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Heavy Metal Analysis Of Stream Sediments In The James River Basin, Missouri, William J. Head

Masters Theses

"A reconnaissance survey of stream sediments using the minus 80 mesh sieve fraction was made at 53 sites throughout the James River basin, Missouri. Sample sites within the 1460 square miles of the basin were chosen at tributary confluences, suspected contamination sources, and known areas of mineralization. Replicates and stream profiles were taken to check for analytical variation and reproducibility of results. Sediment samples were prepared by a hot nitric acid leach method. The sediments were analyzed using an atomic absorption unit to determine Cu, Pb, Zn, and Cd trace metal contents.

Values of selected streams within the basin were …

Corals Of The St. Louis Limestone In The Area Of Calhoun County, Illinois And St. Louis County, Missouri, William Earl Collins

Masters Theses

"The St. Louis Limestone and its equivalent formations crop out from Alaska south to Sonora and from Arizona east to Virginia. The St. Louis, in most cases, is fossiliferous and contains numerous species of foraminifers, echinoderms, bryozoans, molluscans, brachipods, arthropods and coelenterates. Algal mounds and mats are common. The rugose coral fauna of the Middle Mississippian (Meramecian) St. Louis Limestone of southern Calhoun County, Illinois and northern St. Louis County, Missouri was studied to determine first what corals were present and second the validity of the names assigned to the previously described species. It was found that the binomen for …

Quantitative Overdesign By Stochastic Simulation, Raymond A. Freeman

Masters Theses

"The determination of overdesign, or safety, factors for industrial processes is an art acquired by the engineer through experience. In general, safety factors are increased as the uncertainty of the process variable increases; a procedure that can be expensive if safety factors are specified too small or too large. A single release of harmful substances from pollution control installations may cause irreparable damage. Likewise, the production of an off specification product by a chemical process costs money and resources. These facilities must often be designed for widely fluctuating flow rates, compositions, temperatures, and etc. Consequently, the selection of the proper …

Disposal Of Cattle Feedlot Wastes By Anaerobic Digestion, Eric Bayard Rapp

Masters Theses

"Disposal of animal waste represents a severe environmental problem, particularly in areas such as cattle feedlots where livestock are concentrated. Animal waste can be converted to carbon dioxide and methane by the autocatalytic process of anaerobic fermentation. A scheme, based upon this process, for the disposal of the waste from two different size feedlots is presented. The design of this process is based on kinetic data from the literature which are fitted to a kinetic model including diffusional resistances. Economic calculations based upon available cost data are made to determine the profitability of the process. Economic evaluations indicate that this …

The Design And Calibration Of A Vibrating Sample Magnetometer, Donald Dwight Hoffman

Masters Theses

"The design and calibration of a vibrating sample magnetometer is described. The sample motion was in the direction of the external magnetic field which was produced by a superconducting solenoid. The maximum external magnetic field was 70 kilogauss. Sample temperature could be varied from 77°K to 1000°K with a vacuum jacketed furnace. The maximum temperature was obtained with approximately 27 watts. The instrument was calibrated to 1% with a spherical nickel sample"--Abstract, page ii.

Precipitation Of Carbon From Martensite In Ductile Iron, Devendra Ratilal Majmundar

Masters Theses

"Since metallographic studies of quenched and tempered cast iron have indicated that the carbon might precipitate directly as graphite rather than as carbides which are found in steels, this investigation used the Debye-Scherrer x-ray diffraction technique to examine electrolytically extracted residues from quenched and tempered ductile cast iron samples to determine if cementite was present. The precipitation of carbon in quenched samples of this ductile cast iron was found to be similar to the precipitation process in steels. Cementite was identified during the early stages of the tempering process when the tempering temperature was 800 degrees F, 900 degrees F, …

Desorption Of Phosphorus From Si (111) Surfaces, Cesar Michel Magnin

Masters Theses

"Auger electron spectroscopy and mass analysis are used as complementary methods in evaluating desorption kinetics. For phosphorus on silicon, the order of desorption and activation energies of desorption are determined from continuously monitored phosphorus Auger electron signals during heating. These measurements indicate that diatomic phosphorus dissociates when adsorbed onto clean silicon. Mass spectrometer flash desorption spectra show that at least four distinct surface bonds are associated with the desorption of phosphorus. The dominant desorbed species is diatomic phosphorus at high coverage (> 0. 1 monolayer) and atomic phosphorus at low coverage (< 0.07 monolayer)"--Abstract, page ii.

Transmission Measurements Through Liquids In A White Cell, David Earl Hurley

Masters Theses

"The suitability of using the White cell for determining the extinction coefficient of liquids was examined by measuring the attenuation of electromagnetic radiation, in the visible part of the spectrum, through distilled water. The analysis of the transmittance measurements through liquids in a White cell does not provide a sufficient number of independent equations to solve directly for the extinction coefficient. Reasonable estimates however can be made by employing a correction which accounts for changes in the mirror reflectance due to a liquid-mirror interface.

The reduction in the transmittance of distilled water due to an oil film was studied for …

Structure And Chemical Composition Of The Otoliths Of Cyprinus Carpio, Larry Paul Coen

Masters Theses

"The need for the study of microfossils such as foraminifera, conodonts, and otoliths as stratigraphic tools has been well established. However, disarticulated parts such as otoliths and conodonts cannot be effectively used unless they can be recognized. Otoliths, although somewhat unrecognized in the geological record, are far more abundant than articulated skeletons (Frizzell, 1965, p. 86). Therefore, much investigation is being conducted to reveal the origin, function, morphology, and usefulness of the otoliths of fishes.

In this investigation, the asteriscus, well developed only in Ostariophysins (of which the carp is a member), is studied for morphology. New tentative terms are …

Attitude Scaling As A Public Involvement Tool In The Lower Mississippi River Region Comprehensive Study, William A. Lee

Masters Theses

"The planner is under considerable pressure to involve the public in water resource planning. The public, however, often lacks sufficient knowledge to offer useful comments or suggestions. The use of a Likert Type Attitude Scale in the public involvement effort of the Lower Mississippi Region Comprehensive Study demonstrates the usefulness of attitude scaling techniques in obtaining public input to the planning process. The measurement of an individual's attitude, or his thoughts, feelings and disposition to act toward some aspect of his environment with some degree of consistency, gives an indication of the goals and objectives toward which a plan acceptable …

On The Complex Index Of Refraction Of Bulk Materials, Carol Jeanne Warren

Masters Theses

"As a part of the investigation of classical reflectance, it is determined that the hemispherical reflectance for a material with a particular pair of optical constants can be approximated by computing the angular reflectance at sixty degrees, using Fresnel's generalized reflectance formulas.

Reflection methods for the purpose of determining the optical constants of a variety of materials are discussed. The unpolarized reflectance versus angle of incidence technique is used for determination of the optical constants of bulk solids. Restrictions on the simultaneous solution of the Fresnel equations are determined and a computer program is developed to compute values necessary to …

Relative Volatility In The System 1-Butene - N-Butane, Steven Lewis Walker

Masters Theses

"An apparatus suitable for the rapid collection of P-x data at constant T is described. Isothermal P-x data at 40, 70, 100, 130, and 160 degrees Fahrenheit at the extremes of the composition range for the 1-butene - n-butane system are presented as a demonstration of the suitability of the device for its intended purpose. Limiting values of the relative volatility for the binary are presented. The relative volatilities were calculated using limiting forms of the general coexistence equation which are given in the literature. Several recommendations are given for improvements of the equipment and experimental technique"--Abstract, page ii.

The Linear New City -- A Pattern For New Cities Based On Efficiency Of Transportation, Public Services, And Land Use, Elbridge Wesley Bartley Iii

Masters Theses

"The linear new city is defined as a city consisting of some arrangement of relatively narrow, high-density strips, served by various mass transportation systems. Such a new city would be ideally suited to the implementation of the latest technology. The concentration of development along the transportation route would allow certain economies in the supply of utilities and services, as well as insuring that open space would be readily available around and throughout the city. The provisions for transportation, housing, and governmental control should combine to produce a better quality of life for the inhabitants of the linear new city"--Abstract, page …

Managerial Performance Appraisal, Benildus Wai-Young Lau

Masters Theses

"Questionnaire surveys were sent out to two hundred medium-sized companies in industry. The study is an attempt to find the main cause for the unsatisfactory results in most appraisal programs and to make recommendations concerning the implementation of an effective performance appraisal program. Human factors play an utmost important role in the success of the entire appraisal program. An atmosphere of mutual understanding and trust should be established between the well trained supervisor and his subordinate so that the rapport between them can be brought to the highest possible level. Performance appraisal should be considered as an integral part of …

A Technique For Improving Material Balance Accuracy In Reservoir Simulation Models, A. R. Merchant, Marion D. Arnold, A. Herbert Harvey

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

One criterion for determining the precision of pressures calculated by a simulation model is the accuracy of the material balance. A high degree of precision in the calculated pressures is a necessary but not sufficient condition for elimination of significant errors in the prediction of fluid migration in the reservoir. A new procedure, called error matrix technique, has been developed for reduction of material balance errors. This reduction is accomplished by adjusting potential gradients at every grid point in the simulation model so that the material balance is accurately maintained. Performance of a hypothetical oil reservoir was simulated both by …

Stratigraphic Relations Of Members Of The Needles Range Formation At Type Localities In Southwestern Utah, M. G. Best, R. T. Shuey, C. F. Caskey, S. Kerry Grant

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The Needles Range Formation is one of the most extensive of the middle Tertiary ash-flow sheets in the Great Basin of Nevada and western Utah. The original definition of the formation by Mackin (1960) named two members and mentioned three type localities. Our recent studies have shown that this published information now requires revision. To provide a firm basis for stratigraphic studies of the Needles Range Formation, this paper presents geologic maps, measured sections, and paleomagnetic data for three type localities in southwestern Utah. These include the northern Needles Range and Wah Wah Springs localities previously mentioned by Mackin, plus …

Pmr Spectra Of The 4-Alkylnitrobenzenes, Donald W. Beistel, Hsin-Liang Chen

Chemistry Faculty Research & Creative Works

Evidence of first-order alkyl-ring proton coupling is reported for the 4-alkylnitrobenzenes. Typical coupling constants of 0.7 Hz and 0.3 Hz were found for α-alkyl coupling with the ortho and meta ring protons, respectively, when the alkyl function was methyl, ethyl, and isopropyl. No β-alkyl coupling with ring protons was observed for the ethyl, isopropyl, or t -butyl groups, suggesting that the magnitude of the coupling constant is vanishingly small.

The Synthesis And Spectroscopic Properties Of Vanadium(Iii) Squarate Trihydrate, S. M. Condren, Hector O. Mcdonald

Chemistry Faculty Research & Creative Works

Vanadium(III) squarate trihydrate has been prepared; and the infrared, X-ray diffraction, and electronic spectra of the complex indicate that the central metal atom is in a slightly distorted octahedral field. A thermogravimetric study has shown that the complex loses three water molecules upon heating. A hydroxy-bridged, dimeric structure has been proposed from these data. © 1973, American Chemical Society. All rights reserved.

Oxidation Of Tetragonal Pbo In Air, Charles A. Sorrell

Materials Science and Engineering Faculty Research & Creative Works

Isothermal oxidation of tetragonal PbO in air produced multiphase assemblages with apparent equilibrium compositions which varied linearly with temperature from PbO1.548 at 286°C to PbO1.333 at 351°C. Oxidation at each temperature was relatively rapid to PbO1.40 and very slow from PbO1.40 to apparent equilibrium values. Pseudocubic PbO1+x, with compositions between PbO1.41 and PbO1.57, was indexed on a cubic unit cell at the lower O/Pb ratios and on a tetragonal unit cell at the higher ratios. Linear changes in lattice parameters and deviation from cubic symmetry accompanied reversible oxidation and reduction of the phase. Pseudocubic PbO1+x was reduced irreversibly to Pb3O4 …

Polynary Silicon Arsenic Chalcogenide Glasses With High Softening Temperatures, H. E. Anthonis, N. J. Kreidl, W. H. Ratzenboeck

Materials Science and Engineering Faculty Research & Creative Works

The introduction of Ag in SiAsTe glasses permits the incorporation of Se, otherwise volatile and/or degradable as a constituent in Si-containing chalcogenide glasses. SiAsAgTeSe glasses exhibit much higher softening ranges and glass transition temperatures than encountered in known chalgogenide systems. A glass Si35As15Ag10Te20Se20 had the viscosity log ν = 13 at about 500°C, as compared to 370°C for the base glass Si35As25Te40, the viscosity of log ν = 9.8 at about 560°C, as compared to 442°C for the base glass. Phase separation occurs in the system SiAsAgTeSe and becomes manifest in two glass transitions indicated by changes in the slopes …

Oxidation State Control Of Volatile Species In Sintering, P. D. Ownby

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

An Investigation Of Combined Thermal Weakening And Mechanical Disintegration Of Hard Rock, George Bromley Clark, T. F. Lehnhoff, Vernon Dale Allen, Mahendrakumar Ramkrishna Patel

Mining Engineering Faculty Research & Creative Works

"The research under modified Contract No. H0220068 has been devoted to experimental thermal-mechanical fragmentation of Missouri red granite in place, and to supporting theoretical analyses. The results of the previous year's experimental work showed that thermal stresses are several times more effective in fragmenting hard rock when they are created within the rock rather than upon the surface. Also, large blocks {4-foot cubes) are not adequate to simulate the response of in situ rock.

Based upon laboratory tests an experimental round was designed analogous to an explosive blasting round with coiled wire heating elements placed in drill holes. Three displacement …

An Accurate Digital Instrument To Measure Reactor Period, Ernest W. Scott, Paul D. Stigall

Electrical and Computer Engineering Faculty Research & Creative Works

At Facilities Having a Research-Training Reactor, such as the University of Missouri-Rolla Reactor (UMRR), One Finds It Necessary to Perform a Large Number of Rod Calibrations during the Course of the Year. in Practice Rod Worths Are Determined by Measuring the Reactor Period Created by an Incremental Withdrawal of the Rod under Calibration. Period is Then Related to Reactivity Thru the Use of a Publication Such as the AEC Publication, ID016485. This Frequent Measurement of Period Makes It Desirable to Have a Simple, Automatic and Accurate Method to Make Such Measurements. at UMRR We Have Designed, Constructed and Installed Such …

Gaas Laser Experiments For The Undergraduate Laboratory, R. E. Robert, Daniel J. Jones, Kaare J. Nygaard

Physics Faculty Research & Creative Works

No abstract provided.

Possible Applications Of Surface Electromagnetic Waves To Measure Absorption Coefficients, Ralph William Alexander, Robert John Bell, C. A. Ward, James Roger Weaver, I. L. Tyler, B. Fischer

Physics Faculty Research & Creative Works

We Show that Surface Electromagnetic Waves Can Probably Be Used to Measure the Absorption Coefficients of Materials overlaying Metals. the Proposed Experimental Method is Illustrated in the Infrared Frequency Range using Water, Teflon, and Polyethylene as Sample Materials.

Flowware -- A Flow Charting Method To Describe Digital Systems, Wayne Everett Omohundro

Doctoral Dissertations

"FLOWWARE is an interactive, graphical language to aid in the understanding and design of digital networks. The language is based upon the concept of flow charting. The user specifies the register layout of the system and the sequential operation in the form of a diagram on a graphics terminal. FLOWWARE makes full use of a local minicomputer to perform editing and drawing functions, and a remote large computer to perform translation and simulation. This division of labor allows the user to build his description off-line without having the remote computer program active"--Abstract, page ii.

Convergence Of Material Balance In Mathematical Simulation Of Petroleum Reservoirs, Abdul Rashid Merchant

Doctoral Dissertations

One criterion for determining the precision of pressures calculated by a simulation model is the accuracy of the material balance. A high degree of precision in the calculated pressures is a necessary condition for elimination of error in prediction of fluid migration in the reservoir. However, this condition is not sufficient to guarantee accuracy of the simulation, since inaccuracies are introduced by truncation errors, machine round-off errors, and by the use of finite difference approximations to represent nonlinear partial differential equations.

A new procedure called Error Matrix Technique has been developed for reduction of material balance errors. This reduction is …

Numerical Simulation Of Individual Wells In A Field Simulation Model, Ali Mohammed Akbar

Doctoral Dissertations

"Conventional numerical simulation of hydrocarbon reservoirs is inadequate for the prediction of bottom-hole pressures at production wells. This problem can be overcome by using a special mathematical model which combines individual well simulation with reservoir simulation. Severe computational instability is commonly encountered in the radial models due to the relatively small grid-blocks and high fluid velocities in the vicinity of the well bore. This instability is found to be more pronounced during depletion of the reservoir when the pressure near the well bore is below bubble-point pressure. A new technique is introduced here for saturation calculations in the critical region …

Transient State Analysis Of Separated Flow Around A Sphere, Ching-Liang Lin

Doctoral Dissertations

"Transient state solution of the Navier Stokes equation was obtained for incompressible flow around a sphere accelerating from zero initial velocity to its terminal free falling velocity. By assuming rotational symmetry around the axis in the falling direction, the Navier Stokes equation and the continuity equation were simplified in terms of vorticity and stream function. The instantaneous acceleration of the falling sphere was calculated by considering the difference between the gravitational force and the drag force in a transient state. The governing partial differential equations were non-dimensionalized. A set of implicit finite difference equations was developed. In order to obtain …

Stability Of The Developing Laminar Flow In A Circular Tube, Lung-Mau Huang

Doctoral Dissertations

"An investigation is made of the linear stability of the developing laminar flow of an incompressible fluid in the entrance region of a circular tube. Both axisymmetric and non-axisymmetric small disturbances are considered in the analysis. The stability characteristics of the fully developed flow are also re-examined. The main flow velocity distribution used in the stability analysis is that from the solution of the linearized momentum equation. The governing equations for the disturbances and the boundary conditions constitute an eigenvalue problem which is solved by a direct numerical integration scheme along with an iteration technique. The solution starts with a …