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Final Report - Integration Of Aerial Manipulation, Haptics-Based Human-In-The- Loop Control, And Augmented Reality For Bridge Deck Hosing, Paul Oh, Blake Hament, Dongbin Kim Aug 2024

Final Report - Integration Of Aerial Manipulation, Haptics-Based Human-In-The- Loop Control, And Augmented Reality For Bridge Deck Hosing, Paul Oh, Blake Hament, Dongbin Kim

Project AS-9

This Year 5 and Year 6 report integrates the designs, analyses, and results of the previous years. These have culminated into the design, development and deployment of a hosing-drone. This drone carries and 3000 PSI (pounds per square inch) pressure washer often used to clean bridges. This accomplishment leverages the work in aerial manipulation, human-in-the-loop control, haptics, and augmented- and virtual-reality (AR/VR) executed in prior years. Additionally, this report presents results using a cable-driven parallel robot (CDPR) and telescopic mast. This robot provides another platform that has applications in bridge inspection, maintenance and repair.


Meteorological Data Mining And Synthesis For Supplementing On-Site Data For Regulatory Compliance, Ben Sonpon, Shoaib Usman, Joseph Smith, Sarah Kovaleski, Jason Wibbenmeyer Aug 2024

Meteorological Data Mining And Synthesis For Supplementing On-Site Data For Regulatory Compliance, Ben Sonpon, Shoaib Usman, Joseph Smith, Sarah Kovaleski, Jason Wibbenmeyer

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

Many regulatory requirements add significant delay in the licensing of new nuclear power stations. One area of particular interest is the environmental impact of potential atmospheric release. the purpose of this research is to demonstrate effectiveness of meteorological data mining and synthesis from offsite locations to reduce need for onsite data, hence allowing rapid licensing. the automated procedures tested for data mining and extraction of meteorological data from multiple offsite sources and the data analytic tool developed for data fusion are presented here. Three important meteorological parameters from regulatory compliance are considered for this analysis: wind velocity, wind direction, and …


Meteorological Data Mining And Synthesis For Supplementing On-Site Data For Regulatory Compliance, Ben Sonpon, Shoaib Usman, Joseph Smith, Sarah Kovaleski, Jason Wibbenmeyer Aug 2024

Meteorological Data Mining And Synthesis For Supplementing On-Site Data For Regulatory Compliance, Ben Sonpon, Shoaib Usman, Joseph Smith, Sarah Kovaleski, Jason Wibbenmeyer

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

Many regulatory requirements add significant delay in the licensing of new nuclear power stations. One area of particular interest is the environmental impact of potential atmospheric release. The purpose of this research is to demonstrate effectiveness of meteorological data mining and synthesis from offsite locations to reduce need for onsite data, hence allowing rapid licensing. The automated procedures tested for data mining and extraction of meteorological data from multiple offsite sources and the data analytic tool developed for data fusion are presented here. Three important meteorological parameters from regulatory compliance are considered for this analysis: wind velocity, wind direction, and …


Tellurium Enrichment In Copper Tailings: A Mineralogical And Processing Study, José L. Corchado-Albelo, Lana Alagha Aug 2024

Tellurium Enrichment In Copper Tailings: A Mineralogical And Processing Study, José L. Corchado-Albelo, Lana Alagha

Mining Engineering Faculty Research & Creative Works

As the global demand for tellurium (Te) increases, it is crucial to develop efficient recovery methods that consider existing supply streams. This research combines gravity separation and froth flotation processes to enhance the recovery of Te minerals from tailings produced during the beneficiation of copper porphyry ores. Prior to processing, a systematic and comprehensive characterization study of copper tailing (CT) samples was conducted to examine the deportment of Te minerals in different mineral phases and to understand their locking and liberation behavior. Characterization techniques included inductively coupled plasma mass spectrometry (ICP-MS) and TESCAN's integrated mineral analysis (TIMA). Copper tailing characterization …


Determination Of Binary Co2/H2 Adsorption Isotherms And Kinetics Over Porous Organic Cage Cc3 Via Zero-Length Column Technique, Jimmy D.L. Moreno, Kyle Newport, Ali A. Rownaghi, Fateme Rezaei Aug 2024

Determination Of Binary Co2/H2 Adsorption Isotherms And Kinetics Over Porous Organic Cage Cc3 Via Zero-Length Column Technique, Jimmy D.L. Moreno, Kyle Newport, Ali A. Rownaghi, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

Understanding the dynamics of mixed-gas adsorption is essential for industrial-scale adsorptive separations. Also, obtaining binary adsorption isotherms is essential to gain a better understanding of adsorbate-adsorbent interactions in multicomponent gas mixtures. Porous organic cages (POCs) are highly porous, crystalline materials, with a small average pore window that make them promising candidates for separation applications. In this work, we utilized zero-length column (ZLC) technique to not only determine the kinetics of CO2/H2 separation over CC3 but also obtain the binary adsorption isotherms. The ultra crystalline diffusivities of 1.49 x 10–4 and 8.31 x 10–5 cm2 …


Examination And Improvement Of The Taguchi-Based Nanofluids Impact On Co2 Absorption Using Al2o3 Nanoparticles, Safa Waleed Shakir, Saif Saleh Hussein, Shaymaa Hasan Khazaal, Hyder Akram Al-Naseri, Ahmed Mohammed Ahmed, Rana Najah Hachim, Muthanna Hikmat Al-Dahhan Aug 2024

Examination And Improvement Of The Taguchi-Based Nanofluids Impact On Co2 Absorption Using Al2o3 Nanoparticles, Safa Waleed Shakir, Saif Saleh Hussein, Shaymaa Hasan Khazaal, Hyder Akram Al-Naseri, Ahmed Mohammed Ahmed, Rana Najah Hachim, Muthanna Hikmat Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this study, a batch absorption reactor was used to evaluate the nanofluid of a binary aqueous solution of monoethanolamine and 2-amino-2-methyl-1-propanol (MEA/AMP) with nanoparticles of aluminium oxide (Al2O3) as a solvent used to remove carbon dioxide (CO2) from simulated flue gas. Furthermore, the application of the Taguchi experiment design method determined the optimal conditions for the absorption process. This research focuses on the CO2 absorption process and the optimal conditions related to nanoparticle addition. The main effects of using nanofluid were investigated. The concentration of nanoparticles, nanoparticle size, and stirrer speeds were …


Carbon Capture And Renewable Energy Policies: Could Policy Harmonization Be A Puzzle Piece To Solve The Electricity Crisis?, Mahelet G. Fikru, Fateh Belaïd, Hongyan Ma Aug 2024

Carbon Capture And Renewable Energy Policies: Could Policy Harmonization Be A Puzzle Piece To Solve The Electricity Crisis?, Mahelet G. Fikru, Fateh Belaïd, Hongyan Ma

Economics Faculty Research & Creative Works

The electricity market crisis, driven by factors such as increased energy demand, rising fuel prices, aging infrastructure, and greenhouse gas emissions, requires a multifaceted approach including the strategic implementation of Carbon Capture and Storage (CCS) technologies, which despite high costs and potential adverse impact on renewable investments, can allow the use of fossil fuels to maintain grid stability, and simultaneously lower carbon footprint. Across the world, several nations are designing financial incentives and improving regulatory frameworks to reduce barriers to the deployment of CCS. However, it is not clearly understood whether and to what extent such policy support would affect …


Heat Treatment Post-Processing For The Improved Mechanical Properties Of Scalmalloy® Processed Via Directed Energy Deposition, Rachel Boillat-Newport, Sriram Praneeth Isanaka, Frank Liou Aug 2024

Heat Treatment Post-Processing For The Improved Mechanical Properties Of Scalmalloy® Processed Via Directed Energy Deposition, Rachel Boillat-Newport, Sriram Praneeth Isanaka, Frank Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

As high-strength aluminum alloys present several processability issues with additive manufacturing (AM), Scalmalloy®, an Al-Mg-Sc-Zr-based alloy, has been developed. This alloy is age-hardenable, allowing it to precipitate out a strengthening precipitate phase, Al3(Sc,Zr). The manufacturer recommends a single-stage aging treatment at 325 °C for 4 h; however, the majority of the literature studies utilize a powder bed processing known as selective laser melting (SLM) over powder-fed processing directed energy deposition (DED). This study addresses the lack of information on heat treatments for DED fabrication by exploring the application of artificial aging temperatures of 300–400 °C for 2, 4, and 6 …


Tectonic Implications Of Seismic Anisotropy Layering Beneath The Southern Tibetan Plateau Revealed By Integrated Shear Wave Splitting And Receiver Function Analyses, Cong Shen, Stephen S. Gao, Fansheng Kong, Kelly H. Liu Aug 2024

Tectonic Implications Of Seismic Anisotropy Layering Beneath The Southern Tibetan Plateau Revealed By Integrated Shear Wave Splitting And Receiver Function Analyses, Cong Shen, Stephen S. Gao, Fansheng Kong, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To investigate continental dynamics underneath the south-central Tibetan plateau, which composes the Himalayan, Lhasa, and Qiangtang blocks, we have conducted comprehensive examinations of seismic azimuthal anisotropy in the crust using receiver functions (RFs) and crustal and mantle anisotropy using teleseismic shear wave splitting (SWS) analysis. In the Qiangtang block, the observed predominantly E-W fast orientations from RF and SWS analyses with similar magnitude are interpreted as resulting from eastward crustal flow with minor contributions from the mantle. In the Lhasa block, the crustal anisotropy is approximately N-S oriented, which is parallel to the strike of rift basins and southward crustal …


Novel Emergent Phases In A Two-Dimensional Superconductor, Simrandeep Kaur, Hemanta Kumar Kundu, Sumit Kumar, Anjana Dogra, Rajesh Narayanan, Thomas Vojta, Aveek Bid Aug 2024

Novel Emergent Phases In A Two-Dimensional Superconductor, Simrandeep Kaur, Hemanta Kumar Kundu, Sumit Kumar, Anjana Dogra, Rajesh Narayanan, Thomas Vojta, Aveek Bid

Physics Faculty Research & Creative Works

In this letter, we report our observation of an extraordinarily rich phase diagram of a LaScO3/SrTiO3 heterostructure. Close to the superconducting transition temperature, the system hosts a superconducting critical point of the Infinite-randomness type characterized by an effective dynamical exponent ν z that diverges logarithmically. At lower temperatures, we find the emergence of a magnetic field-tuned metallic phase that co-exists with a quantum Griffiths phase (QGP). Our study reveals a previously unobserved phenomenon in 2D superconductors—an unanticipated suppression of the QGP below a crossover temperature in this system. This concealment is accompanied by the destruction of the …


Design And Development Of Uio-67-Coated Pim-1-Based Composites And Demonstration Of Their Detoxification Performance, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei Aug 2024

Design And Development Of Uio-67-Coated Pim-1-Based Composites And Demonstration Of Their Detoxification Performance, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

Polymer-supported MOF composites have emerged as versatile candidates for various separation and catalytic applications. In this study, we demonstrate design and development of UiO-67-coated Ce(OH)4@PIM-1 composites via dip-coating, drop-casting, solid-phase coating, and supramolecular assembly, and assess their preparation-structure-performance relations. The catalytic performance of the composites was investigated through hydrolysis of dimethyl 4-nitrophenyl phosphate (DMNP), as a nerve agent simulant. The findings revealed that while dip-coating method was unable to achieve a thick and uniform coverage of the MOF layer on the Ce(OH)4@PIM-1, the supramolecular assembly gave rise to 16 wt.% MOF loading and the composite prepared …


Instantons In Φ4 Theories: Transseries, Virial Theorems, And Numerical Aspects, Ludovico T. Giorgini, Ulrich D. Jentschura, Enrico M. Malatesta, Tommaso Rizzo, Jean Zinn-Justin Aug 2024

Instantons In Φ4 Theories: Transseries, Virial Theorems, And Numerical Aspects, Ludovico T. Giorgini, Ulrich D. Jentschura, Enrico M. Malatesta, Tommaso Rizzo, Jean Zinn-Justin

Physics Faculty Research & Creative Works

We discuss numerical aspects of instantons in two- and three-dimensional φ4 theories with an internal O(N) symmetry group, the so-called N-vector model. By combining asymptotic transseries expansions for large arguments with convergence acceleration techniques, we obtain high-precision values for certain integrals of the instanton that naturally occur in loop corrections around instanton configurations. Knowledge of these numerical properties is necessary in order to evaluate corrections to the large-order factorial growth of perturbation theory in φ4 theories. The results contribute to the understanding of the mathematical structures underlying the instanton configurations.


Influence Of Aggregate Properties On Skid Resistance Of Pavement Surface Treatments, Alireza Roshan, Magdy Abdelrahman Aug 2024

Influence Of Aggregate Properties On Skid Resistance Of Pavement Surface Treatments, Alireza Roshan, Magdy Abdelrahman

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Skid resistance is a critical aspect for traffic safety since it significantly influences vehicle control and minimizes the distance required for emergency braking. The surface characteristics of pavements play a pivotal role in determining skid resistance. To achieve the optimal skid resistance performance, the pavement must sustain a specific level of friction. Thus, it is advantageous to apply surface treatments in areas that require enhanced friction. This study investigates the impact of factors such as the aggregate source, size, morphological properties, and abrasion levels on the skid resistance and frictional characteristics of a high-friction surface treatment (HFST). A complete investigation …


The Effectiveness Of Waste Tire Pyrolysis Oils (Wtpos) As Rejuvenating Agents For Asphalt Materials, Ahmed S. El-Ashwah, Magdy Abdelrahman Aug 2024

The Effectiveness Of Waste Tire Pyrolysis Oils (Wtpos) As Rejuvenating Agents For Asphalt Materials, Ahmed S. El-Ashwah, Magdy Abdelrahman

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The continuous increase in solid waste materials, such as waste tires, underscores the critical importance of recycling them to mitigate environmental impact and promote sustainable resource management. This research study evaluated the effectiveness of utilizing waste tire pyrolysis oils (WTPOs) as recycling agents for asphalt materials. The chemical composition and thermal behavior of WTPO were analyzed using Fourier transform infrared (FT-IR) spectroscopy and thermogravimetric analysis (TGA). Mechanically, the prepared WTPO binders were assessed by measuring dynamic viscosity and changes in high- and intermediate-temperature performance grades. Additionally, the cracking susceptibility of the binders was evaluated using the Glover-Rowe (G-R) parameter. The …


Indefinability Of Effective Stress For Unsaturated Soils, Xiong Zhang, Sandra Houston Aug 2024

Indefinability Of Effective Stress For Unsaturated Soils, Xiong Zhang, Sandra Houston

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

For decades, researchers have searched for an unsaturated soil effective stress that performs analogously to effective stress for saturated soils and provides some simplifications over net stress and suction approaches. A recent debate is whether problems identified with unsaturated soil effective stress can be resolved via elastoplastic analyses. Effective stress equations are reviewed and categorized as being based on volume change, shear strength, yield, or degree of saturation. These equations are evaluated for consistency with saturated soil effective stress expectations using the Barcelona basic model (BBM), simplified into an integrated elastoplastic framework using the modified state surface approach (MSSA). Under …


Extrudability Window And Offline Test Methods To Predict Buildability Of 3d Printing Concrete, Yu Cun Gu, Kamal H. Khayat Aug 2024

Extrudability Window And Offline Test Methods To Predict Buildability Of 3d Printing Concrete, Yu Cun Gu, Kamal H. Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This Study Investigates the Effect of Thixotropy and Stiffness Evolution on the Extrudability and Buildability of 3D Printing Concrete. Different Types of Supplementary Cementitious Materials and Limestone Filler Were Used to Prepare Mortars with Varying Levels of Thixotropy and Early-Age Stiffness. Mixtures with Yield Stress and Flocculation (Τfloc) of 180–400 and 420–950 Pa, Respectively, Exhibited Adequate Extrudability Without Plastic Collapse. the Printing Was Completed 8–15 Min after Mixing at a Vertical Build-Up Rate of 138 Mm/min. Several Process Parameters, Including Rest Time to Secure a Penetration Resistance of 150 KPa (T150) and Penetration Resistance at Various Rest Times Were Developed …


Quantifying The Impact Of Technology Utilization On Schedule And Cost Performance In Construction Projects, Fareed Salih, Islam H. El-Adaway Aug 2024

Quantifying The Impact Of Technology Utilization On Schedule And Cost Performance In Construction Projects, Fareed Salih, Islam H. El-Adaway

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

There Has Been a Plethora of Research on the Performance of Schedule and Cost in Construction Projects. However, Current Research Falls Short in Investigating the Combined Contribution of Different Construction Technologies on Project Performance Metrics. Specifically, None of the Previous Efforts Have Used Integrated Earned Value Management (EVM) Parameters and Utilized Construction Technologies to Assess Project Schedule and Cost Performance. This Paper Fills This Knowledge Gap. to This End, a Multistep Research Methodology Was Employed to (1) Explore the Utilization Ratings of 13 Construction Technologies based on Data Collected from 52 Industry Experts; (2) Rank These Technologies in Terms of …


Rheology Modification Of Flowable Mortar With Co2, Sean Monkman, Soo Duck Hwang, Kamal Khayat Aug 2024

Rheology Modification Of Flowable Mortar With Co2, Sean Monkman, Soo Duck Hwang, Kamal Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The Rheological Properties of Mortar Samples with Different Additions of CO2 during Mixing Were Determined. Flowable Cement-Based Mortars at Three Different W/c (0.55, 0.45 and 0.35) Were Produced and the Effects of CO2 Gas Were Examined on the Fresh Properties of Slump Flow, Yield Stress and Plastic Viscosity. According to the Experimental Results, the Mortar Yield Stress and Plastic Viscosity Increased Faster over Time Than in a Reference System with the Increasing Addition of CO2 and Greater Effects Were Seen at the Lowest W/c of 0.35 Than at the Others. the Impact of the CO2 on …


Accelerating The Circular Economy Transition: A Construction Value Chain-Structured Portfolio Of Strategies And Implementation Insights, Radwa Eissa, Islam H. El-Adaway Aug 2024

Accelerating The Circular Economy Transition: A Construction Value Chain-Structured Portfolio Of Strategies And Implementation Insights, Radwa Eissa, Islam H. El-Adaway

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Despite the Increasing Recognition of the Potential of Circular Economy (CE) Strategies, their Effective Application to Decarbonize the Construction Value Chain Faces Multiple Challenges. Ambiguity Surrounding CE, stemming from a Lack of Clarity on Actionable Strategies, is a Common Concern. Existing Studies Lack a Holistic Approach for Systematically Integrating CE Principles throughout the Construction Value Chain, resulting in a Scarcity of Information on How to Practically Adopt CE within Projects. This Research Aims to Accelerate CE Adoption by Creating a Value Chain-Structured Portfolio of CE Strategies and Analyzing the Implementation of Such Strategies in Actual Projects. to This End, a …


Effect Of Absorption Kinetics Of Superabsorbent Polymers On Printability And Interlayer Bond Of 3d Printing Concrete, Yu Cun Gu, Shuyi Zheng, Hongyan Ma, Wu Jian Long, Kamal H. Khayat Aug 2024

Effect Of Absorption Kinetics Of Superabsorbent Polymers On Printability And Interlayer Bond Of 3d Printing Concrete, Yu Cun Gu, Shuyi Zheng, Hongyan Ma, Wu Jian Long, Kamal H. Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This study examines the effect of the material characteristics of superabsorbent polymers (SAPs) on the printability and interlayer bond strength of 3D printing concrete. Three types of SAP, including two acrylamide-co-acrylic polymers with coarse and fine particle sizes (S1 and S2) and an acrylic copolymer (S3), were employed. The investigated mortar mixtures had a fixed initial mini-slump flow of 195 ± 10 mm and yield stress of 290 ± 25 Pa. The fluidity of SAP-incorporated mortars was maintained by either adjusting the superplasticizer dosage or increasing the water content. Test results indicate that particle flocculation is dependent on SAP absorption …


Carbon Capture And Renewable Energy Policies: Could Policy Harmonization Be A Puzzle Piece To Solve The Electricity Crisis?, Mahelet G. Fikru, Fateh Belaïd, Hongyan Ma Aug 2024

Carbon Capture And Renewable Energy Policies: Could Policy Harmonization Be A Puzzle Piece To Solve The Electricity Crisis?, Mahelet G. Fikru, Fateh Belaïd, Hongyan Ma

Economics Faculty Research & Creative Works

The electricity market crisis, driven by factors such as increased energy demand, rising fuel prices, aging infrastructure, and greenhouse gas emissions, requires a multifaceted approach including the strategic implementation of Carbon Capture and Storage (CCS) technologies, which despite high costs and potential adverse impact on renewable investments, can allow the use of fossil fuels to maintain grid stability, and simultaneously lower carbon footprint. Across the world, several nations are designing financial incentives and improving regulatory frameworks to reduce barriers to the deployment of CCS. However, it is not clearly understood whether and to what extent such policy support would affect …


The Presence Of Popular Business Titles In Abld Collections, Georgette Nicolosi, Lauren Reiter Jul 2024

The Presence Of Popular Business Titles In Abld Collections, Georgette Nicolosi, Lauren Reiter

University Libraries Faculty Research & Creative Works

Perspectives on the inclusion of popular reading titles within academic libraries have varied over the past few decades. While literature on the purpose of subject-specific fiction titles within academic reading collections exists, research on subject-specific non-fiction items is absent from the literature. The authors of this study recognize the ways in which popular business titles serve numerous purposes within their own institutions. As such, this study seeks to explore the holdings of popular business titles within academic libraries, and whether their physical location can provide an understanding of the perceptions of business leisure reading within academic research institutions. This study …


A Human-Centered Power Conservation Framework Based On Reverse Auction Theory And Machine Learning, Enrico Casella, Simone Silvestri, Denise A. Baker, Sajal K. Das Jul 2024

A Human-Centered Power Conservation Framework Based On Reverse Auction Theory And Machine Learning, Enrico Casella, Simone Silvestri, Denise A. Baker, Sajal K. Das

Computer Science Faculty Research & Creative Works

Extreme outside temperatures resulting from heat waves, winter storms, and similar weather-related events trigger the Heating Ventilation and Air Conditioning (HVAC) systems, resulting in challenging, and potentially catastrophic, peak loads. As a consequence, such extreme outside temperatures put a strain on power grids and may thus lead to blackouts. To avoid the financial and personal repercussions of peak loads, demand response and power conservation represent promising solutions. Despite numerous efforts, it has been shown that the current state-of-the-art fails to consider (1) the complexity of human behavior when interacting with power conservation systems and (2) realistic home-level power dynamics. As …


Modeling Powder Spreadability In Powder-Based Processes Using The Discrete Element Method, Austin T. Sutton, M. Hossein Sehhat, Ming C. Leu, Joseph W. Newkirk Jul 2024

Modeling Powder Spreadability In Powder-Based Processes Using The Discrete Element Method, Austin T. Sutton, M. Hossein Sehhat, Ming C. Leu, Joseph W. Newkirk

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Powder-bed fusion (PBF) processes refer to a subset of Additive Manufacturing (AM) techniques where powder is spread on the build-plate before melting (by a laser or electron beam). While PBF processes are attractive due to their ability for realizing complex structures that are either difficult or impossible to create through conventional means, the parts fabricated with these techniques can exhibit defects such as pores, inclusions, and excessive surface roughness. To minimize these defects, much research has been dedicated towards process maturation by optimizing laser or electron beam parameters. However, these developmental efforts typically do not address the recoating process where …


Kinetic Characterization And Identification Of Key Active Site Residues Of The L-Aspartate N-Hydroxylase, Cree, Sydney B. Johnson, Hannah Valentino, Pablo Sobrado Jul 2024

Kinetic Characterization And Identification Of Key Active Site Residues Of The L-Aspartate N-Hydroxylase, Cree, Sydney B. Johnson, Hannah Valentino, Pablo Sobrado

Chemistry Faculty Research & Creative Works

CreE is a flavin-dependent monooxygenase (FMO) that catalyzes three sequential nitrogen oxidation reactions of L-aspartate to produce nitrosuccinate, contributing to the biosynthesis of the antimicrobial and antiproliferative natural product, cremeomycin. This compound contains a highly reactive diazo functional group for which the reaction of CreE is essential to its formation. Nitro and diazo functional groups can serve as potent electrophiles, important in some challenging nucleophilic addition reactions. Formation of these reactive groups positions CreE as a promising candidate for biomedical and synthetic applications. Here, we present the catalytic mechanism of CreE and the identification of active site residues critical to …


Kinetic Characterization And Identification Of Key Active Site Residues Of The L-Aspartate N-Hydroxylase, Cree, Sydney B. Johnson, Hannah Valentino, Pablo Sobrado Jul 2024

Kinetic Characterization And Identification Of Key Active Site Residues Of The L-Aspartate N-Hydroxylase, Cree, Sydney B. Johnson, Hannah Valentino, Pablo Sobrado

Chemistry Faculty Research & Creative Works

CreE is a flavin-dependent monooxygenase (FMO) that catalyzes three sequential nitrogen oxidation reactions of L-aspartate to produce nitrosuccinate, contributing to the biosynthesis of the antimicrobial and antiproliferative nautral product, cremeomycin. This compound contains a highly reactive diazo functional group for which the reaction of CreE is essential to its formation. Nitro and diazo functional groups can serve as potent electrophiles, important in some challenging nucleophilic addition reactions. Formation of these reactive groups positions CreE as a promising candidate for biomedical and synthetic applications. Here, we present the catalytic mechanism of CreE and the identification of active site residues critical to …


Examining The Oxidation States Of Metals In Aerosols Emitted By Electronic Cigarettes, Kashala Fabrice Kapiamba, Stephen Yaw Owusu, Yangtao Wu, Yue-Wern Huang, Yi Jiang, Yang Wang Jul 2024

Examining The Oxidation States Of Metals In Aerosols Emitted By Electronic Cigarettes, Kashala Fabrice Kapiamba, Stephen Yaw Owusu, Yangtao Wu, Yue-Wern Huang, Yi Jiang, Yang Wang

Biological Sciences Faculty Research & Creative Works

Electronic cigarettes (ECs) emit many toxic substances, including metals, that can pose a threat to users and the environment. The toxicity of the emitted metals depends on their oxidation states. Hence, this study examines the oxidation states of metals observed in EC aerosols. X-ray photoelectron spectroscopy analysis of the filters that collected EC aerosols identified the oxidation states of five primary metals (based on surface sample analysis), including chromium(III) (close to 100%) under low power setting while a noticeable amount of chromium(VI) (15%) at higher power settings of the EC, and copper(II) (100%), zinc(II) (100%), nickel(II) (100%), lead(II) (65%), and …


Hybrid Mechanism Of Electrical Breakdown In Ferroelectric Materials Under High-Pressure Shock Loading, Sergey I. Shkuratov, Jason Baird, Vladimir G. Antipov, Jay B. Chase, Christopher S. Lynch Jul 2024

Hybrid Mechanism Of Electrical Breakdown In Ferroelectric Materials Under High-Pressure Shock Loading, Sergey I. Shkuratov, Jason Baird, Vladimir G. Antipov, Jay B. Chase, Christopher S. Lynch

Mining Engineering Faculty Research & Creative Works

The unique ability of ferroelectrics to generate high voltage under shock loading is limited by electrical breakdown within the shock-compressed ferroelectric material. Breakdown is a hybrid process of initiation and growth. The possible mechanisms of electrical breakdown in ferroelectric films and bulk ceramics subjected to high-pressure shock loading are discussed and experiments designed to elucidate which mechanisms govern breakdown. Gigapascal shock loading experiments were performed on poled Pb0.99(Zr0.95Ti0.05)0.98Nb0.02O3 ferroelectric film specimens in the range of 32-156 μm thickness to determine the dependence of the breakdown field on thickness and …


Development Of Multivariate-Coupled Grouting Diffusion Model For Rcc, Xiao Sun, Yao Wang, Hengrui Liu, Zhuanjia Yang, Hongyan Ma Jul 2024

Development Of Multivariate-Coupled Grouting Diffusion Model For Rcc, Xiao Sun, Yao Wang, Hengrui Liu, Zhuanjia Yang, Hongyan Ma

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The Grouting Quality of Grout-Enriched Roller Compacted Concrete (RCC) is Difficult to Be Quantified Due to the Fact that the Crucial Effects, Such as Infiltration and the Compaction of the Skeleton of the RCC, Are Not Taken into Consideration. Combined with Model Testing, This Study Proposes an Improved Grouting Prediction Model Which Considers the Coupling Effect of Pore Fractal Properties, Time Variation of Grout Rheological Properties and Infiltration. Moreover, the Influence of Construction Parameters Such as Grouting Parameters, Construction Period Selection, Grouting Pipe Arrangement on the Grouting Effect Was Clarified. the Tests Indicated that the Maximum Diffusion Range of Slurry …


Trec Ikat 2023: A Test Collection For Evaluating Conversational And Interactive Knowledge Assistants, Mohammad Aliannejadi, Zahra Abbasiantaeb, Shubham Chatterjee, Jeffrey Dalton, Leif Azzopardi Jul 2024

Trec Ikat 2023: A Test Collection For Evaluating Conversational And Interactive Knowledge Assistants, Mohammad Aliannejadi, Zahra Abbasiantaeb, Shubham Chatterjee, Jeffrey Dalton, Leif Azzopardi

Computer Science Faculty Research & Creative Works

Conversational information seeking has evolved rapidly in the last few years with the development of Large Language Models (LLMs), providing the basis for interpreting and responding in a naturalistic manner to user requests. The extended TREC Interactive Knowledge Assistance Track (iKAT) collection aims to enable researchers to test and evaluate their Conversational Search Agent (CSA). The collection contains a set of 36 personalized dialogues over 20 different topics each coupled with a Personal Text Knowledge Base (PTKB) that defines the bespoke user personas. A total of 344 turns with approximately 26,000 passages are provided as assessments on relevance, as well …