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Paleoseismic Evidence Of Directivity For The 1976 Mw 7.5 Motagua Earthquake, Guatemala, Jonathan Obrist-Farner, Jeremy Maurer, Derek Gibson, Trenton Mcenaney, Andreas Eckert, William F. Kenney, Jeffrey Beeson, Nigel Wattrus, Quin Stangeland, Fatima Reyes Sep 2025

Paleoseismic Evidence Of Directivity For The 1976 Mw 7.5 Motagua Earthquake, Guatemala, Jonathan Obrist-Farner, Jeremy Maurer, Derek Gibson, Trenton Mcenaney, Andreas Eckert, William F. Kenney, Jeffrey Beeson, Nigel Wattrus, Quin Stangeland, Fatima Reyes

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

On 4 February 1976, a Mw 7.5 earthquake along the Motagua fault, Guatemala, ruptured ∼230 km of the North American and Caribbean plate boundary. Today, the plate boundary remains poorly monitored, and the 1976 earthquake is still not fully understood. Here, we present seismic reflection profiles and radiometrically dated sediment core data from six lakes around the Motagua fault, together with reports of destruction and a quasi-dynamic rupture model, which show that the 1976 earthquake experienced strong directivity that impacted the distribution of shaking. The earthquake left behind a detailed record of event deposits (EDs) in five of the six …


Multiply Differential Study Of Detachment With Simultaneous Target Excitation In Anion-Atom Collisions, M. Schulz, F. Herrmann, W. Zhang, D. V. Chicharro, A. Dorn, M. Grieser, F. Grussie, H. Kreckel, O. Novotny, F. Trost, A. Wolf, T. Pfeifer, C. D. Schröter Sep 2025

Multiply Differential Study Of Detachment With Simultaneous Target Excitation In Anion-Atom Collisions, M. Schulz, F. Herrmann, W. Zhang, D. V. Chicharro, A. Dorn, M. Grieser, F. Grussie, H. Kreckel, O. Novotny, F. Trost, A. Wolf, T. Pfeifer, C. D. Schröter

Physics Faculty Research & Creative Works

We have measured momenta of electrons and recoil ions in triple coincidence with neutralized projectiles for slow collisions between various anions and target atoms. From the data we extracted triple differential momentum and angular distributions of electrons ejected in detachment, in detachment with simultaneous target ionization (DI), and in detachment with simultaneous target excitation (DE). The DI rates relative to the DE rates depend sensitively on the projectile speed and on the properties of the target.


Continuous Pump-Probe Experiment To Observe Zeeman Wave-Packet Dynamics, K. L. Romans, K. Foster, S. Majumdar, B. P. Acharya, O. Russ, A. H.N.C. De Silva, Daniel Fischer Sep 2025

Continuous Pump-Probe Experiment To Observe Zeeman Wave-Packet Dynamics, K. L. Romans, K. Foster, S. Majumdar, B. P. Acharya, O. Russ, A. H.N.C. De Silva, Daniel Fischer

Physics Faculty Research & Creative Works

In this work, we study the coherent dynamics of an atomic Zeeman wave packet using a continuous pump-probe scheme. A polarized Zeeman wave packet is created in laser-cooled lithium atoms via few-photon excitation by a femtosecond laser pulse, producing a state with a magnetic moment tilted relative to an external magnetic field. The subsequent Larmor precession of the atomic magnetic moment is probed via continuous ionization by an optical dipole trap (ODT) laser. The resulting ionization fragments—photoelectrons and photo ions—are detected in coincidence using a cold target recoil ion momentum spectrometer (COLTRIMS). While the ODT facilitates further cooling of the …


High-Capacity, Reversible, And Energy-Efficient Water Vapor Sorption By Hierarchical Micro-To-Macroporous Carbon Aerogels From Polybenzoxazine And Polybenzodiazine, Vaibhav A. Edlabadkar, Rushi U. Soni, Stephen Y. Owusu, A. B.M.Shaheen Ud Doulah, Nicholas Leventis, Chariklia Sotiriou-Leventis Sep 2025

High-Capacity, Reversible, And Energy-Efficient Water Vapor Sorption By Hierarchical Micro-To-Macroporous Carbon Aerogels From Polybenzoxazine And Polybenzodiazine, Vaibhav A. Edlabadkar, Rushi U. Soni, Stephen Y. Owusu, A. B.M.Shaheen Ud Doulah, Nicholas Leventis, Chariklia Sotiriou-Leventis

Chemistry Faculty Research & Creative Works

Quantitative, reversible water vapor sorption is in rising demand for applications ranging from home appliances to atmospheric water harvesting. However, most sorbents suffer from low water-uptake capacities, nonreusability, and especially high regeneration temperatures. This study addresses this challenge by introducing polybenzoxazine- (PBO) and polybenzodiazine-derived (PBDAZ) carbon aerogels as reversible high-capacity desiccants. PBO and PBDAZ aerogels were prepared from structurally related monomers via HCl-catalyzed ring opening polymerization. Both types of aerogels were first aromatized at 200–240 °C under air or O2 and then were carbonized at 800 °C under Ar. These as-prepared carbon aerogels were further etched at 1000 °C under …


Generalized Transversality Conditions For Fuzzy Quantum-Symmetric Variational Problems Via Granular Approach, Martin Bohner, Ewa Girejko, Agnieszka B. Malinowska, Linh Nguyen, Baruch Schneider, Tri Truong Sep 2025

Generalized Transversality Conditions For Fuzzy Quantum-Symmetric Variational Problems Via Granular Approach, Martin Bohner, Ewa Girejko, Agnieszka B. Malinowska, Linh Nguyen, Baruch Schneider, Tri Truong

Mathematics and Statistics Faculty Research & Creative Works

This paper investigates fuzzy q-symmetric variational problems with natural boundary conditions. Based on the relative distance measure fuzzy arithmetic and horizontal membership functions (HMFs), we propose novel concepts of differentiability and integrability for fuzzy functions on quantum geometric subsets of real numbers. Then, fundamental foundations of q-symmetric calculus of variations based on HMFs are provided. With the help of HMFs and granular q-symmetric differentiability, we derive necessary optimality conditions for fuzzy q-symmetric variational problems that depend on free endpoints. Moreover, sufficient conditions for minimizers of q-symmetric variational problems are obtained. Some numerical examples illustrating the proposed approach are presented.


Novel Statistical And Topological Data Analyses Of 2d Electronic Images, Robert L. Paige, Vic Patrangenaru Sep 2025

Novel Statistical And Topological Data Analyses Of 2d Electronic Images, Robert L. Paige, Vic Patrangenaru

Mathematics and Statistics Faculty Research & Creative Works

In this paper, novel statistical and topological data analyses of 2D images are developed. One considers methodologies based on the Region Covariance Descriptor (RCD) and Topological Data Analysis (TDA) rooted in the simplicial as well as cubical persistent homologies. These methods provide statistical methods for data from populations of complex data objects that are elements of non-Euclidean spaces. The 2D image data considered consist of pictures of two leaves—A and B—from the same tree, twenty of each leaf, from different perspectives. The novel statistical procedures developed are used for correctly determining that leaf A images and leaf B images are …


Greedy Algorithm For Neural Networks For Indefinite Elliptic Problems, Qingguo Hong, Jiwei Jia, Young Ju Lee, Ziqian Li Sep 2025

Greedy Algorithm For Neural Networks For Indefinite Elliptic Problems, Qingguo Hong, Jiwei Jia, Young Ju Lee, Ziqian Li

Mathematics and Statistics Faculty Research & Creative Works

The paper presents a priori error analysis of the shallow neural network approximation to the solution to the indefinite elliptic equation and a cutting-edge implementation of the Orthogonal Greedy Algorithm (OGA) tailored to overcome the challenges of indefinite elliptic problems, which is a domain where conventional approaches often struggle due to the lack of coerciveness. A rigorous priori error analysis that shows the neural network's ability to approximate the solution of indefinite problems is confirmed numerically by OGA. We also present the error analysis of the relevant numerical quadrature. In particular, massive numerical implementations are conducted to justify the theory, …


Preliminary Investigation Of The Potential Health Risks Of Non-Formfitting Body Armor With A Focus On Female Warfighters, Melissa Sutter, Catherine E. Johnson Sep 2025

Preliminary Investigation Of The Potential Health Risks Of Non-Formfitting Body Armor With A Focus On Female Warfighters, Melissa Sutter, Catherine E. Johnson

Mining Engineering Faculty Research & Creative Works

Introduction Body armor is an important piece of protective equipment for warfighters in battlefield environments. With more women now filling military roles, body armor designs may need to be further refined to accommodate the female anatomy instead of the male-based unisex designs. Unisex designs have been found to have negative effects on female warfighter performance, resulting in discomfort, breathing difficulty, and air gaps forming between the armor and torso. This study aimed to investigate increased injury risk because of air gaps from shock wave exposure on warfighters wearing nonform-fitting armor and the influence of material properties. Based on literature, lowered …


Physics-Based Machine Learning Framework For Predicting Structure-Property Relationships In Ded-Fabricated Low-Alloy Steels †, Atiqur Rahman, Md Hazrat Ali, Asad Waqar Malik, Muhammad Arif Mahmood, Frank Liou Sep 2025

Physics-Based Machine Learning Framework For Predicting Structure-Property Relationships In Ded-Fabricated Low-Alloy Steels †, Atiqur Rahman, Md Hazrat Ali, Asad Waqar Malik, Muhammad Arif Mahmood, Frank Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The Directed Energy Deposition (DED) process has demonstrated high efficiency in manufacturing steel parts with complex geometries and superior capabilities. Understanding the complex interplays of alloy compositions, cooling rates, grain sizes, thermal histories, and mechanical properties remains a significant challenge during DED processing. Interpretable and data-driven modeling has proven effective in tackling this challenge, as machine learning (ML) algorithms continue to advance in capturing complex property structural relationships. However, accurately predicting the prime mechanical properties, including ultimate tensile strength (UTS), yield strength (YS), and hardness value (HV), remains a challenging task due to the complex and non-linear relationships among process …


Ibi-Dt: A Novel Approach Combining Individualized Bayesian Inference And Decision Tree For Identifying Cancer Drivers And Their Interactions, Md Asad Rahman, Gregory F. Cooper, Jinying Zhao, Xinghua Lu, Jinling Liu Sep 2025

Ibi-Dt: A Novel Approach Combining Individualized Bayesian Inference And Decision Tree For Identifying Cancer Drivers And Their Interactions, Md Asad Rahman, Gregory F. Cooper, Jinying Zhao, Xinghua Lu, Jinling Liu

Engineering Management and Systems Engineering Faculty Research & Creative Works

Cancer is mainly caused by a relatively small portion of somatic genome alterations (SGAs), called cancer drivers. Despite success in identifying a good number of cancer drivers, many more remain to be discovered to explain various cancers. Moreover, limited tools are available to identify potential interactions among cancer drivers for a better understanding of oncogenesis. To tackle these challenges, we have developed a novel approach called individualized Bayesian inference using a decision tree (IBI-DT). IBI-DT recognizes the genetic heterogeneity among cancer patients, where different individuals or patient subgroups of distinct genomic makeup may have different drivers. IBI-DT works by constructing …


Synergetic Adsorptive Mechanisms, Reusability And Cost Evaluations Of Green Fabricated Hybrid Barium Cobalt Nanocomposites For Methylene Blue And Lead Removal From Wastewater, Titus Chinedu Egbosiuba, Chibuike Christogonus Njoku, Ijeoma Jacinta Ani, Godwin Ifeanyi Ogbuehi, Abdulkareem Omeiza Yusuf, Abiodun Azeez Saka, Ugochukwu Ewuzie, Ebuka Emmanuel Ezennajiego, Blessing Onyinye Okafor, Walter Chibuike Anene, Cecilia Chika Unegbu, Florence Acha, Monday Uchenna Okoronkwo Sep 2025

Synergetic Adsorptive Mechanisms, Reusability And Cost Evaluations Of Green Fabricated Hybrid Barium Cobalt Nanocomposites For Methylene Blue And Lead Removal From Wastewater, Titus Chinedu Egbosiuba, Chibuike Christogonus Njoku, Ijeoma Jacinta Ani, Godwin Ifeanyi Ogbuehi, Abdulkareem Omeiza Yusuf, Abiodun Azeez Saka, Ugochukwu Ewuzie, Ebuka Emmanuel Ezennajiego, Blessing Onyinye Okafor, Walter Chibuike Anene, Cecilia Chika Unegbu, Florence Acha, Monday Uchenna Okoronkwo

Chemical and Biochemical Engineering Faculty Research & Creative Works

Barium nanoparticles (BaNPs), cobalt nanoparticles (CoNPs), and hybrid barium-cobalt nanocomposites (BaCoNCs) were synthesized using an eco-friendly green technique with Anacardium occidentale leaf extract for sequestration of methylene blue (MB) dye and lead (Pb (II)) ions from industrial wastewater. The nanoparticles and nanocomposites were characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), high-resolution scanning electron microscopy (HRSEM), and Brunauer-Emmett-Teller (BET) analysis to assess their functional groups, crystalline structure, morphology, and surface properties, confirming successful synthesis. Batch adsorption studies showed that optimal pollutant removal occurred at pH values of 8 for MB and 5 for Pb(II), with a contact time …


Fractional Brownian Motion With Mean-Density Interaction: A Myopic Self-Avoiding Fractional Stochastic Process, Jonathan House, Rashad Bakhshizada, Skirmantas Janušonis, Ralf Metzler, Thomas Vojta Sep 2025

Fractional Brownian Motion With Mean-Density Interaction: A Myopic Self-Avoiding Fractional Stochastic Process, Jonathan House, Rashad Bakhshizada, Skirmantas Janušonis, Ralf Metzler, Thomas Vojta

Physics Faculty Research & Creative Works

Fractional Brownian motion is a Gaussian stochastic process with long-range correlations in time; it has been shown to be a useful model of anomalous diffusion. Here, we investigate the effects of mutual interactions in an ensemble of particles undergoing fractional Brownian motion. Specifically, we introduce a mean-density interaction in which each particle in the ensemble is coupled to the gradient of the total, time-integrated density produced by the entire ensemble. We report the results of extensive computer simulations for the mean-squared displacements and the probability densities of particles undergoing one-dimensional fractional Brownian motion with such a mean-density interaction. We find …


Assessing The Effectiveness Of Crawlers And Large Language Models In Detecting Adversarial Hidden Link Threats In Meta Computing, Junjie Xiong, Mingkui Wei, Zhuo Lu, Yao Liu Sep 2025

Assessing The Effectiveness Of Crawlers And Large Language Models In Detecting Adversarial Hidden Link Threats In Meta Computing, Junjie Xiong, Mingkui Wei, Zhuo Lu, Yao Liu

Computer Science Faculty Research & Creative Works

In the emerging field of Meta Computing, where data collection and integration are essential components, the threat of adversary hidden link attacks poses a significant challenge to web crawlers. In this paper, we investigate the influence of these attacks on data collection by web crawlers, which famously elude conventional detection techniques using large language models (LLMs). Empirically, we find some vulnerabilities in the current crawler mechanisms and large language model detection, especially in code inspection, and propose enhancements that will help mitigate these weaknesses. Our assessment of real-world web pages reveals the prevalence and impact of adversary hidden link attacks, …


Cysteine Oxidation Of A Redox Hub Within Complex I Can Facilitate Electron Transport Chain Supercomplex Formation, Runtai Chen, Seyed Amirhossein Tabatabaei Dakhili, Rokas Gerulskis, Yuan Yuan Zhao, Steven Lockhart, Lusine Tonoyan, Arno G. Siraki, Guocheng Huang, Adam Kinnaird, Darren H. Freed, Shelley D. Minteer, Evangelos D. Michelakis, John R. Ussher Sep 2025

Cysteine Oxidation Of A Redox Hub Within Complex I Can Facilitate Electron Transport Chain Supercomplex Formation, Runtai Chen, Seyed Amirhossein Tabatabaei Dakhili, Rokas Gerulskis, Yuan Yuan Zhao, Steven Lockhart, Lusine Tonoyan, Arno G. Siraki, Guocheng Huang, Adam Kinnaird, Darren H. Freed, Shelley D. Minteer, Evangelos D. Michelakis, John R. Ussher

Chemistry Faculty Research & Creative Works

The mitochondrial electron transport chain (ETC) is a four complex unit that could be considered the most essential infrastructure within the mitochondria, as it primarily functions to generate the mitochondrial membrane potential (ΔΨm), which can then be utilized for ATP synthesis or heat production. Another important aspect of ETC function is the generation of mitochondrial reactive oxygen species (mtROS), which are essential physiologic signaling mediators that can be toxic to the cell if their levels become too high. Currently, it remains unresolved how a highly utilized and functioning ETC can sense excessive mtROS generation and adapt, to enhance ΔΨm. Here, …


Short–Range Hard–Sphere Potential And Coulomb Interaction: Deser–Trueman Formula For Rydberg States Of Exotic Atomic Systems, Gregory S. Adkins, Ulrich D. Jentschura Sep 2025

Short–Range Hard–Sphere Potential And Coulomb Interaction: Deser–Trueman Formula For Rydberg States Of Exotic Atomic Systems, Gregory S. Adkins, Ulrich D. Jentschura

Physics Faculty Research & Creative Works

In exotic atomic systems with hadronic constituent particles, it is notoriously difficult to estimate the strong-interaction correction to energy levels. It is well known that, due to the strength of the nuclear interaction, the problem cannot be solved using Wigner–Brillouin perturbation theory alone. Recently, high-angular-momentum Rydberg states of exotic atomic systems with hadronic constituents have been identified as promising candidates in the search for new physics in the low-energy sector of the Standard Model. We thus derive a generalized Deser–Trueman formula for the induced energy shift for a general hydrogenic bound state with principal quantum number n and orbital angular …


Exploring The Adoption Of Construction Technologies In Infrastructure Projects: Bridging Perceptions Of Experts With Real Project Data, Fareed Salih, Islam H. El-Adaway Sep 2025

Exploring The Adoption Of Construction Technologies In Infrastructure Projects: Bridging Perceptions Of Experts With Real Project Data, Fareed Salih, Islam H. El-Adaway

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Infrastructure projects have progressively adopted construction technologies, yet previous studies have not fully explored technology utilization by comparing the perceptions of experts with actual project data. This research fills this knowledge gap. The authors (1) developed, distributed, and collected a survey completed by 52 construction practitioners to investigate the use of these technologies and their associated benefits; (2) checked the survey reliability and validity using Cronbach's alpha test; (3) investigated the perceptions of utilizing construction technologies across industry sectors; (4) explored the perceptions of benefits across industry sectors; (5) analyzed the impact of construction technologies on project objectives and phases …


Data-Driven Shear Capacity Prediction Of Studs Embedded In Uhpc For Steel-Uhpc Composite Structures, Yanping Zhu, Woubishet Zewdu Taffese, Genda Chen Sep 2025

Data-Driven Shear Capacity Prediction Of Studs Embedded In Uhpc For Steel-Uhpc Composite Structures, Yanping Zhu, Woubishet Zewdu Taffese, Genda Chen

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This study employs ensemble learning algorithms to accurately predict the shear capacity of studs embedded in ultrahigh performance concrete (UHPC), a critical aspect of structural engineering. Using a comprehensive data set featuring six UHPC slab features, seven stud features, and one shear pocket feature, 35 ensemble models are developed across five cases and seven algorithms (bagging, random forest, AdaBoost, gradient boosting, XGBoost, CatBoost, and LightGBM). The Shapley additive explanations (SHAP) analysis is conducted on the top-performing models to gain insights into their decision-making mechanisms. Results indicate that transforming UHPC slab geometry parameters into a volume, alongside different diameter ratios, proves …


Temporal Evolution Of Workforce Fatality-Linked Factors In The Transportation Construction Sector, Mariam Elazhary, Islam H. El-Adaway Sep 2025

Temporal Evolution Of Workforce Fatality-Linked Factors In The Transportation Construction Sector, Mariam Elazhary, Islam H. El-Adaway

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Despite advancements in safety measures, fatalities in the transportation sector remain disproportionately higher than in other industries. Transportation sector fatalities arise from a combination of demographic, environmental, and occupational factors that amplify the overall risk. While strides have been made in understanding the factors contributing to fatalities, there remains a critical gap in research focused on their temporal evolution. The goal of this study is to investigate the temporal evolution of fatality-linked association factors in the transportation construction sector. The methodology encompassed three stages. Stage 1 was preprocessing the data: the US Census of Fatal Occupational Injuries, covering 3,792 fatality …


Failure Analysis Of Prestressed Concrete Girder Bridges Under Over-Height Truck Impacts, Mohamed T. Elshazli, Mohamed Elgawady, Tao Xing, Ahmed Ibrahim Sep 2025

Failure Analysis Of Prestressed Concrete Girder Bridges Under Over-Height Truck Impacts, Mohamed T. Elshazli, Mohamed Elgawady, Tao Xing, Ahmed Ibrahim

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Accidental collisions between over-height trucks and bridge superstructures are a common threat to existing bridge infrastructure. These incidents often stem from illegal over-height vehicles or truck operators' unawareness of clearance limits, posing serious safety risks and causing substantial structural damage. This study presents a comprehensive numerical investigation of the dynamic response of prestressed concrete girder bridges subjected to over-height truck impacts. Large-scale finite element models were developed in LS-DYNA, with validation conducted against experimental results. The parametric study explored impact speeds ranging from 16 to 113 km/h (10 to 70 mph), impactor masses between 2 and 6 tons, impact locations, …


Mantle Flow And Fault Zone Related Seismic Anisotropy Revealed By A Dense Linear Broadband Array In Southeast Tibet, Jing Wu, Yinshuang Ai, Stephen S. Gao, Peixi Huang, Fansheng Kong, Deke Xu, Jianguo Song, Xinyu Gao, Mengyi Wei, Long Li, Jien Zhang, Yanbin Zhang, Yingying Zhang Aug 2025

Mantle Flow And Fault Zone Related Seismic Anisotropy Revealed By A Dense Linear Broadband Array In Southeast Tibet, Jing Wu, Yinshuang Ai, Stephen S. Gao, Peixi Huang, Fansheng Kong, Deke Xu, Jianguo Song, Xinyu Gao, Mengyi Wei, Long Li, Jien Zhang, Yanbin Zhang, Yingying Zhang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Southeast Tibet, a key region for the southeastward extrusion of the Tibetan Plateau, remains debated in terms of its tectonic deformation in response to the ongoing collision between the Indian and Eurasian plates. In this study, we applied shear-wave splitting analysis of core-refracted phases recorded by a newly deployed dense seismic array and six permanent stations to delineate crustal and mantle deformation processes. The observed fast polarization directions are predominantly aligned NNW–SSE, while the splitting delay times vary across four sub-blocks. The anisotropy pattern suggests a dominantly asthenospheric origin, consistent with southeastward-directed mantle flow associated with the extrusion of the …


Dissolution Mechanism Of Nonionic Polyether Surfactants In Supercritical Co2, Ning Xu, Yanling Wang, Baojun Bai, Shizhang Cui, Zan Gao, Yu Zhang, Di Li, Wenjing Shi, Wenhui Ding, Peixu Ma Aug 2025

Dissolution Mechanism Of Nonionic Polyether Surfactants In Supercritical Co2, Ning Xu, Yanling Wang, Baojun Bai, Shizhang Cui, Zan Gao, Yu Zhang, Di Li, Wenjing Shi, Wenhui Ding, Peixu Ma

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Polyoxyethylene ether is an efficient CO2-philic compound with significant potential applications in CO2 flooding, which requires CO2-philic surfactants with high solubility in supercritical CO2 (scCO2). This study elucidates the molecular and atomic-level dissolution mechanism of the fatty alcohol polyoxyethylene ether (AEO) in scCO2 by combining phase-behavior experiments and molecular dynamics simulations. The solubility of AEO in scCO2 is measured using a semiconductor laser. AEO containing three polyoxyethylene (EO) groups exhibited the highest solubility in scCO2.The solubility of AEO in scCO2 decreased with an increase in the number …


Efficient Decontamination Of Organophosphate-Based Pesticides And Nerve Agent Simulants Mediated By N-Containing Nucleophiles, Emmanuel Kingsley Darkwah, Puspa Aryal, Saidulu Todeti, Jared Kenik, Samuel Insall, V. Prakash Reddy, Chariklia Sotiriou-Leventis Aug 2025

Efficient Decontamination Of Organophosphate-Based Pesticides And Nerve Agent Simulants Mediated By N-Containing Nucleophiles, Emmanuel Kingsley Darkwah, Puspa Aryal, Saidulu Todeti, Jared Kenik, Samuel Insall, V. Prakash Reddy, Chariklia Sotiriou-Leventis

Chemistry Faculty Research & Creative Works

There is a growing interest in developing safer and more effective decontaminating agents for organophosphate-based pesticides and nerve agents. In this study, we present an effective method for the nonaqueous decontamination of these compounds using small-molecule-based decontaminating agents under ambient conditions. Our approach utilizes aryl and heteroaryl carboxaldehyde hydrazones and hydrazides to effectively hydrolyze nerve agent simulants into their nontoxic degradation products. The effectiveness of this method was evaluated using a range of nerve agent simulants, including dimethyl 4-nitrophenyl phosphate (DMNP), dimethyl methyl phosphonate (DMMP), and triphenyl phosphate (TPhP). In the presence of the heteroaryl hydrazone, the rate of hydrolysis …


Evaluating The Toxicity Of Electronic Cigarette Aerosols For Firsthand And Secondhand Exposure Under Different Device Operating Conditions, Kashala Fabrice Kapiamba, Hsin Yin Chuang, Weixing Hao, Ta Chun Lin, Lung Chi Chen, Yue-Wern Huang, Yang Wang Aug 2025

Evaluating The Toxicity Of Electronic Cigarette Aerosols For Firsthand And Secondhand Exposure Under Different Device Operating Conditions, Kashala Fabrice Kapiamba, Hsin Yin Chuang, Weixing Hao, Ta Chun Lin, Lung Chi Chen, Yue-Wern Huang, Yang Wang

Biological Sciences Faculty Research & Creative Works

The rapid proliferation of electronic cigarettes (ECs) has raised significant concerns about their potential health effects on both users and bystanders. This study systematically investigates the impact of EC aerosol exposure on human alveolar epithelial cells (A549), considering variations in device parameters, nicotine concentration, and exposure type. Using a gravity-based air–liquid interface exposure system, we assessed cytotoxicity and epithelial barrier integrity by measuring cell viability and transepithelial electrical resistance (TEER). Our results indicate that EC aerosol exposure significantly reduces cell viability and disrupts monolayer integrity in a dose- and device-dependent manner. Notably, VUSE (pod-type) exposure led to a 16% decrease …


The Implications Of Insecure Use Of Fonts Against Pdf Documents And Web Pages, Junjie Xiong, Mingkui Wei, Xiao Han, Zhuo Lu, Yao Liu Aug 2025

The Implications Of Insecure Use Of Fonts Against Pdf Documents And Web Pages, Junjie Xiong, Mingkui Wei, Xiao Han, Zhuo Lu, Yao Liu

Computer Science Faculty Research & Creative Works

This paper identifies the importance of the safe use of fonts in web and document security. We find multiple attack surfaces that can be exploited by an adversary using malicious fonts. We conduct a comprehensive evaluation of Portable Document Format (PDF) documents collected from the real world to investigate how an attacker can bypass PDF signatures. We further evaluate the potential security threats that an attacker can bring to web-based emails. Our study shows that various security issues may be caused by the inappropriate use of fonts, which are nevertheless overlooked in the past years. As such, guidelines promoting the …


Receiver Function Imaging Of The Mantle Transition Zone Beneath The East Sayan Mountains And Adjacent Area In Central Asia: Implications For Lithospheric Drip And Intraplate Cenozoic Volcanism, Yangyang Liao, Kelly H. Liu, Stephen S. Gao Aug 2025

Receiver Function Imaging Of The Mantle Transition Zone Beneath The East Sayan Mountains And Adjacent Area In Central Asia: Implications For Lithospheric Drip And Intraplate Cenozoic Volcanism, Yangyang Liao, Kelly H. Liu, Stephen S. Gao

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To provide constraints on the formation mechanisms of intracontinental volcanisms and intriguing lithospheric thickness variations in the East Sayan Mountains and surrounding areas, we stack P-to-s receiver functions to image the 410-km and 660-km discontinuities. Mantle transition zone (MTZ) thickening observed in a continuous area is attributable to ancient slab remnants, and Cenozoic volcanisms in the peripheral area can be explained by slab dehydration. The thinning of the MTZ in the Tuva-Mongolian Massif can be explained by mantle upwelling branches induced by slab subduction. Our results reveal an approximately circular area in the MTZ that is significantly thicker than usual, …


Collapse Of A Quantum Vortex In An Attractive Two-Dimensional Bose Gas, Sambit Banerjee, Kai Zhou, Shiva Kant Tiwari, Hikaru Tamura, Rongjie Li, Panayotis Kevrekidis, Simeon I. Mistakidis, Valentin Walther, Chen Lung Hung Aug 2025

Collapse Of A Quantum Vortex In An Attractive Two-Dimensional Bose Gas, Sambit Banerjee, Kai Zhou, Shiva Kant Tiwari, Hikaru Tamura, Rongjie Li, Panayotis Kevrekidis, Simeon I. Mistakidis, Valentin Walther, Chen Lung Hung

Physics Faculty Research & Creative Works

We experimentally and numerically study the collapse dynamics of a quantum vortex in a two-dimensional atomic superfluid following a fast interaction ramp from repulsion to attraction. We find the conditions and timescales for a superfluid vortex to radially converge into a quasi-stationary density profile, demonstrating the spontaneous formation of a vortex soliton like structure in an atomic Bose gas. We record an emergent self-similar dynamic caused by an azimuthal modulational instability, which amplifies initial density perturbations and leads to the eventual splitting of a solitonic ring profile or direct fragmentation of a superfluid into disordered, but roughly circular arrays of …


Effects Of Spent Coffee Grounds On Improvement Of Resistive Switching Characteristics In Natural Rubber-Based Memory, Muhammad Awais, Nadras Othman, Mohamad Danial Shafiq, Feng Zhao, Kuan Yew Cheong Aug 2025

Effects Of Spent Coffee Grounds On Improvement Of Resistive Switching Characteristics In Natural Rubber-Based Memory, Muhammad Awais, Nadras Othman, Mohamad Danial Shafiq, Feng Zhao, Kuan Yew Cheong

Electrical and Computer Engineering Faculty Research & Creative Works

The recent upsurge in environmental awareness provokes the widespread usage of green materials in sustainable electronic applications. Herein, the effects of spent coffee grounds (SCGs) on natural rubber (NR)-based resistive switching (RS) memory are systematically investigated. This study presents the fabrication of a metal-insulator-metal (MIM) structure using NR incorporated with SCGs (0 to 8 wt.%) as a memristive layer and sandwiched between electrodes. A significant improvement in the ON/OFF ratio from 104 for pure NR to 107, read memory window increased from 2.03 to 2.45 V with improved stability even after 130 cycles of switching is achieved …


Epitaxial Electrodeposition Of Cu-Btc Metal-Organic Framework Thin Films Onto The (100), (110), And (111) Surfaces Of Single-Crystal Gold And Cuprous Oxide Buffer Layers, Xiaoting Zhang, John Z. Tubbesing, Jay A. Switzer Aug 2025

Epitaxial Electrodeposition Of Cu-Btc Metal-Organic Framework Thin Films Onto The (100), (110), And (111) Surfaces Of Single-Crystal Gold And Cuprous Oxide Buffer Layers, Xiaoting Zhang, John Z. Tubbesing, Jay A. Switzer

Chemistry Faculty Research & Creative Works

Metal-organic frameworks (MOFs) have well-defined pore structures. Epitaxial MOFs can produce films with uniform pore sizes and open porosity. However, the growth of epitaxial MOF thin films has remained a challenge. Herein, we demonstrate a cathodic electrodeposition method for the epitaxial growth of a well-known MOF material, copper (II)-benzene-1,3,5-tricarboxylate (Cu-BTC), from solution precursors. The epitaxial electrodeposition of Cu-BTC was achieved in a Cu (NO3)2-H3BTC-H2O2 bath using H2O2 reduction to deprotonate the H3BTC molecule. The Cu-BTC films can be grown to micrometer thicknesses with Faradaic efficiencies up …


Demystifying The Discharge Coefficient For Flow Over Thin Weirs And Sills, Joseph E. Pugh, Subhas Karan Venayagamoorthy, Timothy K. Gates Aug 2025

Demystifying The Discharge Coefficient For Flow Over Thin Weirs And Sills, Joseph E. Pugh, Subhas Karan Venayagamoorthy, Timothy K. Gates

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

A revised derivation of the discharge coefficient for flows over thin weirs and sills in the limits of wall overflow to a free overfall is given. Using dimensional analysis, we show that the discharge coefficient, (Formula presented), in the classical weir-discharge equation is best understood as a weir Froude number, (Formula presented), which accounts for the combined effects of inertia, contraction and viscous energy losses within the flow field. A comprehensive set of experimental data from historical studies is complimented by new data from the authors, featuring both laboratory flume experiments and three-dimensional numerical simulations of weir flows. Synthesis of …


Development And Optimization Of Gradient Pore Structured Porous Ceramics: Modeling, Properties, And Potential For Industrial Production In Thermal Insulation Engineering, Gang Qi, Minghui Li, Ruoyu Chen, Haichuan Wang, Haiming Wen, Yi Ding, Xiaoyu Xia, Dixin Yan, Can Chen, Saisai Li Aug 2025

Development And Optimization Of Gradient Pore Structured Porous Ceramics: Modeling, Properties, And Potential For Industrial Production In Thermal Insulation Engineering, Gang Qi, Minghui Li, Ruoyu Chen, Haichuan Wang, Haiming Wen, Yi Ding, Xiaoyu Xia, Dixin Yan, Can Chen, Saisai Li

Materials Science and Engineering Faculty Research & Creative Works

This study prepared gradient pore structure ceramics from silica fume through direct foaming. The rheological behavior of the slurry was improved by varying the solids content. Physical and mathematical models were developed to describe the longitudinal movement of foam in the ceramic slurry and the mechanism of gradient pore formation. These models were used to predict the pore sizes at different heights within the ceramic. Insulation and mechanical properties were enhanced by optimizing the gradient pore structure. The gradient pore structure resulted in significant directional differences in specimen properties. Additionally, suitable sintering-temperatures for gradient pore structure ceramics are discussed. The …