Digital Commons Network^™

Analyses Of Alternative Energy Deployments, Mathew Thomas

Doctoral Dissertations

"Energy use around the world is rising drastically. Fossil fuels, including liquid fuels, natural gas, and coal, are expected to supply 80% of the world's energy need in 2035. As a result, the world's energy-related carbon dioxide emission is expected to increase from 30.2 billion metric tons in 2008 to 43.2 billion metric tons in 2035. Significant steps are necessary to reduce the dependence on fossil fuel and to reduce greenhouse gas emissions. Renewable and alternative energy technologies can assist in reducing the use of fossil fuels and can reduce greenhouse gas emissions. However, most of the renewable energy technologies …

X-Ray Crystallography For The Study Of Nickel And Iron Salicylaldimines, Carla Schmiesing Eribal

Doctoral Dissertations

"X-ray diffraction of single crystals has developed dramatically over the last century by combining fundamental theories of light, diffraction, and statistics to generate the complete, geometric structure of molecules. The quality of the resulting X -ray structure data are reported in R₁ < 5%, wR2 < 12% and a goodness of fit value of one. This technique was applied specifically to the evaluation of the spin crossover (SCO) compound [Fe(salpm)₂]BF₄ʺ0.5EtOH and how the molecule's geometry changed during a two-step thermal LS-HS conversion. The crystal structure was measured at 100,175,225, and 296 K to yield final R₁ values of 0.047, 0.054, 0.051, and 0.058, respectively. The coordination bond lengths show the spin transitions occur between 100-175K at one crystallographically unique Fe and between 175-225K at the other Fe site. No strong long range interactions are found, suggesting a gradual spin transition. Reaction ofNi(Nalkyl-sal)₂ complexes with Ni(N0₃)₂ form either nickel dimeric, [Ni₃(Rsal)(N0₃)(MeOH)]₂ or trinuclear complexes, Ni₃(Rsal)₄(N0₃)₂. The binuclear complexes, with orthogonal bridging ligands, show overall ferromagnetic interactions. The crystal structures for Ni₃(Rsal)₄(N0₃)₂ from methyl to benzyl were solved and indicate no steric restriction on formation for the series. The trinuclear compounds form an isosceles triangle of metal atoms with the isopropyl analog showing an overall antiferromagnetic interaction with J=+11.386 and J23=-13.891. Lastly, xanthene spirolactam derivatives were structurally analyzed to determine binding modes for their selective and sensitive (µM) detection of metals Cr³⁺, Fe³⁺, Ni²⁺, Co²⁺ and the nerve gas mimic, dichlorophosphate"--Abstract, page iii.

Synthesis And Applications Of Imidazolium-Based Ionic Liquids And Their Polymer Derivatives, Woon Su Oh

Doctoral Dissertations

"Imidazolium-based ionic liquids have been increasingly used as green solvents to replace the volatile and relatively toxic organic solvents, in homogeneous and heterogeneous catalysis, materials science, nano materials, lithium ion batteries, and separation technology. Section 1 describes the modulating effect of the imidazolium based room temperature ionic liquids (RTILs) on the critical micelle concentrations (CMC) of surfactants. CMC of sodium dodecyl sulfate (SDS), an anionic surfactant, has been investigated in aqueous solutions of a variety of room temperature ionic liquids (RTILs). CMC values decrease with increasing alkyl chain-length and with fluorinated side chains on the imidazole moiety. In section 2, …

Glycerin Reformation In High Temperature And Pressure Water, Jason W. Picou

Doctoral Dissertations

"The noncatalytic reformation of glycerin in supercritical water was studied in a Haynes 282 tubular reactor. In order to determine which parameters were the most influential, a 2³ experimental matrix was conducted, with temperatures of 500 and 700⁰C, water/glycerin molar ratios of 3:1 and 13:1, and residence times of 30 and 90 seconds, all at a pressure of 24 MPa. It was found that temperature had the largest effect on the two gasification parameters deemed most important, gasification percentage and hydrogen yield. Based on this, the effect of temperature was further investigated by looking at 5⁰C intervals from 500 to …

Organoclay Dispersion In Linear Low-Density Polyethylene And Maleated Linear Low-Density Polyethylene Via Supercritical Carbon Dioxide Processing, Matthew J. Factor

Doctoral Dissertations

"Research into polymer-clay nanocomposites (PCN's) has been ongoing for decades as a result of the property enhancements offered by clay. To fully exploit these property enhancements, organically modified clays (organoclays) are utilized to promote clay delamination by reducing the disparity between the hydrophilicity of the clay and the hydrophobicity of the highly used polyolefin polymer. Since the organic modification of organoclays can degrade at temperatures typical to many polymers during melt-mix processing, this work utilizes the low-temperature processing fluid supercritical carbon dioxide (scCO₂) to disperse an organoclay into the highly used polymer LLDPE and ascertains the associated processing conditions for …

Characterization Of Wave Transport In Non-Conservative Media With Random And Correlated Disorder, Benjamin Henry Payne

Doctoral Dissertations

"Passive quasi-one-dimensional random media exhibit one of the three regimes of transport - ballistic, diffusive, or Anderson localization - depending on system size. The ballistic and diffusion approximations assumes particle transport, whereas Anderson Localization occurs when wave self-interference effects are dominant. When the system contains absorption or gain, then how the regimes can be characterized becomes unclear. By investigating theoretically and numerically the ratio of transmission to energy in a random medium in one dimension, we show this parameter can be used to characterize localization in random media with gain. Non-conservative media implies a second dimension for the transport parameter …

Updated Eor Screening Criteria And Modeling The Impacts Of Water Salinity Changes On Oil Recovery, Ahmad Aladasani

Doctoral Dissertations

"Developing technologies for enhanced oil recovery (EOR) from existing oil fields would supply the world's energy needs for several decades. The application of EOR in many major oil-producing countries remains in its conceptual stage. Thermal and gas EOR methods achieve high incremental rates; however, their application range has not broadened significantly as they have matured, while the rate at which new, promising EOR methods such as Low-salinity water flooding (LSWF) are being implemented is alarming. Despite, the potential of LSWF its development and application has been hindered by the lack of consensus concerning its recovery mechanism(s). Every oil reservoir has …

Dynamic Decision Making Under Uncertainty In Renewable Energy Portfolio Management And Inventory Management, Jianjun Deng

Doctoral Dissertations

"It is challenging and important for a firm to make effective decisions under uncertainties, such as random fluctuations of products prices or demands, etc. This dissertation formulates mathematic models to help decision makers in energy and retail industries make optimal timing and optimal operational decisions when facing uncertain electricity prices and demands. As for energy portfolio management, the optimal entry and dispatch strategies are investigated for an electricity generating firm to introduce a renewable power plant as an alternative method for generating electricity, with or without construction delay. In addition, the abandonment strategies of considering shutting down one of the …

Evolutionary Computing Driven Search Based Software Testing And Correction, Joshua Lee Wilkerson

Doctoral Dissertations

"For a given program, testing, locating the errors identified, and correcting those errors is a critical, yet expensive process. The field of Search Based Software Engineering (SBSE) addresses these phases by formulating them as search problems. This dissertation addresses these challenging problems through the use of two complimentary evolutionary computing based systems. The first one is the Fitness Guided Fault Localization (FGFL) system, which novelly uses a specification based fitness function to perform fault localization. The second is the Coevolutionary Automated Software Correction (CASC) system, which employs a variety of evolutionary computing techniques to perform testing, correction, and verification of …

Periodic Q-Difference Equations, Rotchana Chieochan

Doctoral Dissertations

"The concept of periodic functions defined on the real numbers or on the integers is a classical topic and has been studied intensively, yielding numerous applications in every kind of science. It is of importance that the real numbers and the integers are closed with respect to addition. However, for a number q > 1, the so-called q-time scale, i.e., the set of nonnegative integer powers of q, is not closed with respect to addition, and therefore it was not possible to define periodic functions on the q-time scale in an obvious way. In this thesis, this important open problem has …

A Progressive Collapse Evaluation Of Steel Structures In High Temperature Environment With Optical Fiber Sensors, Ying Huang

Doctoral Dissertations

"In the process of a progressive failure of steel structures in a post-earthquake fire, real-time assessment and prediction of structural behaviors are of paramount significance to an emergency evacuation and rescue effort. However, existing measurement technologies cannot provide the needed critical data such as large strains at high temperature. To bridge this gap, a novel optical fiber sensor network and an adaptive multi-scale finite element model (FEM) are proposed and developed in this study. The sensor network consists of long period fiber gratings (LPFG) sensors and extrinsic Fabry-Perot interferometer (EFPI) sensors or their integration. Each sensor is designed with a …

Complex Oxides As Novel Transparent Conductors, Altynbek Murat

Doctoral Dissertations

"Ab-initio density functional approach is employed to investigate the structural, optical, and electronic properties of twelve undoped (non)stoichiometric multicomponent oxides with layered structure RAMO₄ [R³⁺ =In or Sc, A³⁺ =Al or Ga, and M²⁺ - Ca, Cd, Mg, or Zn], as candidates for novel transparent conducting oxides. The compositional complexity of RAMO₄ leads to a wide range of band gaps varying from 2.45eV for InGaCdO₄ to 6.29 eV for ScAlMgO₄. We find that despite the different band gaps in the constituent binary oxides, namely, 2-4 eV in CdO, In₂O₃, or AnO; 5-6 eV for Ga₂O₃ or Sc₂O₃; and 7-9 eV …

The Pricing Of Multiple Exercisable American-Style Real Options, Yu Meng

Doctoral Dissertations

"Real options embedded in a project provide management with the flexibility to alter initial investment decisions, thus making them a practical tool for project planning and budgeting. Additional values are contributed to the underlying project due to the flexibilities that are provided by real options. This dissertation presents two models for pricing multiple exercisable American real options, one that employs the binomial tree method and the other one that employs the finite difference method. Different examples of multiple exercisable real options are discussed to demonstrate the two pricing models. Interactions between options and reality constraints are also considered. These two …

Surface Expressions Of Discontinuities, And The Estimation Of Their 3-D Orientations Using Combined Lidar And Optical Imaging, James Nii Aboh Otoo

Doctoral Dissertations

"The importance of the collection and analysis of data on discontinuities cannot be overemphasized. Problems which include sampling difficulties, risks, limited access to rock faces and exposures, and the delay in data collection has led to a high need for data collection tools and analysis techniques that can overcome these problems.

Discontinuities manifest themselves as either traces or as facets. Traces are linear features that intersect with both the discontinuity and the rock cut. Facets are the actual discontinuity surfaces that are exposed in the rock cut. Facets can be natural or induced. Identifying a facet as either natural or …

Lyapunov Based Optimal Control Of A Class Of Nonlinear Systems, Hassan Zargarzadeh

Doctoral Dissertations

"Optimal control of nonlinear systems is in fact difficult since it requires the solution to the Hamilton-Jacobi-Bellman (HJB) equation which has no closed-form solution. In contrast to offline and/or online iterative schemes for optimal control, this dissertation in the form of five papers focuses on the design of iteration free, online optimal adaptive controllers for nonlinear discrete and continuous-time systems whose dynamics are completely or partially unknown even when the states not measurable. Thus, in Paper I, motivated by homogeneous charge compression ignition (HCCI) engine dynamics, a neural network-based infinite horizon robust optimal controller is introduced for uncertain nonaffine nonlinear …

Organic And Composite Aerogels Through Ring Opening Metathesis Polymerization (Romp), Dhairyashil Mohite

Doctoral Dissertations

"Aerogels are open-cell nanoporous materials, unique in terms of low density, low thermal conductivity, low dielectric constants and high acoustic attenuation. Those exceptional properties stem from their complex hierarchical solid framework (agglomerates of porous, fractal secondary nanoparticles), but they also come at a cost: low mechanical strength. This issue has been resolved by crosslinking silica aerogels with organic polymers. The crosslinking polymer has been assumed to form a conformal coating on the surface of the skeletal framework by covalent bridging elementary building blocks. However, "assuming" is not enough: for correlating nanostructure with bulk material properties, it is important to know …

A Socio-Technical Analysis Of Widespread Electric Vehicle Adoption, Onanwa Nneka Egbue

Doctoral Dissertations

A combination of high fuel costs, concerns about petroleum availability, and environmental issues associated with conventional vehicles powered by fossil fuels are driving interests in electric vehicles (EVs). Large-scale deployment of EVs can play a significant role in addressing some of these problems. In spite of the benefits of EVs, several obstacles need to be overcome before EVs will be widely adopted. This research focuses on two socio-technical issues that affect widespread adoption and sustainability of EVs, consumer attitudes and perceptions, and supply chain risks of raw materials for EV battery technology. A major barrier is that consumers tend to …

A Monte Carlo Study Of The Scaling Of Nucleation Rates In A Lennard-Jones System, Mark Allan Thomason

Doctoral Dissertations

Temperature scaling of the homogenous vapor-to-liquid nucleation rate, J, is examined in a model Lennard-Jones (LJ) system. The model uses the Bennett Metropolis Monte Carlo technique to determine small cluster growth/decay rate constant ratios ß_n-1|α_n at four temperatures (T = 40, 50, 60, and 83.6K) below the argon Lennard-Jones critical temperature, T_c. The ß_n-1|α_n for clusters ranging in size from n = 2 to n = 192 LJ particles are applied to a kinetic steady-state nucleation rate formalism and nucleation rates are determined at the same four temperatures. When these rates are …

Measuring The Orientations Of Hidden Subvertical Joints In Highways Rock Cuts Using Ground Penetrating Radar In Combination With Lidar, Adnan Mohammed Aqeel

Doctoral Dissertations

"Mapping discontinuities in rock cuts and measuring their orientations is crucial in assessing the stability of rock masses. This can be done usually using manual methods such as scanline or advanced techniques such as LIDAR. However, these methods are used only to map exposed discontinuities which may cause underestimation for slope stability. Accordingly, ground penetrating radar (GPR) has been recently used to detect such hidden discontinuities.

The used 400 MHz monostatic GPR antenna was significantly able to detect and map hidden subvertical joints within 4 m depths in five sandstone highways rock cuts and within 3 m depths in two …

Chelating Compounds As Potential Flash Rust Inhibitors And Melamine & Aziridine Cure Of Acrylic Colloidal Unimolecular Polymers (Cups), Jigar K. Mistry

Doctoral Dissertations

Waterborne coatings on ferrous substrates usually show flash rusting which decreases the adhesion of the coating and the corrosion products can form a stain. Chelating compounds were investigated as potential flash rust inhibitors. Compounds being evaluated include amine alcohols, diamines and sulfur containing amines. A new corrosion inhibitor 2,5-bis(thioaceticacid)-1,3,4-thiadiazole (H2ADTZ) was synthesized and its performance characteristics were evaluated. It was noted that the observed structure of 1,3,4-thiadiazolidine-2,5-dithione (also known as 2,5-dimercapto-1,3,4-thiadiazole (DMTD or DMcT)) has been previously reported in three different tautomeric forms including -dithiol and -dithione. The relative stability of each form as well as the synthesis and characterization …

Complex Scaling Behavior In Animal Foraging Patterns, Prabhavi Kaushalya Premachandra

Doctoral Dissertations

This dissertation attempts to answer questions from two different areas of biology, ecology and neuroscience, using physics-based techniques. In Section 2, suitability of three competing random walk models is tested to describe the emergent movement patterns of two species of primates. The truncated power law (power law with exponential cut off) is the most suitable random walk model that characterizes the emergent movement patterns of these primates. In Section 3, an agent-based model is used to simulate search behavior in different environments (landscapes) to investigate the impact of the resource landscape on the optimal foraging movement patterns of deterministic foragers. …

Addressing Control And Capacitor Voltage Regulation Challenges In Multilevel Power Electronic Converters, Hossein Sepahvand

Doctoral Dissertations

Multilevel power electronic converters are the current industry solutions for applications that demand medium voltage, reasonable efficiency, and high power quality. The proper operation of these types of power converters requires special control, modulation methods, and capacitor voltage regulation techniques. Both developing capacitor voltage regulation methods and addressing their associated issues with such fall within the primary focus of this dissertation. In this dissertation an investigation was conducted on the capacitor voltage regulation constraints in cascaded H-bridge multilevel converters with a staircase output voltage waveform. In the proposed method, the harmonic elimination technique is used to determine the switching angles. …

Characterization Of Soil Variability For Reliability-Based Design, Sitenikechukwu Onyejekwe

Doctoral Dissertations

"A very carefully planned Missouri-wide field exploration and laboratory investigation program, with a focus on fine-grained soils, was executed with the aim of characterizing the variability of geotechnical parameters statistically with a view to increasing the use of reliability-based design (RBD) among geotechnical engineers. Geotechnical parameters were characterized in terms of both their first and second statistical moments and their coefficient of variation (COV). Their probability distributions and their scale of fluctuation, θ, were also determined. Correlations between difficult-to-obtain parameters and more easily-obtained parameters were developed and the degree of fit of study data to published empirical correlations was investigated. …

Densification And Thermal Properties Of Zirconium Diboride Based Ceramics, Matthew Joseph Thompson

Doctoral Dissertations

"The research presented in this dissertation focuses on the processing and thermomechanical properties of ZrB₂ based ceramics. The overall goal was to improve the understanding of thermal and mechanical properties based on processing conditions and additives to ZrB₂. To achieve this, the relationships between the thermal and mechanical properties were analyzed for ZrB₂ ceramics that were densified by different methods, varying amounts of carbon, B₄C, or TiB₂ additions. Four main areas were investigated in this dissertation. The first showed that decreased processing times, regardless of densification method, improved mechanical strength to >500 MPa. This study also revealed that lower oxygen …

Free-Radical Maleation Of Poly(Butylene Adipate-Co-Terephthalate) In Supercritical Carbon Dioxide And Its Effect On The Percolation And Deformation Mechanism Of Layered Silicate Nanocomposites, Alexandria Niemoeller

Doctoral Dissertations

The utilization of compostable polymers such as poly(butylene adipate-co-terephthalate) (PBAT) in single-use packaging applications can mitigate the water, solvents, and energy required for processing plastic waste. PBAT exhibits exceptional elongational properties, but its moderate water vapor permeability and low tensile modulus limit the applications in which PBAT can be employed. In this work, PBAT nanocomposites were produced at various loadings of organically-modified montmorillonite. The secondary structure of nanoparticles formed within the PBAT matrix was evident in the terminal region of the linear viscoelastic response under oscillatory shear, and a percolation threshold was determined to occur at 3.88% clay by weight. …

Lifetime Prediction And Confidence Bounds In Accelerated Degradation Testing For Lognormal Response Distributions With An Arrhenius Rate Relationship, Steven Michael Alferink

Doctoral Dissertations

"Determining the lifetime of a product is an important component of quality assurance. Traditional life testing methods are infeasible for products that have been designed to have a very long lifetime because they require a lengthy testing period. An alternative method is accelerated degradation testing, where a response variable determining the usability of the product is measured over time under multiple accelerating stress levels. The resulting data are then used to predict the life distribution of the product under the design stress level. In this dissertation, several methods are proposed and studied for obtaining prediction bounds for the lifetime of …

Characterization Of Expanded Polystyrene (Eps) And Cohesive Soil Mixtures, Nicholas Thomas Rocco

Doctoral Dissertations

"Soils modified with expanded polystyrene (EPS) particulates could be used as lightweight fill in a variety of installations including slopes for improved stability, embankments over compressible soils, and to reduce earth pressures next to structures. The addition of low density EPS particulates into soil has a large effect on the mass and volumetric characteristics of these mixtures and their influence on mechanical properties is scarce in the literature. A laboratory characterization program using clay mixed with EPS particulates was conducted for different dosages of EPS. Soils were modified with up to 1.5% EPS by mass, which corresponds to approximately 45% …

An Improved Dipole-Moment Model Based On Near-Field Scanning For Characterizing Near-Field Coupling And Far-Field Radiation From An Ic, Zhenwei Yu

Doctoral Dissertations

"Radio Frequency Interference (RFI) problems are critical issues in wireless platform design. The accurate noise model of integrated circuits (ICs) is needed to help designers to diagnose and predict RFI problems. In this dissertation, an improved IC radiated emission model based on near-field measurements is proposed. The regularization technique and the truncated SVD method are employed together with the least square method to calculate the dipole moments from the near-field data. This dipole model has clear physical meaning: the electric and magnetic dipoles represent the voltage and the current in the circuit, respectively. One application of this dipole model is …

Thermal Properties Of Spinel Based Solid Solutions, Kelley R. Wilkerson

Doctoral Dissertations

"Solid solution formation in spinel based systems proved to be a viable approach to decreasing thermal conductivity. Samples with systematically varied additions of MgGa₂O₄ to MgAl₂O₄ were prepared and thermal diffusivity was measured using the laser ash technique. Additionally, heat capacity was measured using differential scanning calorimetry and modeled for the MgAl₂O₄-MgGa₂O₄ system. At 200⁰C thermal conductivity decreased 24% with a 5 mol% addition of MgGa₂O₄ to the system. The solid solution continued to decrease the thermal conductivity by 13% up to 1000⁰C with 5 mol% addition. The decrease in thermal conductivity ultimately resulted in a decrease in heat flux …

Nitrification Performance Of Activated Sludge Under Low Dissolved Oxygen Conditions, Guoqiang Liu

Doctoral Dissertations

"The combined effects of solids retention time (SRT) and dissolved oxygen (DO) concentration on nitrification, nitrifying bacterial communities, and aeration needs in the activated sludge process were studied. Nitrification was almost completed in the 10, 20, and 40-day SRT reactors with a minimum DO of 0.37, 0.25, and 0.16 mg/L, respectively. Under long-term low DO conditions, the endogenous decay of nitrifiers was slowed down and then nitirfier biomass concentration increased, thereby reducing the adverse effect of low DO on nitrification. Under long-term low DO conditions, the oxygen affinity of nitrite-oxidizing bacteria (NOB) increased significantly and as a result, NOB became …