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Thermochemistry Of Fluorinated Aldehydes And Corresponding Radicals;Thermochemistry And Kinetics Of Diethyl Ether And Ethyl Oxirane Relative To Reactions Under Atmospheric And Combustion Conditions, Douglas Lee Purnell Jr. Oct 2017

Thermochemistry Of Fluorinated Aldehydes And Corresponding Radicals;Thermochemistry And Kinetics Of Diethyl Ether And Ethyl Oxirane Relative To Reactions Under Atmospheric And Combustion Conditions, Douglas Lee Purnell Jr.

Dissertations

Fundamental thermochemical properties including enthalpies (ΔH°f 298), entropies (S°(T)), heat capacities (Cp(T)), and bond dissociation energies (BDEs) for several common and complex hydrocarbon fuel species are determined using computational chemical methods. ΔH°f 298 values are calculated using isodesmic reactions with the CBS-APNO, CBS-4M, CBS-QB3, G2, G3, G4, Weizmann-1 (W1U) and M06-2X, ωB97X, B3-LYP with basis set 6-31G+ (d,p) and 6-31G++(d,p) calculation methods. Structures, moments of inertia, vibrational frequencies, and internal rotor potentials are calculated for contributions to entropies and heat capacities. Kinetic rate parameters are calculated for hydrogen abstraction and …


Erosion Behavior And Scour Risk Of Extremely Coarse Streambeds, Abolfazl Bayat Oct 2017

Erosion Behavior And Scour Risk Of Extremely Coarse Streambeds, Abolfazl Bayat

Dissertations

Bridge scour, which is the erosion of soil and rock around bridge abutments and piers, is the principal cause of bridge failure in the United States and around the world. Previous investigations of scour have focused mostly on fine sediments such as sand, silt, and small gravel, because such alluvium underlies a majority of bridges. The erosion resistance of coarser sediments has received limited attention to date, even though they dominate many small to medium-size rivers in the northern tiers of the United States, Europe, and Asia. This study focuses on the scour behavior of extremely coarse particles (ECP), namely …


Topics On Multiple Hypotheses Testing And Generalized Linear Model, Yalin Zhu Oct 2017

Topics On Multiple Hypotheses Testing And Generalized Linear Model, Yalin Zhu

Dissertations

In applications such as studying drug adverse events (AE) in clinical trials and identifying differentially expressed genes in microarray experiments, the data of the experiments usually consists of frequency counts. In the analysis of such data, researchers often face multiple hypotheses testing based on discrete test statistics. Incorporating this discrete property of the data, several stepwise procedures, which allow to use the CDF of p-values to determine the testing threshold, are proposed for controlling familiwise error rate (FWER). It is shown that the proposed procedures strongly control the FWER and are more powerful than the existing ones for discrete data. …


A Novel E-Voting System With Diverse Security Features, Haijun Pan Oct 2017

A Novel E-Voting System With Diverse Security Features, Haijun Pan

Dissertations

Internet-based E-voting systems can offer great benefits over traditional voting machines in areas, such as protecting voter and candidate privacy, providing accurate vote counting, preventing voter fraud, and shortening the time of vote counting. This dissertation introduces, establishes and improves Internet-based E-voting systems on various aspects of the voting procedure. In addition, our designs also enable voters to track their votes which is a very important element in any elections.

Our novel Internet-based E-voting system is based on the following realistic assumptions: (1) The election authorities are not 100% trustworthy; (2) The E-voting system itself is not 100% trustworthy; (3) …


Formulation And Dissolution Of Polymer Strip Films For The Delivery Of Poorly Water-Soluble Drug Nanoparticles, Scott Matthew Krull Oct 2017

Formulation And Dissolution Of Polymer Strip Films For The Delivery Of Poorly Water-Soluble Drug Nanoparticles, Scott Matthew Krull

Dissertations

Polymer films have emerged as a promising platform for delivery of pharmaceutical products in recent years due to simplified processing, greater flexibility, and improved patient compliance over traditional solid dosage forms. However, the large majority of efforts have focused on incorporation of water-soluble drugs. The objective of this dissertation is to explore the robustness and versatility of the strip film platform for delivery of poorly water-soluble drug nanoparticles to ultimately develop a predictive model for drug release from such films.

The robustness of the polymer strip film platform to successfully deliver a variety of poorly water-soluble drug nanoparticles without the …


Machine Learning Based Digital Image Forensics And Steganalysis, Guanshuo Xu Oct 2017

Machine Learning Based Digital Image Forensics And Steganalysis, Guanshuo Xu

Dissertations

The security and trustworthiness of digital images have become crucial issues due to the simplicity of malicious processing. Therefore, the research on image steganalysis (determining if a given image has secret information hidden inside) and image forensics (determining the origin and authenticity of a given image and revealing the processing history the image has gone through) has become crucial to the digital society.

In this dissertation, the steganalysis and forensics of digital images are treated as pattern classification problems so as to make advanced machine learning (ML) methods applicable. Three topics are covered: (1) architectural design of convolutional neural networks …


Public Perceptions Of The Functions Of Natural And Engineered Infrastructure In Coastal Hazards Mitigation: The Cases Of Two Communities In The Raritan Bayshore, New Jersey, Jaime D. Ewalt Gray Oct 2017

Public Perceptions Of The Functions Of Natural And Engineered Infrastructure In Coastal Hazards Mitigation: The Cases Of Two Communities In The Raritan Bayshore, New Jersey, Jaime D. Ewalt Gray

Dissertations

Emerging United States (U.S.) federal policies call for more comprehensive integration of both engineered and natural infrastructure in mitigating coastal hazards. For such policies to be effectively implemented, the mitigation functions of and relationship between natural infrastructure and engineered infrastructure must be understood and their integrated use accepted by affected actors, especially residents living in at-risk coastal communities. Little is known about public perceptions of the functions of engineered and natural infrastructure in coastal hazard mitigation and the interactions between these two types of infrastructure. This study analyzes perceptions based on semi-structured interviews of 14 residents in Laurence Harbor, Middlesex …


Roles Of Cosolvents On Protein Stability, Zhaoqian Su Oct 2017

Roles Of Cosolvents On Protein Stability, Zhaoqian Su

Dissertations

The function of a protein is determined by its three-dimensional structure which emerges from the delicate balance of forces involving atoms of the protein and the solvent. This balance can be perturbed by changing temperature, pressure, pH and by adding organic molecules known as cosolvents to the solution. Despite the wide use of cosolvents to perturb protein structures in the lab and in living systems, their molecular mechanisms are still not well established. Understanding these mechanisms is a problem of substantial interest, with potential application to the design of new drugs to target proteins. In this dissertation, we probe the …


Annotation Of Multimedia Learning Materials For Semantic Search, Sheetal Rajgure Oct 2017

Annotation Of Multimedia Learning Materials For Semantic Search, Sheetal Rajgure

Dissertations

Multimedia is the main source for online learning materials, such as videos, slides and textbooks, and its size is growing with the popularity of online programs offered by Universities and Massive Open Online Courses (MOOCs). The increasing amount of multimedia learning resources available online makes it very challenging to browse through the materials or find where a specific concept of interest is covered. To enable semantic search on the lecture materials, their content must be annotated and indexed. Manual annotation of learning materials such as videos is tedious and cannot be envisioned for the growing quantity of online materials. One …


Broader Impacts And Participation: Do's And Don'ts, Cristo Leon Sep 2017

Broader Impacts And Participation: Do's And Don'ts, Cristo Leon

STEM for Success Resources

This talk is directed at graduate students interested in pursuing NSF federal research opportunities


Njit Libraries 2016-2017 Annual Report, Njit Libraries Sep 2017

Njit Libraries 2016-2017 Annual Report, Njit Libraries

Library Annual Reports

No abstract provided.


Programming Frameworks For Mobile Sensing, Hillol Debnath Aug 2017

Programming Frameworks For Mobile Sensing, Hillol Debnath

Dissertations

The proliferation of smart mobile devices in people’s daily lives is making context-aware computing a reality. A plethora of sensors available in these devices can be utilized to understand users’ context better. Apps can provide more relevant data or services to the user based on improved understanding of user’s context. With the advent of cloud-assisted mobile platforms, apps can also perform collaborative computation over the sensing data collected from a group of users. However, there are still two main issues: (1) A lack of simple and effective personal sensing frameworks: existing frameworks do not provide support for real-time fusing of …


Estimating Vehicles Emissions At Signalized Intersections In The Highway Capacity Manual, Yuanyuan Fan Aug 2017

Estimating Vehicles Emissions At Signalized Intersections In The Highway Capacity Manual, Yuanyuan Fan

Dissertations

Over the past decades, motor vehicle volumes have continued to increase at a high rate. As a result, engineers in the transportation field not only need more robust knowledge of traffic operation control and transportation planning, but more attention is also needed to understand and estimate the influences that this increasing volume of vehicles has on the environment, especially the influence on air quality. The EPA has stated that reducing carbon monoxide (CO) from vehicle emissions is the most significant way to control air pollution from the transportation sector.

The Highway Capacity Manual is a national and international resource that …


Spatial And Temporal Deformation Pattern Of The Brain From Blunt Trauma, Abdus Ali Aug 2017

Spatial And Temporal Deformation Pattern Of The Brain From Blunt Trauma, Abdus Ali

Theses

It is widely accepted that under extreme loadings the soft tissue of the brain will deform inside the skull, creating large amounts of both stress and strain on the tissue. This can result in a focal injury, or in the case of acceleration and deceleration, diffuse injuries. Any attempt at understanding the underlying mechanisms and effects of TBI, have to start by focusing on what is actually occurring within the brain. The objective of this experiment is to record differences in the spatial and temporal patterns of deformation within the brain during blunt trauma when changing impact parameters. A linear …


Subject And Group Level Changes And Comparison In Functional Connectivity Under Low Vs. High Cognitively Demanding Naturalistic Viewing Conditions Using Fmri, Rakibul Hafiz Aug 2017

Subject And Group Level Changes And Comparison In Functional Connectivity Under Low Vs. High Cognitively Demanding Naturalistic Viewing Conditions Using Fmri, Rakibul Hafiz

Theses

Resting State fMRI is used extensively for analysing brain regions. fMRI is also used to determine task induced activations from cerebral networks. This study involves both rest and task activation data and implements statistical methods applied on Blood Oxygenation Level Dependent (BOLD) signals. The conventional task based designs are very specific and may not reflect day to day activities. The two task conditions in this study are watching a movie called INSCAPE with low cognitive load and segments of contextual Hollywood movies under continuous and natural conditions.

The aim is to investigate individual and group level Functional Connectivity changes between …


Matrix Completion Algorithms With Applications In Biomedicine, E-Commerce And Social Science, Yiran Wang Aug 2017

Matrix Completion Algorithms With Applications In Biomedicine, E-Commerce And Social Science, Yiran Wang

Theses

This thesis investigates matrix completion algorithms with applications in biomedicine, e-commerce and social science. In general, matrix completion algorithms work well for low rank matrices. Such matrices find many applications in recommender systems and social network analysis. On the other hand, biological networks often yield high rank matrices. For example, the adjacency matrix representing interactions between transcription factors and target genes in the cell is a highly sparse matrix, in which most entries correspond to absent interactions and only a few entries correspond to present interactions. This sparse matrix is a high rank or even full rank matrix. Matrix completion …


Direct Computations Of Marangoni Driven Flows Using A Volume Of Fluid Method, Ivana Seric Aug 2017

Direct Computations Of Marangoni Driven Flows Using A Volume Of Fluid Method, Ivana Seric

Dissertations

The volume of fluid (VoF) interface tracking methods have been used for simulating a wide range of interfacial flows. An improved accuracy of the surface tension force computation has enabled the VoF method to become widely used for simulating flows driven by the surface tension force. A general methodology for the inclusion of variable surface tension coefficient into a VoF based Navier-Stokes solver is developed. This new numerical model provides a robust and accurate method for computing the surface gradients directly by finding the tangent directions on the interface using height functions. The implementation applies to both temperature and concentration …


Detecting User Demographics In Twitter To Inform Health Trends In Social Media, Christopher R. Markson Jul 2017

Detecting User Demographics In Twitter To Inform Health Trends In Social Media, Christopher R. Markson

Dissertations

The widespread and popular use of social media and social networking applications offer a promising opportunity for gaining knowledge and insights regarding population health conditions thanks to the diversity and abundance of online user-generated information (UGHI) relating to healthcare and well-being. However, users on social media and social networking sites often do not supply their complete demographic information, which greatly undermines the value of the aforementioned information for health 2.0 research, e.g., for discerning disparities across population groups in certain health conditions. To recover the missing user demographic information, existing methods observe a limited scope of user behaviors, such as …


The Analysis And The Three-Dimensional, Forward-Fit Modeling Of The Hard X-Ray And The Microwave Emissions Of Major Solar Flares, Natsuha Kuroda Jul 2017

The Analysis And The Three-Dimensional, Forward-Fit Modeling Of The Hard X-Ray And The Microwave Emissions Of Major Solar Flares, Natsuha Kuroda

Dissertations

Solar flares are one of the most violent and energetic space weather events that are known to cause various adverse effects on the Earth. One of the major problems that must be solved to understand flares and to be able to predict their magnitudes is how the particles in the solar atmosphere are accelerated after the magnetic reconnection. One way to help solve this problem is to investigate the properties of the high energy electrons produced during the flare impulsive phase, observed in the hard X-ray (HXR) and microwave (MW). The two emissions are considered to be produced by a …


Decision Models For Fast-Fashion Supply And Stocking Problems In Internet Fulfillment Warehouses, Jingran Zhang Jul 2017

Decision Models For Fast-Fashion Supply And Stocking Problems In Internet Fulfillment Warehouses, Jingran Zhang

Dissertations

Internet technology is being widely used to transform all aspects of the modern supply chain. Specifically, accelerated product flows and wide spread information sharing across the supply chain have generated new sets of decision problems. This research addresses two such problems. The first focuses on fast fashion supply chains in which inventory and price are managed in real time to maximize retail cycle revenue. The second is concerned with explosive storage policies in Internet Fulfillment Warehouses (IFW).

Fashion products are characterized by short product life cycles and market success uncertainty. An unsuccessful product will often require multiple price discounts to …


Boundary Integral Equation Based Numerical Solutions Of Helmholtz Transmission Problems For Composite Scatters, Haiyang Qi Jul 2017

Boundary Integral Equation Based Numerical Solutions Of Helmholtz Transmission Problems For Composite Scatters, Haiyang Qi

Dissertations

In this dissertation, an in-depth comparison between boundary integral equation solvers and Domain Decomposition Methods (DDM) for frequency domain Helmholtz transmission problems in composite two-dimensional media is presented. Composite media are characterized by piece-wise constant material properties (i.e., index of refraction) and thus, they exhibit interfaces of material discontinuity and multiple junctions. Whenever possible to use, boundary integral methods for solution of Helmholtz boundary value problems are computationally advantageous. Indeed, in addition to the dimensional reduction and straightforward enforcement of the radiation conditions that these methods enjoy, they do not suffer from the pollution effect present in volumetric discretization. The …


Seepage Monitoring And Diagnosis Of Distresses In An Earth Embankment Dam Using Probability Methods, Seyed Mohammad Reza Mousavian Jul 2017

Seepage Monitoring And Diagnosis Of Distresses In An Earth Embankment Dam Using Probability Methods, Seyed Mohammad Reza Mousavian

Dissertations

Failure of embankment dams may result in catastrophic consequences. Considering seepage and internal erosion are accounted as one of the major causes of failure in earth embankment dams, it is essential to detect any concentrated seepage and sources of distress at early stages. A number of investigation and monitoring methods exist for the detection of seepage, with varying degrees of technological and implementation complexity. This research, focuses on the Electrical Resistivity Monitoring Method (ERM), and develops a condition assessment process that allows 1) the identification of potential seepage areas and progress through visual observation and flow measurement, and 2) the …


Efficient Coarse-Grained Brownian Dynamics Simulations For Dna And Lipid Bilayer Membrane With Hydrodynamic Interactions, Szu-Pei Fu Jul 2017

Efficient Coarse-Grained Brownian Dynamics Simulations For Dna And Lipid Bilayer Membrane With Hydrodynamic Interactions, Szu-Pei Fu

Dissertations

The coarse-grained molecular dynamics (CGMD) or Brownian dynamics (BD) simulation is a particle-based approach that has been applied to a wide range of biological problems that involve interactions with surrounding fluid molecules or the so-called hydrodynamic interactions (HIs). From simple biological systems such as a single DNA macromolecule to large and complicated systems, for instances, vesicles and red blood cells (RBCs), the numerical results have shown outstanding agreements with experiments and continuum modeling by adopting Stokesian dynamics and explicit solvent model. Finally, when combined with fast algorithms such as the fast multipole method (FMM) which has nearly optimal complexity in …


Mobile Cloud Computing And Network Function Virtualization For 5g Systems, Ali Al-Shuwaili Jul 2017

Mobile Cloud Computing And Network Function Virtualization For 5g Systems, Ali Al-Shuwaili

Dissertations

The recent growth of the number of smart mobile devices and the emergence of complex multimedia mobile applications have brought new challenges to the design of wireless mobile networks. The envisioned Fifth-Generation (5G) systems are equipped with different technical solutions that can accommodate the increasing demands for high date rate, latency-limited, energy-efficient and reliable mobile communication networks.

Mobile Cloud Computing (MCC) is a key technology in 5G systems that enables the offloading of computationally heavy applications, such as for augmented or virtual reality, object recognition, or gaming from mobile devices to cloudlet or cloud servers, which are connected to wireless …


Performance Optimization And Energy Efficiency Of Big-Data Computing Workflows, Tong Shu Jul 2017

Performance Optimization And Energy Efficiency Of Big-Data Computing Workflows, Tong Shu

Dissertations

Next-generation e-science is producing colossal amounts of data, now frequently termed as Big Data, on the order of terabyte at present and petabyte or even exabyte in the predictable future. These scientific applications typically feature data-intensive workflows comprised of moldable parallel computing jobs, such as MapReduce, with intricate inter-job dependencies. The granularity of task partitioning in each moldable job of such big data workflows has a significant impact on workflow completion time, energy consumption, and financial cost if executed in clouds, which remains largely unexplored. This dissertation conducts an in-depth investigation into the properties of moldable jobs and provides an …


Long-Term Management And Condition Assessment Of Concrete Culvert, Zhenting Zou Jul 2017

Long-Term Management And Condition Assessment Of Concrete Culvert, Zhenting Zou

Dissertations

Infrastructure is the backbone of national security, economic growth, public safety and other aspects of the society. Nationwide, the condition of America’s infrastructure was graded as “D+” by the American Society of Civil Engineers (ASCE) in 2013.

Owners and responsible agencies have employed various cost-effective maintenance and repair methods as well as analytical tools to repair and extend the service life of the infrastructure. However, without a long-term plan, maintenance work can be delayed by lack of funds. Maintenance delay may cause significant reduction in condition state leading to premature failure of the infrastructure. Consequently, a long-term rehabilitation plan is …


Airspace Analysis For Greener Operations: Towards More Adoptability And Predictability Of Continuous Descent Approach (Cda), Emad Ali Alharbi May 2017

Airspace Analysis For Greener Operations: Towards More Adoptability And Predictability Of Continuous Descent Approach (Cda), Emad Ali Alharbi

Dissertations

Continuous Descent Approach (CDA), also known as Optimized Profile Descent (OPD), is the advanced flight technique for commercial aircraft to descend continuously from cruise altitude to Final Approach Fix (FAF) or touchdown without level-offs and with- or near-idle thrust setting. Descending using CDA, aircraft stays as high as possible for longer time thereby expanding the vertical distance between aircraft's sources of noise and ground, and thus significantly reducing the noise levels for populated areas around airports. Also, descending with idle engines, fuel burn is reduced resulting in reduction of harmful emissions to the environment and fuel consumption to air carriers. …


Novel Membrane Structures For Air And Water Purification, Smruti Ragunath May 2017

Novel Membrane Structures For Air And Water Purification, Smruti Ragunath

Dissertations

Membrane separations have undergone rapid developments in recent years. The key component in the process is the membrane itself which acts as a selective barrier regulating transport of components between the two sections. The main advantage of membrane separation process in comparison to other unit operations is its unique separation principle, ease of operation, lower energy requirement, and can be easily coupled with other downstream processes. Different membrane based applications include filtration, osmosis, dialysis, gas separation, pervaporation, membrane extraction and membrane distillation (MD). The membranes can be fabricated by a variety of processes such as phase inversion, sol-gel, track etching, …


Iii-Nitride Nanowire Light-Emitting Diodes: Design And Characterization, Dipayan Datta Choudhary May 2017

Iii-Nitride Nanowire Light-Emitting Diodes: Design And Characterization, Dipayan Datta Choudhary

Theses

III-nitride semiconductors have been intensively studied for optoelectronic devices, due to the superb advantages offered by this materials system. The direct energy bandgap III-nitride semiconductors can absorb or emit light efficiently over a broad spectrum, ranging from 0.65 eV (InN) to 6.4 eV (AlN), which encompasses from deep ultraviolet to near infrared spectrum. However, due to the lack of native substrates, conventional III-nitride planar heterostructures generally exhibit very high dislocation densities that severely limit the device performance and reliability. On the other hand, nanowire heterostructures can be grown on lattice mismatched substrates with drastically reduced dislocation densities, due to highly …


Experimental Study Of Bubble Rupture During Shock-Fluid Interaction, Subhalakshmi Chandrasekaran May 2017

Experimental Study Of Bubble Rupture During Shock-Fluid Interaction, Subhalakshmi Chandrasekaran

Theses

Head injuries are associated with exposure to high energy explosive detonation. There are four distinct types of blast induced neurotrauma (BINT): 1) these caused by supersonic shock waves propagating in the atmosphere (primary), 2) high velocity impact of shrapnel and debris (secondary) 3) acceleration and deceleration of the body and collision with the solid objects in the field (tertiary) and 4) exposure to high temperature and toxic gases (quaternary). One of the mechanisms implicated in non-impact primary blast-induced traumatic brain injury (bTBI) is cavitation. It is hypothesized that cavitation can occur in the cerebrospinal fluid (CSF) layer, brain interstitial fluid, …