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A Thermodynamic Study Of The Zirconium-Sulfur, Titanium-Sulfur And Hafnium-Sulfur Systems In The Disulfide-Trisulfide Region, Norbert Achilles Vermaut

Doctoral Dissertations

"A static method was used to study the equilibria which exist between the higher sulfides of zirconium and sulfur at temperatures from 700° to 1000 °C. Both disulfide and trisulfide have been identified by chemical analysis and X-ray diffraction. There exists a two-phase region of 'ZrS₂' and 'ZrS₃'. The composition limit of the homogeneous disulfide phase appears to exist between ZrS_1.90 and ZrS_2.00. The lower composition limit of the homogeneous region of the trisulfide phase was established as ZrS_2.75.

An experimental method of Blitz and co-workers, i.e., the use of evacuated …

On The Kirkwood Superposition Approximation, Russell V. Cochran Jr.

Doctoral Dissertations

"When the Kirkwood superposition approximation for the triplet distribution function is used in the Born-Green equation for the pair distribution function of a liquid, the fourth virial coefficient is given incorrectly. In view of this, two suggestions for improving the approximation have been investigated. A suggestion, due to G.H.A. Cole, that better results could be obtained by using a second-order integro-differential equation of the Born-Green type with the superposition approximation used for both the triplet and quadruplet distribution functions has been investigated, and results for a hard-sphere model show that this method gives considerably less reliable results than those obtained …

A Study Of Turbulent Mass Transfer In A Wetted-Wall Column, David William Bunch

Doctoral Dissertations

"The field of mass transfer is one of great interest to the chemical engineer. An understanding of this field is vital in the design of many types of chemical processing equipment, particularly in the areas of distillation, extraction, absorption, adsorption, and reactor analysis and design.

However, much of the knowledge in this area at the present time is in the form of empirical relationships, and the basic theory is still not well delineated. This lack of understanding leads to expensive and over-sized or under-sized equipment.

A particular area within this field which needs additional investigation is the theory of mass …

A Study Of The Eddy Diffusivity In Turbulent Heat Transfer, Frank Fu-Kun Tao

Doctoral Dissertations

"The purpose of this investigation was to determine the eddy thermal diffusivity values as a function of radial position at various Reynolds numbers for a fluid flowing turbulently in a pipe. The ratios of the eddy thermal diffusivity and the eddy viscosity were also investigated.

A vertical column of copper tube two inches in diameter was constructed which consisted of an entrance section for the development of the velocity profile and a heating section for the development of the temperature distribution. The heating section was jacketed and maintained at a constant wall temperature at about 103 ° F by the …

Lattice Parameters, Thermal Expansion Coefficients, Densities, And Imperfections In Silver And In The Alpha-Phase Of The Silver-Indium System, Samir Moustafa Riad

Doctoral Dissertations

“An investigation of structure insensitive properties (lattice parameters, thermal expansion coefficients, densities, and imperfections) of silver and the α-phase of the silver-indium system was suggested by the desirable uses for silver and its indium alloys.

Both silver and indium used were 99.999 per cent pure. The silver-indium alloys were prepared by melting both metals inside evacuated and sealed fused quartz tubes. The solidified alloys were annealed and then examined by X-ray diffraction for homogeneity.

This experimental work is divided into three main parts:-

I. X-ray diffraction investigation to determine the solid solubility limit of the Ag-In α-phase at 25° C, …

Design, Construction And Characterization Of A 10-Liter Batch Pilot Plant Fermentor., Sylvester Ogden

Masters Theses

"A 10-liter batch type pilot plant fermentor has been designed and constructed. The design incorporated most of the desirable features of previous designs reported in the literature.

The stainless steel fermentor has a multi-speed agitator and aeration rates as high as 15 cubic feet per hour. Temperature indicating, temperature controlling, pH measuring, and automatic foam controlling systems are included in the design.

Sulfite oxidation rates have been determined for the unit at 15 operating conditions. A maximum sulfite oxidation rate of 1060 millimoles of oxygen per liter per hour has been obtained.

Fermentation using a Torulopsis utilis yeast culture has …

Investigation Of Zero Sidesway For Rigid Frames, Dolatray S. Mehta

Masters Theses

"This study was made to determine the location of a point at which a vertical load may be applied to a rigid frame structure and produce zero sidesway, the so called zero sidesway axis. For concentrated loads equations have been derived for zero sidesway. For uniform and triangular loads graphs showing zero sidesway for various ratios of column and beam stiffnesses and height ratios have been plotted"--Abstract, page ii.

The Submerged Culture Of Thiobacillus Thio-Oxidans In A Pilot Scale Fermentor, Edward Hibbert Crum

Masters Theses

"A strain of Thiobaci.llus thiooxidans was isolated from a West Virginia coal mine drainage. This strain was characterized by its production of sulfuric acid in shake flasks. The strain was also compared with a pure culture of h thiooxidans obtained from the American Type Culture Collection (ATCC number 8085).

The strain was grown in submerged culture in a 16-liter pilot scale fermenter. Two aeration systems, air and air enriched with carbon dioxide, were examined. The air enriched with carbon dioxide gave a much more rapid growth rate. The culture reached the mid-log phase of growth after 80 hours of incubation …

Structural And Magnetic Characteristics Of The Belton Anomaly, Cass County, Missouri, Nagib Chamon

Masters Theses

"A vertical intensity magnetic survey of approximately 156 square miles in Cass County, central-west Missouri, revealed a broad circular anomaly whose magnetic relief exceeds 1000 gammas. Surface rocks are very gently inclined and are of Pennsylvanian age. Crystalline basement rocks are at a depth of approximately 2400 feet. Analysis of the data shows that the Belton anomaly consists of discontinuous smaller magnetic anomalies surrounding the central part of this broad anomaly. The central area of the Belton anomaly is occupied by a magnetic low. Analytical calculation showed that the source of the magnetic disturbance is at least 3650 feet below …

The Design, Construction, And Operation Of A Conducting Field Analog Computer., Richard T. Johnson

Masters Theses

"The purpose of this investigation is to design and construct a simple conducting field analog to solve problems described by the two-dimensional Poisson or Laplace equations. Decisions concerning choice of conducting media, construction of problem models, and design and construction of a specialized power supply with instrumentation were based on the results of previous experiments. Several problems are solved using the designed apparatus. Partial solutions to these problems are displayed in graphical form.

The greatest deviation of the experimental results from iterative values was consistently less than 8%. In most cases the deviation was less than 6%. The console arrangement …

The Missouri Miner, October 25, 1963

The Missouri Miner Newspaper

No abstract provided.

The Missouri Miner, May 10, 1963

The Missouri Miner Newspaper

No abstract provided.

The Missouri Miner, May 03, 1963

The Missouri Miner Newspaper

No abstract provided.

Theory Of The Effect Of Temperature On The Electron Diffraction Patterns Of Diatomic Molecules, Russell A. Bonham, Jerry Peacher

Physics Faculty Research & Creative Works

The effect of temperature on the electron diffraction pattern of a diatomic molecule is considered from the standpoint of the simple kinematic scattering theory utilizing a quartic vibrational potential. The potential is obtained by an expansion of ħ²J( J+1)/2μr²+D exp[-2a(r-r_e)]-2D exp[-a(r-r_e)] about its minimum value r₀. The second-order wavefunction for the nth vibrational and 7th rotational state of the system has been obtained, and expressions for the electron diffraction quantities r_g, l_e ², and M (s) have been computed. General results for the quantity M (s) …

The Performance Of Beams And Columns Continuously Braced With Diaphragms, George Pincus, Gordon P. Fisher

CCFSS Library (1939 - present)

INTRODUCTION In Progress Report No.1, it was reported that the initial conception of the problem was that diaphragms act almost exclusively in shear when called upon to brace compression members, and that it had been decided to test single columns with finite widths of diaphragm attached, with width of the sheet being varied to provide a range of lateral support up to that which permitted full column strength, based on strong axis to be developed. However, the first test of this kind, Test CB-l, clearly indicated that the diaphragm acted essentially in flexure only and thus had the same effect …

A Time Optimum Bang Bang Control System Under Specified Inputs., John F. Curtin

Masters Theses

"The problem presented is a study, by simulation on an analog computer, of a time optimum "bang bang" control system with a second order plant. Phase plane analysis techniques are used to describe the performance of the second order plant under the action of a maximum effort controller. From this, the system logic is developed for time optimum response to a step reference input. A fast time model of the plant is used to obtain repeated high-speed extrapolations of the plant outputs, at the same time a linear predictor generates future values of the reference. The error functions thus found …

A Study Of Methods For Estimating Parameters In Rational Polynomial Models, Thomas B. Baird

Masters Theses

“The use of rational polynomials for approximating surfaces is investigated in this study. In particular, methods for estimating parameters for a rational polynomial model were investigated.

A method is presented for finding initial estimates of the parameters. Two iterative methods are discussed for improving those estimates in an attempt to minimize the sum of the squares of the residuals. These two methods are (1) Scarborough’s Method for applying the theory of least squares to nonlinear models and (2) the Method of Steepest Descent.

Data from two functions were chosen and approximated as illustrations. Each set of data was used two …

Development Of A Technique For The Determination Of Capillary Pressure Curves Using A Constantly Accelerated Centrifuge, Robert N. Hoffman

Masters Theses

"A new technique for determining capillary pressure curves with a centrifuge has been developed and tested. Capillary pressure curves were determined for six cores by this technique and were compared to the curves for the same cores determined by the semi-permeable barrier technique. The technique differs from previously reported centrifuge techniques in that the centrifuge was slowly accelerated from zero to the maximum desired speed, rather than being held constant at particular, progressively higher speeds. An important advantage of this technique over other methods for determining capillary pressure curves is the short time required to obtain the desired amount of …

An Investigation Of Optimum Journal Bearings., Kulin Purshotam Maskai

Masters Theses

"Not much has been done towards calculating the "Optimum Bearing" from the point of view of maximum load capacity or minimum friction. It has been found that there 1 is not much difference in the "Optimum Bearing" proportions, as calculated, considering either minimum friction or maximum load capacity

Journal bearings are commonly used and they play a very important role in reducing friction and wear. Engineers use past experience in choosing a bearing for the given conditions. A bearing design can be obtained if 'Optium Bearing' proportions are calculated as suggested by Kingsbury (1) in his article on 'Optium Conditions …

Zinc Sulfide-Sulfate Reaction Pressures, William L. Hallerberg

Masters Theses

"A static manometric method was used to find the equilibrium reaction pressure as a function of temperature for the reaction:

11 ZnSO₄ + ZnS → 4 (ZnO·2ZnSO₄) + 4 SO₂

From the reaction pressures, the standard free energy of the reaction was found to be:

ΔF⁰ = + 51,320 - 36.68 T

Using thermodynamic data for ZnSO₄, ZnS and SO₂ the standard free energy of formation of the basic salt ZnO·2ZnSO₄ was found to be:

ΔF⁰ = - 377,000 - 65.9 T cal/mole

in the temperature range 350 to 420⁰ C.

Above …

A Study Of The Relationships Between The Structure And The Consolidation And Swell Characteristics., Victor Foute Spruill

Masters Theses

"This paper reports the experimental results of an investigation of the relationships between the consolidation and swell characteristics of a cohesive soil and the structure of the soil. Consolidation and swell tests were run on samples prepared at their liquid limits in order to permit the effects of structure to show up in the results. The series of samples tested consisted of Putnam Clay Soil with (1) 2% sodium carbonate added, (2) no admixture, (3) 1% calcium hydroxide, and (4) 4% calcium hydroxide. Determinations were made of the per cent consolidation and per cent swell, decrease and increase in height …

Dissolution Rates Of Zone Refined Iron And Steel In Hydrochloric And Sulfuric Acids And In Sodium Chloride Solutions., Gary E. Welch

Masters Theses

"Dissolution rates for two carbon steels were deter­ mined in four concentrations of sulfuric acid at five temperatures and in four concentrations of hydrochloric acid at four temperatures.

No general relationship was found for the variation in activation energies in sulfuric and hydrochloric acid. An explanation of the difference in the reaction rates and a possible explanation of the activation energy is presented on the basis of chunk formation.

The results of this investigation indicate an electrochemical control mechanism for the dissolution reaction of steel in acid solutions.

Results of dissolution rate studies in sulfuric and hydrochloric acid solutions and …

The Reaction Of Sodium Iodide In Acetone With Halogenated Epoxides -- A Mechanism Study, Thomas E. Breuer

Masters Theses

"l-bromo-2,3-epoxybutane reacted with sodium iodide in acetone to give 3-iodo-l,2-epoxybutane in 70.1 per cent yield. 3-bromo-l,2-epoxybutane produced l-iodo-2,3-epoxybutane in 69.9 per cent yield when it was allowed to react with a solution of sodium iodide in acetone. No other product could be isolated after either reaction, although it is possible that another compound may have been produced in very small amounts. The iodoepoxides were oxidized to the corresponding α-iodoacid in approximately ninety per cent yield by silver oxide"--Summary, page 40.

Methods For The Determination Of The Thermal Conductivity Of Solids., A. M. Sivadasan

Masters Theses

"The thermal conductivity of materials is of considerable practical and theoretical interest. Numerous publications on this subject have been presented with widely varying approaches and applications being made. Perhaps for no other thermal property are the published results so widely divergent and subject to such great uncertainty, particularly at high temperatures. This is partly due to unsolved difficulties in measurement, but perhaps to an even greater extent to the fact that the thermal conductivity of a material depends on its physical characteristics as well as some environmental factors such as humidity and temperature. In the case of metals or alloys, …

Stereoradiography As Applied To Problems Of Petrology., Martin Goldstone

Masters Theses

"Stereoscopic examination of radiographs of rock and ore samples allows a rapid, cursory determination of texture and structure without time consuming preparation and use of thin sections. In addition, volumetric estimates of known mineral components can be made providing they possess significantly different x-ray absorption characteristics.

Stereoscopic effect was most pronounced for specimens having well defined components of structure such as bedding, banding, lineation, inclusions, textural variations and moderate to large x-ray absorption differences. In general, these conditions were best met by ores or ore minerals with their related gangue minerals.

Stereoscopic examination was not successful in revealing twinning or …

Geology Of The Northern Half Of The Ellington Quadrangle Missouri., Robert Charles. Thornton

Masters Theses

"Geologic mapping has been completed for the northern half of the Ellington Quadrangle, Missouri. Rocks exposed in the thesis area are Precambrian and Paleozoic in age. The Precambrian rocks are granites and felsite. The Paleozoic rocks include the Potosi and Eminence Formations, of Upper Cambrian age, and the Gasconade Formation of Ordovician age. Distinction between the Potosi and Eminence Formations is difficult because of conformable and transitional relationships. In the thesis area sufficient evidence was available to separate the dolomites of the Potosi and Eminence as mappable units. This mapping should be useful as a basis for more detailed geologic …

A Study Of The Solubility Of Gold In Aluminum And The Extent Of The Al₂Au Phase., Kuldip Singh Chopra

Masters Theses

"The lattice constant of pure aluminum (99.998%) at 25° C 0 was determined to be 4.04953 A and the limit of solubility of gold in aluminum at 58O° c was found to be about o.4 weight percent gold. The minimum of the lattice constant was observed at O.75 weight percent gold. No change in the lattice constant with time was found.

The Al₂Au phase has a range from 77.66 to 78.94 weight percent gold with the theoretical composition of Al₂Au nearly in the middle of the phase. The thermal coefficient of expansion, the density and the …

Influence Of Porosity On The Fracture Stresses Of Electrical Porcelain., Edward Anton Snajdr

Masters Theses

"Spherical pores were induced in a typical quartz electrical porcelain body. Three levels of pore size and four levels of concentration were studied. Large strength sample sizes were employed using a three-point loading and diametral loading method. Data for induced quartz particles is also included"--Abstract, p.ii

The Construction And Evaluation Of A Small Scale Laboratory Fermentor For Batch And Continuous Studies., Robert Murray Logan

Masters Theses

"The purpose or this investigation was to design and construct a suitable apparatus for the aerobic culture or microorganisms to be used for preliminary batch studies and eventually, continuous fermentations.

The general design of the apparatus was patterned after small scale equipment described in the literature. Construction or the apparatus was carried out in the shop of the Department of Chemical Engineering and Chemistry. All of the necessary machining was done by the author.

The aeration-agitation system was evaluated by the use or the sulfite oxidation rate determination. The oxygen transfer rate provided by the apparatus was round to be …

Effect Of Stiffness Ratio On Stresses In A Rigid Frame., James Juh-Ling Tang

Masters Theses

"The elastic center method has been used to analyze several rigid frames with different geometric configurations and with component members of variable cross-sections. The basic approach is to divide the frame into small segments to solve this problem. From this analysis the best frame which is in the range of an economical design may be obtained for a given loading condition"--Abstract, p.2