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An Extendable High Step-Up Dc-Dc Converter For Renewable Energy Applications, Saeed Habibi, Ramin Rahimi, Mehdi Ferdowsi, Pourya Shamsi Jan 2023

An Extendable High Step-Up Dc-Dc Converter For Renewable Energy Applications, Saeed Habibi, Ramin Rahimi, Mehdi Ferdowsi, Pourya Shamsi

Electrical and Computer Engineering Faculty Research & Creative Works

In this paper, a high step-up DC-DC converter based on a switched-inductor-capacitor-diode (SLCD) cell is proposed. the proposed converter provides a high voltage gain, low voltage stress on the power switches and diodes, and a low input current ripple. Moreover, the proposed converter is extendable, meaning that the voltage gain could be further increased by using a higher number of proposed cells in the topology. the steady-state analysis and comparison of the proposed converter to the other existing converters are presented. a 200 W, 40 V to 380 V experimental setup is developed to verify the steady-state analysis of the …


Detailed Analysis Of The Tev Γ-Ray Sources 3hwc J1928+178, 3hwc J1930+188, And The New Source Hawc J1932+192, A. Albert, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, D. Avila Rojas, H. A.Ayala Solares, R. Babu, E. Belmont-Moreno, C. Brisbois, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, O. Chaparro-Amaro, U. Cotti, J. Cotzomi, S. Coutiño De León, E. De La Fuente, C. De Leon, R. Diaz Hernandez, J. C. Diaz-Velez, B. L. Dingus, M. A. Duvernois, M. Durocher, K. Engel, C. Espinoza, K. L. Fan, M. Fernandez Alonso, N. Fraija, J. A. Garcia-Gonzalez, F. Garfias, H. Goksu, M. M. Gonzalez, J. A. Goodman, J. P. Harding, S. Hernandez, J. Hinton, B. Hona, D. Huang, F. Hueyotl-Zahuantitla, P. Huntemeyer, A. Iriarte, A. Jardin-Blicq, V. Joshi, S. Kaufmann, D. Kieda, W. H. Lee, H. Leon Vargas, J. T. Linnemann, A. L. Longinotti, G. Luis-Raya, R. Lopez-Coto, K. Malone, V. Marandon, O. Martinez, J. Martinez-Castro, J. A. Matthews, P. Miranda-Romagnoli, J. A. Moralez-Soto, E. Moreno, M. Mostafa, A. Nayerhoda, L. Nellen, M. Newbold, M. U. Nisa, R. Noriega-Papaqui, L. Olivera-Nieto, N. Omodei, A. Peisker, Y. Perez Araujo, E. G. Perez-Perez, C. D. Rho, D. Rosa-Gonzalez, E. Ruiz-Velasco, H. Salazar, D. Salazar-Gallegos, F. Salesa Greus, A. Sandoval, M. Schneider, J. Serna-Franco, A. J. Smith, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Torres-Escobedo, R. Turner, F. Urena-Mena, L. Villasenor, Xiaojie Wang, F. Werner, E. Willox, H. Zhou Jan 2023

Detailed Analysis Of The Tev Γ-Ray Sources 3hwc J1928+178, 3hwc J1930+188, And The New Source Hawc J1932+192, A. Albert, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, D. Avila Rojas, H. A.Ayala Solares, R. Babu, E. Belmont-Moreno, C. Brisbois, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, O. Chaparro-Amaro, U. Cotti, J. Cotzomi, S. Coutiño De León, E. De La Fuente, C. De Leon, R. Diaz Hernandez, J. C. Diaz-Velez, B. L. Dingus, M. A. Duvernois, M. Durocher, K. Engel, C. Espinoza, K. L. Fan, M. Fernandez Alonso, N. Fraija, J. A. Garcia-Gonzalez, F. Garfias, H. Goksu, M. M. Gonzalez, J. A. Goodman, J. P. Harding, S. Hernandez, J. Hinton, B. Hona, D. Huang, F. Hueyotl-Zahuantitla, P. Huntemeyer, A. Iriarte, A. Jardin-Blicq, V. Joshi, S. Kaufmann, D. Kieda, W. H. Lee, H. Leon Vargas, J. T. Linnemann, A. L. Longinotti, G. Luis-Raya, R. Lopez-Coto, K. Malone, V. Marandon, O. Martinez, J. Martinez-Castro, J. A. Matthews, P. Miranda-Romagnoli, J. A. Moralez-Soto, E. Moreno, M. Mostafa, A. Nayerhoda, L. Nellen, M. Newbold, M. U. Nisa, R. Noriega-Papaqui, L. Olivera-Nieto, N. Omodei, A. Peisker, Y. Perez Araujo, E. G. Perez-Perez, C. D. Rho, D. Rosa-Gonzalez, E. Ruiz-Velasco, H. Salazar, D. Salazar-Gallegos, F. Salesa Greus, A. Sandoval, M. Schneider, J. Serna-Franco, A. J. Smith, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Torres-Escobedo, R. Turner, F. Urena-Mena, L. Villasenor, Xiaojie Wang, F. Werner, E. Willox, H. Zhou

Physics Faculty Research & Creative Works

The latest High Altitude Water Cherenkov (HAWC) point-like source catalog up to 56 TeV reported the detection of two sources in the region of the Galactic plane at galactic longitude 52° < ℓ < 55°, 3HWC J1930+188 and 3HWC J1928+178. The first one is associated with a known TeV source, the supernova remnant SNR G054.1+00.3. It was discovered by one of the currently operating Imaging Atmospheric Cherenkov Telescope (IACT), the Very Energetic Radiation Imaging Telescope Array System (VERITAS), detected by the High Energy Stereoscopic System (H.E.S.S), and identified as a composite SNR. However, the source 3HWC J1928+178, discovered by HAWC and coincident with the pulsar PSR J1928+1746, was not detected by any IACT despite their long exposure on the region, until a recent new analysis of H.E.S.S. data was able to confirm it. Moreover, no X-ray counterpart has been detected from this pulsar. We present a multicomponent fit of this region using the latest HAWC data. This reveals an additional new source, HAWC J1932+192, which is potentially associated with the pulsar PSR J1932+1916, whose γ-ray emission could come from the acceleration of particles in its pulsar wind nebula. In the case of 3HWC J1928+178, several possible explanations are explored, in an attempt to unveil the origins of the very-high-energy γ-ray emission.


Prediction Of Single Proppant Terminal Settling Velocity In High Viscosity Friction Reducers By Using Artificial Neural Networks And Xgboost, Xiaojing Ge, Rong Lu, Ghith Biheri, Abdulmohsin Imqam, Baojun Bai Jan 2023

Prediction Of Single Proppant Terminal Settling Velocity In High Viscosity Friction Reducers By Using Artificial Neural Networks And Xgboost, Xiaojing Ge, Rong Lu, Ghith Biheri, Abdulmohsin Imqam, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

High viscosity friction reducers (HVFRs) have been recently gaining more attention and increasing in use, not only as friction-reducing agents but also as proppant carriers. The settling velocity of the proppant is one of the key outputs to describe their proppant transport capability. However, it is influenced by many factors such as fluid properties, proppant properties, and fracture properties. Many empirical/physics-based models and correlations to predict particle settling velocity have been developed. However, they are usually based on certain assumptions and have applicable limits. In contrast, machine learning models can be considered as a black box. The objective of this …


A Primal Treatise Of Constant-Force Compliant Segment And Mechanism Design With Applications, Vamsi Lodagala Jan 2023

A Primal Treatise Of Constant-Force Compliant Segment And Mechanism Design With Applications, Vamsi Lodagala

Doctoral Dissertations

"The evolution of compliant mechanisms propelled the development of constant-force mechanisms (CFMs) for various applications because of their unique characteristics. Many research endeavors have presented different techniques that often involve some optimization to design the CFMs. However, the mechanics of the generation of constant force at the elemental level is not well understood. This research effort theorizes and validates that simple, compliant segment with different boundary conditions, subjected to axial loading, produce near-constant force without the need for design optimization. Analytical models are developed based on the pseudo-rigid-body model (PRBM) concept to predict their force-displacement behavior, and to establish that …


Intragranular Tungsten-Titanium Carbide Composite Ceramics Via Gas-Solid Displacement Reactions, Ryan Daniel Dempsey Jan 2023

Intragranular Tungsten-Titanium Carbide Composite Ceramics Via Gas-Solid Displacement Reactions, Ryan Daniel Dempsey

Doctoral Dissertations

"Research presented herein details the synthesis and characterization of nanocomposite ceramics featuring novel heterogeneous microstructures of potential interest in a variety of electrical and structural applications. Specifically, W-TiCy composite ceramics featuring tungsten nanoprecipitates located primarily within TiCy grains have been produced via sintering of intragranular nanocomposite powders produced via reaction processing-based techniques. This dissertation details the thermodynamic basis and applied kinetics of a processing scheme for fabricating nanocomposite ceramics whose morphological heterogeneity reflects that originally developed in the powder state. The first study in this series overviews the motivation for applying metallothermic displacement reactions, conducted through gaseous intermediates, to solid …


Effects Of Downwash When Measuring Gas Concentration With Uav-Mounted Gas Sensors, Jacob Lane Brinkman Jan 2023

Effects Of Downwash When Measuring Gas Concentration With Uav-Mounted Gas Sensors, Jacob Lane Brinkman

Doctoral Dissertations

"This research concludes that the downwash region of a rotary-wing unmanned aerial vehicle (UAV) does not produce pressure variations substantial enough to cause significant changes in density-based gas concentration measurements. US regulations evaluate gas concentration as a function of gas density, and accurate concentration measurements are critical for protecting health and safety, which means evaluation of actual downwash effects on measured gas concentration is essential.

During experimentation, the UAV was fixed to a stand in a sealed chamber filled with NOx (NO and NO2) of constant concentration. The UAV rotors ran at hovering speeds, and gas concentrations were …


Electrodeposition Of Epitaxial Wide Bandgap P-Type Semiconductors And Copper Metal For Energy Conversion And Flexible Electronics, Bin Luo Jan 2023

Electrodeposition Of Epitaxial Wide Bandgap P-Type Semiconductors And Copper Metal For Energy Conversion And Flexible Electronics, Bin Luo

Doctoral Dissertations

"Epitaxial electrodeposition is a simple, low-cost technology to produce highly ordered materials on single-crystal surfaces. This research focuses on the epitaxial electrodeposition of wide bandgap p-type semiconductors and epitaxial Cu thin films via a self-assembled monolayer for energy conversion and flexible electronics. Paper I introduces the epitaxial electrodeposition of hole conducting CuSCN nanorods onto Au (111) surface, and lift-off to produce flexible and transparent foils. Highly ordered CuSCN could serve as an inorganic transport layer in various opto-electronic devices such as perovskite solar cells, LEDs, and transistors. An ordered and transparent CuSCN foil was also produced by epitaxial lift-off following …


Novel Quantum Materials For Spintronic And Opto-Electronic Applications, Ali Sarikhani Jan 2023

Novel Quantum Materials For Spintronic And Opto-Electronic Applications, Ali Sarikhani

Doctoral Dissertations

"Multi-functional quantum materials play a crucial role in the development of spintronics and opto-electronics, as their properties can greatly influence device performance. For instance, in spintronics, materials such as ferromagnetic half-metals, Giant Magnetoresistants (GMR), and magnetic semiconductors have been extensively studied due to their ability to manipulate the spin of electrons for applications in magnetic storage. In opto-electronics, materials such as Diluted Magnetic Semiconductors (DMS) and non-oxide Transparent Conductors (TC) offer advantages such as tunable bandgap and high absorption coefficients, which enable improved device performance.

For this purpose, we have experimentally investigated the compounds that have shown theoretically interesting physical …


Fiber Optic Sensors For Liquid Identifications, Wassana Naku Jan 2023

Fiber Optic Sensors For Liquid Identifications, Wassana Naku

Doctoral Dissertations

"The fiber optic Fabry-Perot interferometer (FPI) is a widely utilized sensing configuration, offering numerous advantages over conventional electronic sensors, including high accuracy, distributed sensing capabilities, immunity to electromagnetic interference, and compact size. In this study, we propose a remarkably simple fiber optic-tip sensor system combined with machine learning techniques for the identification of pure and volatile organic liquids (VOLs).

A liquid droplet forms an extrinsic FPI (EFPI), with its effective reflectance being a function of the droplet's length. As the droplet evaporates, its length decreases. We conducted immersion tests using optical fiber tip sensors and monitored the time-transient responses of …


Phosphate And Borophosphate Glasses For Optical And Biomedical Applications, Parker Tracy Freudenberger Jan 2023

Phosphate And Borophosphate Glasses For Optical And Biomedical Applications, Parker Tracy Freudenberger

Doctoral Dissertations

"The goal of this work was to connect the network structures of phosphate and borophosphate glasses to the compositional dependence of properties related to biomedical applications. The glasses were characterized by a variety of techniques, including phosphate ion chromatography, Raman spectroscopy, and 11B and 31P Magic Angle Spinning Nuclear Magnetic Resonance spectroscopy, which provide qualitative and quantitative information about the phosphate and borate moieties that constitute the network structures. The systematic addition of borate to a phosphate glass initially creates tetrahedral borate sites that replace P-O-P linkages with B-O-P linkages, and the properties of the resulting borophosphate glasses …


Application Of Modeling Methodologies To Improve An Emergency Departments Workflow, Prachita Humane Jan 2023

Application Of Modeling Methodologies To Improve An Emergency Departments Workflow, Prachita Humane

Doctoral Dissertations

"The healthcare system in the United States is complex and challenging to understand, and the emergency department (ED) serves as a bridge between outpatient and inpatient care. According to the Centers for Disease Control and Prevention, over 130 million people visited emergency rooms in the United States in 2018. The ED is composed of multiple subunits and components that make it difficult to comprehend fully. In this study, a combination of engineering analysis methods was used to identify and understand the issues in the ED.

The first contribution of this research involved collecting data through job shadowing of human entities …


Investigation Of Recrosslinkable Preformed Particle Gels For Natural Gas Conformance Control, Ali Abdulmohsen Al Brahim Jan 2023

Investigation Of Recrosslinkable Preformed Particle Gels For Natural Gas Conformance Control, Ali Abdulmohsen Al Brahim

Doctoral Dissertations

"Recross linkable Preformed Particle Gel (RPPG) is a novel type of preformed particle gel in which particles can bond together to form a strong bulk gel system after being placed in the target formation. In this research, I systematically evaluated the feasibility of using this product to improve gas flooding conformance for mature reservoirs with conduits or fractures. Two RPPG systems were used for the experiment: a CO2- resistant RPPG (CR-RPPG) synthesized using acrylamide (AM) and 2-acrylamide-2- methylpropane sulfonate acid (AMPS), designed for CO2 flooding; and an acrylamide-co-acrylic acid-based RPPG (LT-RPPG), designed for water flooding. Different experimental apparatuses …


Sustainable Development: A Data Analysis Investigation For A New Conceptual Model, Case Study Comparison And Validation Techniques, Tiffanie Marie Toles Jan 2023

Sustainable Development: A Data Analysis Investigation For A New Conceptual Model, Case Study Comparison And Validation Techniques, Tiffanie Marie Toles

Doctoral Dissertations

"The three pillars model for sustainability, often represented with three intersecting circles described as economic, environmental, and social factors with sustainability being at the center is a complex and philosophically open model [1]. As society promotes efforts to reduce carbon impacts, there becomes a need to critically review the models employed for understanding. This research presents a validated methodology, an updated conceptual configuration of sustainability for overall use, as well as a sustainable development performance measurement system. Using the 2020 Sustainable Development Goals Index Data, 232 indicators from 193 countries were used to evaluate the efficacy of using more than …


Identification, Mapping, Analysis, And Dating Of Composite Mega Landslides In The Colorado Plateau, Conor Maris Watkins Jan 2023

Identification, Mapping, Analysis, And Dating Of Composite Mega Landslides In The Colorado Plateau, Conor Maris Watkins

Doctoral Dissertations

"This research consists of three articles focusing on landslide complexes within the Grand Canyon region of the Colorado Plateau. This is a vast and remote region of rugged topography. The landslide complexes in this study are greater than 10 million cubic meters in volume. The slides are located within different areas of the region and consist of differing geology but share multiple commonalities. Stratigraphic and structural controls tend to dictate where the slides occur. All of the landslides occur where carbonates and/or sandstones overlie over consolidated shales. The shales are susceptible to creep and strain softening where lateral confinement has …


Unsteady Flow Behaviors Generated By Three-Dimensional Lattice Geometries As Measured By Laser Doppler Velocimetry, Yi Qiao Jan 2023

Unsteady Flow Behaviors Generated By Three-Dimensional Lattice Geometries As Measured By Laser Doppler Velocimetry, Yi Qiao

Doctoral Dissertations

"The relation between flow stream turbulence and heat transfer has been known for a long time, that the heat transfer rate is increased if the turbulence or fluctuation level of the flow increases. Open cell foams and compact heat exchangers are two of the most common models applied for heat transfer augmentation. However, the small ligaments of open cell foams limit the heat conducted and smooth passages in compact heat exchangers cannot cause flow unsteadiness. Accordingly, new geometric models are needed to improve the heat transfer enhancement. Three-dimensional (3D) lattice geometries with a range of features and sizes can be …


Efficient High Order Ensemble For Fluid Flow, John Carter Jan 2023

Efficient High Order Ensemble For Fluid Flow, John Carter

Doctoral Dissertations

"This thesis proposes efficient ensemble-based algorithms for solving the full and reduced Magnetohydrodynamics (MHD) equations. The proposed ensemble methods require solving only one linear system with multiple right-hand sides for different realizations, reducing computational cost and simulation time. Four algorithms utilize a Generalized Positive Auxiliary Variable (GPAV) approach and are demonstrated to be second-order accurate and unconditionally stable with respect to the system energy through comprehensive stability analyses and error tests. Two algorithms make use of Artificial Compressibility (AC) to update pressure and a solenoidal constraint for the magnetic field. Numerical simulations are provided to illustrate theoretical results and demonstrate …


Co2-Assisted Ethylene Production And Subsequent Purification: A Materials Development, Kinetic Assessment, And Process Performance Investigation, Khaled Baamran Jan 2023

Co2-Assisted Ethylene Production And Subsequent Purification: A Materials Development, Kinetic Assessment, And Process Performance Investigation, Khaled Baamran

Doctoral Dissertations

"This research focuses on the In-Situ CO2 capture and utilization in the oxidative dehydrogenation of ethane (ODHE) for ethylene production, and a subsequent ethylene purification through adsorptive separation process. In particular, several dual-function materials (DFMs) were developed, formulated into 3D-structure, and investigated for ODHE reaction to ethylene under various process conditions using CO2 as a mild oxidant. The DFMs materials were consisted of CaO and metal oxides (e.g., Cr2O3 and V2O5) supporting H-ZSM-5. The results indicated that higher cell densities lead to better performance due to kinetic enhancement, and the optimum …


Advances In Differentially Methylated Region Detection And Cure Survival Models, Daniel Ahmed Alhassan Jan 2023

Advances In Differentially Methylated Region Detection And Cure Survival Models, Daniel Ahmed Alhassan

Doctoral Dissertations

"This dissertation focuses on two areas of statistics: DNA methylation and survival analysis. The first part of the dissertation pertains to the detection of differentially methylated regions in the human genome. The varying distribution of gaps between succeeding genomic locations, which are represented on the microarray used to quantify methylation, makes it challenging to identify regions that have differential methylation. This emphasizes the need to properly account for the correlation in methylation shared by nearby locations within a specific genomic distance. In this work, a normalized kernel-weighted statistic is proposed to obtain an optimal amount of "information" from neighboring locations …


Data Analytics Of Wettability Alteration With Surfactants In Carbonate Reservoirs, Ya Yao Jan 2023

Data Analytics Of Wettability Alteration With Surfactants In Carbonate Reservoirs, Ya Yao

Doctoral Dissertations

"Wettability alteration with surfactants has been widely applied to improve oil recovery in carbonate reservoirs. An effective surfactant huff-puff application design requires comprehensive guidelines about where, how, and when this method could be applied. Besides, traditional methods to design an effective application and optimize surfactant performance are dependent on extensive experiments and are time-consuming. This study is to assist in the design of surfactant huff-puff via statistical methods and machine learning techniques.

In this study, a dataset including 402 effective surfactant imbibition tests is established by collecting information from nearly 50 publications. The dataset provides a foundation for further data …


Essays On Conditional Heteroscedastic Time Series Models With Asymmetry, Long Memory, And Structural Changes, K C M R Anjana Bandara Yatawara Jan 2023

Essays On Conditional Heteroscedastic Time Series Models With Asymmetry, Long Memory, And Structural Changes, K C M R Anjana Bandara Yatawara

Doctoral Dissertations

"The volatility of asset returns is usually time-varying, necessitating the introduction of models with a conditional heteroskedastic variance structure. In this dissertation, several existing formulations, motivated by the Generalized Autoregressive Conditional Heteroskedastic (GARCH) type models, are further generalized to accommodate more dynamic features of asset returns such as asymmetry, long memory, and structural breaks. First, we introduce a hybrid structure that combines short-memory asymmetric Glosten, Jagannathan, and Runkle (GJR) formulation and the long-memory fractionally integrated GARCH (FIGARCH) process for modeling financial volatility. This formulation not only can model volatility clusters and capture asymmetry but also considers the characteristic of long …


Design, Modeling And Analysis Of An Ac-Ac Dual Active Bridge Converter, Kartikeya Jayadurga Prasad Veeramraju Jan 2023

Design, Modeling And Analysis Of An Ac-Ac Dual Active Bridge Converter, Kartikeya Jayadurga Prasad Veeramraju

Doctoral Dissertations

"The Solid-State Transformer (SST) is gaining attention as an alternative to conventional iron-core transformers in the power electronic community. The power industry's increasing demands for smaller size, higher efficiency, and greater energy density have made the SST an attractive option. Among various power electronic converter topologies, the Dual Active Bridge (DAB) has become popular for its bidirectional power flow capability and galvanic isolation, primarily in the DC application space. Advancements in semiconductor technologies have introduced new bidirectional switches, opening avenues for novel SST topologies. This research investigates the application of the DAB as a single-stage SST and focuses on advancements …


Near-Ir Spectroscopic Analysis Of The Primary Volatile Composition Of Long And Short-Period Comets, Younas Khan Jan 2023

Near-Ir Spectroscopic Analysis Of The Primary Volatile Composition Of Long And Short-Period Comets, Younas Khan

Doctoral Dissertations

"Comets are among the most well-preserved objects that formed in the protosolar nebula ∼4.5 Gyr ago. Hence, they are important for understanding various aspects of the formation, evolution, and habitability of the solar system. Multiple primary volatiles (molecules directly sublimating into the coma from the nucleus) emit via rovibrational transitions in the near-IR, providing opportunities to calculate their abundances. To date, only ∼50 comets have been characterized for their primary volatiles, with the short-period Jupiter-family comets (JFCs) being significantly underrepresented. In contrast, hundreds of comets have been sampled at optical/UV wavelengths, primarily for the composition of daughter species, leading to …


Introduction Of A Variable Inductance Transformer For The Design Of Resonant Power Converters, Angshuman Sharma Jan 2023

Introduction Of A Variable Inductance Transformer For The Design Of Resonant Power Converters, Angshuman Sharma

Doctoral Dissertations

"Magnetic integration is a hot topic in power electronics that concerns the use of a transformer's leakage and magnetizing inductances purposefully in isolated power electronic converters, thereby giving the opportunity to save the cost and footprint of any additional inductor. This is of prime interest, especially in CLLLC resonant converters which require up to three inductors. For a complete integration of these inductances, the concept of a variable inductance transformer (VIT) is introduced in this thesis. A VIT is an adaptive magnetic structure that facilitates an easy adjustment of both magnetizing and leakage inductances to meet their desired values. However, …


Fluorination Of Rubisco-Mimetic Co2 Capture Systems. Theoretical And Experimental Studies Of Ammonium Ion Acidity Depression And Carbamylation, Brian Michael Jameson Jan 2023

Fluorination Of Rubisco-Mimetic Co2 Capture Systems. Theoretical And Experimental Studies Of Ammonium Ion Acidity Depression And Carbamylation, Brian Michael Jameson

Doctoral Dissertations

"RuBisCO-inspired CO2 capture and release (CCR) systems featuring amines have been developed for the purpose of reversable CO2 capture from air. The enzyme active site consists of the tetrapeptide sequence Lys-Asp-Asp-Glu. The Lys sidechain amine undergoes carbamylation and an Mg2+ cation stabilizes the resulting carbamate. The Na-acyl-lysinyl-aspratyl-aspartyl-glutamide (Lys-Asp-Asp-Glu, KDDE) peptide featured maximum capture at pH ≈ 10; a pH region too high for Mg2+ ions to remain in solution. This work aims to achieve pKa depression by introducing fluorine in the proximity of the lysine’s sidechain amine. A comparative analysis was made of butylamine, …


Applied Geochemistry, Geochronology And Biostratigraphy: Case Studies From The 38th Parallel Structures In Missouri And Orange Basin, Offshore Western South Africa, Marissa Kay Spencer Jan 2023

Applied Geochemistry, Geochronology And Biostratigraphy: Case Studies From The 38th Parallel Structures In Missouri And Orange Basin, Offshore Western South Africa, Marissa Kay Spencer

Doctoral Dissertations

"The unique alignment of the Decaturville, Crooked Creek, and Weaubleau geological structures in central Missouri, three of nine known such structures along the 38th parallel in Illinois, Missouri, and Kansas, has puzzled geoscientists for decades. Research using palynology (palynomorphs and particulate organic matter) and radiometric dating of impact spherules were used to constrain age and a relationship between these enigmatic structures and infer their paleoenvironmental conditions. Novel melting damages, unique to impact, were documented in the palynomorphs in all the three structures. Early Ordovician acritarchs with melted processes correlate with 40Ar-39Ar stepwise heating age of impact spherules …


Boosting Snr Of Cascaded Fbgs In A Sapphire Fiber Through A Rapid Heat Treatment, Farhan Mumtaz, Hanok Tekle, Bohong Zhang, Jeffrey D. Smith, Ronald J. O'Malley, Rex Gerald, Jie Huang Jan 2023

Boosting Snr Of Cascaded Fbgs In A Sapphire Fiber Through A Rapid Heat Treatment, Farhan Mumtaz, Hanok Tekle, Bohong Zhang, Jeffrey D. Smith, Ronald J. O'Malley, Rex Gerald, Jie Huang

PSMRC Faculty Research

This Letter reports the performance of femtosecond (fs) laser-written distributed fiber Bragg gratings (FBGs) under high-temperature conditions up to 1600°C and explores the impact of rapid heat treatment on signal-to-noise ratio (SNR) enhancement. FBGs are essential for reliable optical sensing in extreme temperature environments. Comprehensive tests demonstrate the remarkable performance and resilience of FBGs at temperatures up to 1600°C, confirming their suitability for deployment in such conditions. The study also reveals significant fringe visibility improvements of up to ∼10 dB on a 1-m-long sapphire optical fiber through rapid heat treatment, representing a first-time achievement to the best of our knowledge. …


Geometry-Aware Methodology For Coupling Mechanism Analysis And Radiation Mechanism Analysis, Xu Wang Jan 2023

Geometry-Aware Methodology For Coupling Mechanism Analysis And Radiation Mechanism Analysis, Xu Wang

Doctoral Dissertations

"Due to the wide-band spectrum of digital signals, a variety of noise generators, including microprocessors, liquid crystal displays, digital microphones, high-speed traces, and double-data-rate memory modules, are found in consumer electronics products. Noise generated by digital circuits can couple to the antennas and degrade their sensitivity. Additionally, it also couples to metallic housings or heatsinks and produces a significant amount of emission. In this research, methodologies are presented to analyze the coupling and radiation mechanism in electronic devices.

To investigate the coupling between the distributive geometries in the radio frequency interference (RFI) problem, a mesh-dependent partition-based coupling mechanism analysis method …


Characterization And Improvement Of Powder Properties Through Plasma Spheroidization For Use In The Laser Powder Bed Fusion Process, M. Hossein Sehhat Jan 2023

Characterization And Improvement Of Powder Properties Through Plasma Spheroidization For Use In The Laser Powder Bed Fusion Process, M. Hossein Sehhat

Doctoral Dissertations

"This research was conducted to characterize the powder properties using different characterization techniques to enhance the powder behavior in the Laser Powder Bed Fusion (LPBF) process. One of the shortcomings of LPBF process is the high cost of gas-atomized powder feedstock. To overcome this downside, the cheaper water-atomized powder was characterized and used in LPBF process, and its performance was compared with those of gas-atomized powder. Also, the plasma spheroidization process was used to improve the powder characteristics; if the spheroidized powder could function as well as the virgin powder, plasma spheroidization process could be applied to the used powders …


2022 Scholarly Productivity Report, Missouri University Of Science And Technology Dec 2022

2022 Scholarly Productivity Report, Missouri University Of Science And Technology

Civil, Architectural and Environmental Engineering Scholarly Productivity Reports

No abstract provided.


Recent Trends In Mineral Processing Based On Density And Particle Size–A Review, Ahmed Sobhy Dec 2022

Recent Trends In Mineral Processing Based On Density And Particle Size–A Review, Ahmed Sobhy

Mining Engineering Faculty Research & Creative Works

Most mineral beneficiation development in the world focus on size and density-based separation technologies. In recent years, ore size-based and density-based separation technologies have attracted more consideration to obtaining rough or final high-quality products. Due to the dissimilarity of physical properties like particle size and density, valuable and gangue minerals can be segregated via size-based and density-based separation technologies. Removing the impurities and recovering the target minerals are accomplished by size-based separation technologies alone or are usually followed by cleaning processes utilizing density-based separation abilities. The density variation among valuable and gangue minerals leads to dissimilarities in settling velocity in …