Digital Commons Network^™

Anodic Dissolution Of Lead In Aqueous Solutions, Christopher Kuo-Chieh Wu

Masters Theses

"The apparent valence of lead was determined in one normal solutions of potassium nitrate, ammonium acetate, lead nitrate, and lead acetate at temperatures of 25 and 50°C. The current density was varied from 0.001 to 1.00 amp•cm ^-2. The apparent valence of lead ranged between 1.90 and 2.00 in all solutions. The lower valences were reached at higher current densities. The amount of disintegration was very small, and was dependent upon film formation on the surface of the anode.

Potential-current density relationships for the anodic dissolution of lead were obtained in the electrolytes mentioned above. In potassium nitrate and …

A Numerical Method For The Solution Of Cylindrical Shell Structures, Chen-Jow Hsiao

Masters Theses

"Many studies and analyses of shell structures to date have been either so complex and laborious as to preclude their application in practical design problems or so approximate, because of basic assumptions, as to limit their scope of application. Hence, a method of shell analysis which is convenient to use, reasonable in its results and general in its application is really needed. It is the purpose of this study to supply such a method of analysis.

In this investigation it is proposed to replace the shell structure which has an infinite number of degrees of indeterminancy with an analogous framework …

A Numerical Solution For Beam-Columns On Non-Linear Foundations, Wendelin H. Mueller Iii

Masters Theses

"A program for Matlock's recursive method, a numerical method which will analyze beams and columns with linearly varying spring supports, was modified to enable the solution of such members supported by non-linear springs. This modification was accomplished by an iterative technique. The final result of this paper is a computer program which can be used to solve beams or columns with non-linear spring supports, giving as output the deflection, slope, moment, shear, net load and curvature of the structure at uniformly spaced locations"--Abstract, page ii.

Approximate Solution Of The Momentum And Energy Equations For Partially Ionized Argon, Sir-Hoi Chen

Masters Theses

"Based on available experimental data, the transport properties of partially ionized argon gas have been determined by solving the integral equations of momentum and energy conservation by an approximate method. The momentum and the energy conservation integral equations are solved simultaneously by an iteration method by assuming both parabolic and cubic velocity and temperature profiles separately. The results are compared with the case of linear velocity and temperature profiles"--Abstract, page iii.

The Kinetics Of The Reaction Of M-Nitrobenzyl Bromide With Hydroxide Ion In Aqueous-Aprotic Solvent Mixtures, Ramesh Nagindas Sheth

Masters Theses

"The reaction between m-nitrobenzyl bromide and sodium hydroxide in homogeneous aqueous dioxane and aqueous tetrahydrofuran media was studied.

The product of the reaction was identified by infrared, gas chromatography and chemical tests as m-nitrobenzyl alcohol.
The kinetics of the reaction are second order with practically no variation in the rate constants as the % of the organic solvent was changed in the medium. This seems to imply hydrolysis of the organic halide by a process involving both bond-breaking and bond-formation in the transition state.
The activation energy, measured in 50% aqueous dioxane, between 20⁰ and 69.5⁰C at 5 different temperatures, …

Checking Rigid-Framed Structures By Extended Moment-Area Equations, Lucky Li-Chi Chow

Masters Theses

"Using the known moments obtained from the moment distribution solution, the extended moment-area equations are used to check whether or not delta x, delta y, delta theta are truly zero, or are any other quantity they are supposed to be. In order to get a reasonably correct answer, a solution must meet both the elastic checks and the static checks for their equilibrium and compatibility functions. Using the extended moment-area equations, the magnitudes of the slopes and deflections at all of the joints in framed structures can be found easily"--Abstract, page ii.

Bending Of Isosceles Right Triangular Plates, Ping-Tung Huang

Masters Theses

"In this thesis the series expansion method is used to obtain the moments and deflections of an isosceles right triangular plate bent by arbitrary transverse loads. The method is based on using an antisymmetric load on a square plate. Two boundary conditions are solved and the numerical results obtained for these cases are tabulated"--Abstract, page ii.

Kinetics And Mechanisms Of Base-Catalysed Reactions, Rohit Panalal Sheth

Masters Theses

"Base-catalysed reactions normally involve complex series of transformations. their kinetics is usually governed by a variety of equilibria, participating in the overall and concurrent processes as well as by competitive side-reactions that interfere with the normal course of such reactions. Mechanisms which have been proposed, by and large, are primarily based on product, by-product and intermediate analyses together with some scattered kinetic and isotopic evidence. In the cases where kinetic studies have been attempted, highly complex mechanisms have usually been proposed due to the frequent necessity of using heterogeneous media or employing involved mathematical treatments to describe the kinetics of …

Mass Transfer In Droplets With Turbulent Internal Circulation - Mathematical Description, Jayantilal Mohanbhai Patel

Masters Theses

"This investigation was carried out to check the accuracy of the eigenvalues, λ_n, calculated by Wellek and Skelland, using some method other than the Rayleigh-Ritz technique and also, to determine the coefficients, B_n in series solution, which were not calculated before.
The eigenvalues were obtained by trial and error procedure using the standard Runge-Kutta method. The coefficients B_n were obtained by using eigenvalues. By using this information the fractional extraction was calculated as a function of droplet contact time.

The Wellek-Skelland modification was also solved by finite difference technique to compute fraction extracted as a function …

Nucleate Boiling Heat Transfer To Liquid Nitrogen At Atmospheric Pressure, Satish R. Parikh

Masters Theses

"The object of this investigation was to study the effect of micro-roughness, a thin layer of oil, and infra-red radiations on the cylindrical heat transfer surface of copper, in liquid nitrogen and at atmospheric pressure during nucleate boiling. An attempt was made to find any possible effect of orientation of the heat transfer element on nucleate boiling. A number of different runs were taken with different degrees of roughness, and different orientation positions. Nucleate boiling has been found to be nearly independent of the heat transfer surface roughness and of orientation while strongly dependent on the chemical nature of the …

A Photoelastic Study Of The Stresses In A Deep Beam Using Partial Mirrors For Isochromatic Fringe Sharpening And Fringe Multiplication, Edward M. Raney

Masters Theses

"This paper is a photoelastic investigation of the stresses in a deep beam using partial mirrors to obtain isocromatic fringe sharpening and fringe multiplication. This method may be of particular value in photoelastic work for obtaining full field fringe multiplication and fringe sharpening for models which exhibit low fringe orders.

The photoelastic model used in this investigation is a deep beam with a length to depth ratio of one. A uniform load is applied over the center one-half of the beam. The beam is supported by two uniform loads distributed over a length of one-quarter the span.

A first approximation …

Analysis Of Time-Varying Linear Multipole Filters With Sampled Nonstationary Random Inputs, Ming-Chwan Chow

Masters Theses

"In this thesis an analytical method is developed to determine an optimum time-varying linear filter in order to satisfy the following specifications. The filters are of sampled data multipole form with n inputs and m outputs. The signal of each input is a member of a nonstationary random process, and the signal is corrupted by stationary noise.

The statistical optimization theory developed by Wiener is extended to a linear time- varying filter with nonstationary input. Correlation functions are defined for nonstationary ensembles. The mean- square error is calculated in terms of these correlation functions. By minimization of the mean-square error, …

Heat Flow In The Boss Deposit Of Missouri, Don Stainbrook

Masters Theses

"Values of heat flow through a Precambrian mineral deposit were determined in the Boss area of Missouri, where 350 meters of Paleozoic sedimentary rocks overlie a complex series of rhyolite flows which have been altered and contain a copper bearing magnetite deposit. Geothermal data were obtained from a closely spaced grid of 17 diamond drill holes penetrating to depths of 1000 meters below ground surface. Temperature measurements were made at 5 meter intervals in the Precambrian section of all holes. These and thermal conductivity measurements made on representative core samples from 300 to 400 meters below the top of the …

A Study Of Stress Distribution And Measurement Of Axial Strain Around A Pilot Hole During Overboring, Varakantham Sreedhar Reddy

Masters Theses

"Stress distribution around a pilot hole during overcoring was investigated. A study of axial strain on the borehole surface was undertaken. Two-dimensional epoxy resin models were prepared and stress frozen in a centrifuge. The stress-frozen models were examined under a direct-viewing polariscope. The magnitude of axial strain and the effect of strain relaxation on the pilot hole were measured on blocks of brittle materials. Factors contributing to discing of core during the overcoring operation were investigated and a mechanism of failure postulated. The loading conditions simulating in situ, core and bit pressures were applied individually to the brittle models and …

A Periodic Dielectric Rod Antenna, Robert C. Peirson

Masters Theses

"The periodic dielectric rod antenna structure under consideration consists of identical dielectric rod sections of radius a meters situated on a common axis. These sections are of length 1₁ meters and are separated in free space by distance 1₂ meters.

Field analysis employing Floquet's theorem, in terms of the exemplary TM₀₁ circular mode, gives expressions for the various field components and an eigenvalue equation. Digital solution of this eigenvalue equation establishes the location of propagation bands as a function of frequency. Such bands are characteristic of any periodic wave guiding structure."--Abstract, page ii.

A Probability Density Analyzer, Thomas K. Bohley

Masters Theses

"A means is presented by which the probability density of statistical signals may be determined experimentally. The design and construction of an electronic test instrument to measure probability density is discussed. Operating instructions and circuit diagrams are also included"--Abstract, page ii.

Modal Characteristics Of A Vibrating Truss, Edd Leighman Ghent Jr.

Masters Theses

"In this thesis, a complete technique is presented for the vibration analysis of any planar structure which can be classified in the broad category of trusses or frames. Although a theoretical backdrop is included for the' sake of completeness, the intent is to provide a technique that is readily adapted to computer usage and can be handled with a minimum of confusion or misunderstanding.

The problem is solved by the use of a displacement technique wherein the inertia and stiffness properties of a structure are calculated by superimposing the contributions of each component of the structure. The calculation of these …

An Algorithm For The Synthesis Of Nand Logic Networks Using A Diagrammatic Approach, Donald Robert Nelson

Masters Theses

"A diagrammatic approach is presented for the synthesis of multilevel NAND networks realizing combinational logic expressions. The network synthesized is restricted to only uncomplemented inputs. The synthesis algorithm involves the determination of minimum sum of products and product of sums expressions for a Boolean function, construction of an α-ß diagram from these expressions followed by implementation with NAND gates directly from the diagram. The resulting network is a minimal or near minimal NAND gate realization of the given function. The algorithm is applicable to completely or incompletely specified Boolean functions and is extended to include NOR synthesis"--Abstract, page 2.

Structure Contours On The Top And Base Of The M Bed, The Relationship Of Mineralization To Structures, And The Variation Of The M Bed Thickness In The Tri-State District, Missouri, Kansas And Oklahoma, Arvind A. Desai

Masters Theses

"Regional structure and thickness of a single horizon, the M bed, have been studied in the Tri-State district by picking the top and base of the M bed in the logs of 557 selected drill holes and contouring this data together with the aid of local detailed structural information available for individual mining fields. Structures determined from these data were compared to the positions of mined mineralization to determine the control of regional structure upon the localization of ore. Variations in the M bed thickness were compared to the positions of fields of mineralization to examine possible spatial relationships which …

A Nonlinear Sampled Data Feedback Control System Employing Pulsed Thrust Position Control, John D. Corrigan

Masters Theses

"This thesis shows that reaction jet thrust pulses, each of constant amplitude and time duration, in conjunction with sampled data error information can provide satisfactory position and/or attitude control for space vehicles.

Incremental phase-plane analysis of the system yields a technique for determining system response and suggests a means of compensation. Control system response for the vehicle under the influence of external forces is shown to be satisfactory by digital computer simulation"--Abstract, page ii.

Some Effects Of Selected Biodegradable Detergents On The Aeration Of Water And Activated Sludge, Donald Ernest Modesitt

Masters Theses

"The purpose of this study was to determine what effects the presence of selected biodegradable detergents have on the aeration of water and the activated sludge process for aerobic wastewater treatment. The detergents studied were LAS #1, Alfol, and Nalkylene. It was of particular interest to determine if these detergents decreased the oxygen absorptive capacities of water and wastewater. If detrimental effects were produced by the detergents it was then desired to determine if these effects were serious enough to create problems with aerobic wastewater treatment and aeration in receiving bodies of water.

A two liter volume of the liquids …

The Plastic Behavior Of Reinforced Concrete Beams With Varying Percentages Of Reinforcing Steel Symmetrically Placed, J. Leroy Hulsey

Masters Theses

"The purpose of this study is to determine the limitations of the plastic behavior of reinforced concrete beams with varying percentages of high strength steel (ASTM-A-432) cutoff in the compression region d distance beyond the point of inflection. Comparison was made with the derived equations.

Steel was placed symmetrically in order to obtain like action at critical sections. The members tested were of a propped beam nature having a total clear span of 5'6" with a 6" overhang on one end and 1'6" overhang on the other. Concentrated loads were applied so as to obtain midspan loading and fixed end …

Modification Of The Hydraulic Jump By Submerged Jets, Edward Leon Tharp

Masters Theses

"Tests were performed in order to determine the effect of submerged jets injecting water into the base of the hydraulic jump. The jump was studied in terms of the following properties: specific energy of the flow leaving the hydraulic jump, length of the hydraulic jump, tailwater depth, and wave formation properties. These properties for the hydraulic jump with submerged jets were compared to the natural hydraulic jump.

Results of the tests indicate that: submerged jets at any angle tested tend to decrease the specific energy of the water leaving the jump and are more effective than the impulse-momentum principle indicates, …

Analysis Charts For Single And Multi-Span Gabled Frames, John (Chung-Su) Ma

Masters Theses

"A method for analyzing single and multi-span gabled frames using analysis charts is presented. This method requires considerably fewer computations than methods previously used (such as the moment distribution and slope-deflection methods). Analysis charts are presented for single gabled frames having fixed or pinned ends at ground level, and charts are also presented which can be used to efficiently analyze multi-gabled frames.

The data for the analysis charts were obtained using matrix techniques in conjunction with the digital computer. These techniques are described"--Abstract, page ii.

The Anodic Dissolution Of Magnesium In Aqueous Solutions, Chen-I Lu

Masters Theses

"The anodic dissolution of magnesium was studied in MgCl₂-KC1 and MgBr₂-KBr mixtures at 25, 40, and 55 °C. The parameters of the study were current density, concentration of magnesium ion, and temperature. The concentration of magnesium ions was varied from 0.001 to 1 N holding the ionic strength constant at 1.5. The weight loss of magnesium from the electrode during electrolysis was determined by weighing the electrode both before and after electrolysis. The current was measured with a sensitive milliammeter. The range of the current densities was varied from 0.001 to 0.1 amps·cm^-2. The …

A Crystallographic Study Of The Pbzro₃-Pbtio₃-Bifeo₃ Ternary System., Dannie R. Clarida

Masters Theses

"The purpose of this investigation was to conduct a crystallographic study of the PbZrO₃-PbTiO₃-BiFeO₃ ternary system, where all three components are perovskites. Lead zirconate is antiferroelectric, lead titanate is ferroelectric, and bismuth ferrate is thought to be ferroelectric. X-ray diffraction analysis was employed to determine the crystallographic structure and lattice parameters.

A tetragonal region was found to exist in the area of high PbTiO₃ content. A rhombohedral region occurred in the remainder of the system with high BiFeO₃ and PbZrO₃ content, except for an orthorhombic envelope along the PbZrO₃-BiFeO₃ side of the diagram up to approximately 70 per cent BiFeO₃.The …

Some Effects Of Sodium Pentachlorophenol On Activated Sludge And Minnows., James Albert Heidman

Masters Theses

"The primary purpose of this investigation was to determine the effect of sodium pentachlorophenol on activated sludge. An additional objective was to determine the toxicity of sodium pentachlorophenol to minnows.

All activated sludge units were grown on a glucose and mineral nutrient waste. In addition, a unit acclimated to 100 and 250 mg/1 of sodium pentachlorophenol was also studied. The effect of a shock loading of sodium pentachlorophenol was found to depend on the concentration of the loading and also on the group of micro-organisms which were predominating. One activated sludge system was seriously impared at a shock loading of …

Slope Stability Analysis Of A Fissured Glacial Clay, Byron G. Walker

Masters Theses

"A slope in an over-consolidated, fissured clay was analyzed by the Swedish Method of Slices.

Values of cohesion (c) and angles of friction (Ø) were determined by three different types of direct shear tests (undrained, drained and residual).

Factors of safety (functions of c and Ø) indicated that the direct shear test parameter gave a factor of safety approximately four times that represented by failure conditions in the field. Drained tests gave a factor of safety nearly 2.3 times the value represented by field conditions. The conclusion is made that these two tests are of limited value for slope stability …

The Construction Of A Fermi Neutron Chopper For Cross Section Measurements, Cleon Marion Mobley

Masters Theses

"A Fermi neutron chopper and control system has been constructed and put into operation at the end of the UMR Reactor thermal column.

The operation of the chopper has been demonstrated by reproducing the slow neutron cross section data for aluminum and by measuring the previously undetermined slow cross section of cobalt.

The chopper which is powered by a series DC motor consists of 34 cadmium plated stainless steel blades separated by 1/16 inch aluminum spacers. The design incorporates the better characteristics of the Brookhaven and Argonne slow choppers. Speed regulation is accomplished using a silicon controlled rectifier feed back …

Plastic Design Of Steel Frames For Minimum Weight, I-Chen Hung

Masters Theses

"The purpose of this study was to develop a method for weight minimization of the plastically designed frame, braced normal to its plane of action, and composed of prismatic steel members. The method accounts for the non-linear relationship between weight and moment capacity for both beams and columns. Reduction in the pure-bending fully-plastic moment in the presence of axial loading and both beam-column instability and overall frame instability due to sidesway are taken into account. Provision is made for minimization of frames employing standard sections as well as for frames whose built-up members may be chosen from a continuous spectrum. …