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The Story Of Rolla Missouri, Volume 1, Clair V. Mann, Bonita H. Mann

The Story of Rolla Missouri

Volume 1 of The Story of Rolla Missouri covers the years 1844 to 1890.

Magnetic Properties Of Cadmium Manganese Ferrite, B. W. Jong, P. D. Ownby

Materials Science and Engineering Faculty Research & Creative Works

The room-temperature saturation magnetization of CdxMn1-xFe2O4 decreased with increasing cadmium concentration. When 0 < x < 0.5, the decrease in saturation magnetization was due to the increase in the amount of non-mgnetic distorted cubic Cd(Mn, Fe) 2O4.

Thermal Decomposition Of Boron Triiodide On Molybdenum Field Emitter Surfaces, Richard E. Moore, P. Darrell Ownby

Materials Science and Engineering Faculty Research & Creative Works

Boron has been adsorbed onto molybdenum field emitter surfaces by the thermal decomposition of boron triiodide at corrected partial pressures of 1.4 x 10-9 Torr to 4.5 x 10-9 Torr. Based on field emission work function data and an analytical work function versus adsorbate-coverage relationship, a quantitative measure of the monolayer coverage of boron on molybdenum has been determined; this value is 6.3 x 1014 atoms/cm2/monolayer. A parameter, β, is defined which is a measure of the effective yield of adsorbed boron on molyb-denum from BI3. β is formulated in terms of the free energy of dissociation of the BI3 …

Knudsen Effusion Study Of The Vaporization Of Cdo(S), R. Tom Coyle, Gordon Lewis

Materials Science and Engineering Faculty Research & Creative Works

Knudsen effusion studies were conducted on CdO(s) in fused‐SiO2 Knudsen cells from 889 to 1110 K. The orifice size was varied; the largest cell orifice yielded a calculated pressure significantly lower than could be accounted for by experimental error. Average‐slope‐ and average‐free‐energy‐function‐based values of ΔHc298 were 86.9 ± 1.1 and 88.8 ± 0.5 kcal/mol, respectively. The data from the present work were combined with those of previous investigators using a method discussed by McCreary and Thorn; a ΔHc298 of 88.2 ± 0.2 kcal/mol was obtained. Using this combined value for ΔHc298 and ΔSc298= 51.40 ± 0.1 eu (obtained from the …

Magnetostrictive Aftereffect In A Dilute 50fe-50ni-C Alloy, Raj Master, Manfred Wuttig

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Influence Of Oxygen Activity On The Sintering Of Mgcr2o4, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

The sintering behavior of MgCr2O4 powder compacts was investigated as a function of temperature, time, and oxygen activity. The results show that MgCr2O4 cannot be densified to >70% of theoretical density at temperatures up to 1700°C if the oxygen activity exceeds 10−6 atm. The oxygen activity must be decreased to <10−10 atm before densities exceeding 90% of theoretical can be achieved. Weight loss and X‐ray data indicated that maximum density occurred at an oxygen activity just above that where MgCr2O4 becomes unstable. Copyright © 1974, Wiley Blackwell. All rights reserved

Detection Of Impurities In Zinc Sulfate Electrolytes By Cyclic Voltammetry Techniques., Bruce Alan Lamping

Masters Theses

"A cyclic voltammetric technique has been developed for quantitatively detecting the presence of active chemical species present in zinc sulfate electrolytes. The experimental apparatus consisted of a pyrex "H" cell, an Al cathode encased in a Teflon holder, a carbon anode and a mercurous sulfate reference electrode. Voltammograms were obtained from industrial, purified neutral leach solution (Cominco Ltd., Trail, B.C.) acidified to give a final concentration of 0.77 M Zn⁺⁺, 1 M H₂SO₄. The polarization curves were then evaluated and used as a reference standard to compare with results obtained when various organic and …

Oxidation Reactions Of Unsaturated Hydrocarbons For Fuel Cells, James W. Johnson, William Joseph James, A. K. Agrawal

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The anodic oxidation of unsaturated hydrocarbons has been the subject of numerous studies, primarily on Pt and Au electrodes at low temperatures, < 100°C. The complete oxidation to CO₂ is usually the predominant reaction with both H₂O and OH^- having been proposed as the oxygen source. Usually a single study consists of a comprehensive investigation of a single compound on a single electrode or a somewhat limited study of several compounds on a single electrode. A diversity of proposed mechanisms has resulted and is illustrated by the following summary.

Fresnel Drag In Uniformly Moving Media, William F. Parks, J. T. Dowell

Physics Faculty Research & Creative Works

A general first-order formula is derived for the Fresnel-drag effect in a uniformly moving medium with a plane surface. The two classical equations due to Lorentz and Laub are shown to be special cases corresponding to different experimental arrangements. The recent experiment of Bilger and Zavodny on Fresnel drag in a ring laser is discussed. © 1974 The American Physical Society.

Dispersion Curves For Surface Electromagnetic Waves With Damping, Ralph William Alexander, G. S. Kovener, Robert John Bell

Physics Faculty Research & Creative Works

The Recent Observation of Back bending in the Dispersion Curves of Surface Plasmons on Silver Can Be Explained by Use of Fresnel's Equations. in the Presence of Damping, the Results of Attenuated-Total-Reflection Measurements Can Be Displayed as Dispersion Curves Either with or Without Back bending. the Measurements for Silver with Back Bending Are Expected for Experiments in Which the Frequency is Fixed, and the Propagation Constant (Or Angle of Incidence) is Swept. © 1974 the American Physical Society.

Characterization And Pollutional Contribution Of Stormwater Runoff From A Small Urban Area., John Lamb Wendleton

Masters Theses

"Stormwater runoff from urban areas has long been recognized as a pollutional source, however, only in the last decade has there been an extensive eff ort to measure its effect on receiving lakes and streams. Because runoff from small urban communities has received limited attention, this investigation was undertaken to determine the quality and pollutional contribution of stormwater runoff from a small urban area. The specific objectives of the study were: to characterize and correlate runoff quality with land use activity and to qualitatively and quantitatively measure the pollutants discharged with respect to time.

Runoff from 3 test watersheds in …

A Review Of Directed Graphs As Applied To Computors, Paul D. Stigall, Ömür Tasar

Electrical and Computer Engineering Faculty Research & Creative Works

No abstract provided.

The Anodic Dissolution Of Tin In Acidic Chloride Solutions, James W. Johnson, E. C. Liu

Chemical and Biochemical Engineering Faculty Research & Creative Works

The anodic dissolution of Sn in acidic chloride solutions (pH = -2.0 to 2.9) was studied at 25 °C. The apparent valence of the dissolving ions varied from about 0.4 to 2.4, and was a function of both electrolyte and c.d. The complexing of Sn2+ by Cl- had an important influence, with SnCl-3 apparently being the dominant product. A reaction sequence is proposed involving the stepwise oxidation of Sn, accompanied by reaction with Cl-. © 1974.

Surface Elastic Waves In Piezoelectric Semiconductors And Layered Media, Yu-Pin Han

Doctoral Dissertations

"The primary interest of this investigation is to understand the surface elastic wave properties in piezoelectric semiconductors and layered media. Generalized piezoelectric wave equations in piezoelectric semiconductors and layered media are derived. Systems considered are the piezoelectric semiconductor, the two layer piezoelectric insulator-semiconductor, the three layer piezoelectric insulator- gap-semiconductor and the four layer piezoelectric insulator-gap-semiconductor-dielectric substrate. The eigenwave expansion and the iteration methods in the complex domain are used to solve the problems. Mathematically, it represents a solution of the eigenvalue boundary value problem which involves iteration of functions in the complex domain. Solutions obtained are eigenvalues and eigenvectors which …

Cross Sections For Photoionization Of The 6²P-Fine Structure Levels Of Cesium, John Daniel Jones

Doctoral Dissertations

"The cross sections for photoionization of excited cesium from the 6²P_3/2- and 6²P_1/2-fine structure levels have been measured using a triple crossed-beam apparatus. Two photon beams, one for excitation and one for ionization, impinge upon an atomic beam and produce ions at the point of intersection. The relative cross section is determined from a knowledge of the ion count rate and the relative photon flux of the ionization light. The results are normalized to available theoretical calculations and compared with recombination measurements in cesium plasmas. The present cross sections are found to decrease with …

Structural Behavior Of Cold-Formed Steel Members Made Of Thick Sheets And Plates, Ai-Shen Liu

Doctoral Dissertations

"It is well-known that the current AlSI Specification for the design of cold-formed steel structural members has been developed mainly for thin steel sections. In order to extend the applicability of the specification for the design of cold-formed steel members thicker than 1/4 in., both analytical and experimental investigations have recently been conducted with special emphases on the effects of cold work on the mechanical properties of corners and the strength of bolted connections.

For the effects of cold work, previous investigations have shown that the phenomena of strain hardening and strain aging are main factors which affect the mechanical …

A Study Of The Kinetic And Thermodynamic Properties Of Carbon Acids In Methanol, Dennis L. Filger

Doctoral Dissertations

The thermodynamic acidity (pK_a) of iodoform in methanol was determined at 25°C and 35°C; the values are 18.74 and 18.05, respectively . These acidity constants were determined by a modification of the equilibrium quenching technique which involves the conversion of the conjugate base of iodoform, present at equilibrium, to the radioactively labelled acid.

The rate constants for the methoxide-catalyzed hydrogentritium exchange of chloroform, iodoform, 9-phenylfluorene and indene were determined in methanol at various temperatures. The second-order rate constants obtained from these studies were shown to be the rate constants for removal of a triton. The activation parameters (ΔH …

Mathematical Simulation Of Gas And Water Coning In Petroleum Reservoirs By The Dynamic Material Balance Technique, Visheshwar Nath Simlote

Doctoral Dissertations

"The prediction of coning behavior at a producing oil well is one of the most difficult numerical simulation problems. Because of the convergent flow patterns and small sizes of the inner grid blocks, the radial coordinate models used to study the problem have a tendency to become unstable. Since several hundred pore volumes may flow through the inner grid blocks during a rather small time interval, instabilities are likely to occur in the saturation calculations for these grid blocks. The dynamic approach to saturation calculations is a method which first computes the correct material balance and then calculates the saturation …

Base-Induced Reactions Of P-Nitrobenzyl Compounds, Paul Henry Ruehle

Doctoral Dissertations

"The base-induced reactions of several p-nitrobenzyl compounds were studied. The products varied with changes in the leaving groups. With relatively poor leaving groups (Cl, S⁺(Me)₂), p,p'- dinitrostilbene was produced in good yield. The products of the reaction of p-nitrobenzyl chloride and hydroxide ion in 50% aqueous dioxane were 52.0% p,p'-dinitrostilbene, 43.9% cis- and trans-p,p'-dinitrostilbene oxides, 3.2% p-nitrobenzyl alcohol, and traces of other compounds. With dissolved oxygen, no stilbene was produced; the main product was 88% cis- and trans-p,p'-dinitrostilbene oxides. The addition of small amounts of di-t-butyl nitroxide caused a decrease in both the rate of the reaction and the amount …

A Study Of Exothermic Chemical Reaction In A Porous Catalyst Wedge, Joseph Michael Schardl Jr.

Doctoral Dissertations

"Temperature and composition were measured at various locations in a system where ethylene is hydrogenated to ethane on a 1/4 inch porous catalyst wedge made of nickel supported on alumina. 'When the wedge of catalyst was bathed in hydrogen, experimental results indicated a high temperature rise from the feed temperature to the catalyst which is implied by the diffusion controlled regime for solid catalyzed, highly exothermic reactions. This high activity was reversibly reduced by bathing the catalyst wedge in nitrogen for extended time periods (greater than 24 hours). This nitrogen soaking changed the experimental conditions from those of diffusion controlled …

Surface Electromagnetic Waves With Damping I. Isotropic Media Ii. Anisotropic Media, Gary Shannon Kovener

Doctoral Dissertations

Paper 1: “Surface electromagnetic wave (SEW) dispersion curves are usually calculated using a simple equation derived from Maxwell’s equations and boundary conditions. When complex dielectric functions are used for the two media, the component of the propagation vector along the surface k_x becomes infinite as the frequency ω approaches the surface polariton frequency ω_s if ω is considered complex and k_x real. On the other hand, if k_x is considered complex and ω real, the dispersion curves bend back toward smaller k_x as ω approaches ω_s. We have previously demonstrated that both types …

Solid-Fluid Drag Reduction, Ian Radin

Doctoral Dissertations

"Pressure drop measurements were made on a variety of solid-liquid suspension systems in order to study the effects of particle shape and size, concentration, fluid viscosity and tube diameter on drag reduction. Measurements were made over a wide range of Reynolds numbers in two tubes: 1/4 inch and 1 inch in diameter.

Drag reduction could always be obtained with fibrous additives of length-to-diameter ratio greater than 25-35 if the concentration was sufficiently high. The drag reduction behavior of these suspensions is different from that of high polymer and soap solutions. Laminar flow behavior is stabilized giving lower than normal friction …

Feasibility Study Of An Electromagnetic Trap Fusion Reactor., Dennis Gilbert Blondin

Masters Theses

"Through the use of detailed particle and energy balances, electromagnetic traps with magnetic cusps are found to be unsatisfactory for continuous operation when using only neutral particle beams to sustain a thermonuclear plasma. Low power multiplication characteristics inherent in this CTR design probably preclude supplemental plasma heating methods. However, by using an alternate Yin-Yang magnetic system, continuous CTR operating regimes are found at an ion temperature of 20 keV while assuming only neutral particle beam heating. Although these regimes require applied electrostatic potentials approaching a half-million volts, this device demonstrates a capability for efficient power production"-- Abstract, p. ii

Models For Molecular Vibration, Allan Bruce Capps

Masters Theses

“The purpose of the investigation is to determine if a classical model can be used to characterize molecular vibrational and librational (restricted rotation) frequencies. In general, the model treats a molecule as asymmetrical and rigid and simulates the intermolecular forces by springs along the bonds. Molecules constrained to a plane and molecules free to move in three dimensions are analyzed. The frequencies of water molecules are investigated, in particular. The model and analytic components are found to function well. Within the limits set for the model, the water molecule simulation is not successful as the motion becomes anharmonic for energy …

Effect Of Dissolved Water On Physical Properties Of Silver Borate Glasses, E Richard Reynolds

Masters Theses

"The effect of dissolved water on borate glasses containing 4-20 mol % Ag₂O was investigated. Water was dissolved in the glasses by bubbling with a carrier gas (oxygen) containing different partial pressures of water vapor. A minimum in water solubility was found at 11 mol % Ag₂O. Water contents in excess of 0.5 mol % H₂O did not have a great effect on the transition temperature or the dilatometric softening point. Below 15 mol % Ag₂O, the water content had no effect on the thermal expansion coefficients. Beyond 15 mol % Ag …

Computer Analysis Of 3-Phase Induction Motor Operation On An Open-Delta Distribution System, S. Clark Seematter

Masters Theses

"Open-delta/open-delta and open-wye/open-delta transformer banks are often used as an economic means of supplying simultaneous single-phase and 3-phase loads. If the 3-phase load is an induction motor and if these banks are used, the inherent voltage unbalance causes increased losses and uneven heating that may lead to motor failure. Two previously published theories are used to predict motor heating that is caused by the unbalanced voltages and the motor derating that is necessary to prevent insulation failure"--Abstract, page ii.

Magnetostrictive Aftereffects In A Dilute 50fe-50ni-C Alloy, Raj N. Master

Masters Theses

"Crystallographically equivalent interstitial sites are energetically equivalent when the host crystal is free of any fields. This situation is shown in Fig. Pl from which it may be appreciated that the difference of the free energy of the "crystal" with an interstitial "I" located in "x" and "y" sites, respectively, is equal to zero. This energy equivalence of the various interstitial sites is destroyed when the host crystal is subjected to fields such as strain fields, magnetization fields or a combination of both as may be appreciated from Figs. P2 through P4. In this case, the interstitials will preferentially occupy …

Comparison Of Scatter Storage Techniques Using An Analysis Of Variance Model, Robert Lee Kitsch

Masters Theses

"An analysis of variance model is developed to determine if a significant difference exists between various scatter storage techniques. The model is a two-factor hierarchical mixed design with each combination of transformation and search method considered as a treatment. The data used in the analysis is obtained from a computer program which provides statistics on the number of probes needed to load the (k+l)st item into a table for the different treatments. An ANOVA table was then computed for various load factors.

A significant difference among the treatments was detected for load factors above .4. Comparison of individual treatments using …

Transformer Connection Study For 138 Kv To 12.47 Kv Substations Of The Union Electric Company St. Louis, Missouri, John Glenn Walsh

Masters Theses

"This thesis examines the transformer connections that can be used in the new 138-12.47 kV substations on the Union Electric power system. The object is to determine if a zero phase shift transformer without a delta connected tertiary winding can be used and economically justified. Traditionally a delta winding has been automatically included for this application without taking engineering time and effort to study all ramifications including possible dollar savings available with other connections. Three transformer manufacturers supplied technical and cost data which are analyzed, based on Union Electric system conditions. Consideration of relaying, harmonics and unbalanced loading shows that …

Diurnal Solar Heating And Cooling Of A Water Reservoir, Stephen Patrick Lepper

Masters Theses

"The transient diurnal heating of a water reservoir by solar radiation; and its cooling by surface convection, evaporation, and radiation emission was analytically modeled. The directional and spectral properties of the incident solar radiation, the air-water interface, and the selective attenuation of radiant energy by the water were properly included in the analysis. The diurnal vertical temperature distribution was predicted by numerically solving the energy equation using a finite difference technique. It was determined that the surface boundary conditions and the selective absorption of radiant energy by the water strongly influence the thermal stratification of stagnant water.

The diurnal compensating …