Digital Commons Network^™

Stratigraphy, Genesis, And Economic Potential Of The Southern Part Of The Florida Land-Pebble Phosphate Field, Dean Stanley Clark

Doctoral Dissertations

"The important and highly productive Florida land-pebble phosphate field is located in west central peninsular Florida in portions of Hillsborough, Polk, Hardee, and Manatee counties. The Pine Level phosphate area, described in detail in this report, is south of the previously known and mined deposits and occurs in portions of Manatee, Sarasota, and De Soto counties. Results of the current geologic study of the Pine Level phosphate deposit and the evaluation of the overall potential of this southern part of the land-pebble field are presented.

The entire southern part of the phosphate field is underlain by more than 15,000 feet …

The Mio-Eugeosynclinal Thrust Interface And Related Petroleum Implications In The Sason-Baykan Area, Southeast Turkey, Ismail Özkaya

Doctoral Dissertations

"A detailed investigation of the stratigraphy, structure and petroleum geology of the Sason-Baykan region in 600 square km area of the thrust belt of southeast Turkey was completed at a scale 1: 25 000. Geosynclinal sediments within the area were redated.

Results of field study indicate a massive plate of metamorphic rocks and crystalline limestones was thrust southward over geosynclinals sediments. These in turn were thrust over the southern marginal basin deposits. A stratigraphic sequence of the allochthonous geosynclinals sediments was reconstructed and correlated with the autochthonous Tertiary section. Contrary to earlier views the allochthonous sediments and accompanying igneous rocks …

Digital Spectrum Analyzer Systems: A Model And System Implementation, Richard Ray Kuenzer

Doctoral Dissertations

"This thesis introduces digital spectrum analyzer systems and presents a generalized model which can be used to implement new systems. The model is presented using the Digital Design Language (DDL) to facilitate system programming. Three hardware systems are defined and their merits are considered. Procedures are given to aid in implementing an analyzer system on a wide range of hardware configurations. A digital spectrum analyzer system which was implemented at the University of Missouri - Rolla and is presently being used by electrical engineering students is presented. This system utilizes the IBM 360/SO computer located in the Computer Center at …

Mass Transfer With Second-Order Chemical Reaction Inside Circulating Fluid Droplets, Roy James Brunson

Doctoral Dissertations

"The solution of a mathematical model is presented which describes mass transfer accompanied by a second-order chemical reaction inside a circulating, fluid sphere for the laminar flow region. The values for eight different mass transfer indices are presented as a function of the Peclet number, reaction number, diffusivity ratio, concentration ratio, and the dimensionless contact time. The results of this work are compared with the film and penetration theories for mass transfer with reaction as modified to apply inside a fluid sphere. This work corrects the three factors which limit the accuracy of applying previous theories to fluid spheres: geometrical …

Grain Boundary Diffusion In Ionic Crystals, Kulwant Singh Sabharwal

Doctoral Dissertations

"The diffusion of ¹³¹I in single crystals and along the tilt grain boundaries of pure and calcium chloride doped (142±5 ppm) bicrystals of sodium chloride, grown by Czochralski technique, was investigated using a microtome sectioning technique. Results on bulk diffusion in pure NaCl agree well with the results of earlier investigators and are represented by the D=(504 cm²/sec)exp (-2.27 ev/kT). Enhanced diffusion of ¹³¹I is observed along the grain boundaries and the presence of the dopant lowers the grain boundary diffusivity over the entire temperature range of 430ºC - 570ºC studied in the present investigation. Thermal activation and electrical polarization …

A Learning Receiver For Communication In Three-Component Multipath Channels, Richard Paul Brueggemann

Doctoral Dissertations

"An adaptive receiver is designed for transmissions through a time-varying multipath channel which may include both specular and diffuse components. The design is based on the theory of unsupervised learning machines and the receiver is a recursive structure which does not grow in complexity with each new observation, but is Bayes' optimal at each instant of time. The multipath medium is modelled as an aggregate of L conditionally independent transmission paths, each consisting of random and/or fixed reflections, and is identified in terms of three components: (1) indirect diffuse scatter, (2) indirect specular reflection, and (3) direct transmission. The channel …

Iicads--Integrated Interactive Computer Aided Design System, Archie Golden Lambert

Doctoral Dissertations

"This research has three goals. The first goal is to develop a software interface (supervisor) to support and control a variety of interactive subsystem modules; thus eliminating manual scheduling of interactive jobs. The second goal is to develop a common methodology for interactive subsystem design. The third goal is to develop a linear systems analysis package using the facilities developed under the first two goals. A software interface (supervisor) to support and control a variety of interactive subsystem modules is described. The supervisor operates under the constraints of a large multiprogramming variable task operating system as opposed to a time …

Substituent Effects On The Magnetic Resonance Spectra Of 1, 4-Disubstituted Benzenes, Holger Er-Chah Chen

Doctoral Dissertations

"The Nuclear Magnetic Resonance spectra of five complete series of para-substituted benzenes have been investigated: the benzoic acids, benzonitriles, benzoyl chlorides, methyl benzoates and nitrobenzenes. Precise values of aromatic proton chemical shifts and coupling constants were obtained from LAOCOON3 computer analyses of the spectra. Using the relative internal chemical shift technique of Beachell and Beistel, excellent linear correlations among all five series were found. All substituents gave proton shifts which lay on the least-squares line, so it is concluded that all substituents are well behaved. Using the correlation plots the chemical shifts of the aromatic ring protons can be predicted …

Diffusiophoretic Forces Between Juxtaposed Atmospheric Particles, Allen L. Williams

Doctoral Dissertations

"The role of diffusiophoretics and Stefan flow in droplet growth by accretion and in-cloud scavenging is examined. A calculation is made for the diffusive forces between two juxtaposed spheres one or both of which are undergoing diffusional growth and the influence of the diffusive force on the trajectories of two spheres, assumed to obey the creeping flow equations is found. The results are: a) the diffusiophoretic force between two water droplets is zero. b) the diffusiophoretic force between a spherical ice particle and a water droplet, although non-zero, is too small to appreciably influence the fall trajectories. c) the diffusiophoretic …

Probabilistic Models For Construction Estimating And Bidding, James E. Spooner

Doctoral Dissertations

"Two probabilistic models are offered as a means for quantitatively determining contingency in a lump-sum bid. The first model is based on the isolated project and requires subjective evaluation of probabilities associated with the individual elements of the estimate. Contingency is defined as a function of the standard deviation of project field costs. Procedures are developed to obtain the variance of the total field cost from three-value estimates of the primary quantities. The second model considers the business as a stochastic process with an initial risk reserve and a positive risk loading, and contingency in this model is a function …

A Yield And Fracture Model For Ti-6al-4v Titanium And 7075-T6 Aluminum, Richard L. Pendleton

Doctoral Dissertations

"The objective of the research being reported in this thesis was to conduct a series of experiments on two commonly used structural metals in several different environmental pressures so that a graphical representation of the material response both to yielding and fracture could be ascertained. It was further intended to show that parameters herein defined and called effective stress, effective strain, and pressure are useful parameters for graphically representing the material response. The final goal of this research was to show that the graphical representation does, in fact, predict the yield and fracture for a simple forming process. The forming …

An Acceleration Technique For A Conjugate Direction Algorithm For Nonlinear Regression, Larry Wilmer Cornwell

Doctoral Dissertations

"A linear acceleration technique, LAT, is developed which is applied to three conjugate direction algorithms: (1) Fletcher-Reeves algorithm, (2) Davidon-Fletcher-Powell algorithm and (3) Grey's Orthonormal Optimization Procedure (GOOP). Eight problems are solved by the three algorithms mentioned above and the Levenberg-Marquardt algorithm. The addition of the LAT algorithm improves the rate of convergence for the GOOP algorithm in all problems attempted and for some problems using the Fletcher-Reeves algorithm and the Davidon-Fletcher-Powell algorithm. Using the number of operations to perform function and derivative evaluations, the algorithms mentioned above are compared. Although the GOOP algorithm is relatively unknown outside of the …

The Average Dissipation Curve Of An Attenuative Layered Earth Medium, Joong Hee Chun

Doctoral Dissertations

"A feasible method of estimating the attenuative properties of a layered earth medium from a reflection seismogram has been developed. An average attenuation factor of n layers in the least squares sense is designated as ß and its usefulness in real applications is investigated. Techniques of extracting dissipation factors from both noise free and noisy reflection seismic traces are discussed. In order to describe the change of the factors with an increase of depth, an average dissipation curve the form of which is similar to the average velocity of layered medium is also introduced. Both the ß and the average …

Selected First Row Transition Metal Coordination Compounds Of 2-(N-Aminomethyl)-3-Quinuclidinone Chelates, Richard Cecil Dickinson

Doctoral Dissertations

"As part of a project directed towards elucidating the characteristics of ligands which coordinate to give complexes having tetrahedral structures, a study of chelates containing the bulky quinuclidine group has been made. With 2-(N-morpholinylmethyl)-3-quinuclidinone (MQN), complexes having the general formula M(MQN)X₂ were prepared where the metal ion was Co(II), Ni(II), Fe(II), Cu(II), and Mn(II). The ligands 2-(N-piperidinylmethyl)-3-quinuclidinone (PQN) and 2-(N-dimethylaminomethyl)-3-quinuclidinone (DQN) were prepared along with the analogous cobalt(II) chloride complexes. The series of complexes Co(MQN)X₂ where X = Cl, Br, or I were prepared, and magnetic susceptibilities and spectral data obtained. They have room temperature magnetic moments in the range …

The Utilization Of High Sensitivity Noble Gas Mass Spectrometry In The Detection Of Iodine-129 And Plutonium-244, Mervet S. Boulos

Doctoral Dissertations

"Mass spectrometric analysis of the xenon isotopes in natural gas wells demonstrates that radioactive isotopes of element number 53 (I) and element number 94 (Pu) were present at the time of the Earth's formation. Evidence for the now extinct nuclide¹²⁹I (t_1/2 = 17 x 10⁶ years) was found in CO₂ -rich gas while evidence for the now extinct ²⁴⁴Pu (t_1/2 = 82 x 10⁶ years) was discovered in other natural gas wells. The amounts of ¹²⁹I in thyroids was measured by combining neutron activation analysis with noble gas mass spectrometry. The current …

Ionization Mechanisms In Cesium, Yu Bong Hahn

Doctoral Dissertations

"Autoionizing states in Cs between 12 and 20 eV have been studied by electron impact. The retarding-potential-difference(RPD) method was used to obtain an electron beam with energy spread of about 0.1 eV. To determine the threshold energies, inelastically scattered electrons were analyzed by the trapped-electron method. We have been able to identify about 20 levels, and the agreement with spectroscopic data is excellent. A peak appearing at 12.80 eV is probably due to the quartet states observed by Feldman and Novick"--Abstract, page 2. "The structure in the electron impact ionization cross section in cesium can be partially accounted for by …

Geochemical Anomalies In The Igneous Wall Rock At Mayflower Mine, Park City District, Utah, Zuhair Al-Shaieb

Doctoral Dissertations

"Approximately 500 samples were collected from the igneous wall rock of the Mayflower Mine, Park City District, Utah. The mine is the sixth largest gold producer in the United States. The samples were analyzed for copper lead, zinc silver, manganese, sodium, potassium, calcium, magnesium and iron by atomic absorption spectrophotometry. Gold was determined by neutron activation analysis, silicon and sulfur by x-ray fluorescence spectrometery. The calculation of the mineral norm from the chemical analysis showed the wall rock to be of granodioritic composition. A study of selected vein samples indicates that the copper, silver and gold content in the veins …

Time Resolved Measurements Of Droplet Growth In A Wilson Cloud Chamber, Michael Anthony Vietti

Doctoral Dissertations

"The growth rates of water drops in a Wilson expansion cloud chamber are measured with air, argon and helium as the carrier gas, in the size range of .5 to 10 microns. The drops growing in the supersaturated chamber exhibit oscillations in the scattered intensity as predicted by Mie theory. Scattered intensity is measured at 30 degrees to the He-Ne laser beam. Supersaturation ratios during growth range from S =1.2 to S = 3.5 for all three gases. The initial temperature is measured and the pressure is monitored continuously so that droplet growth theory can be compared with experiment. Three …

Structure Of Zero Divisors, And Other Algebraic Structures, In Higher Dimensional Real Cayley-Dickson Algebras, Harmon Caril Brown

Doctoral Dissertations

"Real Cayley-Dickson algebras are a class of 2ⁿ-dimensional real algebras containing the real numbers, complex numbers, quaternions, and the octonions (Cayley numbers) as special cases. Each real Cayley-Dickson algebra of dimension greater than eight (a higher dimensional real Cayley-Dickson algebra) is a real normed algebra containing a multiplicative identity and an inverse for each nonzero element. In addition, each element a in the algebra has defined for it a conjugate element ā analogous to the conjugate in the complex numbers. These algebras are not alternative, but are flexible and satisfy the noncommutative Jordan identity. Each element in these algebras can …

Computer Assisted Teaching Of Steel Design, Wendelin Henry Mueller Iii

Doctoral Dissertations

"A method for use in creating a university level course is presented. The specifics of each of the steps is given in general terms to allow its application to as many different topics as possible. This method is then specifically applied in the formation of a fundamental steel design course using the American Institute of Steel Construction Specification. The reasoning utilized in each phase of development is documented. A lecture style presentation complemented by a series of student oriented computer programs was chosen for use. The details of the course material in outline form is given along with the computer …

Condensation And Sublimation Of Carbon Dioxide And Water Molecules At Cryogenic Temperatures, Victor Cazcarra

Doctoral Dissertations

"Measurements of the condensation coefficient of CO₂ and H₂O have been made using a molecular beam and quartz crystal microbalances. The dependence of the condensation coefficient on variables such as population density on the substrate, temperature of the substrate, molecular beam intensity and temperature of the molecular beam, was investigated. The results are explained using heterogeneous nucleation theory for low density population, and a new approach for high density population is presented. The rate of sublimation of these two gases was measured directly. The results are reported in terms of vapor pressure in the range 10⁻⁹ to 10⁻⁴ Torr. The …

Wall Rock Geochemistry Of The Chester Vein, Sunshine Mine, Kellogg, Idaho, Nicholas Howard Tibbs

Doctoral Dissertations

"The Chester vein has been the major source of ore from the Sunshine mine, largest single producer of silver in the world. 425 samples of quartzite and argillite wall rocks were collected in 13 traverses across this vein on the 4400, 4600, and 4800 mining levels. These samples were analyzed for aluminum, magnesium, calcium, sodium, potassium, manganese, iron, lead, copper, and zinc by atomic absorption spectroscopy, and for silicon and sulfur by x-ray emission spectroscopy. Element distribution plots, linear correlation coefficient matrices, varimax factor analysis, and cluster analysis were employed to determine the geochemical processes that occurred in the wall …

The Scattering Of Elastic Waves By Void Cavities, Jerry Lee Davis

Doctoral Dissertations

"Elastodynamic multipole theory, the theory of least squares, and the theory of integral representation of solutions are employed in solving certain problems involving an elastic solid containing a source and a scatterer. Both the source and scatterer are of finite geometrical extent; they occupy non-intersecting regions. The source is separable, i.e., its mathematical specification consists of an arbitrary vector function of position multiplied by a time function, which is further assumed to be a sinusoid. The scatterer emphasized is a finite void cavity of arbitrary shape; however, scatterers composed of rigid material may also be treated. The calculation of a …

Methods And Applications Of Systems Identification, Allen Glenn Behring

Doctoral Dissertations

"A "Schmidt filter" is proposed to compute an optimal orthonormal basis for a set of "noisy" filter input functions. Procedures for determining the transfer function and inverse transfer function of the filter are given. The Schmidt filter is applied to the problem of determining mathematical models of discrete, stationary, linear, dynamic systems for the case where measurements may be corrupted by noise of unknown statistics. The identification problem is reconsidered for the case where noise and signal moments are specified. Procedures are given which insure unbiased, adaptive estimates of system order and parameters for this case. These theoretical propositions are …

Hydro-Thermal Generation Unit Commitment And Dispatch Using A Dynamic Programming Approach, Warren Dean Graham

Doctoral Dissertations

"The problem of thermal unit commitment is solved with dynamic programming. A practical example is given which solves the problem for a six generator system over a one year time span. This long range solution is used with a hydro optimization procedure to give an optimized hydro-thermal unit commitment solution. From this, a worth of hydro value is computed for each month, which may be used in the daily dispatching of thermal units and hydro. Applications of the program are also shown for aiding in generator maintenance scheduling and evaluating purchase power contracts with neighboring utilities. Error analysis is made …

An Experimental Investigation Of The Effects Of Ambient And Heated Steady Flow And Intense Sound Levels On The Response Of Acoustic Filter Elements, Raymond H. Schaffart

Doctoral Dissertations

"The primary purpose of this research was to investigate the effects of flow and finite amplitude waves on the response of acoustic elements. A further purpose was to evaluate the effects of elevated temperatures and cross-sectional dimensions on element performance. As an integral part of this work various laboratory techniques were explored for their suitability.

Empirical models for the acoustic impedance of side branch resonators were developed for the two operational modes, i.e., flow past the resonator and finite amplitude wave inputs. A description of the complex variation of the acoustic resistance of the resonator with flow past and variable …

Force Analysis Of Involute Spur Gears, Janakkumar Girjashanker Dave

Masters Theses

"This study is devoted to the fundamental action which occurs between spur gears with involute tooth profiles when power is transmitted at a constant angular velocity ratio. Various aspects of the interaction between two mating teeth are considered. Analytic expressions for the variation of the force transmitted between two teeth are derived. Two cases are considered which include and exclude the effects of sliding friction between the teeth. The parametric equations of the involute curves for two mating teeth are derived in terms of body-fixed coordinates. Analytical expressions for Hertz compressive stresses in the teeth were also obtained. The same …

An Accurate Digital Instrument To Measure Reactor Period, Ernest Wayne Scott

Masters Theses

"At facilities having a research-training reactor, such as the University of Missouri-Rolla Reactor (UMRR), one finds it necessary to perform a large number of rod calibrations during the course of the year. In practice rod worths are determined by measuring the reactor period created by an incremental withdrawal of the rod under calibration. Period is then related to reactivity thru the use of a publication such as the AEC publication, TID-4500.

This frequent measurement of period makes it desirable to have a simple, automatic and accurate method to make such measurements. At UMRR we have designed, constructed and installed such …

A Study Of Plane Wave Filter Analysis With Flow, Thomas Valle Huber

Masters Theses

"The purpose of this investigation is to determine the effect of slow steady flow on the reflection and transmission characteristics of acoustic filters.

A standing wave tube and transmission tube apparatus, designed and built by a previous investigator, was modified to accept slow steady flow. Reflection characteristics were determined from measurements made on the inlet side of the filters investigated. These data along with measurements taken with the transmission tube apparatus were used to determine transmission characteristics. The calculations were simplified by terminating the filters anechoically. The filters used in this investigation were an expansion chamber, an automobile type muffler …

Digital Registration Of Stereo Images Using The Fast Fourier Transform, Victor Francis Wilreker Jr.

Masters Theses

"The exact alignment of multispectral imagery is a requirement of any image classification system. This investigation develops a system of programs which result in a technique that corrects for the translational and rotational misalignment of two images. Rotational and translational components are determined by using the fast Fourier transform to find the points of maximum correlation between the two images. The registration of two equal but misaligned boxes is given as an example of how the transform technique is used in correlating the images. The results of registering two digitized images that were obtained by scanning a pair of color …