Anamika Patel

Theses

The objective of this thesis was 1) to study the radiative properties of silicon in the wavelength range of 1 to 20 microns and temperature range of 30 to 1000°C for the development of a multi-wavelength pyrometer 2) to develop a [sic] methodologies for deconvolution of the measured optical properties to yield fundamental optical constants of bulk materials. A novel spectral emissometer has been utilized for measurement of the temperature dependent radiative properties of silicon. The temperature determination capability of the emissometer was tested and verified using a standard thermocouple embedded in a silicon wafer. The temperature measurement accuracy, with …

Incentive Factors That Affect The Redevelopment Of Brownfield Sites In New Jersey, Edison L. Hammond

Theses

This thesis sought to addressthree main questions:

· Are brownfieldsa significant problem in New Jersey and its municipalities?

· What factors havecontributed to brownfields' continued existence?

· What factors aremost important for correcting brownfields in the state?

The study involved surveyingFederal and state agencies, NonGovernmental Organizations (NGOs) andmunicipalities that work with brownfields. It involved a survey questionnaire,followed by a detailed telephone interview to determine municipalities'satisfaction with actions and policies taken by state agencies on brownfieldredevelopment.

Eight Federal and state agenciesand NGOs participated, along with ten municipalities from around thestate. The major findings were: brownfields are a significant problemat all levels; …

Control Of Nox In Alkaline Media With Tertiary Butyl Hydroperoxide, David R. Edwards

Theses

Alkaline solutions of tert-butyl hydroperoxide (TBHP) selectively remove NO from simulated flue gasses. The investigation was conducted in a bubbling scrubber. NO removal efficiency of the scrubbing solutions was evaluated as a function of various operating parameters such as pH, oxidant concentration, oxidant to base mole ratio, residence time, temperature and flue gas compositions.

Alkaline solutions of TBHP show promise of being an economical choice for the selective removal of NO from flue gas. Solutions containing 0.2 M TBHP, 0.03 M NaOH (pH 12.5), and 1 minute NO residence time remove NO to below detectable levels at 53°C. The source, …

Development Of A Framework For Internet Based Education System, Srinivas Lanka

Theses

Development of a framework for Internet based education has demonstrated the use of Oracle tools for the use of delivery of education on the World Wide Web. This also has proved that for an efficient dynamic education scenario, the use of a database-based system with a proper retrieval system is required.

We have designed the system on an Oracle backend system with Designer/2000. Developer/2000 helped us with the design and development of the system. Oracle Web Server 2.1 helped us with the retrieval of the web pages.

The entire design of the system and the reasoning behind the system has …

In Vitro Cytotoxicity Study Of Glutaraldehyde And No-React Treated Bioprosthetic Heart Valves And The Aortic Wall, Roger Ongosi

Theses

Valvular failure due to calcification and leaflet disruption of artificial bioprostheses is still a major concern in valve replacement surgery. Previous studies have shown that Glutaraldehyde, a chemical used in the treatment of artificial valves promotes calcification. In this investigation glutaraldehyde and No-React® treated tissue samples of pericardium, cusp and the aortic wall were tested for cytocompatibility using live mouse fibroblast cultures. The samples were cut into 3 X 3 mm2 washed in phosphate buffered saline solution, transferred into cell culture flask containing cells that had been cultured for 24 hours and incubated at 37 "C in 5 % CO2. …

Samuel Florman And Literature Of Technology, Paul F. Sharke

Theses

In 1996, engineer and author Samuel Florman asked why engineering and technology had been represented only lightly in literature. From a mere handful of books dealing with this topic, he named The Control of Nature (1989), by John McPhee, Zen and the Art of Motorcycle Maintenance (1974), by Robert Pirsig, and The Soul of a New Machine (1981), by Tracy Kidder, as being among the best examples of a literary expression of engineering. These three works are examined here in light of Florman's own four books on the subject of engineering, The Existential Pleasures of Engineering (1976), Blaming Technology …

A Microcosm Study In The Reductive Dechlorination Of Tetrachloroethylene Using Fermentation Acids And Alcohols As Electron Donors, Anthony Siccard Iii

Theses

Anaerobic microcosms of Arthur Kill (New Jersey) sediment were used to investigate the effects of several electron donors on tetrachloroethylene (PCE) dechlorination activity. The substates tested were methanol, butanol, butyrate, lactate and succinate both by themselves and in various combinations. Different levels of PCE dehalogenation were noticed in all of the microcosms regardless of the electron donor used. Vinyl chloride was the major dehalogenation product detected in the majority of the microcosms. The causitive organism or group that carried our the reductive dehalogenation was not identified. Only the microcosms admended with a mixture of butanol/methanol were able to fully reduce …

Bootstrapping Tsmars Models, Liangzhong Chen

Theses

We investigate bootstrap inference methods for nonlinear time series models obtained using Multivariate Adaptive Regression Splines for Time Series (TSMARS), for which theoretical properties are not currently known. We use two different methods of bootstrapping to obtain confidence intervals for the underlying nonlinear function and prediction intervals for future values, based on estimated TSMARS models for the bootstrapped data. We also explore the method of Bootstrap AGGregatING (Bagging), due to Breiman (1996), to investigate whether the residual and prediction mean squared errors from a fitted TSMARS model can be reduced by averaging across the values obtained from each of the …