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Functionally Graded Ti6sl4v And Inconel 625 By Laser Metal Deposition, Syamala Rani Pulugurtha

Doctoral Dissertations

"The objective of the current work was to fabricate a crack-free functionally graded Ti6Al4V and Inconel 625 thin wall structure by Laser Metal Deposition (LMD). One potential application for the current material system is the ability to fabricate a functionally graded alloy that can be used in a space heat exchanger. The two alloys, Inconel 625 and Ti6Al4V are currently used for aerospace applications. They were chosen as candidates for grading because functionally grading those combines the properties of high strength/weight ratio of Ti6Al4V and high temperature oxidation resistance of Inconel 625 into one multifunctional material for the end application. …

On Some Inferential Problems With Recurrent Event Models, Withanage Ajith Raveendra De Mel

Doctoral Dissertations

"Recurrent events (RE) occur in many disciplines, such as biomedical, engineering, actuarial science, sociology, economy to name a few. It is then important to develop dynamic models for their modeling and analysis. Of interest with data collected in a RE monitoring are inferential problems pertaining to the distribution function F of the time between occurrences, or that of the distribution function G of the monitoring window, and their functionals such as quantiles, mean. These problems include, but not limited to: estimating F parametrically or nonparametrically; goodness of fit tests on an hypothesized family of distributions; efficient of tests; regression-type models, …

Energy Efficient And Latency Aware Adaptive Compression In Wireless Sensor Networks, Thomas Mark Daniel Szalapski

Doctoral Dissertations

"Wireless sensor networks are composed of a few to several thousand sensors deployed over an area or on specific objects to sense data and report that data back to a sink either directly or through a series of hops across other sensor nodes. There are many applications for wireless sensor networks including environment monitoring, wildlife tracking, security, structural heath monitoring, troop tracking, and many others. The sensors communicate wirelessly and are typically very small in size and powered by batteries. Wireless sensor networks are thus often constrained in bandwidth, processor speed, and power. Also, many wireless sensor network applications have …

Radio Frequency Interference (Rfi) Modeling Of Complex Modules In Mobile Devices And System-Level Modeling For Transient Esd Simulation, Tianqi Li

Doctoral Dissertations

"The thesis is composed of three papers, which cover the systematic modeling of radio-frequency-interference (RFI) and electro-static-discharge (ESD) problems happened in mobile devices.

In the first paper, an averaging technique is developed, for phase resolved scanning over random fields generated by multiple uncorrelated stochastic sources. This method can separate the field contribution of each noise source and resulting field patterns as if the out-of-interest sources were turned off. The scanned data can be used for emission source localization, far-field pattern calculation and Huygens's box modeling.

In the second paper, using Huygens's Equivalent Theorem a systematic approach for the modeling of …

Seismic Repair Of Bridge Columns With Interlocking Spirals And Fractured Bars, Yang Yang

Doctoral Dissertations

"During earthquakes, reinforced concrete (RC) bridge columns may experience different levels of damage such as cracking, spalling, or crushing of concrete and yielding, buckling, or fracture of reinforcing bars. This study developed and assessed permanent and emergency methods to repair damaged bridge columns with fractured longitudinal reinforcement through experimental and modeling work. The permanent repair method involved replacement of the plastic hinge region by removal of spirals, replacement of longitudinal bar segments by mechanically splicing with new bars segments attached with mechanical couplers, replacement of concrete, and installation of an externally bonded carbon fiber reinforced polymer (CFRP) jacket. The emergency …

Degradable Nanocomposite Preformed Particle Gel For Chemical Enhanced Oil Recovery Applications, Paul Tongwa

Doctoral Dissertations

”This work presents two new materials that can be potentially used in conformance control to increase ultimate oil recovery from mature oilfields.

The first product is a degradable nanocomposite preformed particle gel for enhanced in-depth mobility control. Three different types of degradable nanocomposite preformed particle gels were synthesized. These three nanocomposite hydrogels were made using Laponite XLG, Calcium Montmorillonite, and Sodium Montmorillonite nanomaterials. It was observed that after degradation, Laponite XLG nanocomposite hydrogels had the highest post-degradation viscosity (4437 cp), followed by sodium nanocomposite hydrogels (129 cp), and lastly calcium nanocomposite hydrogels (75.5 cp). Thus, degradable Laponite XLG nanocomposite hydrogels …

Experimental And Computational Investigation Of Flow Of Pebbles In A Pebble Bed Nuclear Reactor, Vaibhav B. Khane

Doctoral Dissertations

"The Pebble Bed Reactor (PBR) is a 4th generation nuclear reactor which is conceptually similar to moving bed reactors used in the chemical and petrochemical industries. In a PBR core, nuclear fuel in the form of pebbles moves slowly under the influence of gravity. Due to the dynamic nature of the core, a thorough understanding about slow and dense granular flow of pebbles is required from both a reactor safety and performance evaluation point of view.

In this dissertation, a new integrated experimental and computational study of granular flow in a PBR has been performed. Continuous pebble re-circulation experimental set-up, …

Measurements And Transient Multistep Outflow Simulation Of Soil-Water Characteristic Curve For Soils Modified With Biopolymers, Xiaoyi Zhao

Masters Theses

"In recent decades, biopolymers have shown promising applications in soil modification due to its environmental friendly nature. Most of the studies, however, focused on mechanical properties at saturated or unsaturated conditions. The study on unsaturated soil behaviors under controlled pore air and pore water pressures were limited. Soil-water characteristic curve (SWCC), relating water content with matric suction is a key property to evaluate unsaturated soils. With SWCC, other soil properties, such as hydraulic conductivity and shear strength can be estimated. In this study, SWCC of sands modified with different biopolymers were measured with both Tempe cell and Fredlund SWCC device. …

M-Grid : A Distributed Framework For Multidimensional Indexing And Querying Of Location Based Big Data, Shashank Kumar

Masters Theses

"The widespread use of mobile devices and the real time availability of user-location information is facilitating the development of new personalized, location-based applications and services (LBSs). Such applications require multi-attribute query processing, handling of high access scalability, support for millions of users, real time querying capability and analysis of large volumes of data. Cloud computing aided a new generation of distributed databases commonly known as key-value stores. Key-value stores were designed to extract value from very large volumes of data while being highly available, fault-tolerant and scalable, hence providing much needed features to support LBSs. However complex queries on multidimensional …

Test Development To Determine The Feasibility Of Rubber Tractor Treads For Use As Blasting Mats, Matthew Kurtis Coy

Masters Theses

"The objective of this thesis was to determine if rubber tractor treads could be used as an alternative material for blasting mats. These treads are made from steel cable and vulcanized rubber and are very tough. However, once they reach the end of their life on mobile equipment, they are destined for a landfill, or dump site because they are too tough to recycle. A potential alternative use for them is as blasting mats.

An examination of existing mat designs was conducted to better understand the matting methods used by the blasting industry today, to learn from those designs allow …

Thermodynamics And Crystallography Of The Γ→Ε→Α' Transformation In Femnalsic Steels, Scott Thomas Pisarik

Masters Theses

"FeMnAlSiC steels which exhibit two-stage transformation induced plasticity (TRIP) behavior characterized by the γ→ε→α' dual stage martensitic transformation promise to take a leading role in the development of 3rd generation advanced high strength steels. The crystallographic orientation relationship of the γ→α' and γ→ε athermal martensitic transformations in these steels has been determined as the Kurdjumov-Sachs and the Shoji-Nishiyama, respectively. Six crystallographic variants of α-martensite consisting of three twin-related variant pairs were observed in ε- bands. A planar parallelism of {0001}ε || {110}α' and a directional relation of α' lying within 1⁰ of ε existed for these variants. Two regular solution …

Feasibility Study Of A Two-Fluid Small Modular Molten Salt Reactor With In Core Heat Removal Capability, Brandon James Lahmann

Masters Theses

"A feasibility study of a two-fluid small modular molten salt reactor (MSR) with in core heat removal was performed. The initial fuel block dimension for the configuration was based on the Fuji MSR. The fuel was a mixed fluoride salt of density 3.25 g/cc, composed of 71 LiF - 16 BeF₂ - 12 ThF₄- 1 ²³³UF₄ molar percentages. The coolant salt was Li₄(FLiBe) of density 1.94 g/cc. The work set out to establish whether or not such a reactor is thermodynamically feasible when optimized for various neutronics parameters. A Java based API was …

Microwave-Assisted Synthesis Of Pd Nanoparticles Supported On Fe 3o4, Co3o4, And Ni(Oh)2 Nanoplates And Catalysis Application For Co Oxidation, Hany A. Elazab, Sherif Moussa, B. Frank Gupton, M. Samy El-Shall

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this paper, we report a simple, versatile, and rapid method for the synthesis of Pd nanoparticle catalysts supported on Fe₃O₄, Co₃O₄, and Ni (OH)2 nanoplates via microwave irradiation. The important advantage of microwave dielectric heating over convective heating is that the reactants can be added at room temperature (or slightly higher temperatures) without the need for high-temperature injection. Furthermore, the method can be used to synthesize metal nanoparticle catalysts supported on metal oxide nanoparticles in one step. We also demonstrate that the catalyst-support interaction plays an important role in the low …

Aerogels As Diverse Nanomaterials, Abhishek N. Bang

Doctoral Dissertations

"Aerogels are 3-D light-weight nanoporous materials pursued for their low thermal conductivity, low dielectric constant and high acoustic attenuation. Those exceptional macroscopic properties of aerogels are dependent on the chemical nature of nanoparticles, complex hierarchical solid skeletal framework and porosity. Also, the free space can become host for functional guests such as pharmaceuticals. In chapter I, we investigated randomly mesoporous bio-compatible polymer-crosslinked dysprosia aerogels as drug delivery vehicles and demonstrated storage and release of drugs under physiological conditions. Comparative study with ordered and randomly mesoporous silica showed high drug uptake and slower release rate for random nanostructures (silica or dysprosia) …

Cerium-Based Conversion Coatings On Magnesium Alloys, Carlos E. Castaño

Doctoral Dissertations

"This research is primarily focused on gaining a better understanding of the deposition and corrosion behavior of cerium-based conversion coatings (CeCCs) on AZ31B and AZ91D Mg alloys. Deposition of homogenous and protective CeCCs was highly dependent on the surface preparation steps. The best results were obtained when Mg samples underwent grinding, acid cleaning, and alkaline cleaning processes. This reduced the number of active cathodic sites and promoted the formation of a protective Al-rich Mg oxide/hydroxide layer. Electrochemical properties of the CeCCs were also strongly correlated with morphological, microstructural, and chemical characteristics. Protective CeCCs were deposited on both AZ31 and AZ91 …

Preformed Particle Gel Transport Through Fractures, Hao Zhang

Doctoral Dissertations

"Polymer gel treatment is one of the most cost-effective methods to control water production in mature oil fields. The main objective of gel treatments is to reduce water or gas flow through high-permeability channels or fractures without damaging productive zones. Preformed particle gels (PPGs) have been applied for conformance control because they can overcome some potential drawbacks inherent in an in-situ gelation system.

In this study, lab experiments were performed to quantify PPG propagation through fractures and fracture-like channels by using screen models and open fracture models. The main findings in these experiments can guide the selection of best particle …

Manufacturing Of Vegetable Oils-Based Epoxy And Composites For Structural Applications, Rongpeng Wang

Doctoral Dissertations

"Epoxidized vegetable oil (EVO) is one of the largest industrial applications of vegetable oils (VOs) and is widely used as a plasticizer and as a synthetic intermediate for polyol or unsaturated polyester. However, the utility of EVO as monomer for high performance epoxy thermoset polymer is limited by its reactivity and by the resulting physical properties. Herein, VO-based epoxy monomers, i.e., glycidyl esters of epoxidized fatty acids derived from soybean oil (EGS) or linseed oil (EGL), have been synthesized and were benchmarked against commercial available diglycidyl ether of bisphenol A (DGEBA) and also epoxidized soybean oil (ESO) controls. EGS and …

Privacy And Trustworthiness Management In Moving Object Environments, Sashi Gurung

Doctoral Dissertations

"The use of location-based services (LBS) (e.g., Intel's Thing Finder) is expanding. Besides the traditional centralized location-based services, distributed ones are also emerging due to the development of Vehicular Ad-hoc Networks (VANETs), a dynamic network which allows vehicles to communicate with one another. Due to the nature of the need of tracking users' locations, LBS have raised increasing concerns on users' location privacy. Although many research has been carried out for users to submit their locations anonymously, the collected anonymous location data may still be mapped to individuals when the adversary has related background knowledge.

To improve location privacy, in …

The Effect Of Composition On The Viscosity, Crystallization And Dissolution Of Simple Borate Glasses And Compositional Design Of Borate Based Bioactive Glasses, Kathryn Lynn Goetschius

Doctoral Dissertations

"Borate glasses have recently been developed for a variety of medical applications, but much less is known about their structures and properties than more common silicate glasses. Melt properties and crystallization tendency for compositions in the Na₂O-CaO-B₂O₃ system were characterized using differential thermal analysis and viscosity measurements. Characteristic viscosity (isokom) temperatures varied with the ratio between the modifier content (Na₂O+CaO) and B₂O₃, particularly at lower temperatures, consistent with the changes in the relative concentrations of tetrahedral borons in the glass structure.

Similar glasses were used to study dissolution processes …

Local Liquid Velocity Measurement Of Trickle Bed Reactor Using Digitial Industrial X-Ray Radiography, Khairul Anuar Mohd Salleh

Doctoral Dissertations

"Trickle Bed Reactors (TBRs) are fixed beds of particles in which both liquid and gas flow concurrently downward. They are widely used to produce not only fuels but also lubrication products. The measurement and the knowledge of local liquid velocities (VLL) in TBRs is less which is essential for advancing the understanding of its hydrodynamics and for validation computational fluid dynamics (CFD). Therefore, this work focused on developing a new, non-invasive, statistically reliable technique that can be used to measure local liquid velocity (V_LL) in two-dimensions (2-D). This is performed by combining Digital Industrial X-ray Radiography (DIR) and …

First-Principles Investigations Of Iron-Based Alloys And Their Properties, Krista Renee Limmer

Doctoral Dissertations

"Fundamental understanding of the complex interactions governing structure-property relationships in iron-based alloys is necessary to advance ferrous metallurgy. Two key components of alloy design are carbide formation and stabilization and controlling the active deformation mechanism. Following a first-principles methodology, understanding on the electronic level of these components has been gained for predictive modeling of alloys.

Transition metal carbides have long played an important role in alloy design, though the complexity of their interactions with the ferrous matrix is not well understood. Bulk, surface, and interface properties of vanadium carbide, VC_x, were calculated to provide insight for the carbide …

Part I: In-Situ Fluorometric Quantification Of Microalgal Neutral Lipids Part Ii: Thermal Degradation Behavior Of Investment Casting Polymer Patterns, Hongfang Zhao

Doctoral Dissertations

"Research described in this dissertation covers two topics. Part-I is focused on in-situ determination of neutral lipid content of microalgae using a lipophilic fluorescent dye. The traditional Nile red stain-based method for detecting microalgal intracellular lipids is limited due to varying composition and thickness of rigid cell walls. In this study, the addition of dilute acid and heating of solution, were found to greatly enhance staining efficiency of Nile red for microalgal species evaluated. Oil-in-water (O/W) microemulsion stabilized by a non-ionic surfactant was employed as a pseudo-standard that mimics lipid-bearing microalgal cells suspended in water. The average neutral lipid contents …

Probabilistic Engineering Analysis And Design Under Time-Dependent Uncertainty, Zhen Hu

Doctoral Dissertations

"Time-dependent uncertainties, such as time-variant stochastic loadings and random deterioration of material properties, are inherent in engineering applications. Not considering these uncertainties in the design process may result in catastrophic failures after the designed products are put into operation. Although significant progress has been made in probabilistic engineering design, quantifying and mitigating the effects of time-dependent uncertainty is still challenging. This dissertation aims to help build high reliability into products under time-dependent uncertainty by addressing two research issues. The first one is to efficiently and accurately predict the time-dependent reliability while the second one is to effectively design the time-dependent …

Semantic Model And Updated Screening Criteria For Polymer Flooding, Laila Dao Saleh

Doctoral Dissertations

"Enhanced oil recovery (EOR) processes produce oil that conventional methods leave behind, where interfacial forces, heavy oil viscosity, and reservoir heterogeneity make it difficult to produce. Many EOR methods are available but usually cannot be used at the same time for a candidate reservoir. Therefore, it is important to select the most appropriate EOR process from among the possible techniques. EOR screening criteria have been created using EOR datasets and serve as the first step to compare the suitability of each technique for a specific reservoir. Most of these datasets are based on field data collected from EOR surveys published …

Sustainability Analysis In Integrated Inventory Control And Transportation Systems, Brian Joseph Schaefer

Doctoral Dissertations

"Due to the importance of costs as well as environmental effects of logistical activities throughout supply chains, such as inventory holding, freight transportation, and warehousing activities, this dissertation models and analyzes four integrated inventory control and transportation problems that account for economic and environmental aspects of a supply chain agents related decisions.

The first model presents an integrated inventory control and transportation problem in a single item deterministic demand setting. A supply chain agents inventory control and transportation mode selection problem is solved under carbon cap, carbon cap and trade, carbon cap and offset, and carbon tax regulations. The second …

Automated Classification Of Malignant Melanoma Based On Detection Of Atypical Pigment Network In Dermoscopy Images Of Skin Lesions, Nabin K. Mishra

Doctoral Dissertations

“Melanoma causes more deaths than any other form of skin cancer. Early melanoma detection is important to prevent progression to a more deadly stage. Automated computer-based identification of melanoma from dermoscopic images of skin lesions is the most efficient method in early diagnosis. An automated melanoma identification system must include multiple steps, involving lesion segmentation, feature extraction, feature combination and classification. In this research, a classifier-based approach for automatically selecting a lesion border mask for segmentation of dermoscopic skin lesion images is presented. A logistic regression based model selects a single lesion border mask from multiple border masks generated by …

A Unified Bond Theory, Probabilistic Meso-Scale Modeling, And Experimental Validation Of Deformed Steel Rebar In Normal Strength Concrete, Chenglin Wu

Doctoral Dissertations

"Bond between deformed rebar and concrete is affected by rebar deformation pattern, concrete properties, concrete confinement, and rebar-concrete interfacial properties. Two distinct groups of bond models were traditionally developed based on the dominant effects of concrete splitting and near-interface shear-off failures. Their accuracy highly depended upon the test data sets selected in analysis and calibration. In this study, a unified bond model is proposed and developed based on an analogy to the indentation problem around the rib front of deformed rebar. This mechanics-based model can take into account the combined effect of concrete splitting and interface shear-off failures, resulting in …

Biomineralization Of Carbonates In Modern Microbial Sediments And Its Implications For Co₂ Sequestration, Varun Gnanaprian Paul

Doctoral Dissertations

"Several bacterial species influence carbonate mineral precipitation by modifying pH, alkalinity, Ca²⁺ activity and by providing nucleation sites for mineralization. Two studies have been undertaken to explore microbial influence in the mineralization of carbonates. In the first study, the ability of sulfate-reducing bacteria (SRB) to induce carbonate mineralization was investigated as a means to enhance mineral sequestration of CO₂. Sulfate-reducing bacteria enriched from hypersaline Storr's Lake, The Bahamas; Lake Estancia, New Mexico; and Great Salt Plains Lake, Oklahoma, were tested in reactors under varying CO₂ concentrations. Carbonate mineral precipitation was achieved only in reactors with Lake Estancia SRB community and …

Energy Efficient Security And Privacy Management In Sensor Clouds, Vimal Kumar

Doctoral Dissertations

"Sensor Cloud is a new model of computing for Wireless Sensor Networks, which facilitates resource sharing and enables large scale sensor networks. A multi-user distributed system, however, where resources are shared, has inherent challenges in security and privacy. The data being generated by the wireless sensors in a sensor cloud need to be protected against adversaries, which may be outsiders as well as insiders. Similarly the code which is disseminated to the sensors by the sensor cloud needs to be protected against inside and outside adversaries. Moreover, since the wireless sensors cannot support complex, energy intensive measures, the security and …

Elevated Temperature Mechanical Properties Of Zirconium Diboride Based Ceramics, Eric W. Neuman

Doctoral Dissertations

"Research presented in this dissertation focused on the mechanical behavior of ZrB₂ based ceramic at elevated temperatures. Flexure strength, fracture toughness, and elastic modulus were measured at temperatures up to 2300ºC for three compositions: monolithic ZrB₂ (Z); ZrB₂ - 30 vol% SiC - 2 vol% B₄ C (ZS); and ZrB₂ - 10 vol% ZrC (ZC). In argon, Z, ZS, and ZC had strengths of 210 (at 2300ºC), 260 (at 2200ºC), and 295 MPa (at 2300ºC), the highest temperatures tested for each composition. Fractography was used extensively to characterize the strength limiting flaws as a function of temperature. Strength of ZS …