Digital Commons Network^™

Radiative Lifetime Of The A¹Π State And The Transition Moment Variation Of The Fourth Positive Band System Of Carbon Monoxide, Joseph George Chervenak

Doctoral Dissertations

"The lifetime of the A¹π state of carbon monoxide has been measured using a pulsed invertron excitation source and delayed coincidence measurement technique on the fourth positive system. Eighteen bands, originating from the upper states v' = 0 to 5, were examined at pressures between 500 and 50 microns, with no pressure dependence noted. The data were corrected for photon "pile up" and least-squares fitted to the sum of two exponentials. The transition moment was found to vary and was expanded about the r-centroid of the v' = 0 to v" = 0 transition. Oscillator strengths are calculated and compared …

Investigations Of Several Variables In The Dwight-Lloyd Mcwane Ironmaking Process, James Orlan Hood Jr.

Masters Theses

"The Dwight- Lloyd McWane Ironmaking Process (D-LM) is the first commercial process of its particular type and one of the few commercial processes involving prereduction of iron ore in existence today. This presentation reviews some promising ironmaking processes which involve iron ore prereduction, with special attention being given the D-LM process. Although the D-LM process is continuous from iron ore to high quality molten cast iron, the research and discussion herein is limited to principal variables involved in the production of high quality carbonized pellets in the prereduction phase of the operation. The variables of process temperature and pellet carbon …

The Influence Of A Carbon Ablation Layer On Radiation From A Hydrogen Shock Layer, Birbal Singh

Masters Theses

"The effect of ablation heat shields on the radiative heat transfer to vehicles entering hydrogen atmospheres at thermo-dynamic conditions similar to those expected in Jovian atmospheres is investigated. The shock layer is assumed to consist of two plane parallel layers, one consisting of pure hydrogen species, and the other consisting of carbon species only. Each layer is assumed to be in local thermodynamic equilibrium at its respective temperature. The thermodynamic conditions in the hydrogen layer are arrived at by solving the Rankine-Hugoniot Equations across the shock. The temperature of carbon layer is taken as (3000, 5000, and 7000ºK) to cover …

A Mathematical Model For The Neutron Dependence Of Neutral Base Region Recombination, Jonas Bereisa Jr.

Masters Theses

"A discrete, deterministic, mathematical model is developed for the neutral bulk base region of graded base devices which accounts for both the effects of recombination and the built-in electric field in the bulk base region at low, intermediate, and moderate current/injection levels. This model is applied to a study of neutron radiation effects in double diffused silicon transistors. Exact expressions are developed for the injected emitter, base and collector currents, the base recombination term, and the ratio of base current increase to collector current decrease as functions of device geometry, impurity profile, and neutron fluence. Neutron-induced current gain degradation is …

Abandoned Automobiles :A Case History Of Land Pollution, Robert William Arden

Masters Theses

"A study has been made of the abandoned automobile problem as it now exists throughout the United States with particular emphasis on the problem in the Saint Louis area. The primary goal of this study was to determine those factors which most influence the collection and disposal of derelict vehicles. The problem was examined in the following major areas: (1) The history of the problem in the Saint Louis area and the various attempts made to correct it, (2) the various businesses directly involved with the disposal of junk automobiles, namely, the auto wreckers and the scrap processors, and (3) …

A Computer Simulation Of The Internal Ballistics Of Recoilless-Rifle Rocket Launchers, John Edd Mosier

Masters Theses

"A computer program has been developed to simulate the basic mechanics and gas dynamics associated with launching a solid propellant rocket from a recoilless rifle. This program, entitled "KICKIT," may be used to predict the performance and evaluate many of the pertinent design parameters of both conventional recoilless rifles and a recoilless rocket launcher system. This program is a valuable analytical tool which enables the designer either to optimize the system design or predict the behavior of the system under off-design conditions"--Abstract, Page ii.

The Failure Criteria And Deformational Moduli Of Granular Rock, Kyung Chul Ko

Masters Theses

"Analytical solutions of stress for composite material are obtained by means of mathematical theory of elasticity, assuming spherical inclusions and uniform displacements of boundaries of representative elements. These solutions show that the failure criteria of composite materials are complicated functions of the elastic moduli of matrix, inclusion and composite, and the volume ratio of matrix and inclusion. Combining this theory with Griffith's theory gives a new criteria for brittle failure of granular rook. This theory appears to provide a nearly perfect model for granular rooks, inasmuch as: a) most assumptions used in other criteria are eliminated, b) most phenomena in …

Analysis And Control Of Noise Produced By Small Pneumatic Tools, Phillip Ray Elam

Masters Theses

"Noise measurements were made near the exhaust of three small pneumatic tools operating under various loads and with various components removed. One-third octave analyses were performed on the noise for identification of noise sources and to determine possible noise reduction techniques. It was determined that the noise spectra consisted of broad band turbulent flow noise plus periodic components at the tool motor blade passage frequency and harmonics of this frequency. One tool, the nut setter, was selected for reverberant field noise analyses and noise reduction studies. Reverberant field measurements indicated that most of the tool noise was transmitted through the …

The Semibullvalene Question: A Semi-Empirical Molecular Orbital And Bond Energy Approach, Shiow Yeh Lee

Masters Theses

"Semi-empirical molecular orbital calculations of the Extended Ruckel and MIND0/1 type have been performed on semibullvalene and the supposed transition state for its degenerate [3,3] sigmatropic rearrangement. The results have been coupled with bond energy calculations to ascertain whether semibullvalene is homo-aromatic or is undergoing a rearrangement of exceedingly low activation energy. A preponderance of the resulting data suggests that semibullvalene is homo-aromatic"--Abstract, page ii.

Initial Operation And Calibration Of The Umr Supersonic Axisymmetric Wind Tunnel, James Riley Murphy

Masters Theses

"Initial testing and a preliminary calibration were conducted in the UMR supersonic variable Mach number axisymmetric blowdown wind tunnel facility. During initial operations problems were encountered with control valve seat failure, control valve response and stability, and automatic operation. After having brittle fracture failures with seats made of nylon, Teflon and Telfon-copper composite, a copper seat was found to perform satisfactorily with minimal valve leakage. Control valve response and stability were greatly influenced by the setting of the needle valve located between the total pressure probe and the controller. The needle valve setting was observed to depend upon the stagnation …

The Possible Correlation Of Carcinogenic Activity With Electronic Structure Of Benz(A)Anthracene, Patricia Joan Blair

Masters Theses

"The electronic structure of benz(a)anthracene based on the sigma and pi electrons was predicted by the modified intermediate neglect of differential overlap (MINDO) molecular orbital method and compared with the pi electronic structure determined by the Pople method. The crystalline molecular structure was used for both methods. The Pople calculation was also done on the aromatic molecular structure and a combination structure which assumed the bond lengths of the crystal structure and the bond angles of the aromatic structure. Chemical properties predicted by the MINDO and POPLE electronic structures were compared; the MINDO results provided the best agreement with experimental …

Bound-Free Continuum Radiation From Non-Gray Nonisothermal Shock Layers, Chu Yih Wang

Masters Theses

"This study investigates the continuum radiative flux from nonisothermal stagnation shock layers composed of atomic gases. The general equations for the composition are derived and the Rankine-Hugoniot equations are simplified and solved to give the thermodynamic conditions of the shock layers. To accurately model the stagnation shock layer, the plasma must be considered to be nonisothermal. In the current study, linear shock layer temperature profiles are assumed. Consequently, the fluid dynamics and the radiation are uncoupled. The radiation model assumes one-dimensional radiative energy transport and considers only continuum processes. The radiative flux is calculated by considereing ground to free state …

Statistical Estimate Of Positional Error Inherent In Very Low Frequency Radio Navigation (Range-Range), Jimmie D. Mcginnis

Masters Theses

"To determine the effectiveness of Very Low Frequency (VLF) navigation in certain areas of the world, it is necessary that a method be developed to estimate the positional error associated with VLF relative positioning techniques. This paper presents a method which consists of a least-mean-squared procedure to sum up the errors contributed by each station being monitored. Since phase jitter (i.e., phase fluctuation) is a random variable, a statistical approach is employed to produce a one Σ ellipse centered about the true position. In short, this method defines the size and orientation of an area called an error ellipse which …

The Design And Construction Of An Inertia Welder, Arthur Ferdinand Grimm

Masters Theses

"The purpose of this investigation was the design and fabrication of a machine to bond metal to metal using the inertia method of friction welding. This method of bonding is considered far superior to the heretofore employed friction welding processes as will be explained later. The inertia method controls the energy imparted to the weld by using a flywheel which has been brought to a state of predetermined kinetic energy due to rotation. This energy is then transferred to the weld zone in the form of heat due to rotational friction. Hollow specimens with a cross-sectional area of 0.306 square …

Note On "Approximate Free Energies For Heisenberg Ferromagnets", J. H. Hemmann, Harry A. Brown

Physics Faculty Research & Creative Works

No abstract provided.

A Systematic Study Of Instrument Variables Upon The Accuracy Of Microprobe Analysis, R. A. Parr

Masters Theses

"The purpose of this investigation was to study the effect of instrument parameter changes upon X-ray intensity measurements of the copper-manganese system. The parameters utilized in this study included: (1) polished, contaminated, and 600 grit surfaces ; (2) constant sample current and constant beam current modes; and (3) 15 KV, 20 KV, and 25 KV accelerating potentials. Inspection of the data disclosed three interesting points: (1) copper and manganese X-ray intensity measurements appear to be a linear function of composition in the 15 KV through 25 KV accelerating potential range; (2) electron backscatter measurements consistently show in a limited range …

An Investigation Of The Adjustable Element Concept For Design Of Automotive Exhaust Mufflers, Phillip Scott Gegesky

Masters Theses

"The concept of the adjustable muffler is felt to be a step in the direction of easing the present tedium of constructing and testing prototype mufflers. The evaluation of such a muffler also furthers the knowledge of the interaction of acoustic elements. A review of past and present efforts in the design and evaluation of acoustic filters and filter elements is herein presented. Some consideration is given to phenomena, such as tube attenuation and transverse modes of vibration, which are encountered in muffler evaluation techniques. The characteristics of wave guides are discussed at length. The solution of the plane wave …

Mass Transfer From Spherical Gas Bubbles And Liquid Droplets Moving Through Power-Law Fluids In The Laminar Flow Regime, Robert M. Wellek, Cheng Chun Huang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Calculated mass transfer coefficients for the continuous phase are presented for internally circulating spheres of a Newtonian fluid traveling through a power-law-type continuous phase in the so-called creeping-flow region. The Nakano and Tien stream functions allow the Sherwood number to be computed as a function of the Peclet number, power-law index, and a viscosity ratio parameter. The Hirose and Moo-Young relation is shown to be a limiting case of this numerical solution. Mass transfer rates increase as the fluids become more pseudoplastic and/or the continuous phase consistency index increases, all other factors held constant. © 1970, American Chemical Society. All …

Thermochemical Hydrogen-Deuterium Isotope Effects, Wayne C. Duer

Doctoral Dissertations

"The heats of solution at 25.0 ± 0. 1°C for each member of hydrogen-deuterium isotopic pairs (chloroform/chloroform-d, acetone/acetone-d₆, methanol/methanol-d₁, ethanol/ethanol-d₁, and water/heavy water) have been determined as a function of molality in a variety of solvents. The heats for most of the systems could be described as a linear function of average molality with an average deviation in fit of less than one per cent. Using these linear equations, heats of solution at infinite dilution were obtained by extrapolation to zero molality. The heats of solution at infinite dilution of the hydrogen containing compounds were subtracted from those of the …

A Computer Simulation Of Mine Air Shaft Thermodynamics, Ambyo Sumopandhi Mangunwidjojo

Doctoral Dissertations

"Several earlier investigations have been conducted into various aspects of heat problems in underground mines. The application of general gas laws and thermodynamics in the approach of mine ventilation has been helpful in elucidating certain difficulties associated with the subject. By combining several of the techniques perfected by these researchers and applying Carrier's method of calculation for heat flow from exposed rock strata into a workable plan, a method was developed whereby it is possible to accurately and conveniently predict the quality of working environment at any point within a deep mine. The findings of this study may be of …

Higher Space Mode Analysis Of A Large Cylindrical Pulsed H₂O System, Harold David Hollis

Doctoral Dissertations

"By utilizing a geometrically centered pulsed source internal to a large (B²_g) ≈ 0.002) cylindrical H₂O system, the neutron flux was measured as a function of position and time. A least square fit of the data yielded the fundamental and five higher decay constants and amplitudes of the thermal neutron flux. Symmetrical and enhanced neutron densities were obtained as a result of the internal source. Long waiting times were unnecessary and data acquisition was accelerated.

The decay constants were found to be independent of position, pulse width, counting time and rates, method of normalization, or waiting time. …

Binary Molecular Diffusivities In Liquids: Prediction And Comparison With Experimental Data, Ronald Dean Mitchell

Doctoral Dissertations

"The Eyring rate theory equation has been modified successfully to enable predictions of binary molecular diffusivities for a wide variety of liquid-liquid systems. The activation free energy for binary diffusion has been evaluated in terms of the activation free energies for self diffusion of the solvent and solute. This was accomplished through the use of regular solution theory by relating the bond breaking energy of the jump step to the bond breaking energy in evaporation. Diffusivities estimated by this equation and the equations developed by Olander, by Gainer and Metzner, and by Wilke and Chang were compared with experimental data. …

A Study Of Far Infrared Grid Filters, Harold Victor Romero

Doctoral Dissertations

"The diffraction theory for the transmission of electromagnetic fields through a grid in a dielectric is derived and experimentally checked in the visible wavelength region. In the far infrared, an approximate mathematical representation is found to describe the grids in dielectrics. The empirical equations in the far infrared are combined with the electrical circuit-transmission line analog for inductive grids. Detailed structure of the transmittance versus wave number curves are presented. Then the theory of multielement grid filters is derived and compared with experiment. The properties of the filters can be predicted from a knowledge of the characteristics of the individual …

Temperature Variation In Distribution Of Relaxation Times In Aluminosilicate Glasses, David Wayne Moore

Doctoral Dissertations

"The distribution of relaxation times for the alkali peak in a Li₂ O·A1₂O₃ ·2.0SiO₂ glass and for the mixed alkali peak in a 0.5Li₂O·0.5Na₂O·A1₂O₃·2.OSiO₂ glass was studied using the internal friction technique. A lognormal distribution of relaxation times provided the best agreement with the experimental data. The ß parameter of the lognormal distribution function, which is related to the half-height peak width, varied with temperature, indicating that the distribution of relaxation times is dependent upon the activation energy and the activation entropy of the relaxation mechanism. The major contributor to the distribution of relaxation times is a wide distribution in …

An Experimental And Theoretical Study Of The Nucleation Of Water Vapor On Ions In Helium And Argon, Daniel R. White

Doctoral Dissertations

"The nucleation of water vapor on ions in atmospheres of helium and argon was studied using an expansion type cloud chamber. Separation of the positive and negative ions was achieved so that the nucleation could be studied as a function of both the sign of the ionic charge and the supersaturation. A semiphenominological theory was developed as an extension of the classical theory to include the effects of the ionic charge on the nucleation process. The theoretical model of the prenucleation embryo was assumed to possess an oriented dipole surface layer with the direction of orientation dependent on the sign …

A Fundamental Investigation Of The Gas Phase Polymerization Of Styrene And Vinyl Type Monomers In A Low Power Inductively Coupled 4 Mhz Rf Plasma, L. F. Thompson

Doctoral Dissertations

"A study has been made on the plasma polymerization of styrene and vinyl type monomers in a cold, low power, inductively-coupled RF plasma. All vinyl type monomers yielded an insoluble, crosslinked film which was slightly colored. A kinetic study is reported for styrene. The effects of power level, bleed rate of monomer, pressure and reactor geometry on the rate of polymer formation are reported. A mechanism is postulated for plasma polymerization. It was found that the initiation step was the rate controlling step and that the reaction followed a cationic polymerization scheme. Both crosslinking and discoloration of the polymers occur …

A Quasi-Lattice Model Of Simple Liquids, Jesse Herbert Collins

Doctoral Dissertations

"A cellular model of simple liquids is proposed which eliminates the objectionable feature of long range order found in other cell models. The volume is divided into N identical spherically symmetric cells, each occupied by one molecule. The cell-center density distribution relative to an average given cell center forms a series of Gaussian peaks whose width is proportional to the square root of the distance from the given cell center. The number of cell centers and average radial distance represented by each of the peaks correspond to a face-centered cubic lattice. The molecular pair distribution function is determined for several …

A Simulation And Diagnosis System Incorporating Various Time Delay Models And Functional Elements, David Michael Rouse

Doctoral Dissertations

"The application of digital simulation to all phases of digital network design is considered here as oppossed [sic] to development of simulation for one or two restricted parts of the digital process. For this reason a simulator is presented which can be consistent by varying the level of expression from the simulation of architectural structures to such detailed simulation requirements as race analysis of asynchronous sequential circuits. In order to make system simulation more than just an idea, it must be capable of handling large circuits in reasonable times. It is demonstrated that functional simulation has the potential to increase …

A Three-Dimensional Mathematical Simulator Of Multiphase Systems In A Petroleum Reservoir, Leonard Koederitz

Doctoral Dissertations

"A generalized digital analysis for calculating three phase, three dimensional flow in reservoirs is developed. The computerized mathematical model is applicable to depletion drive, gas injection, water injection, and/or aquifer drive systems with modifications specific to the simulation criterion of that type of drive and includes fluid compressibility effects, gravity drainage and capillary pressure. The simulation allows arbitrary consideration of reservoir heterogeneity, geometry, well locations and rates of production. An innovation to the alternating direction technique for linear differential equations discussed by Brian is developed and employed in order to render the method of solution applicable to non-linear differential equations. …

Effects Of Cold Work In Cold-Formed Steel Structural Members, S. J. Britvec, Alexander Chajes, K. W. Warren, Jairo Uribe, George Winter

CCFSS Library (1939 - present)

No abstract provided.