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Comparative Catalytic Pyrolysis Of Wheat Straw For Enhanced Bio-Oil Production, Nourhan H. Khashaba, Noura F. Abdelsalam, Hany A. Elazab, Mamdouh A. Gadalla, Thokozani Majozi, Fatma H. Ashour Jul 2026

Comparative Catalytic Pyrolysis Of Wheat Straw For Enhanced Bio-Oil Production, Nourhan H. Khashaba, Noura F. Abdelsalam, Hany A. Elazab, Mamdouh A. Gadalla, Thokozani Majozi, Fatma H. Ashour

Chemical and Biochemical Engineering Faculty Research & Creative Works

Catalytic fast pyrolysis of lignocellulosic biomass is a promising thermochemical route for producing renewable biofuels and value-added chemicals. Many African countries have abundant underutilized agricultural residues whose reuse can improve waste management while reducing reliance on fossil fuels. This study used wheat straw as a representative residue to examine how two catalysts—zinc oxide (ZnO) and cement kiln dust (CKD)—affect bio-oil yield and quality. Bench-scale experiments were performed in a fixed-bed reactor under an inert nitrogen atmosphere at 500–600 °C. Each catalyst was tested separately at loadings from 0 to 7 g per 500 g of biomass to evaluate impacts on …


Multi-Parametric Nonlinear Programming For Lossy Lmp Sensitivity Analysis Using Outer Progressive Cuts, Yuhan Huang, Tao Ding, Chenggang Mu, Rui Bo, Pengwei Du Jul 2026

Multi-Parametric Nonlinear Programming For Lossy Lmp Sensitivity Analysis Using Outer Progressive Cuts, Yuhan Huang, Tao Ding, Chenggang Mu, Rui Bo, Pengwei Du

Electrical and Computer Engineering Faculty Research & Creative Works

Accurate sensitivity analysis of locational marginal price (LMP) is crucial for risk hedging and market management. This paper proposes multiparametric nonlinear programming for sensitivity analysis of LMP with nonlinear network loss, also known as lossy LMP. Global analytical solutions for lossy LMP and the corresponding critical regions are derived. An outer progressive cut algorithm is developed to constrain the network loss error within a specific range for the whole parametric domain. Case studies show the improved accuracy over methods with lossless or fixed loss factors, and a two-order-of-magnitude online speedup over Monte Carlo methods while maintaining lower total computational time.


Distinct Regulatory Dna Methylation Signatures Across Multiple Sclerosis, Neuromyelitis Optica, And Neurological Post-Acute Sequelae Of Covid-19, Syed Ilyas Munzir, Daniel B. Hier, Michael D. Carrithers Jul 2026

Distinct Regulatory Dna Methylation Signatures Across Multiple Sclerosis, Neuromyelitis Optica, And Neurological Post-Acute Sequelae Of Covid-19, Syed Ilyas Munzir, Daniel B. Hier, Michael D. Carrithers

Electrical and Computer Engineering Faculty Research & Creative Works

Background/Objectives: Our prior epigenome-wide association study (EWAS) on multiple sclerosis (MS) identified myeloid-associated methylation signatures and an association with enhancer regions. Here we compared differential DNA methylation across three central nervous system inflammatory disorders: MS, neuromyelitis optica (NMO), and neurologic post-acute sequelae of COVID-19 (neuro-PASC). Methods: Whole-blood DNA was profiled on Infinium MethylationEPIC arrays. Analyses included EWAS at the CpG level, differentially methylation region (DMR) analysis, and gene regulatory-element enrichment using Locus Overlap Analysis (LOLA). Limma linear models were adjusted for race, EPIC array version, age, sex, disease-modifying treatment class, and blood cell composition. Results: All three diseases were associated …


Coupled Multiphysics Transport-Reaction Modeling Framework For Combustion Synthesis Of Cement Phases: Insights Into Β-C2s Formation And Wavefront Dynamics, Sayee Srikarah Volaity, Shubham Agrawal, Aditya Kumar, Narayanan Neithalath Jun 2026

Coupled Multiphysics Transport-Reaction Modeling Framework For Combustion Synthesis Of Cement Phases: Insights Into Β-C2s Formation And Wavefront Dynamics, Sayee Srikarah Volaity, Shubham Agrawal, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Biofuel-based combustion synthesis (BCS) processes offer low-temperature, low-carbon routes to lime and clinker production. However, they involve tightly coupled interactions between heat transfer, gas flow, and sequential solid-state reactions within reactive pellets. Experiments typically provide surface temperature evolution and final phase assemblages but give limited insight into the conversion process and the interaction between composition and process conditions. A coupled transport-reaction framework is developed here to resolve this limitation─the synthesis of β-C2S (belite), a major cementing phase, serving as an example. Transient conservation equations for energy, momentum, and species are solved for a porous pellet exchanging heat and mass with …


Characteristics And Microscopic Mechanisms Of Nsep-Modified Asphalt With Reduced Fume Emission And Enhanced Environmental Benefits, Yiliang Li, Jianguo Wei, Anmin Zou, Jinming Li, Jenny Liu, Di Wang, Xuan Xiao, Yuming Zhou Jun 2026

Characteristics And Microscopic Mechanisms Of Nsep-Modified Asphalt With Reduced Fume Emission And Enhanced Environmental Benefits, Yiliang Li, Jianguo Wei, Anmin Zou, Jinming Li, Jenny Liu, Di Wang, Xuan Xiao, Yuming Zhou

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Toxic fumes emitted during the construction and maintenance of hot-mix asphalt mixtures represent a significant challenge for both the environment and construction workers. To reduce the generation of these toxic fumes, nano-sepiolite (NSEP, a natural mineral) powder was incorporated into base asphalt (BA), styrene-butadiene-styrene (SBS) -modified asphalt (SBSA), and crumb rubber-modified asphalt (CRA) to formulate sepiolite-modified asphalt binders. The rheological properties of these NSEP-modified asphalts were evaluated using dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests. Subsequently, smoke density tests and gas chromatography-mass spectrometry (GC-MS) were utilized to analyze the quantity and composition of the volatile organic compounds …


Binding Energy Of Muonic Beryllium: Perturbative Versus All-Order Calculations, Shikha Rathi, Ulrich D. Jentschura, Paul Indelicato, Ben Ohayon Jun 2026

Binding Energy Of Muonic Beryllium: Perturbative Versus All-Order Calculations, Shikha Rathi, Ulrich D. Jentschura, Paul Indelicato, Ben Ohayon

Physics Faculty Research & Creative Works

We compute the ground-state binding energy of muonic (Formula presented) (Formula presented) Be in two ways: first, the fully perturbative treatment of the nuclear-size effect often employed in light systems, and second, an approach that accounts for the finite-nuclear-size to all orders (and is inspired by calculations otherwise employed for heavy muonic ions). The results are compared term by term and show that both approaches agree to better than one part-per-million of the total energy. The objective of this work is twofold. The first is practical: to provide a parameterization that allows the extraction of the (Formula presented) (Formula presented) …


Label-Flip Attack Detection Via Trust-Weighted Aggregation In Federated Learning For Underground Mine Security, Md Sazedur Rahman, Sanjay Madria, Samuel Frimpong Jun 2026

Label-Flip Attack Detection Via Trust-Weighted Aggregation In Federated Learning For Underground Mine Security, Md Sazedur Rahman, Sanjay Madria, Samuel Frimpong

Computer Science Faculty Research & Creative Works

Underground mining operations are increasingly dependent on autonomous vehicles, robotic drilling systems, and intelligent inspection platforms operating in confined, GPS-denied tunnel environments. These systems rely on distributed perception models to interpret navigation cues, hazard warnings, and environmental signals in real time. While centralized deep learning can enhance model performance, transferring raw operational data across mining sites introduces serious confidentiality and security risks. Federated Learning (FL) offers a privacy-preserving alternative by enabling collaborative model training without sharing local datasets. However, deploying FL in underground mining introduces several critical challenges: (i) Training labels may be modified either maliciously by compromised clients or …


Rheological Protocol To Assess And Optimize Latex Coagulation Dynamics For The Thin Glove Coagulant Dipping Process, Monday U. Okoronkwo, Kok Kong Ng, Wolfram Franke, Gaurav Sant Jun 2026

Rheological Protocol To Assess And Optimize Latex Coagulation Dynamics For The Thin Glove Coagulant Dipping Process, Monday U. Okoronkwo, Kok Kong Ng, Wolfram Franke, Gaurav Sant

Chemical and Biochemical Engineering Faculty Research & Creative Works

Many products that directly impact the quality of human life today — gloves, catheters, condoms, and baby bottle teats — are made through the latex-dipping technology. While a variety of methods have been developed – e.g., particle counting, turbidimetry, microscopy, and light scattering – which are suitable for studying the coagulation of latex at very low concentrations, much less work has focused on methods suitable for in-situ characterization of latex coagulation in concentrated solutions (e.g., as relevant to the dipping process). This paper presents a process-relevant rheological protocol for assessing and optimizing latex coagulation dynamics for the thin glove coagulant …


High-Throughput Optical Analysis To Inform Design Of Electrochemical Biosensors, Nathan J. Ricks, Michael A. Pence, Monica Brachi, Shelley D. Minteer Jun 2026

High-Throughput Optical Analysis To Inform Design Of Electrochemical Biosensors, Nathan J. Ricks, Michael A. Pence, Monica Brachi, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

Electrochemical biosensors are central to wearable diagnostics, point-of-care testing, and continuous health monitoring due to their low power requirements, compatibility with miniaturized electronics, and proven clinical impact. Despite these advantages, the development of new electrochemical biosensors remains slow, constrained by limited throughput, complex electrode–biomolecule interfaces, and challenges associated with selectivity and performance in chemically complex environments. This perspective outlines how the next generation of electrochemical biosensors can be enabled by decoupling high-throughput front-end discovery and optimization from electrochemical readouts using nonelectrochemical surrogate assays. Optical, affinity, and cell-sorting platforms, including SELEX, fluorescence-activated cell sorting, and chemically coupled fluorescence assays, allow orders-of-magnitude …


Data-Driven Electrochemistry Reveals The Impact Of Hydrophobicity On Aptamer Cross-Reactivity, Emily Carroll, Michael A. Pence, Elizabeth Winterholler, Taylor D. Sparks, Shelley D. Minteer Jun 2026

Data-Driven Electrochemistry Reveals The Impact Of Hydrophobicity On Aptamer Cross-Reactivity, Emily Carroll, Michael A. Pence, Elizabeth Winterholler, Taylor D. Sparks, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

Electrochemical aptamer-based (E-AB) biosensors offer a promising platform for reagentless detection of molecular targets, yet aptamer recognition can be limited by cross-reactivity, particularly for hydrophobic analytes such as steroid hormones. To investigate how cross-reactivity influences E-AB sensor performance, we use automation and machine learning to screen a library of possible interferent molecules against a steroid-binding aptamer, with progesterone serving as a physiologically relevant test case. Here, we develop a label-free E-AB sensor for progesterone detection using a methylene blue-modified aptamer anchored with a hexanethiol linker. We then used an automated electrochemistry platform to perform reproducible and high-throughput characterization of our …


Interseismic Creep Along The Enriquillo–Plantain Garden Fault, Haiti, Estimated From Insar, Rishabh Dutta, Jeremy L. Maurer, Yi Chieh Lee Jun 2026

Interseismic Creep Along The Enriquillo–Plantain Garden Fault, Haiti, Estimated From Insar, Rishabh Dutta, Jeremy L. Maurer, Yi Chieh Lee

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The Enriquillo–Plantain Garden fault zone (EPGFZ) is a major left-lateral strike-slip fault in southern Haiti hosting several recent destructive earthquakes, including the 2021 MW 7.1 Nippes event with primary thrust-slip. To investigate how strain is accommodated in the vicinity of the 2021 event, we analyzed Sentinel-1 interferometric synthetic aperture radar (InSAR) data from 2017 to 2021 using a PS + DS (persistent + distributed scatterers) InSAR time-series approach to overcome decorrelation in this highly vegetated region. We reveal interseismic creep along the EPGF and adjacent Grand'Anse–Sud border faults, with pure strike-slip mechanism and rates up to 9 mm/yr. We suggest …


Transforming Dredged Sediment Into Reactive Clay: Critical Review Of Calcination, Reactivity, And Sustainable Valorization As Supplementary Cementitious Material, Seongho Han, Sanghwon Wi, Koochul Ji, Keun Hyeok Yang, Farshad Rajabipour, Kamal H. Khayat, Jinyoung Yoon Jun 2026

Transforming Dredged Sediment Into Reactive Clay: Critical Review Of Calcination, Reactivity, And Sustainable Valorization As Supplementary Cementitious Material, Seongho Han, Sanghwon Wi, Koochul Ji, Keun Hyeok Yang, Farshad Rajabipour, Kamal H. Khayat, Jinyoung Yoon

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Dredged sediment (DS) is generated worldwide in large volumes through routine port and waterway maintenance, yet its disposal presents environmental and economic challenges. Recently, calcined dredged sediment (CDS) has emerged as a supplementary cementitious material (SCM), offering a viable alternative to traditional SCMs, such as fly ash and slag cement. This review synthesizes current knowledge on the physical, chemical, and mineralogical characteristics of raw DS and pretreatment strategies aimed at dewatering, organic matter removal, and contaminant stabilization. The effects of calcination on the production of reactive amorphous aluminosilicates are also discussed. Emphasis is placed on physicochemical changes revealed by experimental …


Low-Carbon Concrete For Sustainable Construction: A Comprehensive Review Of Performance Characteristics, Implementation Challenges, And Decarbonization Pathways, Fazel Azarhomayun, Jingjie Wei, Kamal H. Khayat Jun 2026

Low-Carbon Concrete For Sustainable Construction: A Comprehensive Review Of Performance Characteristics, Implementation Challenges, And Decarbonization Pathways, Fazel Azarhomayun, Jingjie Wei, Kamal H. Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Reducing the carbon footprint of concrete has become a central objective in sustainable construction. Low-carbon concrete (LCC), developed primarily through clinker reduction, supplementary cementitious materials, and alternative binder strategies, offers a promising route for lowering embodied emissions while maintaining the performance requirements of structural concrete. This comprehensive review consolidates the current state of knowledge on LCC, identifies critical research and implementation gaps, and examines its material composition, mixture-design methodologies, performance characteristics, structural applications, implementation challenges, and decarbonization pathways. Single-SCM systems have been reported at clinker-replacement levels approaching 50%, although durability at these replacement levels, particularly carbonation resistance, remains system- and …


Design Framework For Polymer Gel Treatments From A Database Of Field Projects, Baojun Bai, Munqith Aldhaheri, Mingzhen Wei Jun 2026

Design Framework For Polymer Gel Treatments From A Database Of Field Projects, Baojun Bai, Munqith Aldhaheri, Mingzhen Wei

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This study compiles and analyzes data from over 125 published field projects around the world, covering nearly 900 treated wells. Building on those detailed studies, this paper distills the most important findings into a concise, practical, and actionable framework to guide where in-situ gel treatments should be applied, how they should be designed, and how their outcomes can be evaluated. The proposed workflow guides engineers through five integrated stages: screening appropriate gel types, designing formulation and injection strategies, predicting field response, evaluating treatment performance, and conducting iterative refinement with feedback loops to adjust designs based on observed outcomes. The framework …


An Instance Segmentation Based Global Mppt Method For Pv Systems Under Partial Shading Condition, Ehab Ur Rahman, Yousef Mahmoud, Rui Bo Jun 2026

An Instance Segmentation Based Global Mppt Method For Pv Systems Under Partial Shading Condition, Ehab Ur Rahman, Yousef Mahmoud, Rui Bo

Electrical and Computer Engineering Faculty Research & Creative Works

Partial shading in photovoltaic (PV) systems creates multiple Local Maximum Power Points (LMPPs) on the power-voltage (P-V) curve, causing conventional Maximum Power Point Tracking (MPPT) algorithms to converge prematurely to suboptimal operating points and resulting in significant energy losses. This work proposes a novel vision-based framework that integrates computer vision with Global Maximum Power Point Tracking (GMPPT) to maximize energy harvesting in partially shaded PV systems. The proposed method captures real-time imagery of PV panels to identify cell-level shading patterns, which are subsequently mapped to module electrical characteristics to enable direct analytical estimation of the GMPP voltage. An instance segmentation …


Converting Co2 Into Carbon Nanotubes Via Sequential Co2 Methanation And Methane Pyrolysis, Kaiying Wang, Hao Feng, Ahmad Helaley, Xiaoqing He, Bohong Zhang, Jie Huang, Xinhua Liang Jun 2026

Converting Co2 Into Carbon Nanotubes Via Sequential Co2 Methanation And Methane Pyrolysis, Kaiying Wang, Hao Feng, Ahmad Helaley, Xiaoqing He, Bohong Zhang, Jie Huang, Xinhua Liang

Electrical and Computer Engineering Faculty Research & Creative Works

This study presents a sequential thermochemical catalytic process for converting CO2 into carbon nanotubes (CNTs), achieving nearly 99% overall CO2 conversion and solid carbon yields of up to 49% in a single pass. The overall transformation is divided into two thermodynamically favorable steps: (1) low-temperature CO2 methanation to CH4 over a sol-gel-prepared Ni87Ce6.5Zr6.5-SG catalyst, which achieved >95% CO2 conversion at 250 °C in a single pass, and (2) subsequent methane pyrolysis to CNTs and H2 over a Ni@Al2O3-IE core-shell catalyst, which showed improved stability and carbon …


Oriented Electrospun Fibers Of Poly(Pro-Curcumin/Peg) Sequester Reactive Oxygen Species And Promote The Growth Of Schwann Cells, Jack W. Devlin, Payton R. O'Connor, Conrad H. Cheung, John T. Leman, Martin Oudega, Edmund F. Palermo, Ryan J. Gilbert Jun 2026

Oriented Electrospun Fibers Of Poly(Pro-Curcumin/Peg) Sequester Reactive Oxygen Species And Promote The Growth Of Schwann Cells, Jack W. Devlin, Payton R. O'Connor, Conrad H. Cheung, John T. Leman, Martin Oudega, Edmund F. Palermo, Ryan J. Gilbert

Chemical and Biochemical Engineering Faculty Research & Creative Works

In the biological injury microenvironment, pathologically elevated oxidative stress hinders healthy cell migration. Aligned electrospun fibers are used as tissue engineering scaffolds to support and guide the directionality of cell migration. The ability of cells in the central nervous system to sequester and quench reactive oxygen species is limited, and most electrospun fibers do not exert any antioxidant activity on contact. Thus, the challenge remains in designing a scaffold that can both guide cells to the injury site as well as sequester and quench excess free radicals, allowing cells to thrive and potentially regenerate. Curcumin is a well-known, potent antioxidant, …


Employing Ac And Dc Electrolysis To Modulate Electroenzymatic Pathways For Efficient And Stereoselective H-D Exchange, Wassim El Housseini, Rokas Gerulskis, Nibedita Behera, Huaijun Guan, Rohit G. Jadhav, Zachary A. Nguyen, Egor Baiarashov, Michael A. Pence, Vamshi Krishna Kamaja, Trevor Larkin, Long Luo, Shelley D. Minteer Jun 2026

Employing Ac And Dc Electrolysis To Modulate Electroenzymatic Pathways For Efficient And Stereoselective H-D Exchange, Wassim El Housseini, Rokas Gerulskis, Nibedita Behera, Huaijun Guan, Rohit G. Jadhav, Zachary A. Nguyen, Egor Baiarashov, Michael A. Pence, Vamshi Krishna Kamaja, Trevor Larkin, Long Luo, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

Stereoselective hydrogen isotope exchange (HIE) at chiral centers is an increasingly important strategy for preparing labeled molecules, yet its practical implementation depends on reliable control of nicotinamide cofactor regeneration. Here we introduce a redox-programmable electroenzymatic platform for stereoselective HIE based on electrode-controlled manipulation of the nicotinamide cofactor state. A wired ferredoxin–NADP+ reductase (FNR) electrode enables reversible electrochemical interconversion of NADP+ and its deuterated reduced form (NADPD) directly from D2O. Coupling this cofactor cycling with enantioselective alcohol dehydrogenases (ADHs) establishes a reversible alcohol–ketone redox manifold that drives efficient and stereoselective H-D exchange at chiral alcohols. Stereochemical outcomes are programmed …


Investigation Of Portland Limestone Cement Blended With Biochar From Downdraft Gasification: Hydration Kinetics, Microstructure, Rheology, And Performance Mechanisms, Ugochukwu Ewuzie, Paul C. Ani, Abdulkareem O. Yusuf, Joseph D. Smith, Monday Uchenna Okoronkwo Jun 2026

Investigation Of Portland Limestone Cement Blended With Biochar From Downdraft Gasification: Hydration Kinetics, Microstructure, Rheology, And Performance Mechanisms, Ugochukwu Ewuzie, Paul C. Ani, Abdulkareem O. Yusuf, Joseph D. Smith, Monday Uchenna Okoronkwo

Chemical and Biochemical Engineering Faculty Research & Creative Works

The widespread adoption of Portland Limestone Cement (PLC) in U.S. concrete production has necessitated research into commercially available supplementary cementitious materials (SCMs) for formulating high-performance, low-carbon blended binders with PLC. This study investigated the influence of biochar (BC) in biochar-PLC composites (CBCs), focusing on hydration kinetics, microstructure, rheology, pore-solution chemistry, compressive strength, and the underlying mechanisms. Biochar was produced via downdraft gasification at 850 °C and incorporated into PLC at 5, 7, and 10% substitution by mass. Isothermal calorimetry and hydration data modeled using the Knudsen equation revealed that BC retarded early hydration but improved hydration degree and later-age heat …


Olaf: Towards Robust Llm-Based Annotation Framework In Empirical Software Engineering, Mia Mohammad Imran, Tarannum Shaila Zaman Jun 2026

Olaf: Towards Robust Llm-Based Annotation Framework In Empirical Software Engineering, Mia Mohammad Imran, Tarannum Shaila Zaman

Computer Science Faculty Research & Creative Works

Large Language Models (LLMs) are increasingly used in empirical software engineering (ESE) to automate or assist annotation tasks such as labeling commits, issues, and qualitative artifacts. Yet the reliability and reproducibility of such annotations remain underexplored. Existing studies often lack standardized measures for reliability, calibration, and drift, and frequently omit essential configuration details. We argue that LLM-based annotation should be treated as a measurement process rather than a purely automated activity. In this position paper, we outline the Operationalization for LLM-based Annotation Framework (OLAF), a conceptual framework that organizes key constructs: reliability, calibration, drift, consensus, aggregation, and transparency. The paper …


From Ports To Projects: Estimating The Impact Of Supply Chain Volatility And Trade Policy Changes On Construction Material Prices, Ahmed Shiha, Islam H. El-Adaway Jun 2026

From Ports To Projects: Estimating The Impact Of Supply Chain Volatility And Trade Policy Changes On Construction Material Prices, Ahmed Shiha, Islam H. El-Adaway

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Construction material markets are often reliant on imported commodities. Import tariffs and temporary trade barriers disrupt supply chains, presenting stakeholders with uncertainties regarding how such disruption impacts construction material prices. Despite the plethora of research efforts that examine the effects of economic conditions on construction material prices, the impacts of the import quantities remain understudied. This paper fills this knowledge gap using a multistep methodology. First, the prices of major construction materials and the quantities of the relevant imported commodities are retrieved. Second, the stability of their historical trends was assessed using econometrics-based tests. Third, a nonlinear autoregressive distributed lag …


Recent Advances In The Rheological Properties Of Ultra-High-Performance Concrete: A Critical Review, Le Teng, Kamal H. Khayat, Jiaping Liu Jun 2026

Recent Advances In The Rheological Properties Of Ultra-High-Performance Concrete: A Critical Review, Le Teng, Kamal H. Khayat, Jiaping Liu

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Ultra-high-performance concrete (UHPC) with adapted rheology continues to attract interest considering the requirement for novel processing techniques such as self-consolidating, pumping, spraying, and three-dimensional (3D) printing. The rheology of UHPC is complex due to its high solid volume fraction, low water content, and wide range of constituent materials that affect its flow properties. This work provides guidance for tailoring the mixture proportioning of UHPC to secure proper rheological properties and performance of UHPC for various applications. In the first part of this work, key physical, physicochemical, and chemical factors that can affect the rheological properties of UHPC are discussed. Rheological …


Hydroxamate Formation In The Lipopeptide Containing Siderophore Taiwachelin, Aaron J. Gringer, Kernen P. Agwaza, Isabel Da Fonseca, Pablo Sobrado Jun 2026

Hydroxamate Formation In The Lipopeptide Containing Siderophore Taiwachelin, Aaron J. Gringer, Kernen P. Agwaza, Isabel Da Fonseca, Pablo Sobrado

Chemistry Faculty Research & Creative Works

Cupriavidus taiwanensis is a nitrogen-fixing bacterium found in root nodules of the invasive tropical weed Mimosa pudica . C. taiwanensis has been shown to grow in environments contaminated with heavy metals such as Pb, Cu, and Cd. Taiwachelin, a recently identified siderophore produced by C. taiwanensis , is an iron chelator that contains a hydroxamate functional group for metal binding. In its biosynthesis, a flavin-dependent N-monooxygenase (NMO) was predicted to hydroxylate l -ornithine, leading to formation of the metal binding hydroxamate moiety. Here, we report the cloning, expression, and biochemical characterization of this enzyme, herein referred to as CtNMO. CtNMO …


A Fiftieth Year Retrospective On The 1976 Mw 7.5 Motagua Earthquake In Guatemala, Grant Clark, Trenton Mcenaney, Jeremy Maurer, Andreas Eckert, Stephen S. Gao, Omar G. Flores, Robin Yani, Tina Niemi, Christoph Grützner, Francisco Gomez, Jonathan Obrist-Farner Jun 2026

A Fiftieth Year Retrospective On The 1976 Mw 7.5 Motagua Earthquake In Guatemala, Grant Clark, Trenton Mcenaney, Jeremy Maurer, Andreas Eckert, Stephen S. Gao, Omar G. Flores, Robin Yani, Tina Niemi, Christoph Grützner, Francisco Gomez, Jonathan Obrist-Farner

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

On 4 February 1976, an Mw > 7:5 earthquake ruptured ∼240 km of the Motagua fault in Guatemala, causing ∼23,000 fatalities. This event provided evidence for the fault's role as a major transform boundary between the North American and Caribbean plates. Field observations, seismological analyses, and postseismic studies helped constrain fundamental aspects of the 1976 earthquake mechanics and the spatial complexity of the rupture. This event opened a window for studies documenting past deformation along this plate boundary across multiple spatial and temporal scales. Five decades of research have established this earthquake as an important event for understanding strike-slip ruptures along …


Eliminating Barriers For The Implementation Of Automation In The Mining Industry, Sefiu O. Adewuyi, Kray Luxbacher, Kanagy David, Miller Ben, Miller Hugh, Michael Moats, Savit Mark Jun 2026

Eliminating Barriers For The Implementation Of Automation In The Mining Industry, Sefiu O. Adewuyi, Kray Luxbacher, Kanagy David, Miller Ben, Miller Hugh, Michael Moats, Savit Mark

Materials Science and Engineering Faculty Research & Creative Works

The integration of new technologies into U.S. mining operations is necessary for achieving continuous improvement in worker health and safety, as well as improving operational efficiency, but many have questioned why uptake of autonomy in the U.S. mining industry has been slow compared to other nations. Despite extensive research on mining automation, there remains a critical gap in understanding and systematically identifying the barriers to its adoption within the U.S. mining industry and globally. To quantify these barriers, a workshop model of data collection was employed. A total of 708 invitations were extended to professionals to participate in nine different …


The Impact Of Carbon Capture Technologies On Energy Prices, Bruktawit M. Ahmed, Mahelet G. Fikru Jun 2026

The Impact Of Carbon Capture Technologies On Energy Prices, Bruktawit M. Ahmed, Mahelet G. Fikru

Economics Faculty Research & Creative Works

Despite previous literature evaluating the economic feasibility of carbon capture and storage (CCS) in the energy and power sector, there are limited studies examining the impact on consumer prices - particularly energy prices and their variability. Using a Monte Carlo simulation based on a profit-maximization model in an oligopolistic market, we examine how production and abatement costs, policy incentives — including a carbon tax, renewable energy subsidies, and CCS subsidies — and energy demand parameters influence the percentage of carbon captured by a producer operating a diverse portfolio of energy-generating technologies. Additionally, we assess how these factors contribute to fluctuations …


Exploiting Underground Mine Topology For Resilient Concurrent Lora Mesh Emergency Communications: Architecture, Protocol Design, And Performance Analysis, Hilary Kelechi Anabi, Samuel Frimpong, Muhammad Azeem Raza Jun 2026

Exploiting Underground Mine Topology For Resilient Concurrent Lora Mesh Emergency Communications: Architecture, Protocol Design, And Performance Analysis, Hilary Kelechi Anabi, Samuel Frimpong, Muhammad Azeem Raza

Mining Engineering Faculty Research & Creative Works

Underground mine emergencies compromise fixed communication infrastructure exactly when situational awareness is most critical for effective rescue operations. Existing LoRa mesh protocols fail in underground mines because they ignore the structured topology of tunnel networks, specifically the waveguide effect along straight galleries, severe signal discontinuity at junctions, and the dead-end geometry of working faces. This paper presents the Topology-Aware Concurrent LoRa (TACL) mesh protocol, in which each node autonomously infers its structural role from local RF observations and packet header information, without GPS, pre-loaded mine maps, or central coordination. Role classification resolves the contender estimation problem (Formula presented.) left open …


Low-Cost Path-Loss Characterization For Underground Mine Tunnels Using Lora Transceivers At 915 Mhz, Hilary Kelechi Anabi, Samuel Frimpong, Muhammad Azeem Raza Jun 2026

Low-Cost Path-Loss Characterization For Underground Mine Tunnels Using Lora Transceivers At 915 Mhz, Hilary Kelechi Anabi, Samuel Frimpong, Muhammad Azeem Raza

Mining Engineering Faculty Research & Creative Works

Accurate path-loss models are essential for planning reliable wireless networks in underground mines, yet existing characterization studies rely on specialized channel sounders and vector network analyzers costing tens of thousands of dollars, placing them beyond the reach of most mine operators. This paper demonstrates that LoRa transceivers costing approximately US $15 per node can serve as a self-contained path-loss measurement instrument, logging the received signal strength indicator (RSSI) and signal-to-noise ratio (SNR) directly to a CSV file over a standard USB serial connection. A measurement campaign conducted at the Missouri S&T Experimental Mine on 31 March 2026 collected 4801 packets …


Tracking Continuous Non-Differentiable Trajectories In Euler–Lagrange Systems With Continuous Dynamics, Nilay Kant Jun 2026

Tracking Continuous Non-Differentiable Trajectories In Euler–Lagrange Systems With Continuous Dynamics, Nilay Kant

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Tracking controllers for Euler–Lagrange systems are designed under the assumption that reference trajectories are continuous, and at least twice differentiable with respect to time. However, this assumption precludes several use cases, such as when a robot end-effector must track a path with corners at constant speed. This paper introduces the control design for tracking continuous but non-differentiable trajectories in fully actuated Euler–Lagrange systems that have continuous-time dynamics. The proposed controller combines a continuous feedback law with impulsive inputs, that are intermittently applied at the instants of non-differentiability. A Lyapunov stability analysis establishes global exponential convergence of the tracking error to …


A Carbon Fiber-Based Self-Sensing Approach For Monitoring Damage Evolution In Coal Pillars, Shan Ning, Weibing Zhu, Jie Gao, Wei Qin, Guang Xu, Jingmin Xu Jun 2026

A Carbon Fiber-Based Self-Sensing Approach For Monitoring Damage Evolution In Coal Pillars, Shan Ning, Weibing Zhu, Jie Gao, Wei Qin, Guang Xu, Jingmin Xu

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Under long-term high stress and dynamic disturbances, damage accumulation within underground coal masses can induce sudden instability, posing a considerable threat to coal mine safety. Real-time acquisition of coal damage information is essential for disaster prevention and control. This study proposes a coal damage and fracturing monitoring approach based on a carbon fiber composite mortar (CFCM) coating. By applying the CFCM coating to coal specimen surfaces and monitoring resistance changes, the dynamic evolution of damage can be tracked. The study combines experimental mechanical loading, continuous electrical resistance monitoring and acoustic emission recording with detailed numerical modelling to comprehensively evaluate sensing …