Digital Commons Network^™

Nonlinear Flow Structures From The Interaction Of Internal Waves With Topography, Matthew R. Klema, S. Karan Venayagamoorthy

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This paper presents numerical simulations of the interaction of first-mode internal waves with a topographic edge at the intermediate scale, O (100) m, with a focus on the evolution of flow structures. Flow structure variation and evolution is explored through direct modifications to the amplitude of the internal wave interacting with topographic features of varying wave-topographic slope (g/s), height of the topography to the total domain depth (ht/d), and the wave Froude number (Fr = U0/cph), where g is the internal wave slope, s is the topographic slope, ht is the height of the topography, d is the simulation depth, …

Dendrimer Gel Nanoparticles With Dual-Targeting Of Upar And Ribonucleotide Reductase R2 Influence Necrosis, Apoptosis, And Cell Cycle Arrest In Triple-Negative Breast Cancer, Hsin Yin Chuang, Yue-Wern Huang, Hu Yang

Biological Sciences Faculty Research & Creative Works

Triple-negative breast cancer (TNBC) is an aggressive breast cancer subtype with limited treatment options due to the absence of estrogen (ER), progesterone (PR), and human epidermal growth factor receptor 2 (HER2) receptors. We previously developed highly adaptable polyamidoamine (PAMAM) dendrimer-based gel nanoparticles (GDP-uPA/GTI) with dual-targeting capabilities against urokinase-type plasminogen activator receptor (uPAR) and ribonucleotide reductase R2 (R2) to achieve selective antitumor effects. In this study, we investigated the underlying mechanisms of GDP-uPA/GTI-induced tumor inhibition. In vivo, GDP-uPA/GTI significantly downregulated R2 expression and activated caspase 8 and caspase 3, indicating caspase-dependent apoptosis. Histological evaluation of major organs revealed no observable toxicity. …

Bone Void Filler Materials For Augmentation In Comminuted Fractures: A Comprehensive Review, S. Sina Mohammadi, Sunjeev S. Phull, B. Sonny Bal, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Comminuted fractures, characterized by multiple bone fragments, present significant challenges in orthopedic surgery. Effective treatment often requires augmentation techniques to enhance fixation stability and promote bone regeneration. This review explores the application of bone void filler materials, including autografts, allografts, polymethyl methacrylate (PMMA), and synthetic bone substitutes such as calcium phosphate ceramics and bioactive glass, in managing comminuted fractures. Autografts are the gold standard due to their superior osteogenic potential but are limited by donor site morbidity and availability. Allografts mitigate these issues but face concerns regarding immunogenicity and reduced biological activity. PMMA, widely used for structural augmentation, provides immediate …

Resolving The Energy Efficiency Paradox: Leveraging Benefits For Saudi Arabia’S Building Sector, Fateh Belaïd, Mahelet G. Fikru

Economics Faculty Research & Creative Works

This article examines the economics of energy efficiency in Saudi Arabia's building sector, centering on the "energy efficiency paradox," the observed under adoption of cost-effective technologies despite their clear benefits—such as reducing energy use and associated emissions. We show that a mix of market barriers and behavioral biases—including split incentives, informational gaps, and the value-action gap—constrains adoption of energy-efficient solutions. Recent modeling suggests that improved air-conditioning labels could save up to 80 TWh of electricity annually, though rebound effects may erode some of these gains. Our analysis shows that tackling market failures is necessary but not enough. Strong building codes …

Enhancing Management Of Transportation Projects: Integration Factors For Using Smart Contracts, Mariam Elazhary, Islam H. El-Adaway

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The US Department of Transportation (USDOT) delivers a wide range of infrastructure projects, backed by a fiscal year 2023 budget exceeding $100 billion. These projects face mounting pressures to meet performance, accountability, and delivery standards, driven by their dependence on public funding and their operational complexity. Transportation infrastructure presents sector-specific challenges - such as time-sensitive user disruptions, multiparty coordination, and asset intersection risks - that demand more robust, automated, and transparent project delivery mechanisms. Blockchain-enabled smart contracts have emerged as a promising solution to address these operational pain points through real-time automation, immutable data records, and decentralized transaction processing. However, …

Bond Behavior Of Full-Scale Beams Using Sustainable Self-Compacting Concrete, Hayder H. Alghazali, Atheer H.M. Algburi, John J. Myers

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Sustainable concrete is a step towards greener and more eco-friendly concrete construction practices, helping to solve global environmental problems. The present study focuses on the bond behavior between steel reinforcement and greener self-compacting concrete, specifically sustainable self-compacting concrete (SUS-SCC). Three SUS-SCC mixtures with different fly ash (FA) to cement replacement levels of [50, 60, and 70% (by mass)] were developed. Twelve full-scale SUS-SCC beams with a cross-section of (305 x 57) mm and a total length of 3048 mm were cast and tested using a four-point load test setup. The effect of longitudinal and lateral steel reinforcement ratios in the …

Experimental Determination Of Tnt Equivalence Values For Binary Energetic Materials, Gracie May M. James, Rachel L. Bauer, Emily M. Johnson, Catherine E. Johnson

Mining Engineering Faculty Research & Creative Works

TNT equivalency quantifies the impact of energetic materials relative to TNT, aiding in safety guidelines and performance evaluations. Despite widespread use in industry, military, and research, many binary energetics lack published TNT equivalence values. This study experimentally determines TNT equivalency values for Helix, Texpak, Rimfire, Tannerite, and Kinepak using three tests: (1) plate dent, (2) reaction velocity and (3) air blast. Each test evaluates distinct aspects of energetic performance, addressing both close-in destructive power and downstream effects. Helix produced TNT equivalence values from 0.64 to 1.10, comparable to TNT, while Kinepak had lower values (0.18 to 0.58) indicating limited brisance, …

Unlocking The Potential Of Copper Sulfide Tailings As A Secondary Source For Tellurium And Precious Metals: A Comprehensive Characterization Study, Fardis Nakhaei, Lana Alagha, Gary Wyss

Mining Engineering Faculty Research & Creative Works

This study investigated historical copper sulfide tailings as an unconventional source of tellurium (Te), gold (Au), and silver (Ag). Advanced analytical studies were conducted to determine the geochemical and mineralogical properties of the tailing samples. The results showed that tetradymite (Bi2Te2S) was the predominant Te-bearing mineral, while hessite (Ag2Te) was a minor Te carrier, both notably occurring within fine-grained (< 8 μm) inclusions in pyrite. Gold was present as native Au, electrum (Au-Ag), and within complex silver tellurides hosted primarily in chalcopyrite and pyrite. Froth flotation studies showed that the 180 to 38 μm size range was the optimum feed size that yielded recoveries of 59 %, 37 %, and 27 % for Te, Au, and Ag, respectively. These findings suggested that froth flotation is a feasible method for concentrating Te-Au-Ag-bearing phases. Given the strong association between Te, Au, Ag, and Cu, the co-extraction of these metals should significantly enhance the economic viability of tailings' processing.

Method To Measure Blast Overpressure Exposure On Military Personnel Using Orthogonal Sensor Orientations, Nicholas W. Kuehl, Catherine E. Johnson

Mining Engineering Faculty Research & Creative Works

Measuring and recording blast exposure to military personnel from shoulder-fired weaponry or improvised explosive devices to correlate health outcomes like mild traumatic brain injury has been a goal for many years. To ensure overpressure is recorded, sensor manufacturers either recommend multiple sensors on different parts of the body or have integrated multiple sensors into one unit. Despite this, knowing the sensor orientation in relation to the blast source is important to know if it's a head on, side on or oblique pressure recording. This research investigates whether pressures recorded at three independent orientations in the x, y and z planes …

Effects Of Wc Additions On The Phase Formation Of (Hf,Nb,Ta,Ti,Zr)C-(Hf,Nb,Ta,Ti,Zr)B2 High Entropy Dual Phase Ceramics, Rubia Hassan, William G. Fahrenholtz, Gregory E. Hilmas

Materials Science and Engineering Faculty Research & Creative Works

High entropy dual phase (Hf,Nb,Ta,Ti,Zr)C-(Hf,Nb,Ta,Ti,Zr)B2 ultra-high temperature ceramics were produced from powders synthesized by boro-carbothermal reduction. Systematic additions of 2.5 wt%, 5 wt%, and 10 wt% WC were incorporated after powder synthesis. Additions of 2.5 wt% and 5 wt% WC dissolved into the host ceramics, resulting in complete solid solution formation and nearly full densification. In contrast, a secondary monoboride phase evolved for the composition with 10 wt% WC, in addition to the main high entropy carbide and diboride phases. Thermodynamic analysis revealed that WB formation was favorable for WC additions in the presence of metal diborides at the sintering …

Thermal Properties Of High Entropy Dual Phase (Hf,Nb,Ta,Ti,Zr,)C-(Hf,Nb,Ta,Ti,Zr)B2 Ceramics: Comparison With The High Entropy Single-Phase Ceramics And The Effect Of Wc Additions, Rubia Hassan, William G. Fahrenholtz, Gregory E. Hilmas

Materials Science and Engineering Faculty Research & Creative Works

The heat capacity, thermal diffusivity and thermal conductivity of (Hf,Nb,Ta,Ti,Zr)C-(Hf,Nb,Ta,Ti,Zr)B₂ high entropy dual phase ceramics were evaluated from room temperature to 1800 °C and compared with the constituent high entropy single phase ceramics of the same nominal compositions. Thermal conductivity of the (Hf,Nb,Ta,Ti,Zr)C-(Hf,Nb,Ta,Ti,Zr)B₂ dual phase ceramic increased from 17.7 W m⁻¹ K⁻¹ at room temperature to 54 W m⁻¹ K⁻¹ at 1800 °C. The addition of WC to the dual phase ceramic reduced its thermal conductivity. For the addition of 5 wt% WC, room temperature thermal conductivity was 16.8 W m⁻¹ K^{−1 …}

A Precipitation-Hardened High-Entropy Alloy With Excellent Mechanical Properties Additively Manufactured By In-Situ Alloying, Matthew Luebbe, Shahryar Mooraj, Jonathan Poplawsky, Hans Pommerenke, Wen Chen, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Studies on precipitation-hardened high-entropy alloys (PHEAs) have demonstrated high strength, good ductility, and thermal stability, making them excellent candidates for high-temperature structural applications such as nuclear reactors. However, many complex parts for those applications would need to be produced via additive manufacturing (AM), whose rapid cooling rates and multiple heating cycles could change the microstructure of the chosen alloys and accordingly their mechanical properties. A PHEA, (Fe0.3Ni0.3Mn0.3Cr0.1)88Ti4Al8, which was developed and produced via conventional manufacturing in our previous work with high strength but low ductility, was chosen to test the effects of AM on the microstructure and mechanical properties. Scanning …

Effect Of Powder Recycling On Powder Characteristics And Mechanical Properties Of Materials Produced By Laser Powder Bed Fusion (Lpbf): A Review, Mihiretu Ganta, Marta Kurek, Arezoo Emdadi, Tadeusz Łagoda, Marek Pagáč

Materials Science and Engineering Faculty Research & Creative Works

As the Laser powder bed fusion (LPBF) process advances toward industrial-scale production, the sustainability of metal powder feedstocks has become a focal point of research. The powder recycling approach, while environmentally and economically favorable, results in a series of physicochemical variations that could compromise the part quality. The resulting variation in powder characteristics with powder recycling could affect the powder layer density and melt pool dynamics, resulting in defect formation and hindering the structural integrity of LPBFed parts. These alterations pose significant constraints to mechanical performance, particularly in fatigue-sensitive applications where even minor imperfections can substantially reduce service life. The …

Variable-Temperature Plasmonic High-Entropy Carbides, Simon Divilov, Sean D. Griesemer, Robert C. Koennecker, Michael J. Ammendola, Adam C. Zettel, Hagen Eckert, Jeffrey R. Shallenberger, Xiomara Campilongo, William G. Fahrenholtz, Arrigo Calzolari, Douglas E. Wolfe, Stefano Curtarolo

Materials Science and Engineering Faculty Research & Creative Works

Effective thermal management at variable and extreme temperatures face limitations for the development of novel energy and aerospace applications. Plasmonic approaches, shown to be capable of tailoring black-body emission, could be effective if materials with high-temperature and tunable plasmonic resonance were available. Here, we report a synergy between experimental and theoretical results proving that many high-entropy transition metal carbides, consisting of four or more metals at equal molar ratio, have plasmonic resonance at room, high (>1000∘C) and variable temperatures. We also found that these high-entropy carbides can be tuned and show considerable plasmonic thermal cycling stability. This paradigm-shift approach …

The Equity Implications Of Pecuniary Externalities On An Electric Grid, Charles Sims, Gasser G. Ali, J. Scott Holladay, Tim Roberson, Chien Fei Chen, Islam H. El-Adaway

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The adoption of rooftop photovoltaic (PV) systems can create upward pressure on retail electricity rates as utilities are forced to spread their fixed costs of generation and transmission across a smaller customer base. Since high-income households are more likely to purchase PV systems, low-income households may be disproportionately impacted by these rate increases. Using a novel combination of agent-based computational economic modeling and a choice experiment of rooftop solar adoption, we show how this pecuniary externality between low- and high-income customers increases low-income electricity bills by 10% in an area with some of the highest poverty rates in the United …

December 2025 Cafe Newsletter, Missouri University Of Science And Technology

CAFE Faculty Newsletters

Center for Advancing Faculty Excellence (CAFE) newsletter Dec. 2025.

Data Center Composite Load Model Parameters’ Tuning, Mohammed Sleiman, Amirreza Sahami, Oluwatimilehin Adeosun, Nathaniel Rice, Katelyn Vance

Electrical and Computer Engineering Faculty Research & Creative Works

The vast expansion of data center campuses has created concentrated and highly dynamic electrical loads that challenge traditional transmission system planning and protection studies. This paper presents a novel approach to model the load of data centers and validate their dynamic performance in a composite-load-model (CMLD) framework.

The data center has three major modules: a static element representing the static devices and busway impedance; an electronic-based element constituting power converters such as rectifiers and inverters, associated power supplies, and a motor-based element encompassing the induction nature of chillers, fans and pumps. Each module represented equivalent algebraic and differential equations depicting …

Data Driven Design Of Ultra High Performance Concrete Prospects And Application, Bryan K. Aylas-Paredes, Taihao Han, Advaith Neithalath, Jie Huang, Ashutosh Goel, Aditya Kumar, Narayanan Neithalath

Electrical and Computer Engineering Faculty Research & Creative Works

Ultra-high-performance concrete (UHPC) is a specialized class of cementitious composites that is increasingly used in various applications, including bridge decks, connections between precast components, piers, columns, overlays, and the repair and strengthening of bridge elements. The mechanical and durability properties of UHPC are significantly influenced by factors such as low water-to-binder ratios, the inclusion of supplementary cementitious materials (SCMs), and fiber reinforcement. Machine learning (ML) has been employed to predict the performance of UHPC and optimize its mixture designs by using various raw materials. This study first provides a comprehensive review of ML applications in UHPC, focusing on predicting workability, …

Fluorosilane-Induced Softening And Collapse Of Micropillar Arrays, Gabriela Moreira Lana, Maja Fehlberg, Petra Herbeck-Engel, Gisela Heppe, Raimund Schlüßler, Torsten Jähnke, Eduard Arzt, Roland Bennewitz

Chemical and Biochemical Engineering Faculty Research & Creative Works

Replica molding is a widely used technique for the fabrication of polymer microstructures. As structural dimensions decrease, anti-stick surface treatment of the mold becomes increasingly critical to ensure clean demolding and preserve structural integrity. We fabricated arrays of micropillars with 20 µm diameter and 60 µm height using medical-grade polydimethylsiloxane (PDMS), MDX4-4210, and observed a high fraction of collapsed pillars for the first molding after fluorosilanization of the mold to reduce sticking. To address this issue, we systematically investigated the surface treatment protocol for the molds, made from the PDMS Sylgard 184. We provide results from complementary measurement methods, to …

Synergistic Doping And Coating Strategy For Boosting Na0.7mno2 Cathode Performance In Sodium-Ion Batteries, Ahmad Helaley, Han Yu, Manashi Nath, Xinhua Liang

Chemistry Faculty Research & Creative Works

Advancing sodium-ion battery (SIB) technology requires novel approaches to optimize cathode materials for improved electrochemical performance. In this study, we employ atomic layer deposition (ALD) to precisely modify the surface of P2-type Na_0.7MnO₂ cathodes with different coating materials including ZnO, NiO, and Al₂O₃, followed by post-annealing at 750°C for 10 hours. The strategic combination of ALD and thermal treatment can achieve thin film coating on particle surface and promote element doping into the near-surface lattice, as confirmed by electron energy loss spectroscopy (EELS) analysis. The incorporation of Zn, Al, and Ni results in …

Connected-Component Labeling Using Hls For High-Energy Particle Physics Instruments, Nick Song, Marion Sudvarg, Roger Chamberlain

Computer Science Faculty Research & Creative Works

Many instruments used in high-energy particle physics observations, e.g., gamma-ray telescopes, use FPGAs for front-end signal processing of raw sensor data. The use of high-level synthesis (HLS) to express the signal processing algorithms has the potential to significantly reduce development time for new instruments of this type. We describe our experience with one of the computational stages in the signal processing pipeline, island detection, exploring its implementation across multiple configurations: 1D versus 2D islands, and 4-way versus 8-way connected-component labeling (CCL) in the 2D configuration. We report resource usage and performance for both configurations of 2D island detection, including the …

Modular Architecture For High-Performance And Low Overhead Data Transfers, Rasman Mubtasim Swargo, Engin Arslan, Md Arifuzzaman

Computer Science Faculty Research & Creative Works

High-performance applications necessitate rapid and dependable transfer of massive datasets across geographically dispersed locations. Traditional file transfer tools often suffer from resource underutilization and instability due to fixed configurations or monolithic optimization methods. We propose AutoMDT, a novel Modular Data Transfer Architecture, to address these issues by employing a deep reinforcement learning agent to simultaneously optimize concurrency levels for read, network, and write operations. This solution incorporates a lightweight network-system simulator, enabling offline training of a Proximal Policy Optimization (PPO) agent in approximately 45 minutes on average, thereby overcoming the impracticality of lengthy online training in production networks. AutoMDT's modular …

Modeling And Optimizing Real-Time Telescope Interaction For Multi-Wavelength Observation Of Gamma-Ray Bursts, Ye Htet, Marion Sudvarg, Honghao Yang, Jeremy Buhler, Roger Chamberlain, James Buckley

Computer Science Faculty Research & Creative Works

Multi-wavelength observation of gamma-ray bursts (GRBs) requires real-time interaction among multiple telescopes. A gamma-ray telescope detects and localizes a GRB in the sky and must then communicate with an optical telescope to direct the latter toward the GRB as quickly as possible. We previously developed software for ADAPT, a suborbital gamma-ray telescope, to localize GRBs in real time, on a timescale shorter than that of the GRB itself. This work therefore studies progressive localization, in which ADAPT computes a series of increasingly accurate location estimates during a GRB to enable a partner instrument to more rapidly find it. We describe …

Comparative Study Of Interfacial Bond Strength Of Steel H-Pile With Ultra-High Performance And Polymer Concrete Jacket, Binod Shrestha, Mohanad M. Abdulazeez, Mohamed A. Elgawady

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This study investigates the bond behavior of steel H-pile encased in concrete jackets under push-out loading, considering the effects of concrete type and embedment length. Nine full-scale specimens were tested using three concrete types: ultra-high-performance concrete (UHPC), Methyl Methacrylate Polymer Concrete (MMA-PC), and conventional concrete (CC), with embedment lengths of 63.5 mm, 127 mm, and 190.5 mm. The experimental results revealed that MMA-PC jacket demonstrated the highest bond strength, though gains were marginal beyond 127 mm. UHPC exhibited superior tensile strength and ductility, preventing splitting failure. UHPC also displayed the highest interfacial fracture energy of 9.63 N/mm, exceeding MMA-PC and …

Treatment Intensification Of Digester Dewatering Sidestreams Via Pilot- And Demonstration-Scale Revolving Algal Biofilms At Municipal Water Resource Recovery Facilities, Audrey E. Kocher, Hunter W. Schroer, Christopher A. Marks, Craig L. Just

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

As water resource recovery facilities (WRRFs) pursue decarbonization, the treatment of concentrated side streams from anaerobic digestion offers a critical opportunity to reduce energy use and greenhouse gas emissions. This study evaluated the intensification potential of revolving algal biofilms (RAB) for side stream nutrient removal via partial nitrification at pilot- and demonstration-scales. RAB systems were deployed at municipal WRRFs in Boulder and Iowa City, treating real dewatering side streams across a range of ammonium (NH4⁺–N) surface area loading rates (SALR) reaching up to 196 g N m^–2d^–2. The results demonstrated that RAB systems can …

Proactllm: Proactive Conversational Information Seeking With Large Language Models, Shubham Chatterjee, Xi Wang, Shuo Zhang, Sajad Ebrahimi, Zhaochun Ren, Debasis Ganguly, Gareth Jones, Emine Arrousse, Hamed Zamani

Computer Science Faculty Research & Creative Works

Large Language Models (LLMs) have transformed information access by enabling human-like text understanding and generation. This workshop explores the next step for conversational AI: building proactive information-seeking assistants that go beyond reactive question answering. We aim to investigate how LLMs can anticipate user needs, model complex context, support mixed-initiative interactions, integrate retrieval and external tools, personalize responses, adapt through feedback, and ensure fairness, transparency, and cognitive grounding. Bringing together experts from NLP, IR, HCI, and cognitive science, the workshop will serve as a timely forum for advancing intelligent, proactive dialogue systems. It will also foster interdisciplinary collaboration.

Elucidating The Effects Of Water Activity On The Hydration Kinetics And Thermodynamics Of Ye’Elimite–Calcium Sulfate Hydrate Systems, Godwin I. Ogbuehi, Rupack R. Halder, Aditya Kumar, Gaurav Sant, Monday U. Okoronkwo

Materials Science and Engineering Faculty Research & Creative Works

Relative humidity and water activity (aH) reductions have been known to suppress the hydration of anhydrous cement clinker phases. However, the relationship between ye'elimite (C4A3$) hydration kinetics and water activity remain unclear. This study employs experimental and thermodynamic modeling approaches to investigate the influence of water activity on ye'elimite hydration in the "C4A3$ + water", and "C4A3$ + gypsum + water" systems. Experimental findings indicate that as water activity decreases, C4A3$ hydration diminishes until the reaction is brought to a halt at a threshold aH. The critical aHand corresponding solubility constant of C4A3$ (KC4A3S¯) estimated from thermodynamic analysis are 0.46 …

Quantum Phase Coherent Tunneling In A Mixed-Morphology Superlattice Heterostructure, Qing Shao, Can C. Aygen, Xianyu Chen, Woongkyu Lee, Robert P.H. Chang, Julia E. Medvedeva, Matthew A. Grayson

Physics Faculty Research & Creative Works

Multilayer phase coherence is demonstrated in a mixed morphology superlattice heterostructure, generalizing the paradigm for superlattice miniband engineering. Thirty years since the original proposal by Tsu, a superlattice has been realized with alternating amorphous (a-MoO₃) and polycrystalline (pc-In2O₃) layers, whose high-quality exhibits quantum phase coherence across multiple periods of amorphous barriers. Cross-plane phase coherence is quantified via weak localization signatures in magnetic field under the diffusive Fermi-surface model.

Effects Of Yttrium And Barium Trace Impurities On The Dielectric Properties Of  Srtio3 (111) Single Crystals At Cryogenic Temperatures, Hung Trinh, Alan Devoe, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Commercially available single crystals of (111) SrTiO₃ were found to contain impurities of varying amounts that strongly affected their dielectric performance at cryogenic temperatures. Three crystals with total impurities of 111, 126, and 625 ppm, primarily of barium and yttrium, were analyzed. Relative permittivity (εr) and loss tangent were investigated with high resolution as a function of temperature (4 K to 100 K), DC voltage (0 V/cm to 800 V/cm), and frequency (100 Hz to 1 MHz). An impurity level as low as ≈500 ppm barium resulted in an increase of the maximum permittivity (εm) to approximately 50,000 at …

Enhanced The Simultaneous Recovery/Extraction Of Combined Heavy Metals Of Lead And Vanadium From Synthetic Wastewater Using An Emulsion Liquid Membrane (Elm) With Nanoparticles And Ionic Liquid, Qusay Al-Obaidi, Nora Yehia Selem, Oumaima Karai, Kaoutar Benabderazak, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Recovery/extracting of a combination of lead (Pb(II)) and vanadium (V(V)) ions from wastewater has been enhanced by an emulsion liquid membrane with the presence of magnesium oxide (MgO) or aluminum oxide (Al₂O₃) nanoparticles (20–50 nm size range) in the internal/stripping phase (W1) and ionic liquid ([OMIM] PF6) in the organic/oil phase (O). The study found that the recovery/extraction batch time was shortened, enhancing emulsion extraction efficiency and stability. Furthermore, the study outcomes extend the ELM separation techniques to industrial-scale pollutant recovery/extraction applications, especially heavy metal ions, from industrial effluent. The percentage of Pb(II) recovery/extraction was increased …