Digital Commons Network^™

Lithospheric Drip And Mantle Thermal Upwelling Beneath Central Asia And The Southern Great Plains Of North America: Evidence From Receiver Function Imaging, Yangyang Liao

Doctoral Dissertations

"Investigating the depth of mantle transition zone (MTZ) discontinuities provides insights into mantle dynamics, including regional-scale downwelling of mantle lithosphere (i.e., lithospheric drip) and upwelling of thermal materials (i.e., mantle plume). In our study, we employ receiver functions to image the 410 km (d410) and 660 km (d660) mantle discontinuities and to ascertain thickness of the MTZ beneath Central Asia and the Great Plains in United States. The findings unveil a significantly thickened transition zone, exhibiting an average thickness of 284 km beneath East Sayan. When considered alongside geochemical observations, our results indicate that the descent of the lithosphere is …

Exploring Seismic Anisotropy In The Crust And Mantle Of The Tibetan Plateau And Analyzing Seismic Velocity Variations In Yellowstone, Cong Shen

Doctoral Dissertations

"Seismology is a scientific discipline that utilizes seismic waves to investigate the deep structures within the Earth's interior, which are otherwise inaccessible to direct observation by humans. These seismic waves can be categorized into two types: body waves and surface waves, each with distinct propagation modes and behaviors, carrying valuable information about their travel paths. The first paper concentrates on the analysis and inversion of body waves produced by large seismic events. It employs shear wave splitting and receiver function methods to explore the geodynamic structure of the south-central Tibetan Plateau, near the plate boundary. The investigation covers the depth …

Mission-Driven Inverse-Design Of Conventional And Unconventional Airplane Configurations Using Machine Learning, Rohan Srinivas Sharma

Doctoral Dissertations

"A key challenge in airplane design has been the long-desired ability to quickly create an airplane design with specific performance properties. To tackle this problem, researchers have traditionally leveraged design space exploration methodologies to iteratively explore a design space via surrogate models. On the other hand, inverse design is a process wherein performance objectives are fixed while a suitable design for satisfying these requirements is calculated. In recent years, artificial neural networks (ANNs) have been explored as viable surrogate models because traditional surrogate models struggle with the large number of output to input mapping needed for inverse design problems. In …

Efficient Modeling And Simulation For The Aerothermal Analysis Of Particle-Laden Hypersonic Flows, Andrew Hinkle

Doctoral Dissertations

"Standard approaches for simulating hypersonic flows in particle-laden environments have key limitations in practice, such as high cost and numerical noise. In this work, efficient solution strategies for particle-laden hypersonic flows were developed using both Lagrangian and Eulerian models for the particle phase with the focus on investigating spacecraft surface erosion, as well as convective and radiative heat flux augmentation due to atmospheric particulate encountered during planetary entry.

First, an efficient integration strategy for Lagrangian methods, the Trajectory Control Volume (TCV) method, was developed for steady analysis of dilute particle phase problems on general geometries. The TCV method was shown …

Investigation Of Wide Beam And Interfacial Shear Transfer In Reinforced Concrete Structures, Nikkolas Edgmond

Doctoral Dissertations

"The use of reinforced concrete (RC) allows for unique designs of structural elements and connections because of the ability to vary the geometry and reinforcement detailing with ease. However, this freedom in the design process can lead to specialized conditions that have not been extensively studied by means of experimental testing. This is especially true for components or regions of components that are subjected to high shear loads, which are susceptible to undesirable and brittle failures. While many studies have been conducted to investigate the shear behavior of RC structural members and components to determine the critical design parameters, these …

Analytical Methods For Monitoring Traumatic Brain Injury Biomarkers/Treatment And Pharmaceutical Residual Solvents, Olajide Philip Adetunji

Doctoral Dissertations

"The development of highly sensitive and efficient analytical methods utilizing advanced instrumentation is necessary to help improve disease diagnosis and therapeutics. A major neuro-consequence of traumatic brain injury (TBI) is oxidative stress from the generation of reactive oxygen species and the depletion of antioxidant defenses. Alteration in concentrations of certain small molecules also occurs with the disease progression and can help understand TBI pathophysiology. Two analytical methods employing liquid chromatography with tandem mass spectrometry (LC-MS/MS) were developed and validated to monitor the potential small-molecule TBI biomarkers at sub-ppb levels. Subsequently, the neuroprotective effect of an antioxidant prodrug, N-acetylcysteine amide (NACA), …

The Development Of Hard Materials And Fibrous Monolith Composites For Friction Stir Welding, Paul Michael Brune

Doctoral Dissertations

"This research focuses on the development of hard materials and fibrous monolith composites for the purpose of adding to current friction stir welding tool technology. Well studied hard material systems, such as WC-Co, were incorporated and evaluated as cell materials for fibrous monolith composites with ductile cell boundaries of Co, W, and Mo. The indentation behavior of the WC-Co and WC-Co-cBN composites indicated possible crack deflection at the cell/cell boundary interface. Cylindrical pin friction stir welding tools were developed for each of the three fibrous monolith material systems. Welding was achieved on AA1100 aluminum, 260 brass, and AISI 1018 steel …

Improving Syngas Quality In A Downdraft Biomass Gasifier With Blended Feedstocks, Rania Almusafir

Doctoral Dissertations

"Biomass gasification is the greatest potential renewable energy source and will play an important role in the energy mix of the future. To achieve a high quality of produced synthesis gas (syngas) in the gasification system, the syngas cleaning and cooling processes pose challenges. The main objectives of the present work are advancing the knowledge of the gasification process and producing syngas in the studied pilot-scale downdraft biomass gasifier.

A Thermogravimetric analysis (TGA) has been developed and utilized to experimentally investigate the impact of biomass feedstock diversity on the performance of the gasification process of hardwood (HW), softwood (SW) pellets, …

Topography Of The 410 And 660 Km Discontinuities Beneath The Tibetan Plateau And Adjacent Areas, Zexin Miao

Doctoral Dissertations

"The Tibetan Plateau represents the ongoing geotectonic aftermath of a continental collision initiated approximately 65 million years ago. Despite numerous seismological studies, controversies remain regarding the structure, evolution, and dynamics of the crust and mantle beneath Tibetan Plateau. In this study, we used teleseismic broadband data to investigate the topography of the mantle transition zone (MTZ) discontinuities. A total of ~655,000 receiver functions from 735 stations was utilized to image the 410 and 660 km discontinuities bordering the MTZ. Combining the observed and velocity corrected results, several areas in the central Tibet exhibit a typical d410 and an anomalously deep …

Processing-Microstructure-Properties Relationships In Additively Manufactured Zrb2-Sic Ceramics, Marharyta Lakusta

Doctoral Dissertations

"The study explores the pressure less sintering (PS) and chemical compatibility of ZrB₂-30 vol.%SiC produced by additive manufacturing (AM) with CO₂. The oxidation kinetics and scale microstructures were compared for ZrB₂-SiC made by hot pressing (HP) and by AM coupled with PS. All specimens exhibited parabolic oxidation kinetics. The difference in oxidation behavior becomes evident at temperatures of 1100-1400°C (200-900h). Oxidation rates increased as grain size increased. Similar oxide scale morphologies were observed in both CO₂ and air, with an outer borosilicate layer and an inner porous ZrO₂ layer containing partially oxidized …

Adversarial Transferability And Generalization In Robust Deep Learning, Tao Wu

Doctoral Dissertations

Despite its remarkable achievements across a multitude of benchmark tasks, deep learning (DL) models exhibit significant fragility to adversarial examples, i.e., subtle modifications applied to inputs during testing yet effective in misleading DL models. These meticulously crafted perturbations possess the remarkable property of transferability: an adversarial example that effectively fools one model often retains its effectiveness against another model, even if the two models were trained independently. This research delves into the characteristics influencing the transferability of adversarial examples from three distinct and complementary perspectives: data, model, and optimization. Firstly, from the data perspective, we propose a new method of …

In-Depth Characterization Of The Selective Oxidation Products Of Hafnium Carbide, Jonathan Allen Scott

Doctoral Dissertations

"Materials capable of withstanding oxidative environments at temperatures >2000°C are necessary for hypersonic applications. Hafnium carbide (HfC) shows a combination of properties that lends itself toward these applications; however, its oxidation behavior is poorly understood. At 1300°C, HfC was found to oxidize via the following mechanism: 1) Initial oxidation of both C and Hf present in the system, 2) Formation of an interconnected pore network, whose size is related to the volume of gases being generated during the oxidation process, 3) Growth of the oxide scale to become sufficiently protective, 4) Formation of an initially amorphous “HfO₂C” at …

Paleoecological And Paleoclimatic Reconstructions Based On Holocene Sediment Cores, Lake Izabal, Eastern Guatemala, Erdoo Mongol

Doctoral Dissertations

"The Maya Region in Central America is characterized by pronounced discrepancies in precipitation, resulting in high precipitation gradients that support large-scale differences in vegetation across the region. Several lake deposits and other paleoclimate archives in the region have been studied to reconstruct past climates and palaeoecological conditions. However, actual data from proxy records have not been qualitatively and quantitatively utilized to interpret the behavior of the vegetation in moister areas within the Maya Region, such as the Lake Izabal Basin (LIB). The palynomorphs from two sediment cores in the LIB provided a good opportunity to infer the patterns of past …

Critical Behavior And Dynamics Of The Superfluid-Mott Glass Transition, Jack Russell Crewse

Doctoral Dissertations

This work studies the effects of disorder on the thermodynamic critical behavior and dynamical properties of the superfluid-Mott glass quantum phase transition. After a brief introduction covering relevant fundamentals, we present the dissertation in the form of four separate but related publications. In the first two publications, we calculate the thermodynamic critical exponents of the superfluid-Mott glass quantum phase transition in both two and three spatial dimensions. The undiluted transition exhibits critical exponents that violate the Harris criterion, and thus the critical behavior is expected to change upon introducing disorder. We confirm this behavior via Monte Carlo simulation of a …

Optimizing The Total Life Cycle Of Li-Ion Batteries: From Constant Gradient Charging To Aged Cell Performance Restoration, Kasim Adesegun Adewuyi

Doctoral Dissertations

As demand for Lithium-Ion Batteries (LIBs) have skyrocketed over the past decade, the need for better charging methodologies and recycling methods have become vitally important. At a fundamental level, this dissertation strives to fulfill the green promise of a future without fossil fuels. In order to promote a transition away from fossil fuels, LIBs for vehicles require ultrafast charging times equivalent to a normal vehicle (6 mins). However, this process leads to high volume expansion for next generation electrode materials which causes degradation. Without limiting this factor, the environmental impact shifts from oil rigs to Li mines and landfills. The …

Investigating Detonation Parameters Through The Plate Dent Test: A Novel Approach For Characterizing Detonation Curvature And Thickness, Emily Michelle Johnson

Doctoral Dissertations

Detonation is the driving factor behind how an explosive, used in an array of applications, performs. Understanding and measuring detonation parameters of an explosive is key in explosive charge design and application. Currently, determining parameters is costly as the instrumentation needed is expensive in terms of price, maintenance, and personnel. This research examines two methods of determining detonation parameters through measurement of secondary material response to the detonation wave in an effort to provide an alternate, simple, and inexpensive method of measurement. The first of these studies focuses on the Gurney Model and demonstrates that the model's accuracy was diminished …

Investigation Wettability Contact Angle Using 2d Imaging Technology, Saleh Alsayegh

Doctoral Dissertations

"Investigation wetting preference of tight carbonate reservoir rocks and several other unconventional reservoir rocks, and their relation to oil production, is becoming noticeably important for field development in Kuwait, as in many future unconventional tight carbonate reservoirs in the Middle East. The overall objective of this investigating and modeling study is to discover many fundamental relationships from totality wettability preference as a tool for reservoir recovery predictions and management. The investigation includes advancing position of water wet preference into smaller capillaries of the matrix voids and incrementally more oil-wet into larger capillaries of natural fractures (NF). Also, investigating water/ oil …

High-Resolution Spectroscopy Of Interstellar Lines And Comets, Chemeda Tadese Ejeta

Doctoral Dissertations

"The study of interstellar molecules such as CO is crucial because interstellar ices in the core of a pre-solar molecular cloud provide the starting point for volatile evolution in the protoplanetary disk. A record of the initial volatile composition of the protoplanetary disk can be obtained from the study of the chemical composition of cometary nuclei. Because of their long residence in the Oort cloud and infrequent passage through the inner solar system, long-period comets are one of the most primitive bodies in our solar system that can tell us about the composition of the early solar system. High-resolution infrared …

Deep Reinforcement Learning Based Strategies For Inverter Dominated Microgrids, Oroghene Oboreh-Snapps

Doctoral Dissertations

The integration of inverter-based distributed generators (IBDGs) in modern power systems has ushered in a new era of renewable energy utilization, prompting the rise of Microgrid (MG) architectures. Nevertheless, as IBDG penetration increases, a host of challenges surface. Foremost among these challenges are issues related to frequency stability stemming from the inherent lack of inertia in IBDGs, and inaccurate sharing of reactive and active power, particularly evident in parallel IBDG networks with mismatched feeder impedance. This research presents novel solutions to these challenges by adopting deep reinforcement learning (DRL), specifically, the twin delayed deep deterministic policy gradient (TD3) algorithm, to …

High Viscosity Friction Reducer Evaluation At High Temperature And High Tds Environments, Ghith Ali Ahmed Biheri

Doctoral Dissertations

"In unconventional reservoirs, proppant transport during hydraulic fracturing treatments could be successful when the proppant is placed further within the reservoir's fracture networks. This could increase the reservoir formation conductivities and improve the productivity of the wells. This job of improving the reservoir conductivity by distributing and transporting proppant can be conducted by reliable fracture fluids with excellent fluid rheology (e.g., viscosity and elasticity). However, several challenges, including the high temperatures and the presence of high TDS in produced water, may limit the capability of fracture fluids to transport proppant. Additionally, the use of fracture fluid has raised fears regarding …

A Structure From Motion Photogrammetric Method For Continuously Measuring And Tracking The Deformations Of Soils During Triaxial Testing, Xiaolong Xia

Doctoral Dissertations

"Measuring soil deformation characteristics during triaxial testing is an important part of characterizing the stress-strain behavior of both saturated and unsaturated soils. The total and local deformations and volume changes of a soil specimen are indispensable parameters that need to be measured and are of great significance for understanding volume change and shear strength characteristics of the soil. Over the past several decades, numerous efforts have been made to measure the soil deformations during triaxial testing. However, it remains a great challenge for researchers to measure the volume-changes of unsaturated soils due to the existence of the air phase.

This …

Novel Supercritical Biodiesel Plant Design & Process Scale-Up, Ghana Shyam Paudel

Doctoral Dissertations

"Current energy prices, national energy security, and global climate change fuel our momentum to find efficient advanced fuels choices. In this study, biodiesel processing, and a novel design for next generation biodiesel plants are explored. During a National Science Foundation (NSF) I-Corps project we identified three creative and profitable improvements to the process: 1. Incorporating Energy intensive separations and reactions 2. Utilizing Low commodity glycerol and 3. Applying process intensification principles.

Current biodiesel processes are catalyzed processes using continuous stir reactors with distillation systems to separate material constituents. We tested a lab-scale nocatalyst supercritical biodiesel process using waste cooking oil …

Sustainable Cementitious Materials For Building And Sorption Applications, Sukanta Kumar Mondal

Doctoral Dissertations

"Ordinary Portland Cement (OPC) is the most widely used cement material, but it contributes over 8% of the global CO₂ emission and the process is energy intensive. Moreover, OPC faces durability challenges, particularly in aggressive environments. Hence, there is rapidly increasing interest in sustainable alternative cements with lower carbon footprint, lower energy consumption, and those that offer superior properties that are beneficial for specific applications. Two sustainable cementitious materials that are frequently researched as an alternative to OPC are calcium sulfoaluminate (CSA) cement and alkali-activated materials (AAMs). CSA cement lowers CO₂ emission by over 40% compared to OPC, …

Re-Evaluating Missouri’S Strategic Element Potential: A Geochemical Study Of The Mesoproterozoic Fe-Cu-Co-Ree Deposits In Southeast Missouri, Usa, Brandon James Sullivan

Doctoral Dissertations

"Iron-oxide-copper-gold (IOCG) deposits are poorly understood mineral systems. For example, we do not know why Cu- and Co-rich IOCG deposits typically occur proximal to Fe ore deposits that are notably Cu and Co-poor, such as Iron Oxide Apatite (IOA) deposits. To better understand the formation of IOA and IOCG deposits in Missouri, USA, this PhD thesis examines the genesis of the Kratz Spring IOA and the Boss Central Dome IOCG deposits. This study presents the first constraints on formation conditions and fluid sources in the studied deposits using integrated petrographic, mineral composition, and Fe isotope analyses of oxide minerals. Observations …

Advancing A Systems Perspective On Innovative Behavior, Stephen Demski

Doctoral Dissertations

"Engineering organizations pursue innovation in strategy, structure, processes, and the services and products offered to remain relevant and competitive. Identifying factors supporting or constraining innovative work behavior and recognizing the complexity of their interactions are vital to sustaining an innovative workforce, yet how factors interact has not been comprehensively studied.

Recognizing innovative work behavior as the output of a complex system of factors guided this study’s literature search that identified over one hundred individual, team, and organizational factors influencing innovative behavior, interviews of engineers to learn what factors are essential in their work environment, and Delphi survey to rank factors, …

Advanced Manufacturing Of Nanomaterials For Energy Storage And Biomedical Applications, Hiep Pham

Doctoral Dissertations

"Nanomaterials have emerged as an important component to the advancement of many fields, ranging from advanced energy materials in the energy field to highly sophisticated treatment vehicles in the biomedical field. Understanding the physical behavior of nanomaterials is critical to design materials with excellent properties and performance for the many disciplines in which they are utilized and is necessary to master the various manufacturing processes that influence nanomaterial properties and behavior. This research focused on a fundamental study into the behaviors of newly developed nanomaterials under both conventional and new manufacturing processes for high performance lithium-ion batteries and for advanced …

Investigation Of Asphaltene Instability Under Gas Injection In Unconventional Reservoirs And Its Impact On Oil Recovery Performance, Mukhtar Elturki

Doctoral Dissertations

"Unconventional reservoirs, such as shale gas and tight oil formations, have become an important source of energy in recent years. However, these reservoirs often contain high levels of asphaltenes, which can lead to deposition and blockages in production wells and reduce the flow of hydrocarbons during gas enhanced oil recovery (GEOR) techniques. This study aims to experimentally evaluate the impact of miscible and immiscible carbon dioxide (CO₂) and nitrogen (N₂) on asphaltene deposition and its impact on oil recovery performance in unconventional shale reservoirs.

This research began with a comprehensive literature review and data analysis of GEOR methods in unconventional …

Monitoring And Control Of Coal Dust Exposure Using Low-Cost Pm Sensors And Computational Fluid Dynamics, Nana Kobina Amoako Amoah

Doctoral Dissertations

"Overexposure to respirable coal mine dust has been linked to causing serious health problems including coal workers pneumoconiosis (CWP) and chronic massive fibrosis. The prevalence of these health problems has been on the increase since the 2000s due to increased exposure levels with roof bolter operators having the highest exposure levels. The currently used PDM3700 is too expensive, heavy and bulky which limits their use only for regulatory monitoring failing to measure miners’ personal exposure levels. Also, since roof bolter operators are more prone to elevated coal dust levels, the canopy air curtain (CAC) was developed to protect then high …

Modeling And Analysis Methods For Esd And Emi Problems, Xin Yan

Doctoral Dissertations

"Electrostatic discharge (ESD) failures and Electromagnetic interference (EMI) problems are becoming more critical in electronic devices and large systems. In this work, four studies are presented to model and analyze ESD and EMI problems.

First, a simplified physical-based model for deep-snapback transient voltage suppressors (TVS) is developed. While based on physics, the number of parameters and components is minimized. Results show that the proposed model captures the most important behaviors of the TVS response using a limited number of parameters, allowing the model to be tuned relatively easily using data obtained only from package-level transient and quasi-static measurements. Second, a …

Chirality Determination Using Three-Wave Mixing Microwave Spectroscopy, Nicole Taylor Moon

Doctoral Dissertations

"Rotational spectroscopy has established itself as a reliable gas-phase spectroscopic technique for the structural determination of molecules. This reliability has stemmed from both advancements in microwave technology and a willingness from the community to push the boundaries of the field. In this dissertation, the boundaries are tested in both how well the technique can determine the structure of molecules exhibiting large amplitude motion and through chirality determination. The first half of this dissertation explores the use of deep averaging to determine the structure of silicon containing molecules in collaboration with Dr. Guirgis from the College of Charleston. For each of …