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Component Level Em Emission Assessment And Management For Rf Desensitization, Xiangrui Su, Wenchang Huang, Junghee Cho, Joonki Paek, Chulsoon Hwang Jan 2025

Component Level Em Emission Assessment And Management For Rf Desensitization, Xiangrui Su, Wenchang Huang, Junghee Cho, Joonki Paek, Chulsoon Hwang

Electrical and Computer Engineering Faculty Research & Creative Works

Radio frequency (RF) desensitization is a common issue caused by high-speed components in modern electronic devices. Consequently, numerous studies have focused on characterizing and quantifying electromagnetic (EM) emission sources by using near field scanning to detect EM noise sources. However, before near field scanning, no predetermined threshold is available to quickly assess whether an EM noise source will pose RF desensitization risks in the receiving antenna. This article presents a method to optimize near field scanning settings through EM emission management analysis. Drawing on experience from numerous EM emission studies, we introduce an EM emission management procedure for two common …


Discrimination Of Temperature And Strain By Characterizing Two Femtosecond Laser-Written Coincident Sapphire Fiber Bragg Gratings For Harsh Environment Applications, Farhan Mumtaz, Bohong Zhang, Koustav Dey, Jeffrey D. Smith, Ronald J. O'Malley, Jie Huang Jan 2025

Discrimination Of Temperature And Strain By Characterizing Two Femtosecond Laser-Written Coincident Sapphire Fiber Bragg Gratings For Harsh Environment Applications, Farhan Mumtaz, Bohong Zhang, Koustav Dey, Jeffrey D. Smith, Ronald J. O'Malley, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

In this study, two co-incident sapphire fiber Bragg gratings (SFBGs) were successfully inscribed utilizing a femtosecond (fs) laser to achieve a high fringe contrast interferogram. These two SFBGs employ a unique configuration, one parallel to the center axis, called p-SFBG, and the other forming an angle from the center-axis, called a-SFBG, allowing for simultaneous strain and temperature measurements with low crosstalk. As a proof of concept, p-SFBG and a-SFBG using line-by-line method are characterized, which are shorter in length (i.e., 1.5 mm), producing reflectivity of ~3dB. This effort demonstrates the use of two coincident SFBGs forming an angle of 2.29° …


Simultaneous Measurement Of Early-Stage Corrosion And Strain Levels In Steel Rebar Based On Graphene Oxide-Coated Ncf-Fbg Fiber Optic Sensor, Fujian Tang, Baihe Qu, Hong Nan Li, Jie Huang Jan 2025

Simultaneous Measurement Of Early-Stage Corrosion And Strain Levels In Steel Rebar Based On Graphene Oxide-Coated Ncf-Fbg Fiber Optic Sensor, Fujian Tang, Baihe Qu, Hong Nan Li, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

Rebar corrosion significantly reduces the lifespan of reinforced concrete structures. The value of rebar strain, especially for some key structural components, indicates the safety margin of structures. In this study, a graphene oxide (GO) coated no-core fiber-fiber Bragg grating (NCF-FBG) fiber optic sensor is proposed for simultaneously measuring strain values and early-stage corrosion of steel rebar for the first time. The impact of GO coating thickness on the monitoring sensitivity is considered. A setup was manufactured to simultaneously perform tension, optical, and corrosion tests. The strain was applied up to 1200 μϵ. The rebar corrosion was assessed using electrochemical method …


Safe Optimal Control Of Quadrotor Formations Using Multilayer Neural Networks And Continual Learning, Ehsan Soleimani, Irfan Ahmad Ganie, S. Jagannathan Jan 2025

Safe Optimal Control Of Quadrotor Formations Using Multilayer Neural Networks And Continual Learning, Ehsan Soleimani, Irfan Ahmad Ganie, S. Jagannathan

Electrical and Computer Engineering Faculty Research & Creative Works

This article presents an integral reinforcement learning-based optimal formation tracking scheme for multiple quadrotors unmanned aerial vehicles (QUAVs) experiencing nonlinear coupled dynamics and subject to constraints. We use multilayer neural networks (MNN) within an actor-critic framework where the MNN weights are tuned using singular value decomposition (SVD) of the activation function gradient to approximate optimal control policy via backstepping. Additionally, barrier Lyapunov functions (BLF) are introduced to ensure set invariance, thereby maintaining the quadrotors within a defined safety space due to constraints. A novel weight update law for each layer is derived using the HJB approximation error and control input …


Explainable And Safety Aware Deep Reinforcement Learning-Based Control Of Nonlinear Discrete-Time Systems Using Neural Network Gradient Decomposition, Behzad Farzanegan, S. Jagannathan Jan 2025

Explainable And Safety Aware Deep Reinforcement Learning-Based Control Of Nonlinear Discrete-Time Systems Using Neural Network Gradient Decomposition, Behzad Farzanegan, S. Jagannathan

Electrical and Computer Engineering Faculty Research & Creative Works

This paper presents an explainable deep-reinforcement learning (DRL)-based safety-aware optimal adaptive tracking (SOAT) scheme for a class of nonlinear discrete-time (DT) affine systems subject to state inequality constraints. The DRL-based SOAT utilizes a multilayer neural network (MNN)-based actor-critic to estimate the cost function and optimal policy while the MNN update laws are tuned both using the singular value decomposition (SVD) of activation function gradient in order to mitigate the vanishing gradient issue and safety-aware Bellman error at each layer. An approximate safety-aware optimal policy is developed using Karush–Kuhn–Tucker (KKT) conditions by incorporating the higher-order control barrier function (HOCBF) into the …


Adaptive Nussbaum Design For Nonholonomic Systems With Asymptotic Stabilization Against False Data Injection, Guilong Liu, Yongliang Yang, Weinan Gao, Donald C. Wunsch Jan 2025

Adaptive Nussbaum Design For Nonholonomic Systems With Asymptotic Stabilization Against False Data Injection, Guilong Liu, Yongliang Yang, Weinan Gao, Donald C. Wunsch

Electrical and Computer Engineering Faculty Research & Creative Works

This article addresses the stabilization challenges of nonholonomic systems under the threat of false data injection (FDI) attacks, which compromise the integrity of state information. A novel adaptive control strategy using Nussbaum-type gains is proposed to ensure the asymptotic stability of the closed-loop system while maintaining signal boundedness. The approach extends conventional Nussbaum designs to handle multiple unknown control directions. It integrates online learning mechanisms to mitigate the impact of FDI attacks. Additionally, adaptive backstepping and fuzzy-logic systems are utilized to approximate and compensate for unknown nonlinear dynamics. The methodology transforms nonholonomic systems into equivalent cascade structures to address inherent …


An Extensive Analysis Of Match-Tracking Methods For Artmap, Niklas M. Melton, Leonardo Enzo Brito Da Silva, Donald C. Wunsch Jan 2025

An Extensive Analysis Of Match-Tracking Methods For Artmap, Niklas M. Melton, Leonardo Enzo Brito Da Silva, Donald C. Wunsch

Electrical and Computer Engineering Faculty Research & Creative Works

This paper identifies and studies five match-tracking (MT) methods in the adaptive resonance theory (ART) literature and conducts a detailed comparative analysis of these in ARTMAP applications. We focus on model performance for each MT method with respect to time and space efficiency as well as classification accuracy. Experimental results indicate that one MT variant, used in ARTMAP applications for the first time in this work, provides significant improvements in computational efficiency: depending on the ARTMAP variant, it was able to achieve up to one order of magnitude reduction in both time and space requirements, albeit with a compromise in …


Active And Reactive Power Flow Control Of The Dual Active Bridge Converter, Lauryn Morris, Thomas W. Francois, Jonathan Saelens, Oroghene Oboreh-Snapps, Arnold Fernandes, Praneeth Uddarraju, Sophia A. Strathman, Jonathan W. Kimball Jan 2025

Active And Reactive Power Flow Control Of The Dual Active Bridge Converter, Lauryn Morris, Thomas W. Francois, Jonathan Saelens, Oroghene Oboreh-Snapps, Arnold Fernandes, Praneeth Uddarraju, Sophia A. Strathman, Jonathan W. Kimball

Electrical and Computer Engineering Faculty Research & Creative Works

The Dual Active Bridge (DAB) is a reliable and efficient converter capable of providing bi-directional power transfer and galvanic isolation. An ac-ac DAB can control both active and reactive power flow. The present work introduces a combined feedback/feed-forward current control system, utilizing the calculated and measured converter currents translated into the dq reference frame, to control the output power. The system was simulated in PLECS to demonstrate the control algorithm's ability to track the dq currents and provide the necessary output power.


Print Quality Assessment Of Additively Manufactured Resonant Structures, Logan M. Wilcox, Alexander Hook, Emma T. Bohannon, Cody Morrow, Doyle T. Motes, Kristen M. Donnell Jan 2025

Print Quality Assessment Of Additively Manufactured Resonant Structures, Logan M. Wilcox, Alexander Hook, Emma T. Bohannon, Cody Morrow, Doyle T. Motes, Kristen M. Donnell

Electrical and Computer Engineering Faculty Research & Creative Works

Due to the increased popularity of additive manufacturing (AM) and availability of electrically conductive filaments, the potential for using AM to fabricate high frequency resonant structures has been realized. As these structures require specific operating conditions to provide the desired resonant response (such as substrate/superstrate material, operating frequency, polarization, etc.), print quality validation through an assessment of the resonant response can be difficult to accomplish. To this end, active microwave thermography (AMT) is proposed as an alternative technique to assess and validate an AM resonant structure. Two AM resonant structures were manufactured using fused deposition modeling (FDM) and the resonant …


Training Neural Networks With A Self-Adaptive Ant Colony Algorithm, Ashraf M. Abdelbar, Donald C. Wunsch Jan 2025

Training Neural Networks With A Self-Adaptive Ant Colony Algorithm, Ashraf M. Abdelbar, Donald C. Wunsch

Electrical and Computer Engineering Faculty Research & Creative Works

ACOR is a well-established ant colony optimization algorithm that has been applied to neural network training. We present an approach for the dynamic adaptation of the ACOR algorithm's search intensification/diversification parameter q, based on using several pre-specified parameter configurations, which we call personalities. Before an ant begins to generate a candidate solution, it stochastically adopts a personality based on the relative past success of the different personalities. The success of a personality is measured, in turn, by the relative quality of previous solutions generated by ants adopting that personality. The premise of our approach is that some personalities will be …


Design And Numerical Investigation Of Surface Plasmon Resonance–Based Refractive Index Sensor, Inamullah Sario, Ghulam Abbas Lashari, Abdul Aziz Memon, Farhan Mumtaz Jan 2025

Design And Numerical Investigation Of Surface Plasmon Resonance–Based Refractive Index Sensor, Inamullah Sario, Ghulam Abbas Lashari, Abdul Aziz Memon, Farhan Mumtaz

Electrical and Computer Engineering Faculty Research & Creative Works

A photonic crystal fiber–surface plasmon resonance (PCF-SPR)-based refractive index (RI) sensor with a novel design is presented in this paper. This sensor detects the anomalies in the sample analyte by detecting the change in its RI. Silver (Ag) is used as a plasmonic material with a unique terracotta structure to sense the RI variations in the surrounding medium, also called an analyte or sample. A thin layer of titanium dioxide (TiO2) measuring 10 nm is applied on top of the plasmonic material to prevent the oxidation of silver. The designed sensor detected a good range of analyte RI from 1.31 …


High-Frequency Accurate Dual-Side Equivalent Circuit Model For Transformers, Reza Vahdani, Junyong Park, Manish Kizhakkeveettil Mathew, Zhekun Peng, Chiuk Song, Hyucksu Kweon, Jiang Lijun, Donghyun Kim Jan 2025

High-Frequency Accurate Dual-Side Equivalent Circuit Model For Transformers, Reza Vahdani, Junyong Park, Manish Kizhakkeveettil Mathew, Zhekun Peng, Chiuk Song, Hyucksu Kweon, Jiang Lijun, Donghyun Kim

Electrical and Computer Engineering Faculty Research & Creative Works

This study delves into the modeling of a transformer in the frequency range of 100 KHz to 30 MHZ. The coupling coefficient was considered as a function of leakage and self-inductance and incorporated in the optimization process of transformer modeling in the proposed method. The equivalent circuit focused on the critical aspects of leakage inductance, parasitic capacitance, and winding effects. At first, the winding effect of an air-core inductor over wide frequency range with both single-layer and double-layer windings was shown. Then an equivalent circuit was proposed to model a transformer over this frequency range. The comparison between the measured …


Metal-Organic Thin Film Coated On Optical Fiber, Nahideh Salehifar Jan 2025

Metal-Organic Thin Film Coated On Optical Fiber, Nahideh Salehifar

Doctoral Dissertations

This dissertation explores the development of metal-organic framework (MOF)-based optical fiber sensors for detecting volatile organic compounds (VOCs) at low concentrations (parts-per-billion to parts-per-million). In the first part of the study, theoretical calculations were performed using effective medium approximation (EMA) models, including Lorentz–Lorentz, Maxwell–Garnett, and Bruggeman equations, to predict the refractive index changes of MOFs upon gas adsorption. These models were applied to MOFs such as ZIF-7, ZIF-8, ZIF-90, MIL-101(Cr), and HKUST-1 to evaluate their potential for gas sensing.

In the second part of the dissertation, experimental work was conducted to validate the theoretical predictions. MOF-coated optical fibers were fabricated …


Deep Learning And Adaptive Clustering Approaches For Flood Prediction And Efficient Sensor Placement In Missouri, Fahimeh Sharafkhani Jan 2025

Deep Learning And Adaptive Clustering Approaches For Flood Prediction And Efficient Sensor Placement In Missouri, Fahimeh Sharafkhani

Doctoral Dissertations

Floods represent formidable natural calamities, posing a significant threat to communities and infrastructure due to their unpredictable and often devastating consequences. The occurrence of floods is influenced by a convergence of meteorological, hydrological, and geographical factors, resulting in changes to the patterns of rising water levels. Machine learning models have emerged as favored tools in recent times for modeling water levels and enhancing the precision of flood predictions. This research employs both supervised and unsupervised machine learning models, with the main objective of improving the accuracy of flood predictions and sensor placement. Four distinct deep learning models are used to …


Evaluating And Relaxing The Limits On Flexural Reinforcement Ratio Of Masonry Shear Walls, Tousif Mahmood Jan 2025

Evaluating And Relaxing The Limits On Flexural Reinforcement Ratio Of Masonry Shear Walls, Tousif Mahmood

Doctoral Dissertations

Reinforced masonry shear walls (RMSWs), essential for lateral and out-of-plane load-resisting systems in modern construction are constrained by TMS 402/602 code limits on reinforcement ratios ("ρ" _"max" ) and axial compressive stresses (≤10% of masonry compressive strength, f_m^'), undermining masonry’s inherent compression capacity under high axial loads. This dissertation investigates the seismic performance of reinforced masonry shear walls (RMSWs) subjected to high axial compressive stresses (10–20% of f_m^'), with a focus on walls violating the maximum reinforcement ratio ("ρ" _"max") and axial load limits of TMS 402-22. Through experimental testing of 30 large-scale fully grouted (FG) and partially grouted (PG) …


Experimental Study Of Defects In Coaxial Wire-Based Laser Metal Deposition, Remy Mathenia Jan 2025

Experimental Study Of Defects In Coaxial Wire-Based Laser Metal Deposition, Remy Mathenia

Doctoral Dissertations

This work seeks to improve the usability and capability of coaxial wire-based laser metal deposition (LMD) through the experimental study of process parameters on output geometry, directional effects, and defect formation. Wire-based LMD is a directed energy deposition (DED) strategy that uses a focused laser heat source to melt and fuse metal wire as it is deposited. This process is used to build parts layer-by-layer until a desired geometry is accomplished. LMD enables the creation of complex components at a high build rate with low material and energy waste. This work focuses on the deposition of titanium wire in the …


Measurement Method And Applications Of Transfer Function In Rf Desensitization Problem, Xiangrui Su Jan 2025

Measurement Method And Applications Of Transfer Function In Rf Desensitization Problem, Xiangrui Su

Doctoral Dissertations

Radio frequency (RF) desensitization issues comprise two components: noise radiation sources and the transfer function from noise sources to the victim antenna. RFI is a critical challenge in modern electronic systems, particularly in densely packed environments. This work presents a comprehensive study of RFI, addressing key aspects through three novel contributions. First, a transfer function measurement method is developed for compact metallic enclosures. This method provides a precise characterization of the electromagnetic (EM) environment within confined spaces, enabling accurate identification of interference pathways. Second, an EM emission management analysis framework is proposed, leveraging transfer functions to quantify and mitigate interference …


The Real-Time Detection Infrastructure Of Ligo, Virgo, And Kagra: Data Products, Current Performance, And Future Developments, Sushant Sharma Chaudhary Jan 2025

The Real-Time Detection Infrastructure Of Ligo, Virgo, And Kagra: Data Products, Current Performance, And Future Developments, Sushant Sharma Chaudhary

Doctoral Dissertations

The discovery of the binary neutron star merger event GW170817 marked the dawn of Multi-Messenger Astronomy (MMA) with Gravitational Waves (GWs). Such multi-messenger events are of immense scientific interest due to the wealth of information they provide through joint observations across different messengers. In this rapidly evolving field, prompt identification and timely distribution of alerts is critical for follow-up observations.

This work offers a comprehensive overview of the LIGO-Virgo-KAGRA (LVK) Collaboration’s low-latency analysis pipeline for GW events, covering key stages from calibration and data analysis to the issuance of public alerts. I examine the latency and accuracy of each stage …


The Structure, Properties And Dissolution Behaviors Of Phosphate Glasses, Han Zhang Jan 2025

The Structure, Properties And Dissolution Behaviors Of Phosphate Glasses, Han Zhang

Doctoral Dissertations

The poor chemical durability remains a critical challenge for the application of phosphate glasses. This study investigates the compositional influences on the structure, properties and chemical durability of Li2O-ZnO-P2O5 glasses. Their structural characteristics were analyzed utilizing high-performance liquid chromatography, Raman spectroscopy, and X-ray photoelectron spectroscopy. The incorporation of (Li2O+ZnO) in LZeq glasses depolymerizes the phosphate network. In LZ40P and LZ45P glasses, Li+ initially replaces Zn2+ associated with non-bridging oxygens (NBOs) in Q2 tetrahedra. Once the substitution in Q2 is complete, further Li⁺ incorporation leads to the replacement of Zn2+ in Q1 …


Design And Synthesis Of Organocatalyts For Efficient Decontamination Of Organophosphate-Based Nerve Agents And Pesticides, Emmanuel Kingsley Darkwah Jan 2025

Design And Synthesis Of Organocatalyts For Efficient Decontamination Of Organophosphate-Based Nerve Agents And Pesticides, Emmanuel Kingsley Darkwah

Doctoral Dissertations

Exposure to organophosphate-based nerve agents and pesticides poses significant health and security threats to civilians, soldiers, and first responders. Despite extensive efforts to develop chemical detoxification agents for use in topical applications on exposed skin surfaces and for intravenous injections, there remains an unmet need for effective, non-hazardous decontaminating agents. The current state-of-the-art decontaminating agent, Dekon-139 (2,3-butanedione oxime, potassium salt), exhibits adverse effects when applied to the skin.

In this study, we designed and synthesized pharmaceutically relevant aminoguanidine-derived aldimines that are relatively non-toxic and substantially more effective at decontaminating nerve agents and pesticides compared to existing agents, and they act …


Optical Detection Of Instantaneous Microwave Frequency And Displacement, Behzad Boroomandisorkhabi Jan 2025

Optical Detection Of Instantaneous Microwave Frequency And Displacement, Behzad Boroomandisorkhabi

Doctoral Dissertations

Research presented in this research is focused on developing and implementing novel photonic systems for instantaneous microwave frequency and displacement measurement, emphasizing cost-effectiveness, scalability, and high resolution. The research is encapsulated in three core studies: the design of all-fiber ultrafast ranging Lidar for medical motion management, the application of dispersive interferometry using picosecond laser pulses for laser ranging, and the integration of microwave photonic systems with digital signal processing (DSP) for enhanced measurement precision.

The work achieves micrometer-scale displacement accuracy and microwave frequency resolutions within ±1 MHz across wide dynamic ranges by leveraging dispersive interferometry and time-stretch techniques. The studies …


Design Of Real-Time And Energy-Efficient Driver Assist Systems Using Electroencephalogram And Neuromorphic Computing, Nathan Alan Lutes Jan 2025

Design Of Real-Time And Energy-Efficient Driver Assist Systems Using Electroencephalogram And Neuromorphic Computing, Nathan Alan Lutes

Doctoral Dissertations

Despite the technological breakthroughs in advanced driver assist systems, distracted driving persists as a major challenge to roadway safety. This investigation advances the body of knowledge towards a solution by developing an individualized driver-state detection method using electroencephalogram (EEG) and neuromorphic computing to provide a less invasive and more energy efficient ADAS solution. It furthermore explores the changes in brain functional connectivity under distracted conditions to better understand brain state information that could be used for neuro-feedback intervention systems. The first contribution introduces the concept of using Convolutional Spiking Neural Networks (CSNNs) for recognition of patterns with movement-intention predictive power …


Assessing And Comparing Geophysical Methods For Resolving Shallow Subsurface Geology, Abdullah Basaloom Jan 2025

Assessing And Comparing Geophysical Methods For Resolving Shallow Subsurface Geology, Abdullah Basaloom

Doctoral Dissertations

Geophysical methods are essential tools for investigating shallow subsurface structures, offering non-invasive means to characterize geological features and detect anomalies. Techniques such as electrical resistivity tomography (ERT), towed Transient Electromagnetic (tTEM), seismic refraction, magnetic, gravity, and magnetotelluric (MT) are commonly employed to image subsurface conditions with high resolution.

This study started with an in-depth analysis of comparing results co-located in space to assess uncertainties and resolution in the obtained resistivity models in the Kansas River Alluvial Aquifer (KRAA). Our results provided a quantitative interpretation of resistivity estimates between different geo-electrical methods (ERT, tTEM and DPEC). Following this, we provided a …


Novel Nano-Formulations Based On Flash Nanoprecipitation For Ocular Drug Delivery, Lin Qi Jan 2025

Novel Nano-Formulations Based On Flash Nanoprecipitation For Ocular Drug Delivery, Lin Qi

Doctoral Dissertations

Effective ocular drug delivery has always been a challenge for clinical and research. Although many nanotechnology-based formulations have been developed and showed great potential in ocular drug delivery, this is far from enough to meet clinical requirements. These studies aimed at the design and synthesis of novel nanoparticles using multi-inlet vortex mixer (MIVM) to improve ocular drug delivery efficiency. The first project involves packaging two different anti-glaucoma drugs, brimonidine (BM) and betaxolol (BX), into solid drug nanoparticles (SDNs) by MIVM, which can achieve both functions, reducing aqueous humor production and promoting aqueous humor efflux. The studies demonstrate that the SDNs …


Topics On Ai Fairness Preferences In Kidney Transplantation, Mukund Telukunta Jan 2025

Topics On Ai Fairness Preferences In Kidney Transplantation, Mukund Telukunta

Doctoral Dissertations

Modern kidney transplantation incorporates artificial intelligence (AI) decision-support systems which exhibit social discrimination due to biases inherited from training data. Although researchers have proposed various group-based fairness notions to assess biases in AI, it remains uncertain which criterion is most suitable for evaluating biases in such complex healthcare systems. This dissertation explores human perception of fairness to identify the most appropriate fairness criterion for assessing AI tools in kidney transplantation, focusing on the preferences of non-expert (e.g. public, patients) stakeholders. The study examines two distinct AI systems employed in kidney transplantation: a classification model and a regression model. Human subject …


Higher-Order Statistics And Normalized Decay Analysis For Detector Deadtime Characterization, Abdallah Wazzan Jan 2025

Higher-Order Statistics And Normalized Decay Analysis For Detector Deadtime Characterization, Abdallah Wazzan

Doctoral Dissertations

Detector deadtime limits radiation measurement accuracy at high count rates, yet current methods rely on idealized paralyzable or non-paralyzable models. Real detectors exhibit hybrid behavior requiring advanced characterization approaches. This study explores deadtime characterization using two Monte Carlo simulation approaches: higher-order statistical analysis of inter-arrival times and simplified deadtime correction with hybrid models.

Using MATLAB (PULSE-WIZ), we analyzed full decay curves spanning ~4.5 half-lives of Cobalt-60 and Vanadium-52, examining coefficient of variation (CV), skewness, and kurtosis of inter-arrival times, plus normalized decay curves with Full Width at Half Maximum (FWHM) analysis. Hybrid models incorporated paralyzable and non-paralyzable components with dead …


Development, Characterization And Testing Of Traditonal And Advanced Nuclear Fuel Cladding Materials, Joshua Eddy Rittenhouse Jan 2025

Development, Characterization And Testing Of Traditonal And Advanced Nuclear Fuel Cladding Materials, Joshua Eddy Rittenhouse

Doctoral Dissertations

Kanthal D and FeCrAl alloys in general, are prospective candidates as accident tolerant nuclear fuel cladding materials. The work presented herein focuses on applying two techniques of severe plastic deformation, equal channel angular pressing (ECAP) and high-pressure torsion (HPT), as means of grain refinement to improve irradiation resistance. Samples of as-received, ECAP, and HPT processed Kanthal D were exposed to neutron irradiation to a dose of 2 DPA at two different temperatures, 300 °C and 500 °C. Detailed characterization was performed including mechanical and microstructural, and several positive improvements with regards to irradiation resistance were identified in the ECAP and …


Synthesis And Analysis Of Materials For Quantum Devices, Mathew Pollard Jan 2025

Synthesis And Analysis Of Materials For Quantum Devices, Mathew Pollard

Doctoral Dissertations

Quantum materials play a pivotal role in the advancement of next-generation technology. Superconducting quantum computing, dissipationless spintronics, or valleytronics offer promising ways forward beyond traditional chip miniaturization. Josephson Junctions (JJs) have already revolutionized quantum information and high precision detectors. Quantum systems, however, are either hard to control, produce, and/or maintain. This calls for a better understanding of microscopic properties and tuning of these quantum states.

In this work, we experimentally investigated growth methods to control the electric and magnetic properties of Topological Insulator (TI) Sb2Te3 through Cr-doping. Our results demonstrate the onset of a Magnetic Topological Insulator (MTI) and have …


Advancing Thermodynamic Modeling In Materials Design: From Phase Stability In Metallic Systems To Ferroelectric Property Prediction In Functional Oxide, Kyaw Hla Saing Chak Jan 2025

Advancing Thermodynamic Modeling In Materials Design: From Phase Stability In Metallic Systems To Ferroelectric Property Prediction In Functional Oxide, Kyaw Hla Saing Chak

Doctoral Dissertations

This dissertation advances the CALPHAD (CALculation of PHase Diagrams) approach for thermodynamic modeling which often lacks sufficient description of crystal lattices for critical phases in multicomponent system. Additionally, CALPHAD does not consider the structural features and its connection with functional properties for functional materials. To address these issues, a novel dual-ordered sublattice model for the κ-phase in Fe-Al-C system, (Fe,Al)3(Fe,Al)1(C,Va)1(C,Va)3, is introduced that improves predictions of equilibrium compositions and phase stability by accounting for both substitutional and interstitial ordering. For the Fe-B-C system, new sublattice formulations for FCC [(Fe)1(C,B,Va)1] and BCC [(Fe,B)1(C,B,Va)3], phases enhance boron solubility predictions and reveal insights …


Enhanced Optimization Of Mass Transfer For Carbon Capture And Wastewater Remediation In Algal Systems Through Algorithmic And Bioprocessing Techniques, Peter Ofuje Obidi Jan 2025

Enhanced Optimization Of Mass Transfer For Carbon Capture And Wastewater Remediation In Algal Systems Through Algorithmic And Bioprocessing Techniques, Peter Ofuje Obidi

Doctoral Dissertations

The scalability and industrial deployment of algal cultivation systems are limited by suboptimal mass transfer, constraining their effectiveness in carbon capture and wastewater remediation. This research investigated these challenges through integrated optimization methodologies that combine algorithmic frameworks with enhanced bioprocessing techniques to enhance efficiency, economy, and scalability. A System-of-Systems (SoS) meta-architecture was developed using genetic algorithms and fuzzy assessor functions to demonstrate a pathway toward cost reduction. Rigorous mechanical and chemical characterizations were quantitatively analyzed to reveal existing optimization strategies and further evaluated the best strategies to use in enhancing mass transfer for improved biomass yield. The work also integrates …