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A Study Of The Supercooling Behavior Of High Purity Liquid Bismuth, B. L. Bramfitt

Doctoral Dissertations

"This investigation involves a study of the supercooling behavior of pure bismuth as affected by the melting atmosphere, the amount of superheat, and the intentional addition of metallic and non-metallic foreign materials to the melt. It was found that the amount of oxide on the melt surface is a controlling factor in the degree of supercooling obtainable in bismuth. In the presence of a thick bismuth oxide surface layer the amount of superheat below a 15°C drastically decreases the amount of supercooling due to the retention of nuclei in the surface film that promote nucleation upon cooling of the melt. …

A Theoretical Approach To The Problem Of Determining Ejecta Volumes In A Gravitational Vacuumed Half-Space, William J. Karwoski

Doctoral Dissertations

"The formation of an explosion crater is a highly complex process. All of the pertinent parameters governing the mechanisms of cratering are not clearly understood or known. Many cratering experiments were performed in desert alluvium in an effort to relate crater dimensions with charge weight and depth of burst. Various scaling laws were devised in an attempt to correlate the data gathered from these experiments. When cube-root scaling was used to correlate results of tests conducted at a constant scaled depth of burst, larger charge weights consistently gave smaller scaled results. This was particularly true of apparent crater volume. When …

Aeration Studies In Submerged Fermentations Using A Steam-Sterilizable Dissolved Oxygen Sensor Of Improved Design, Carl J. Wallace

Doctoral Dissertations

"Large-scale submerged fermentations have been important for many years for the production of antibiotics, vitamins, enzymes, etc.; however, aeration studies have been severely restricted in these processes because of the unavailability of adequate oxygen sensing equipment.

A steam-sterilizable oxygen sensor of improved design was developed out of an investigation of several potential sensors. This rapidly responding galvanic probe made use of a lead anode, a silver cathode, an acetate buffer as the electrolyte, and a one mil Teflon® membrane as the diffusion barrier. Its sensitivity was approximately 40 µamps and full response required approximately 5 minutes.

Use was made of …

Numerical Solution Of Water Hammer Analysis Including Friction Losses, Lih Hsun Weng

Masters Theses

"The water hammer phenomena is a very important problem in pipe lines and gate operations. There are many analytical solutions tor water hammer problems including friction losses, but most of them use a linear approximation tor the friction effect that is different from the actual situation. Also the existing methods for solving water hammer problems involve difficult mathematical operations that are impractical and inaccurate.

In order to find a more rapid method for solving water hammer problems including friction losses and to obtain closer agreement with the actual condition, the problem is solved here using the basic partial differential equations …

Study Of Mass Transfer Through Porous, Water-Repellent Membranes, Virendra V. Tanna

Masters Theses

"A new method of desalination using a porous, water-repellent membrane was studied. The membrane utilized surface forces to support a vapor phase in its pores which separated the salt water from fresh water. The method used a vapor pressure difference across the membrane as the driving force for mass transfer of water from the salt water phase to the fresh water. This vapor pressure difference was obtained by maintaining a temperature difference between the two liquid phases.

The experimental data and results indicated the feasibility of vaporization through porous, water-repellent membranes. The flux of water through a membrane made of …

A Study Of The Development Of A Heuristic Program That Solves Symbolic Laplace Transformation Problems, Arthur E. Zackrison

Masters Theses

"A medium-speed general purpose digital computer (IBM 1620 Model II) was programmed to solve symbolic Laplace transformation problems. Although the applied mathematician and modern engineer has many uses for the symbolic solution of a problem, the potential of symbolic manipulation by a computer has not yet been sufficiently developed to help them because of many problems. This paper discusses the program and based on the author’s experience with it’s [sic] performance, clarifies the position of several of these difficulties and reaches some conclusions concerning computer solution of such problems"--Abstract, page ii.

Measurement Of The Velocity And Temperature Profiles Of Air Swirling Through A Conical Shaped Nozzle, Stephen Abner Thompson

Masters Theses

"A study was conducted to determine the velocity and temperature distributions in swirling flow of air through a converging nozzle. Radial traverses were taken at three axial positions with a specially designed pitot tube constructed of hypodermic needles. The most significant finding was the large magnitude of the radial velocity component. A combination of reversed axial flow along the nozzle axis, and an outward flow near the nozzle surface was also experienced. An increase of temperature with increasing radial position may be attributed to the Ranque-Hilsch effect"--Abstract, page ii.

Calibration Of An Instrument To Calibrate Accelerometers, Nader Khorzad

Masters Theses

"The purpose of this research was to calibrate an instrument with which an accelerometer could be calibrated accurately. The instruments used were a piezoelectric shaker and a modified Michelson interferometer together with necessary electronic equipment. This equipment was used to calibrate a Kistler Model 808A accelerometer.

Weight was added to the shaker in the second part of this experiment in order to determine its effect on the amplitude and frequency of oscillation of the shaker.

Results show that this instrument may be used to calibrate an accelerometer quite accurately. The weight added to the shaker will effect only the amplitude …

Empirical Evaluation Of The Eccentric Orifice In Small Diameter Pipes, Gary A. Hinz

Masters Theses

"This investigation has taken different orifice sizes (0.3005", 0.4000", 0.5045", 0.6015") and tested their flow characteristics when used in a 1" diameter pipe. Each orifice was initially placed in a fully eccentric position, that is the circumference of the orifice was placed tangent to the inside circumference of the pipe. Data was taken with the orifice eccentric to concentric in increments of 0.050".

Plots of flow coefficient versus Reynold's number were made for each position of the four orifices tested.

Empirical equations were developed for determining the flow coefficient of the various orifice sizes placed in any eccentric position.

It …

Effect Of Artificial Roughness On Convection, Lee W. Burford

Masters Theses

"Considerable work has been done in recent years, and is still being done, to find ways of increasing the heat transfer rate in fluid heat exchangers. One particular type of potential heat exchanger that has been studied analytically, as well as experimentally, is the use of artificially roughened tubing.

The test sections used in this experiment consisted of four aluminum pipes, three of which have been artificially roughened internally by machining ninety- degree V-shape grooves along the axis of the pipes. The grooves were 30/1000, 60/1000, and 90/1000 inches in depth. The remaining pipe was a smooth test section with …

Comparison Of Plastic Stress-Strain Material Properties As Determined From Conventional Experiments, Wen Mo Chen

Masters Theses

"In problems of engineering design, it is usually assumed that the stress-strain diagrams of a given material, as obtained from different loading conditions, are the same. In fact, by using the classical theory of plasticity, it can be shown that, with an appropriate selection of stress and strain related parameters, the diagrams should coincide.

Three different materials - magnesium, aluminum and steel, have been tested under tension, compression, torsion and bending loads. Stress-strain diagrams were constructed from these observations. This thesis presents an analysis of the relative agreement between the theoretical and experimental results of these materials"--Abstract, page i.

Catalytic Effects On Radiation-Induced Polymerization Of Methyl Methacryalate, David E. Bartine

Masters Theses

"A study has been made of the effect of Kaolin clay particle size and acidity on the degree of radiation-induced polymerization of methyl methacrylate. The results indicate that the degree of polymerization varies with the clay particle size, and that the amount of polymer produced is influenced by the pH of the clay"--Abstract, page ii.

The Performance Of A Countercurrent Extraction Column With Vibrated Packing, Mehmet Uran ÖZsoy

Masters Theses

"The performance of a continuous countercurrent extraction column with a packing -- that could be vibrated vertically at various amplitudes and frequencies by a variable speed motor -- was investigated under both non-flooding and flooding conditions using the high interfacial tension benzene-acetic acid-water ternary system. In all the experimental runs, which were sequenced randomly with a full-factorial experiment design, mass transfer of the solute (acetic acid) from the aqueous to the organic phase was studied. Column performance was evaluated in terms of the height of an overall transfer unit, HTU, based on the benzene phase. The variables studied were: amplitude …

The Anodic Oxidation Of Crotonic Acid In Basic Solutions, Richard C. Porter

Masters Theses

"The purpose of this study was to investigate the anodic oxidation of crotonic acid in basic solutions. Potassium hydroxide solutions of pH 12.3 and KOH-K₂CO₃ solutions of pH 11.5 and 10.5 were used. The investigation was carried out on platinized-platinum anodes at 80°C.

Experimental studies were conducted to determine the effects of crotonic acid concentration, pH, and temperature on the current. Faradaic efficiency was determined by analysis of CO₂ produced and was approximately 100 per cent.

The results were interpreted in terms of a mechanism having the following characteristics:

1. The first electron transfer is the rate …

An Investigation Of The Limitations Of The Antenna Range At The University Of Missouri At Rolla, Ronald Earl Nelson

Masters Theses

"The University of Missouri Antenna Range is described and criteria on range components for acceptable operation are discussed. Discussion of the results of an experimental investigation of component systems of the antenna range is presented. Experimental results are compared to criteria for acceptable operation and recommendations for the improvement of the facility is made. Suggestions are made as to its usage at higher frequencies"--Abstract, page ii.

Geochemical And Petrological Study Of The Precambrian Iron Metallogenic Province Of Southeast Missouri, Geza Kisvarsanyi

Doctoral Dissertations

"The general purpose of this dissertation was to investigate and establish petrological and geochemical relationships, if any, between the Precambrian iron deposits and associated host rocks. A more specific objective was to determine the distribution of some significant minor elements in the rocks and mineral deposits and to include specific mineralogical and petrological studies of the iron deposits and country rocks important to a better understanding of the genetic and geochemical relationships ... A primary task in the investigation was the study of the trace element population of individual iron deposits and establishment of differences, if they exist, between the …

The Thermodynamics Of The Zno-Fe₂O₃-Fe₃O₄ System, Dennis George Dreyer

Masters Theses

"A study was made of the ZnO-Fe₂O₃-Fe₃O₄ system at 1200ºC using oxygen pressures between 0.1 and 1x10⁻⁴ atmospheres. The results of this study were used to calculate the activities of ZnO, Fe₂O₄, and Fe₃O₄ in the spinel solid solution region of this ternary system. The activities of ZnFe₂O₄ and Fe₃O₄ across the pseudo-binary system were then calculated. The activities of the components in both the ternar and pseudo-binary systems exhibited large positive deviations from Raoult's Law, being more pronounced at the higher Fe₃O₄ content. The free energy, enthalpy, and entropy of mixing of the pseudo-binary system ZnFe₂O₄-Fe₃O₄ at 1200ºC were …

Theory Of The Lunar Photoelectron Atmosphere, Hal Emerson Mccloud Jr.

Doctoral Dissertations

"By considering the mechanics of an electron projected into an arbitrary potential field together with Poisson's equation it is possible to set up a differential equation for the electrostatic potential. The equation may be integrated and the photoelectron density found as a function of height for four approximate models. A simple model based upon monoenergetic photons and monoenergetic electrons ejected vertically upward yields rough estimates of the parameters of interest. Another model takes into account the fact that the photoelectrons are ejected at all angles. A general model takes into account the illumination of the lunar surface by solar (black …

Continuously Tapered Dielectric Matching Transitions For Waveguides, William E. Hord

Doctoral Dissertations

"Dielectric matching transitions at microwave frequencies are used for matching air filled waveguides into dielectric filled waveguides for maser work or into dielectric rod antennas. Also dielectric loading has been shown to improve the performance of the ferrite isolators.

The dielectric matching transitions that have been analyzed in the literature are of the stepped type. The continuously tapered dielectric matching transitions investigated in this dissertation provide increased bandwidth with very little increase of physical complexity.

The dissertation provides an analytical method for analysis and design for the continuously tapered dielectric matching transition. First-order and second-order approximate solutions for both symmetrical …

Some Geological And Magnetic Characteristics Of Buried And Resurrected Precambrian Hills Of Southeastern Missouri, James Edward Palmer

Doctoral Dissertations

"PURPOSE AND SCOPE OF INVESTIGATION The major purpose of this investigation was to determine by a comprehensive study various geological and magnetic characteristics of buried and resurrected Precambrian hills of the Central Ozarks. A second important objective was the determination of characteristics which might aid in the location of buried Precambrian hills. A final objective was the testing of the magnetic surface integration method for identification and determination of depth of buried Precambrian hills.

This investigation is limited to buried and resurrected Precambrian hills of the Central Ozarks. It is concerned primarily with the structure and stratigraphy of sediments adjacent …

The Anodic Behavior Of Zinc In Aqueous Salt Solutions, Yun-Chung Sun

Doctoral Dissertations

"The increasing demand for protective metals as coatings and non-corrosive alloys has caused extensive research on the fundamental behavior of metals in corrosive media. The problem of controlling the destructive process of metallic corrosion still exists and becomes urgent in this space age. The desirablity of metals such as beryllium, magnesium, and zinc in air frame and space structural units, because of their high strength to weight ratio, has been responsible for the considerable progress in their technology in recent years.

The basic mechanism of the anodic dissolution of metals such as zinc, cadmium, and magnesium in salt solution is …

The Anodic Dissolution Of Cadmium In Aqueous Solutions, San-Cheng Lai

Doctoral Dissertations

"The purpose of this investigation was to study the effect of cadmium ions on the anodic dissolution of cadmium in salt solutions of ·constant ionic strength. The concentration of the cadmium ions was varied from 0.001 to 1 N and the current density ranged from 0.001 to 0.1 amp•cm^-2. The temperature was controlled at 25°C.

....A mathematical model was postulated expressing the anodic dissolution rate as the sum of electrochemical, local corrosion, and disintegration rates."--Abstract, page iii.

An Investigation Of The Induction Heating Characteristics Of Powdered Susceptors Dispersed In A Non-Conducting Medium, Robert Leon Wright

Doctoral Dissertations

"This investigation determined some of the induction heating characteristics of powdered magnetite, iron and ferrosilicon susceptor dispersed in silica sand which had been coated with thermosetting resin. The powdered susceptor particles in the mixture were heated by the field of an induction coil, consequently heating the resin coated sand and bonding the sand grains together.

It was found that the type, relative amount,and particle size of the susceptor were important variables to be considered in the induction heating characteristics. Hysteresis losses in the susceptor particles, which are a function of the coil current, frequency, and permeability, appear to be the …

Cenozoic And Recent Lunulitiform Bryozoans Of The Gulf And Atlantic Coasts, Ronald Greeley

Doctoral Dissertations

"Free, cup-shaped colonies of cheilostomatous bryozoans, equipped with vibracula, are termed lunulitiform bryozoans. This group is found in sandy and calcareous Cenozoic deposits of the Gulf and Atlantic Coastal Plains. Cupuliform bryozoans are taxonomically distinct from, but in many ways similar to, lunulitiform bryozoans; the two groups are frequently found together.

Known lunulitiform genera of the Gulf and Atlantic Coastal Plains are diagnosed and their species described: Lunulites Lamarck, fifteen species, one new; Oligotresium Gabb and Horn, six species, two new; Discoporella d'Orbigny, two species; Cupuladria Canu and Bassler, two species; Selenaria Busk, one species; Otionella Canu and Bassler, four …

Hydrogen Absorption And Corrosion Studies Of Zone-Refined Iron, Chang Don Kim

Doctoral Dissertations

"The lattice constants of zone-refined iron filings and iron whiskers are 2.86623 and 2.86626 Å at 25°C respectively. Their thermal expansion coefficients are both the same, 12.1 x 10⁻⁶ /°C at temperatures 10 - 65°C.

The influence of hydrogen on the lattice constant of iron was investigated and it was found that hydrogen has no effect (within the limits of errors) on the lattice constant of iron at room temperature regardless of the charging methods. However, at elevated temperatures hydrogen expands the iron lattice due to increased solubility of the gas. The lattice constant of iron in vacuum and in …

Diffusional Drop Growth In A Supersaturated Atmosphere, John C. Carstens

Doctoral Dissertations

"The effect which a growing droplet has on the supersaturated atmosphere surrounding it is analyzed by assuming a macroscopic diffusional growth mechanism involving both heat and vapor. The problem is solved, for cloud-chamber conditions, first for very short times assuming a fixed radius, and then for longer times assuming the establishment of "quasi" steady-state conditions. Knowledge of the way in which droplet growth affects supersaturation is important in the evaluation of nucleation rates"--Abstract, page ii.

A Study Of The Anodic Oxidation Of Acetylene On Gold Electrodes, Jo Lisle Reed

Doctoral Dissertations

"The object of this investigation was to establish a mechanism for the anodic oxidation of acetylene on gold electrodes in aqueous solutions. It is known that anodic oxidation of organic compounds on gold electrodes produces a large number of organic intermediates and end products. Therefore, it appeared worthwhile to establish a mechanism that could provide a better understanding of the fuel cell electrode kinetics and possibly lead to new methods of organic syntheses"--Introduction, page 2.

Turbulence Measurements In Polymer Solutions Using Hot-Film Anemometry, Gary Kent Patterson

Doctoral Dissertations

"Hot-film anemometry was used to study the detailed structure of turbulence (intensities, energy spectra, and auto-correlations) in Newtonian solvents, non-drag reducing polymer solutions, and drag reducing polymer solutions. This was done in two smooth wall tubes with diameters of 1.0 inch and 2.0 inches. A probe traversing mechanism was used for measurements at radial positions from the center to as near the wall as possible for both the film probes (r/a=0.85 in the 2-inch tube) and the impact tubes (r/ a=0.98). The impact tubes were used to measure velocities for film probe calibration.

The solvents used in this investigation were …

The Statistical Mechanics Of Kink Interactions, Michael Brewer Mcneil

Doctoral Dissertations

"Using a potential derived from continuum elasticity, the interactions between kinks on a dislocation line are studied as special cases of the problem of a one-dimensional system of interacting particles. By the use of constant pressure ensembles, the principal kink-interaction problems of physical interest are solved. The application of these solutions to the theoretical analyses of work hardening and internal friction is explored and comparisons made to previous work in which kink interactions were neglected; it is found that, as would be expected, variations of equilibrium kink populations with external stress cannot account for the Bordoni peak, which must therefore …

Re-Evaporation Nuclei And Evaporation In A Wilson Cloud Chamber, James G. Smith

Doctoral Dissertations

"Experimental techniques are developed for observing droplet evaporation in the submicroscopic size range. An expansion-compression cloud chamber with an atmosphere of tank helium saturated with water vapor is employed. This work was undertaken with the aim of examining submicroscopic droplet behavior and the existence of re-evaporation nuclei, a form of memory effect.

The theories of evaporation and nucleation on submicroscopic drop residues were re-examined, and alterations which appear to be consistent with the results of this work were incorporated into the evaporation theory.

The observed continually decreasing evaporation rate with diminishing droplet size confirms the existence of re-evaporation nuclei, but …