Digital Commons Network^™

Novel Porous Polymer Compositions For The Synthesis Of Monolithic Bimodal Microporous/Macroporous Carbon Compositions Useful For Selective Co₂ Sequestration, Nicholas Leventis, Chariklia Sotiriou-Leventis, Malik Adnan Saeed

Chemistry Faculty Research & Creative Works

The present invention discloses novel porous polymeric compositions comprising random copolymers of amides, imides, ureas, and carbamic-anhydrides, useful for the synthesis of monolithic bimodal microporous/macroporous carbon aerogels. It also discloses methods for producing said microporous/macroporous carbon aerogels by the reaction of a polyisocyanate compound and a polycarboxylic acid compound, followed by pyrolytic carbonization, and by reactive etching with CO₂ at elevated temperatures. Also disclosed are methods for using the microporous/macroporous carbon aerogels in the selective capture and sequestration of carbon dioxide.

Signatures Of Autoionization In The Angular Electron Distribution In Two-Photon Double Ionization Of Ar, S. Augustin, Michael Schulz, G. Schmid, K. Schnorr, E. V. Gryzlova, H. Lindenblatt, S. Meister, Y. F. Liu, F. Trost, L. Fechner, A. N. Grum-Grzhimailo, S. M. Burkov, M. Braune, R. Treusch

Physics Faculty Research & Creative Works

A kinematically complete experiment on two-photon double ionization of Ar by free-electron laser radiation with a photon energy of 27.93 eV was performed. The electron energy spectra show that double ionization is dominated by the sequential process. Comparison of the electron angular distributions to our data for single ionization and to theory confirms that even in the sequential process the electrons from both ionization steps are correlated with each other through polarization of the intermediate Ar+ state. Furthermore, a very important role of autoionization in both ionization steps is found.

Solid State Nmr Spectroscopy/Imaging In Situ Measuring Devices And Methods For Calibration And Determining One Or More Quantitative Properties Of A Target Sample, Lingyu Chi, Ming Huang, Rex E. Gerald, Klaus Woelk

Chemistry Faculty Research & Creative Works

In situ measuring devices, methods of making the same, and methods of using the same are provided herein. The in situ measuring devices can include a capillary tube having a reference material sealed inside the capillary tube, where the capillary tube is positioned inside of a solid state or MAS NMR rotor. A target sample can also be positioned in the interior of the solid state or MAS NMR rotor but is sequestered from the reference material by a capillary tube wall. The in situ measuring devices can be used in solid state MAS NMR spectroscopy to quantify one or …

Solid State Nmr Spectroscopy/Imaging In Situ Measuring Devices And Methods For Calibration And Determining One Or More Quantitative Properties Of A Target Sampleabstract, Lingyu Chi, Ming Huang, R. Gerald Ii, Klaus Woelk

Chemistry Faculty Research & Creative Works

In situ measuring devices, methods of making the same, and methods of using the same are provided herein. The in situ measuring devices can include a capillary tube having a reference material sealed inside the capillary tube, where the capillary tube is positioned inside of a solid state or MAS NMR rotor. A target sample can also be positioned in the interior of the solid state or MAS NMR rotor but is sequestered from the reference material by a capillary tube wall. The in situ measuring devices can be used in solid state MAS NMR spectroscopy to quantify one or …

A Further Extension Of The Extended Riemann-Liouville Fractional Derivative Operator, Martin Bohner, Gauhar Rahman, Shahid Mubeen, Kottakkaran Sooppy Nisar

Mathematics and Statistics Faculty Research & Creative Works

The main objective of this paper is to establish the extension of an extended fractional derivative operator by using an extended beta function recently defined by Parmar et al. by considering the Bessel functions in its kernel. We also give some results related to the newly defined fractional operator, such as Mellin transform and relations to extended hypergeometric and Appell's function via generating functions.

Locomotion Of A Cylindrical Rolling Robot With A Shape Changing Outer Surface, Michael G. Puopolo, Jamey D. Jacob, Emilio Gabino

Mechanical and Aerospace Engineering Faculty Research & Creative Works

A cylindrical rolling robot is developed that generates roll torque by changing the shape of its flexible, elliptical outer surface whenever one of four elliptical axes rotates past an inclination called trigger angle. The robot is equipped with a sensing/control system by which it measures angular position and angular velocity, and computes error with respect to a desired step angular velocity profile. When shape change is triggered, the newly assumed shape of the outer surface is determined according to the computed error. A series of trial rolls is conducted using various trigger angles, and energy consumed by the actuation motor …

Multi-Task Allocation In Mobile Crowd Sensing With Individual Task Quality Assurance, Jiangtao Wang, Yasha Wang, Daqing Zhang, Feng Wang, Haoyi Xiong, Chao Chen, Qin Lv, Zhaopeng Qiu

Computer Science Faculty Research & Creative Works

Task allocation is a fundamental research issue in mobile crowd sensing. While earlier research focused mainly on single tasks, recent studies have started to investigate multi-task allocation, which considers the interdependency among multiple tasks. A common drawback shared by existing multi-task allocation approaches is that, although the overall utility of multiple tasks is optimized, the sensing quality of individual tasks may become poor as the number of tasks increases. To overcome this drawback, we re-define the multi-task allocation problem by introducing task-specific minimal sensing quality thresholds, with the objective of assigning an appropriate set of tasks to each worker such …

Metaphysics Or Metaphors For The Anthropocene? Scientific Naturalism And The Agency Of Things, Patrick Gamez

Arts, Languages and Philosophy Faculty Research & Creative Works

In this paper, I provide the outlines of an alternative meta philosophical orientation for Continental philosophy, namely, a form of scientific naturalism that has proximate roots in the work of Bachelard and Althusser. I describe this orientation as an "alternative" insofar as it provides a framework for doing justice to some of the motivations behind the recent revival of metaphysics in Continental philosophy, in particular its ecological-ethical motivations. In the second section of the paper, I demonstrate how ecological-ethical issues motivate new metaphysicians like Bruno Latour, Jane Bennett, Timothy Morton, Ian Bogost, and Graham Harman to impute to objects real …

A Spatio-Temporal Model Reveals Self-Limiting Fcɛri Cross-Linking By Multivalent Antigens, Md Shahinuzzaman, Jawahar Khetan, Dipak Barua

Chemical and Biochemical Engineering Faculty Research & Creative Works

Aggregation of cell surface receptor proteins by multivalent antigens is an essential early step for immune cell signalling. A number of experimental and modelling studies in the past have investigated multivalent ligand-mediated aggregation of IgE receptors (FcɛRI) in the plasma membrane of mast cells. However, understanding of the mechanisms of FcɛRI aggregation remains incomplete. Experimental reports indicate that FcɛRI forms relatively small and finite-sized clusters when stimulated by a multivalent ligand. By contrast, modelling studies have shown that receptor cross-linking by a trivalent ligand may lead to the formation of large receptor superaggregates that …

Missouri S&T Magazine Fall/Winter 2018, Missouri S&T Marketing And Communications Department, Miner Alumni Association

Missouri S&T Magazine

No abstract provided.

Tunnel Diode Resonator For Precision Magnetic Susceptibility Measurements In A Mk Temperature Range And Large Dc Magnetic Fields, Hyunsoo Kim, M. A. Tanatar, R. Prozorov

Physics Faculty Research & Creative Works

Precision radio-frequency measurements of the magnetic susceptibility using the tunnel diode resonator (TDR) technique are used to study the delicate effects in magnetic and superconducting materials. High resolution (in ppb range) measurements are particularly important for studies of the London and Campbell penetration depths in a superconductor and for the investigation of magnetic transitions in (anti)ferromagnets. Due to the small rf magnetic-excitation in a mOe range, the TDR is especially useful at low-temperatures in a mK range, if Joule heating generated in the TDR circuitry is efficiently removed and the circuit is stabilized with sub-mK precision. Unfortunately, the circuit has …

Electronic Fingerprints Of Cr And V Dopants In The Topological Insulator Sb₂Te₃, Wenhan Zhang, Damien West, Seng Huat Lee, Yunsheng Qiu, Cui-Zu Chang, Jagadeesh S. Moodera, Yew San Hor, Shengbai Zhang, Weida Wu

Physics Faculty Research & Creative Works

By combining scanning tunneling microscopy/spectroscopy and first-principles calculations, we systematically study the local electronic states of magnetic dopants V and Cr in the topological insulator (TI) Sb₂Te₃. Spectroscopic imaging shows diverse local defect states between Cr and V, which agree with our first-principle calculations. The unique spectroscopic features of V and Cr dopants provide electronic fingerprints for the codoped magnetic TI samples with the enhanced quantum anomalous Hall effect. Our results also facilitate the exploration of the underlying mechanism of the enhanced quantum anomalous Hall temperature in Cr/V codoped TIs.

Gravitational Effects In G -Factor Measurements And High-Precision Spectroscopy: Limits Of Einstein's Equivalence Principle, Ulrich D. Jentschura

Physics Faculty Research & Creative Works

We study the interplay of general relativity, the equivalence principle, and high-precision experiments involving atomic transitions and g-factor measurements. In particular, we derive a generalized Dirac Hamiltonian, which describes both the gravitational coupling for weak fields and the electromagnetic coupling, e.g., to a central Coulomb field. An approximate form of this Hamiltonian is used to derive the leading gravitational corrections to transition frequencies and g factors. The position dependence of atomic transitions is shown to be compatible with the equivalence principle, up to a very good approximation. The compatibility of g-factor measurements requires a deeper subtle analysis in order to …

Advanced Metal Oxides And Nitrides Thermoelectric Materials For Energy Harvesting, Yining Feng, Evan Witkoske, Elizabeth S. Bell, Yang Wang, Athanasios Tzempelikos, Ian T. Ferguson, Na Lu

Electrical and Computer Engineering Faculty Research & Creative Works

Metal oxides and nitrides are widely used in many applications as a result of their high mechanical, chemical, and electrical properties. In high temperature thermoelectric applications, oxides and nitrides exhibit high thermopower and thermal stability. Moreover, most oxides and nitrides are consisted of earth abundant elements, which are non-toxic, cost effective and easy for large-scale synthesis. In this article, we reviewed the recent advances of metal oxides and nitrides and their applications in thermoelectric. The materials that are examined include both p-type semiconductors (e.g. NaxCoO₂, Ca₃Co₄O₉, GaN) and n-type semiconductors (e.g. ZnO-based, …

Graphene-Based Materials For The Fast Removal Of Cytokines From Blood Plasma, Mykola Seredych, Bernard Haines, Viktoriia Sokolova, Paul Cheung, Fayan Meng, Lon Stone, Lyuba Mikhalovska, Sergey Mikhalovsky, Vadym Mochalin, Yury Gogotsi

Chemistry Faculty Research & Creative Works

There is a range of medical conditions, which include acute organ failure, bacterial and viral infection, and sepsis, that result in overactivation of the inflammatory response of the organism and release of proinflammatory cytokines into the bloodstream. Fast removal of these cytokines from blood circulation could offer a potentially efficient treatment of such conditions. This study aims at the development and assessment of novel biocompatible graphene-based adsorbents for blood purification from proinflammatory cytokines. These graphene-based materials were chosen on the basis of their surface accessibility for small molecules further facilitated by the interlayer porosity, which is comparable to the size …

Effect Of Environmental Variables On Ti-64 Am Simulation Results, Aaron Flood, Frank W. Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

In metal AM the environment is critical and therefore care should be taken to ensure that the simulation matches reality. This paper will investigate the effect that various environmental factors have on the results of the simulation. This will help to determine their importance in the simulation setup. The material properties which relate to this are the convective coefficient and the emissivity. These material properties will be investigated to determine their effect on the outcome of the simulation. In addition to these properties, the size of the substrate will be investigated to determine if any results are altered. Lastly, the …

A Distributed Semi-Supervised Platform For Dnase-Seq Data Analytics Using Deep Generative Convolutional Networks, Shayan Shams, Richard Platania, Joohyun Kim, Jian Zhang, Kisung Lee, Seungwon Yang, Seung Jong Park

Computer Science Faculty Research & Creative Works

A deep learning approach for analyzing DNase-seq datasets is presented, which has promising potentials for unraveling biological underpinnings on transcription regulation mechanisms. Further understanding of these mechanisms can lead to important advances in life sciences in general and drug, biomarker discovery, and cancer research in particular. Motivated by recent remarkable advances in the field of deep learning, we developed a platform, Deep Semi-Supervised DNase-seq Analytics (DSSDA). Primarily empowered by deep generative Convolutional Networks (ConvNets), the most notable aspect is the capability of semi-supervised learning, which is highly beneficial for common biological settings often plagued with a less sufficient number of …

Co2-Eor Mechanisms In Huff-N-Puff Operations In Shale Oil Reservoirs Based On History Matching Results, Dheiaa Alfarge, Mingzhen Wei, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Improved Oil Recovery (IOR) techniques in Unconventional Liquids Rich Reservoirs (ULR) are still a new concept because there is no commercial project for any IOR technique so far. Carbon dioxide (CO₂) based EOR technique has been effectively applied to improve oil recovery in the tight formations of conventional reservoirs. Extending this approach to unconventional formations has been extensively investigated over the last decade because CO₂ has unique properties which make it the first option of EOR methods to be tried. However, the applications and mechanisms for CO2-EOR in unconventional reservoirs would not necessarily be the same as …

General Rules For Pre-Process Planning In Powder Bed Fusion System -- A Review, Tan Pan, Sreekar Karnati, Frank W. Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Powder bed fusion (PBF) is one of the current additive manufacturing techniques that can fabricate almost fully dense functional metal components. Through a layer by layer fabrication methodology, complex geometries to meet the requirements of aerospace, automotive, biomedicine industries, etc. can be produced. The success of a build largely depends on having a flawless pre-process planning, including build orientation selection, support structure optimization, process parameter chosen, etc., which closely relates to the quality of the final products. Geometric inaccuracy and poor surface quality can occur due to a bad build plan. This review presents the crucial general planning rules for …

Work-In-Progress: Rws - A Roulette Wheel Scheduler For Preventing Execution Pattern Leakage, Ying Zhang, Lingxiang Wang, Wei Jiang, Zhishan Guo

Computer Science Faculty Research & Creative Works

Many real-time systems are safety-critical, where reliability is crucial. Under traditional scheduling mechanism, the execution patterns of the tasks on such system can be easily derived from side-channel attacks, such that attackers can launch short high-priority tasks at critical instants which may cause deadline miss for high-critical tasks. In order to protect the system from such kind of attacks, this paper proposes the roulette wheel scheduler (RWS) to randomize the task execution pattern. Under RWS, probabilities will be assigned to each task at predefined scheduling points, and the choice for execution is randomized, such that the execution pattern is no …

Node-Based Resilience Measure Clustering With Applications To Noisy And Overlapping Communities In Complex Networks, John Matta, Tayo Obafemi-Ajayi, Jeffrey Borwey, Koushik Sinha, Donald C. Wunsch, Gunes Ercal

Electrical and Computer Engineering Faculty Research & Creative Works

This paper examines a schema for graph-theoretic clustering using node-based resilience measures. Node-based resilience measures optimize an objective based on a critical set of nodes whose removal causes some severity of disconnection in the network. Beyond presenting a general framework for the usage of node-based resilience measures for variations of clustering problems, we experimentally validate the usefulness of such methods in accomplishing the following: (i) clustering a graph in one step without knowing the number of clusters a priori; (ii) removing noise from noisy data; and (iii) detecting overlapping communities. We demonstrate that this clustering schema can be applied successfully …

Evidence For The Formation Of A Radical-Mediated Flavin-N5 Covalent Intermediate, Yumin Dai, Hannah Valentino, Pablo Sobrado

Chemistry Faculty Research & Creative Works

The redox-neutral reaction catalyzed by 2-haloacrylate hydratase (2-HAH) leads to the conversion of 2-chloroacrylate to pyruvate. Previous mechanistic studies demonstrated the formation of a flavin-iminium ion as an important intermediate in the 2-HAH catalytic cycle. Time-resolved flavin absorbance studies were performed in this study, and the data showed that the enzyme is capable of stabilizing both anionic and neutral flavin semiquinone species. The presence of a radical scavenger decreases the activity in a concentration-dependent manner. These data are consistent with the flavin iminium intermediate occurring by radical recombination.

Gpu-Accelerated Large-Scale Genome Assembly, Sayan Goswami, Kisung Lee, Shayan Shams, Seung Jong Park

Computer Science Faculty Research & Creative Works

Spurred by a widening gap between hardware accelerators and traditional processors, numerous bioinformatics applications have harnessed the computing power of GPUS and reported substantial performance improvements compared to their CPU-based counterparts. However, most of these GPU-based applications only focus on the read alignment problem, while the field of de novo assembly still relies mostly on CPU-based solutions. This is primarily due to the nature of the assembly workload which is not only compute-intensive but also extremely data-intensive. Such workloads require large memories, making it difficult to adapt them to use GPUS with their limited memory capacities. To the best of …

Algorithms Cs2500, Simone Silvestri, Ken Goss, Zhishan Guo, Ashikahmed Bhuiyan

AOER Course Materials

No abstract provided.

2018-2019 New Faculty Handbook, Center For Advancing Faculty Excellence

Campus Resources for Faculty

Welcome to Missouri S&T!

We are delighted that you are here. Missouri S&T is committed to helping you succeed. In this Handbook you will find the resources that will not only help you become familiar with the campus, but also will enhance your teaching, research, and service endeavors.

The following pages identify resources ranging from a map of the campus and a directory of contact information for key offices on campus to the schedule of Early Career Faculty Forum events for the academic year and some helpful tips on teaching. Some of the offices identified in the handbook will have …

Command Governor-Based Adaptive Control For Dynamical Systems With Matched And Unmatched Uncertainties, Metehan Yayla, Ehsan Arabi, Ali Turker Kutay, Tansel Yucelen

Mechanical and Aerospace Engineering Faculty Research & Creative Works

In this paper, we propose a command governor-based adaptive control architecture for stabilizing uncertain dynamical systems with not only matched but also unmatched uncertainties and achieving the desired command following performance of a user-defined subset of the accessible states. In our proposed solution, online least-squares solutions for the matched and unmatched parameters are obtained through integration method and they are employed in the adaptive control framework. Specifically, the matched uncertainty is identified and its effect upon the system behavior is entirely attenuated. Moreover, using the unmatched uncertainty approximation obtained through radial basis function neural networks, the command governor signal is …

Optical Lens Attack On Monocular Depth Estimation For Autonomous Driving, Ce Zhou, Qiben Yan, Daniel Kent, Guangjing Wang, Weikang Ding, Ziqi Zhang, Hayder Radha

Computer Science Faculty Research & Creative Works

Monocular Depth Estimation (MDE) is a pivotal component of vision-based Autonomous Driving (AD) systems, enabling vehicles to estimate the depth of surrounding objects using a single camera image. This estimation guides essential driving decisions, such as braking before an obstacle or changing lanes to avoid collisions. In this paper, we explore vulnerabilities of MDE algorithms in AD systems, presenting 𝐿𝑒𝑛𝑠𝐴𝑡𝑡𝑎𝑐𝑘, a novel physical attack that strategically places optical lenses on the camera of an autonomous vehicle to manipulate the perceived object depths. 𝐿𝑒𝑛𝑠𝐴𝑡𝑡𝑎𝑐𝑘 encompasses two attack formats: concave lens attack and convex lens attack, each utilizing different optical lenses to …

Extinction Transitions In Correlated External Noise, Alexander H. O. Wada, Matthew Small, Thomas Vojta

Physics Faculty Research & Creative Works

We analyze the influence of long-range correlated (colored) external noise on extinction phase transitions in growth and spreading processes. Uncorrelated environmental noise (i.e., temporal disorder) was recently shown to give rise to an unusual infinite-noise critical point [Europhys. Lett. 112, 30002 (2015)EULEEJ0295-507510.1209/0295-5075/112/30002]. It is characterized by enormous density fluctuations that increase without limit at criticality. As a result, a typical population decays much faster than the ensemble average, which is dominated by rare events. Using the logistic evolution equation as an example, we show here that positively correlated (red) environmental noise further enhances these effects. This means, the correlations accelerate …

Quantum Critical Behavior Of A Three-Dimensional Superfluid-Mott Glass Transition, Jack Crewse, Cameron Lerch, Thomas Vojta

Physics Faculty Research & Creative Works

The superfluid to insulator quantum phase transition of a three-dimensional particle-hole symmetric system of disordered bosons is studied. To this end, a site-diluted quantum rotor Hamiltonian is mapped onto a classical (3+1)-dimensional XY model with columnar disorder and analyzed by means of large-scale Monte Carlo simulations. The superfluid-Mott insulator transition of the clean, undiluted system is in the four-dimensional XY universality class and shows mean-field critical behavior with logarithmic corrections. The clean correlation length exponent ν=1/2 violates the Harris criterion, indicating that disorder must be a relevant perturbation. For nonzero dilutions below the lattice percolation threshold of p_c=0.688392, …

The Role Of Multiple Electron Processes For Fast Ion H₂O Collisions, N. Bachi, G. S. Otero, S. Otranto, Ronald E. Olson

Physics Faculty Research & Creative Works

In this work, collision processes between C⁶⁺, O⁸⁺ and Si¹³⁺ ions and H₂O molecules that lead to target ionization are studied by means of the classical trajectory Monte Carlo method. We employ an 8-electron model in which the H₂O electron densities and energies dynamically adapt during ionization processes to those corresponding to the H₂O^q+ ions by assuming vertical transitions between the different molecular ionic states. Net total ionization cross sections and single differential cross sections in energy and angle are shown for 4 MeV/u projectiles and compared to available …