Digital Commons Network^™

Novel Design And Manufacturing Strategies For Portable Air-Breathing Proton Exchange Membrane Fuel Cells, Sriram Praneeth Isanaka

Doctoral Dissertations

"The purpose of this dissertation is to study the importance of design novelty and advanced manufacturing and assembly practices towards portable air-breathing proton exchange membrane fuel cells. Traditional proton exchange membrane fuel cell designs have always been based on prismatic shapes and expensive materials like graphite and steel. The novel design strategies theorized as part of this research though have led to the creation of working prototypes with unconventional form factors, materials and manufacturing methods. The benefits include improved reactant flow characteristics, superior power densities, reduced cost, and simplified manufacturing and assembly complexity as compared to conventional proton exchange membrane …

Nanostructured Materials Prepared By Atomic Layer Deposition For Catalysis And Lithium-Ion Battery Applications, Rajankumar Patel

Doctoral Dissertations

"Atomic/molecular layer deposition (ALD/MLD) has emerged as an important technique for depositing thin films in both scientific research and industrial applications. In this dissertation, ALD/MLD was used to create novel nanostructures for two different applications, catalysis and lithium-ion batteries.

MLD was used to prepare ultra-thin dense hybrid organic/inorganic polymer films. Oxidizing the hybrid films removed the organic components and produced the desired nanoporous films. Both porous alumina and titania films can be prepared by such a way. A novel nanostructured catalyst (Pt/SiO₂) with an ultra-thin porous alumina shell obtained from the thermal decomposition of an aluminium alkoxide film …

Single Particle-Inductively Coupled Plasma-Mass Spectrometry Technology Development For Metallic Nanoparticle Characterization In Complex Matrices, Yongbo Dan

Doctoral Dissertations

"As the rapid growing of nanotechnology, the release of engineered nanoparticles (ENPs) into the environment is inevitable. After entering the real environment, ENPs tend to react with different components of the ecosystem (e.g. water, soil, air, plants) and make their characterization difficult. Analyzing ENPs in these complex matrices still remains as a grand challenge. ENPs characterization is normally the first step of risk assessment. Current analytical techniques have shown some limitations in revealing the unique characteristics of ENPs in complex matrices and reliable analytical techniques are in urgent need. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) is an emerging …

Experimental Performance Evaluation And Design Of Schemes For Passive Rfid Network, Shadi Ebrahimi-Asl

Doctoral Dissertations

"Passive Radio Frequency Identification (RFID) is a short range technology for transferring information. The main advantage of passive RFID systems over active communication systems is the battery-less operation at the client sides. However, there are two major challenges that limit the widespread adaptation of passive RFID systems: short communication range and low read rate in dense deployments. This dissertation addresses these issues by studying the root causes and develops solutions for them.

In this dissertation, understanding the backscattering behavior of antennas and also the mutual coupling interactions among them are found to be the root causes of the two above-mentioned …

Integrated Geophysical Approach Using Electrical Resistivity Tomography And Multichannel Analysis Of Surface Wave In Assessing Wilson Spring Development, Ibrahim E. Ahmed

Doctoral Dissertations

"This research investigated fractured zones leading to preferential flow paths of Wilson Spring. In this context, electrical resistivity tomography (ERT) data and multi-channel analyses of surface waves (MASW) data were acquired at studied site with the purpose of mapping a variable depth to top of bedrock and geological structures.

Interpretation of the boreholes, MASW, and ERT data indicated that a depth to top of rock does vary significantly at the studied site due to many solution-widened fractures. Multiple near-vertical solution-widened fractures were mapped in the studied site based on the interpretation of the ERT data. The mapped solution-widened fractures appear …

Bioactivity/Cytotoxicity Of Micro-/Nano-Materials And Novel Development Of Fiber-Optic Probes For Single Cell Monitoring, Qingbo Yang

Doctoral Dissertations

"Manufactured nano-/micro-materials (MNMs) have been widely used and their interactions with niche biological environment are highly concerned for both of their biohazardous and bioactive effects, whereas no available comprehensive evaluations or regulations have been provided yet. This dissertation thus focuses on three major aspects: 1) fundamental toxicity understandings of a typical MNMs (zinc oxide nanoparticles), 2) bioactivity evaluations of representative bioactive MNMs, and 3) development of novel micro-probes for high spatial resolution monitoring. Firstly, the NP's concentration, irradiation, hydrodynamic size, and the localized pH, ionic strength, NP zeta-potential as well as dissolved oxygen levels were found correlated with the production …

Rehabilitation And Strengthening Of Reinforced Concrete Members Using A Fiber Reinforced Cementitious Matrix Composite, Zena Riyadh Aljazaeri

Doctoral Dissertations

“Externally bonded fiber reinforced cementitious matrix (FRCM) for structural members was tested and evaluated as a new class of composite material for repairing and strengthening infrastructures. In comparison with fiber reinforced polymer (FRP) composites, FRCM composite has a superior high temperature resistance and great compatibility with concrete substrates. Experimental investigation is ongoing in the United States to evaluate the structural and durability performance of FRCM composite to be implemented in field applications. This experimental program consisted of testing 12 strengthened reinforced concrete (RC) beams to study the fatigue and flexure performance under environmental exposure and sustained stress, 10 strengthened RC …

Modeling Of Rheological Properties For Entangled Polymer Systems, Nilanjana Banerjee

Doctoral Dissertations

"The study of entangled polymer rheology both in the field of medicine and polymer processing has their major importance. Mechanical properties of biomolecules are studied in order to better understand cellular behavior. Similarly, industrial processing of polymers needs thorough understanding of rheology so as to improve process techniques. Work in this dissertation has been organized into three major sections. Firstly, numerical/analytical models are reviewed for describing rheological properties and mechanical behaviors of cytoskeleton. The cytoskeleton models are classified into categories according to the length scales of the phenomena of interest. The main principles and characteristics of each model are summarized …

Blended Learning In Chemistry Laboratory Courses: Enhancing Learning Outcomes And Aligning Student Needs With Available Resources, Shayna Brianne Burchett

Doctoral Dissertations

"Freshman science courses are intended to prepare students for the rigor and expectations of subsequent college science. While secondary education aims to prepare students for the college curriculum, many incoming freshman lack the sense of responsibility for their own learning that is essential for success in a college-level course. The freshman general-chemistry laboratory course at Missouri University of Science and Technology (Missouri S&T) was identified as a bottleneck course with a demand beyond accommodation capacity. To address the bottleneck and develop a sense of learner responsibility, a decision was made to investigate laboratory course delivery strategies. As a result of …

Dynamic Impact Of Ageing Dump Truck Suspension Systems On Whole-Body Vibrations In High-Impact Shovel Loading Operations, Saeid R. Dindarloo

Doctoral Dissertations

"Surface mining operations typically deploy large shovels, with 100+ tons per pass capacity, to load dump trucks in a phenomenon described as high-impact shovel loading operations (HISLO). The HISLO phenomenon causes excessive shock and vibrations in the dump truck assembly resulting in whole body vibration (WBV) exposures to operators. The truck suspension system performance deteriorates with time; therefore their effectiveness in attenuating vibrations reduces. No research has been conducted to study the impact of ageing suspension mechanisms on the magnitudes of WBV in HISLO operations.

This study is a pioneering effort to provide fundamental and applied knowledge for understanding the …

Assessment Of Highway Condition Using Combined Geophysical Surveys, Abdallah Alhadi Dera

Doctoral Dissertations

"Four pavement sections were investigated using ground penetrating radar (GPR) and Ultrasonic Surface Wave (USW). The objective of this research was to compare the effectiveness of two non-destructive geophysical tools, GPR and the PSPA, in assessing the condition of the pavements, composed of different construction materials. The GPR data were acquired using a 1.5 GHz antenna along five traverses spaced at two ft. intervals approximately 1000 ft. long. On the other hand, the PSPA data were acquired at the stations spaced at 1000 ft. along the five GPR traverses. Core samples were collected at each site to constrain the interpretation …

Scale-Up Investigation And Hydrodynamics Study Of Gas-Solid Fluidized Bed Reactor Using Advanced Non-Invasive Measurement Techniques, Abdelsalam Efhaima

Doctoral Dissertations

"This research focuses on validating our newly developed mechanistic scale-up methodology for hydrodynamics similarity of gas-solid fluidized bed reactors (FBRs) by implementing our advanced non-invasive measurement techniques which are gamma ray computed tomography (CT) and radioactive particle tracking (RPT) that measure local hydrodynamic parameters. Experiments were carried out in two fluidized beds of 14 cm and 44 cm in diameter using air as the gas phase and particles of different materials. Since in these reactors the gas dynamic dictates the bed hydrodynamics, the new mechanistic scale-up methodology is based on maintaining similar or closer time averaged radial profiles of gas …

Modeling Daily Electricity Load Curve Using Cubic Splines And Functional Principal Components, Abdelmonaem Salem Jornaz

Doctoral Dissertations

"Forecasting electricity load is very important to the electric utilities as well as producers of power because accurate predictions can cut down costs by avoiding power shortages or surpluses. Of specific interest is the 24-hour daily electricity load profile, which provides insight into periods of high demand and periods where the use of electricity is at a minimum. Researchers have proposed many approaches to modeling electricity prices, real-time load, and day-ahead demand, with varying success. In this dissertation three new approaches to modeling and forecasting the 24-hour daily electricity load profiles are presented. The application of the proposed methods is …

Microwave Material Characterization Of Alkali-Silica Reaction (Asr) Gel In Cementitious Materials, Ashkan Hashemi

Doctoral Dissertations

"Since alkali-silica reaction (ASR) was recognized as a durability challenge in cement-based materials over 70 years ago, numerous methods have been utilized to prevent, detect, and mitigate this issue. However, quantifying the amount of produced ASR byproducts (i.e., ASR gel) in-service is still of great interest in the infrastructure industry. The overarching objective of this dissertation is to bring a new understanding to the fundamentals of ASR formation from a microwave dielectric property characterization point-of-view, and more importantly, to investigate the potential for devising a microwave nondestructive testing approach for ASR gel detection and evaluation. To this end, a comprehensive …

Novel Approaches To Clustering, Biclustering Algorithms Based On Adaptive Resonance Theory And Intelligent Control, Sejun Kim

Doctoral Dissertations

"The problem of clustering is one of the most widely studied area in data mining and machine learning. Adaptive resonance theory (ART), an unsupervised learning clustering algorithm, is a clustering method that can learn arbitrary input patterns in a stable, fast and self-organizing way. This dissertation focuses on unsupervised learning methods, mostly based on variations of ART.

Hierarchical ART clustering is studied by generating a tree of ART units with GPU based parallelization to provide fast and finesse clustering. Experiment results show that the our method achieves significant training speed increase in generating deep ART trees compared with that from …

Azimuthal Anisotropy Beneath North Central Africa From Shear Wave Splitting Analysis, Awad Abdussalam Henish Lemnifi

Doctoral Dissertations

"This study represents the first multi-station investigation of azimuthal anisotropy beneath the interior of north central Africa, including Libya and adjacent regions, using shear wave splitting (SWS) analysis. Data used in the study include recently available broadband seismic data obtained from 15 stations managed by the Libyan Center for Remote Sensing and Space Science, and those from five other stations at which data are publicly accessible. A total of 583 pairs of high-quality SWS measurements utilizing the PKS, SKKS, and SKS phases demonstrate primarily N-S fast orientations with an average splitting delay time of approximately 1.2 s. An absence of …

Modeling, Analysis, And Simulation For Aqueous-Based Ceramic Pastes In Freeze-Form Extrusion Fabrication Process, Mingyang Li

Doctoral Dissertations

"During the freeze-form extrusion fabrication process, both the extrusion and freezing processes are complex due to the aqueous-based ceramic pastes' non-Newtonian behavior, large latent heat of the water contained in the paste, and the small temperature difference between the ambient and the paste. In this study, the steady-state relationship between plunger velocity and extrusion force is developed based on a modified Herschel-Bulkley viscosity model and the Navier-Stokes equations, and the dynamic response of the extrusion force is described by a first-order nonlinear equation when plunger velocity is taken as an input. It is shown that the extrusion response time depends …

Applications Of Simulation And Optimization Techniques In Optimizing Room And Pillar Mining Systems, Angelina Konadu Anani

Doctoral Dissertations

"The goal of this research was to apply simulation and optimization techniques in solving mine design and production sequencing problems in room and pillar mines (R&P). The specific objectives were to: (1) apply Discrete Event Simulation (DES) to determine the optimal width of coal R&P panels under specific mining conditions; (2) investigate if the shuttle car fleet size used to mine a particular panel width is optimal in different segments of the panel; (3) test the hypothesis that binary integer linear programming (BILP) can be used to account for mining risk in R&P long range mine production sequencing; and (4) …

Continuous Flow Reactor For Carbonic Acid Hydrolysis/Pretreatment Of Microalgal Biomass To Produce Bioethanol, Nicholas Dudenhoeffer

Doctoral Dissertations

"In order to maximize bioethanol production an efficient pretreatment method for the hydrolysis of polysaccharides to fermentable sugars is necessary. Commonly used pretreatment methods are the slow enzymatic hydrolysis and the corrosive mineral acid hydrolysis process that requires a post-treatment neutralization step and generates waste stream. We investigated the high temperature water with carbonic acid catalyst as an alternative method. Carbonic acid generated from dissolved CO₂ is inexpensive and environmentally benign, and easily removed by decompression. A high pressure continuous flow reactor that can continuously process the wet biomass stream and perform the carbonic acid hydrolysis in-situ using the …

Construction Of Multi-State Potential Energy Surfaces For Spectroscopy And Dynamics, Phalgun Lolur

Doctoral Dissertations

"This dissertation is about construction and visualization of multi-state Born-Oppenheimer potential energy surfaces which are essential for studying spectroscopy and dynamics. A potential energy surface is a mathematical function that represents the energy of a system as a function of its molecular geometry. The Born-Oppenheimer approximation enables us to solve the Schrödinger equation by separating the nuclear and electronic motions. Construction of potential energy surfaces has become a basic and crucial operation for chemists in order to compute various electronic states of molecules for understanding the spectroscopy, kinetics and dynamics of molecules. These methods have been used to successfully (i) …

Existence And Classification Of Nonoscillatory Solutions Of Two Dimensional Time Scale Systems, Özkan Özturk

Doctoral Dissertations

"During the past years, there has been an increasing interest in studying oscillation and nonoscillation criteria for dynamic equations and systems on time scales that harmonize the oscillation and nonoscillation theory for the continuous and discrete cases in order to combine them in one comprehensive theory and eliminate obscurity from both.

We not only classify nonoscillatory solutions of dynamic equations and systems on time scales but also guarantee the (non)existence of such solutions by using the Knaster fixed point theorem, Schauder - Tychonoff fixed point theorem, and Schauder fixed point theorem. The approach is based on the sign of nonoscillatory …

Contribution Of New Thiol Antioxidant In The Treatment Of Acetaminophen Toxicity, Ahdab Naeem Khayyat

Doctoral Dissertations

"Acetaminophen (N-acetyl-p-aminophenol, APAP) is one of the most widely used over-the-counter antipyretic analgesic medications. It is safe at therapeutic doses, but an overdose can result in severe hepato-nephrotoxicity, a leading cause of drug-induced acute liver failure in the U.S. Although a few different mechanisms have been proposed for APAP-induced toxicity, a significant amount of evidence has pointed to the potential involvement of oxidative stress in acetaminophen toxicity. Depletion of glutathione (GSH) is one of the initiating steps in APAP-induced toxicity; therefore, one strategy for restricting organ damage is to restore GSH levels by using GSH prodrugs like N-acetylcysteine (NAC). Although …

A Domain Independent Method To Assess System Of System Meta-Architectures Using Domain Specific Fuzzy Information, Louis Edward Pape Ii

Doctoral Dissertations

"This research proposes a domain independent method to build and assess systems of systems (SoS) architecture models. A simplified meta-architecture containing each component system's participation and a first order, binary, system-to-system interface is proposed. The method describes how to elicit desired SoS attributes from stakeholders. Measures of the attributes depend on systems' participation and interfaces, that is, on the SoS architecture. The goal is to model a realizable SoS configuration, optimized over multiple attributes. Key attribute measures are combined in a fuzzy inference system to assess an overall fitness measure for any SoS in the meta-architecture. A genetic algorithm is …

On The Spheroidal Graphite Growth And The Austenite Solidification In Ductile Irons, Jingjing Qing

Doctoral Dissertations

"Evolutions of austenite and nodular/spheroidal graphite particles during solidifications of ductile irons were experimentally investigated. Spheroidal graphite particle and austenite dendrite were found nucleated independently in liquid. Austenite dendrite engulfed the spheroidal graphite particles after contact and an austenite shell formed around a spheroidal graphite particle. The graphite diameter at which the austenite shell closed around nodule was determined. Statistically determined graphite size distributions indicated multiple graphite nucleation events during solidification.

Structures in a graphite nodule varied depending on the growth stages of the nodule in ductile iron. Curved graphene layers appearing as faceted growth ledges swept circumferentially around the …

Cable Shovel Dipper Stress And Fatigue Failure Modeling In Formation Excavation Engineering, Muhammad Azeem Raza

Doctoral Dissertations

"Large capacity shovels are used to achieve economic bulk production in surface mining operations. The suspended payload combined with dipper weight and formation resistive forces results in severe stress loading of the shovel front-end assembly. Material flaws, high stresses and harsh excavation conditions can initiate cracks in the dipper-teeth assembly. High stresses can cause these cracks to propagate to critical lengths resulting in fatigue failure, unscheduled downtimes, costly unplanned repairs, and downstream processing circuit problems. The literature reveals that dipper-related problems significantly reduce shovel up-time. This research is a pioneering effort towards developing a solid frame work for stress profiling, …

Boundary Control Of Parabolic Pde Using Adaptive Dynamic Programming, Behzad Talaei

Doctoral Dissertations

"In this dissertation, novel adaptive/approximate dynamic programming (ADP) based state and output feedback control methods are presented for distributed parameter systems (DPS) which are expressed as uncertain parabolic partial differential equations (PDEs) in one and two dimensional domains. In the first step, the output feedback control design using an early lumping method is introduced after model reduction. Subsequently controllers were developed in four stages; Unlike current approaches in the literature, state and output feedback approaches were designed without utilizing model reduction for uncertain linear, coupled nonlinear and two-dimensional parabolic PDEs, respectively. In all of these techniques, the infinite horizon cost …

Study Of Heat Transfer Phenomenon During Natural Convection, Muhammad Yousaf

Doctoral Dissertations

"The purpose of the present study was to numerically investigate the effects of the roughness elements on the heat transfer during natural convection. A computational algorithm was developed based on the Lattice Boltzmann method to conduct numerical study in two-dimensional rectangular cavities and Rayleigh-Bénard cell. A single relaxation time Bhatnagar-Gross-Krook model of Lattice Boltzmann method was used to solve the coupled momentum and energy equations in two-dimensional lattices. Computational model was validated against previous benchmark solutions, and a good agreement was found to exist. A Newtonian fluid of Prandtl (Pr) number 1.0 was considered for this numerical study. The range …

Hierarchical Control Of Complex Manufacturing Processes, Hesam Zomorodi Moghadam

Doctoral Dissertations

"The need for changing the control objective during the process has been reported in many systems in manufacturing, robotics, etc. However, not many works have been devoted to systematically investigating the proper strategies for these types of problems. In this dissertation, two approaches to such problems have been suggested for fast varying systems. The first approach, addresses problems where some of the objectives are statically related to the states of the systems. Hierarchical Optimal Control was proposed to simplify the nonlinearity caused by adding the statically related objectives into control problem. The proposed method was implemented for contour-position control of …

Geotechnical State-Of-The-Art In Guatemala -- Ground Stabilization, Fernando Rafael Callejas Benitez

Doctoral Dissertations

"History provides an understanding of the present and in a way, a guide for the future. The state-of-the-art is often referred to as a snapshot of the most significant works and contributions made in a field of study; In this case the focus is on Guatemalan geotechnical engineering. This study presents a comprehensive description of the different events that impulse geotechnical engineering in Guatemala.

As part of the description of the state-of-the-practice an investigation of the different human (engineers/contractors) and physical resources (laboratories/field equipment) and their capabilities are presented. An overview of the civil engineering programs is presented. Then, the …

Fully Differential Study Of Projectile Coherence Effects In Ionization Of Molecular Hydrogen And Atomic Helium, Thusitha Priyantha Arthanayaka

Doctoral Dissertations

"It has been well established, that projectile coherent properties are important for the study of atomic fragmentation processes. Recent studies of ionization of molecular hydrogen had demonstrated that measured double differential cross sections (DDCS) are very sensitive to the coherent length of the projectile. These measurements have been performed with varied coherence length of the projectiles by controlling the geometry of the collimating slits, which are placed before the target. Later, fully differential cross sections (FDCS) for a coherent and an incoherent projectile beam has been study for the same collision system and the results confirmed the important role of …