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Characterization Of Small Molecules And Ions By Atmospheric Pressure Ionization-Mass Spectrometry, Maleesha De Silva

Theses and Dissertations

Mass spectrometry (MS) has become a widely used technique for the characterization of a wide range of substances in diverse fields. The selection of appropriate ionization techniques, source parameters, charge carriers based on the analyte’s polarity is essential in MS as only the ions are detected. When using a soft ionization technique, single stage-MS at best provides only chemical composition; thus, tandem MS is needed to determine structural information and dissociation pathways. This dissertation focuses on the characterization of various small molecules and ions using different ionization techniques, charge carriers, and collision-induced dissociation (CID).

In Chapter II, commercially available ionic …

Testing Of Methods For Reducing Motivational Bias In Multi - Criteria Decision Analysis Problems, Chadwick Samuel Kerr

Theses and Dissertations

The idea of multi-criteria decision making has been around for quite a while. All judgement tasks are potential points of bias introduction. Each judgement task was assessed to identify common biases introduced through an extensive literature review for each task and bias. In several other studies, the distinction is made between cognitive and motivational biases. Cognitive biases are widely studied and well known with mitigations that have been validated. Motivational biases are judgements influenced by the decision maker’s desire for a specific outcome, also referred to as intentional bias, that are hard to correct and received very little testing and …

Development Of A Bioinspired Nugalbot For Precision Seeding Of Rice, Harsa Dhani

Theses and Dissertations

Many people around the world live in islands with mountainous lands. These people plant upland rice for their staple food. However, farming in these disadvantageous farms requires high input and gains low yield. One possible solution for improving productivity is by utilizing precision seeding. This study is focused on developing a robot for precision seeding of rice that is suitable for farming in rough terrain. A bioinspired human arm robot for picking seeds and making a hole on the ground was developed in accordance with Aalborg method for bioinspired design. Development of a mobile platform to carry the robot arm …

The Effects Of Cover Crops In An Integrated Livestock/Continuous Corn Cropping System In East-Central Mississippi, Ken Randolph Waddell

Theses and Dissertations

There is growing interest within the agricultural industry on how cover crop systems affect soil health and economic productivity in integrated crop-livestock systems. This study investigated the combined effects of cover crop species; no-till and conventional till; and grazed (G) and un-grazed (UG) in a continuous corn (Zea mays) production system in east-central Mississippi. Cover crops were established in the fall of 2019 and 2020 in two separate field studies. Corn yield was not affected by grazing or tillage but was affected by cover crop species. We then compared the difference in cover crop species treatments with their respective corn …

Design Of Plastic Contaminant Eliminator In Seed Cotton, Joshua H. Tandio

Theses and Dissertations

Plastic contamination in cotton is a problem in cotton industry and researchers have worked on this problem with different approaches. This thesis documents the design of mechanical and electronic real-time systems for detecting and removing plastic contaminants. The mechanical system was designed to expose plastic embedded inside the seed cotton to the sensor and to separate plastic contaminated cotton from the process stream. The detection system consisted of an embedded computer interfaced with a USB camera and Neural Network (NN) software running in it. Two NN models were tested, a transfer learning model and a built-from-scratch original model. The original …

Virtual Reality And Postural Control: The Virtual Moving Room Paradigm, Hannah R. Freeman

Theses and Dissertations

Virtual reality (VR) is becoming increasingly important in balance training. However, the influence of VR generated visual perturbation, through the novel virtual moving room paradigm, is unknown. Thirty healthy individuals had their static balance assessed on a BTrackS balance plate under eight different conditions: baseline eyes open and eyes closed with and without VR, unexpected toward and away moving VR perturbation, and expected toward and away moving VR perturbation. Multiple statistical analyses were conducted, and the results revealed significantly higher postural sway variables in the unexpected moving toward trials compared to the other moving room conditions; significantly higher postural sway …

Identity Formation Of Black Surinamese Dutch Women, Ashley Melcherts

Theses and Dissertations

This qualitative study explores the self-identification of young Black Surinamese Dutch women in the racialized context of Dutch society, how family and school contribute to identity formation, and how identity shapes the everyday lives of young women of color in predominantly white institutions in the Netherlands. Eight online in-depth interviews were conducted with Black Surinamese Dutch college women in the Netherlands about how they understand their identities, how they perceive the process of learning about their identities, and how their identities shape their everyday experiences in Dutch society. Findings illustrate the influence of family in shaping ideas about identity, the …

Systematics And Population Structure Of Amblyomma Maculatum Group Ticks And Rickettsia Parkeri, An Emerging Human Pathogen In Southern Arizona, Usa, Michelle E. J. Allerdice

Theses and Dissertations

The recent discovery of Amblyomma maculatum sensu lato (s. l.) ticks in southern Arizona has renewed discussions around species designations for members of the Amblyomma maculatum tick group. Amblyomma maculatum s. l. from Arizona appear to be morphologically intermediate between A. maculatum sensu stricto (s. s.) and A. triste s. s. At present there is no conclusive species designation for the ticks from Arizona. My research focused on analyzing the systematics of both A. maculatum s. l. and Rickettsia parkeri, a common bacterial pathogen transmitted by these ticks.

In the laboratory, A. maculatum s. l. from Arizona and A. maculatum …

Evaluation Of Alternate Wetting And Drying Irrigation Management In Rice, Richard Lee Atwill Ii

Theses and Dissertations

Water level declines in the Mississippi River Valley Alluvial Aquifer (MRVAA) are attributed largely to withdrawals for rice (Oryza sativa L.) irrigation. This study was performed to determine if alternative irrigation strategies for rice could reduce withdrawal from the MRVAA without having an adverse effect on grain yield, grain quality, control of barnyardgrass, and profitability. Research was conducted in Stoneville, MS and 19 on-farm locations across the Delta region of Mississippi from 2014 through 2017 to determine the irrigation threshold for alternate wetting and drying (AWD) rice irrigation, the effect of AWD management on barnyardgrass control, and effects of …

Mitigation Of Herbicide Resistance Development Among Weed Species In Cotton And Peanut, Justin S. Calhoun

Theses and Dissertations

Herbicide resistance development among weed populations in cotton and peanut is becoming increasingly difficult to manage. If resistant populations continue to persist, weed control practices for producers will become less efficient and more costly. The objective of this research was to evaluate alternative weed control techniques designed to mitigate herbicide resistance development for their agronomic and economic impact on weed management systems. Studies were conducted in 2019, 2020, and 2021 at multiple locations in Mississippi and Arkansas investigating multiple techniques including the addition of soil surfactants in herbicide tank mixtures, increasing SOAs utilized in peanut herbicide programs, applying non-labeled herbicides …

Soybean (Glycine Max) Response To Multiple, Sublethal Exposures Of 2,4-D And Dicamba From Vegetative Through Reproductive Growth, Graham Robert Oakley

Theses and Dissertations

This study was conducted to determine whether soybean productivity is affected by multiple, sublethal herbicide exposures. The effects of dicamba and 2,4-D on soybean (Glycine max) productivity was investigated at 17 site-years. Relative to a single exposure of dicamba at R1, an additional exposure at either V3 or R3 reduced yield up to 23%. Three or more applications did not further decrease yields relative to an R1&R3 exposure. For 2,4-D, a single application to V3, R1, R3, or R5 soybean did not affect grain yield. However, two exposures of 2,4-D occurring from V3 through R3 reduced yield 5 to 7%. …

Feasibility Of Delivering Fall Prevention Intervention For People With Intellectual Disability In Group-Homes, Poram Choi

Theses and Dissertations

Adults with intellectual disability (ID) have a higher rate of falls than the general population, and changing health behaviors through exercise program could enhance health and reduce falls in this population. However, the feasibility study of fall prevention based on the theoretical framework for adults with ID has not been explored to date. This study examined the feasibility of a home-based exercise intervention for people with ID living in a residential setting. We provided an 8 week intervention consisting of a training workshop for support workers and sessions for adults with ID devoted to behavior reward, education about fall prevention …

Examining The Need For Parental Satisfaction With The Msu Extension Equine Assisted Therapy Program, Ashlyn Ann Kiker

Theses and Dissertations

Animal assisted interventions are becoming more prevalent in our society. Animal interventions have become a popular therapy technique that exist to aid a variety of disabilities. Equine therapeutic riding has become one of the most popular forms of animal assisted therapy for both children and adults. While research shows the importance and benefits of animal assisted therapy for children, there is a lack of research concerning parental satisfaction within therapeutic riding programs.

This study tested a newly developed instrument for measuring parental satisfaction for therapeutic riding programs. The Parent/Caregiver Evaluation Tool (Kerr, 2021) was administered to parents/caregivers whose children participated …

The Efficacy Of The Low-Fodmap Diet To Alleviate Symptoms Of Irritable Bowel Syndrome In Adults: A Systematic Review, Jacqueline Nicole Rustom

Theses and Dissertations

Irritable bowel syndrome (IBS) is a functional bowel disorder with 6.5% worldwide prevalence that causes gas production, abdominal distension, and abdominal pain or discomfort. This systematic review describes efficacy of the Low-Fermentable Oligosaccharides, Disaccharides, Monosaccharides And Polyols (FODMAP) diet (Low-FODMAP diet or LFD) to alleviate IBS symptoms using the PRISMA guidelines. Nine randomized controlled trials (RCT) and one non-RCT consecutive controlled study published between 2015 to 2019 were identified using PubMed and CENTRAL. Included studies involved adult IBS participants with symptoms of abdominal pain, constipation, and/or diarrhea. A total of 530 participants completed the interventions from the 10 studies included …

The Art Of Amphibian Conservation: Linking In-Situ And Ex-Situ Populations Of Endangered Species Through Genome Banking, Isabella Joann Burger

Theses and Dissertations

Limited breeding success in captive breeding programs has necessitated the development of assisted reproductive technologies (ART) to preserve and increase genetic variation and population numbers of both captive and wild amphibian groups. ART has been shown to be successful in numerous anuran species, and current studies focus on the application of ART in ex-situ populations. The focus of this project is to show that linking in-situ and ex-situ amphibian populations through sperm cryopreservation, genome banking, and in-vitro fertilization is possible, with the goal of increasing gene diversity throughout groups in order to produce self-sustaining, wild populations in the future. Specific …

Urban-Rural Differences In Lifespan Variation In The United States, Benjamin H. Walker

Theses and Dissertations

Since the mid-1980s, mortality rate improvements in urban areas have outpaced those in rural areas, leading to substantial urban-rural disparities in mortality. Research on urban-rural mortality disparities has focused exclusively on differences in mortality between urban and rural areas and has not examined differences in the amount of inequality in the length of life within these areas. Lifespan variation is an important dimension of health inequality that complements traditional metrics of mortality (i.e., mortality rates and life expectancy) by indicating the amount of inequality of lifespans within a population. This dissertation provides several contributions to our understanding of urban-rural differences …

The Development Of An Immersive Virtual Exploratory Engine (Ivee) For Immersive Analytics, Sofia Karam

Theses and Dissertations

Due to increasing data complexity, researchers are struggling to visually explore data using traditional methods. Research has shown that a variety of analytics-related tasks can be enhanced using new emerging technologies (e.g., virtual reality [VR] and augmented reality [AR]). This paper provides a detailed design approach for developing an immersive virtual engine system for conducting exploratory and descriptive data analytics. This system is called the Immersive Virtual Exploratory Engine (IVEE), is a VR system that allows users to experience full intractability with its graphical elements and examines various datasets within the same immersive environment. Basic plots—such as histograms, line plots, …

Detecting Malware In Memory With Memory Object Relationships, Demarcus M. Thomas Sr.

Theses and Dissertations

Malware is a growing concern that not only affects large businesses but the basic consumer as well. As a result, there is a need to develop tools that can identify the malicious activities of malware authors. A useful technique to achieve this is memory forensics. Memory forensics is the study of volatile data and its structures in Random Access Memory (RAM). It can be utilized to pinpoint what actions have occurred on a computer system.

This dissertation utilizes memory forensics to extract relationships between objects and supervised machine learning as a novel method for identifying malicious processes in a system …

Verification Of Acoustic Dissipation In Two-Phase Dilute Dispersed Flow Models In Computational Fluid Dynamics, Brennan Reeder

Theses and Dissertations

With existing numerical models for fluid particle systems in CHEM, the acoustic-particle interactions associated with two-phase dilute dispersed flow can be captured and the particle model can be validated using experimental and analytical data and verified using numerical techniques. The experimental and analytical data come from Zink and Delsasso and provides data for particles of diameters 5 to 15 microns for frequencies between 500Hz to 13600Hz. In the particle number density measurements by Zink and Delsasso there was a 10% estimated error range. Using the fourth order skew symmetric flux in CHEM and the built in Eulerian and Lagrangian particle …

Impacts Of Sea-Level Rise On Urban Properties In Tampa Due To Climate Change, Weiwei Xie

Theses and Dissertations

The fast urbanization produces a large and growing population in coastal areas. However, the rise of sea level, one of the most significant impacts of global warming, makes coastal communities much more vulnerable to flooding than before. This Master’s thesis study investigates sea-level rise impacts on parcel-level property in the specific coastal city of Tampa, Florida, USA. An improved sea-level rise model based on satellite altimeter data is first used to predict future sea levels. Based on high-resolution LiDAR digital elevation data and property map, flooded properties are identified to evaluate property damage cost. This empirical analysis provides an in-depth …

Using Social Media As A Communication Tool: A Study Of Ministries Of Sport And Sport For Development And Peace Organizations In Sub-Saharan Africa, Kelsey Slater

Theses and Dissertations

This study expanded on the previous research surrounding the Facebook and Twitter use of non-governmental sport for development and peace (SDP) organizations as well governmental Ministries of Sport. Following the theoretical framework of Lovejoy and Saxton (2012) this research examined specifically how non-governmental and governmental sport organizations share information, form a community and encourage action with their social media audiences. A content analysis of 6003 social media posts demonstrated that both Ministries of Sport and SDP non-governmental organizations (NGOs) primarily use social media to disseminate information to their followers, however, SDP NGOs were more likely to use social media posts …

Predictive Computational Materials Modeling With Machine Learning: Creating The Next Generation Of Atomistic Potential Using Neural Networks, Mashroor Shafat Nitol

Theses and Dissertations

Machine learning techniques using artificial neural networks (ANNs) have proven to be effective tools to rapidly mimic first principles calculations. These tools are capable of sub meV/atom accuracy while operating with linear scaling with respect to the system size. Here novel interatomic potentials are constructed based on the rapid artificial neural network (RANN) formalism. This approach generates precise force fields for various metals that have historically been difficult to describe at the atomic scale. These force fields can be utilized in molecular dynamics simulations to provide new physical insights. The RANN formalism, which is incorporated into a LAMMPS molecular dynamics …

Mixing Temperature, Binder Content, And Dust Content Effects On Stone Matrix Asphalt, Abhinash Subedi

Theses and Dissertations

This study focuses on the effects of mixing temperature, binder content, and dust content on the performance of Stone Matrix Asphalt (SMA). Mixes produced at different mixing temperatures and with or without added polymer modified binder (P_b) and/or bag house dust (BHD) were evaluated. Two different types of specimens: laboratory mixed laboratory compacted, and plant mixed laboratory compacted were evaluated by Cantabro Mass Loss (CML) testing in an unaged condition or after a laboratory conditioning protocol (CP) was applied. Additional P_b and BHD were added to plant produced mixes in the laboratory before mixing. Results showed that …

Using A Systemic Skills Model To Build An Effective 21st Century Workforce: Factors That Impact The Ability To Navigate Complex Systems, Morteza Nagahi

Theses and Dissertations

The growth of technology and the proliferation of information made modern complex systems more fragile and vulnerable. As a result, competitive advantage is no longer achieved exclusively through strategic planning but by developing an influential cadre of technical people who can efficiently manage and navigate modern complex systems. The dissertation aims to provide educators, practitioners, and organizations with a model that helps to measure individuals’ systems thinking skills, complex problem solving, personality traits, and the impacting demographic factors such as managerial and work experience, current occupation type, organizational ownership structure, and education level. The intent is to study how these …

School Transportation Protocol And Procedures Related To Students’ Safety And Discipline: Reflective Experiences Of School Bus Drivers And School Administrators, David Luke

Theses and Dissertations

This dissertation deals with the protocol and procedures related to students’ safety and discipline while on a school bus as experienced by school bus drivers’ and school administrators’ experiences as a guide for changes to the existing programs. The following was the overarching research question that guided the study: How do school bus drivers and school administrators describe their reflective experiences related to bus driver training and protocol and procedures associated with student safety and discipline?

A qualitative research design was selected for the study. A case study approach was used to collect and analyze data for the study.

Participants …

Description Of The Conjunctival Microbiome Of Normal Non-Brachycephalic Dogs And The Effects Of Antiseptic Preparation, Lindsay Seyer

Theses and Dissertations

Surgical preparation reduces commensal bacterial load. Currently, no standardized preoperative ocular preparation method in the dog has been reported. Previous studies use culture-based methods to determine commensal bacterial populations. Recent reports suggest that high-throughput sequencing may be superior to culture techniques to determine bacterial communities in the eye and other tissues. The goal of this study was to describe the conjunctival commensal ocular microbiome and bacterial community using DNA sequencing and aerobic cultures of six normal, healthy dogs and investigate the short and long-term effects of an antiseptic protocol on the ocular microbiome. Samples were obtained prior to, immediately following, …

Torque Vectoring To Maximize Straight-Line Efficiency In An All-Electric Vehicle With Independent Rear Motor Control, William Blake Brown

Theses and Dissertations

BEVs are a critical pathway towards achieving energy independence and meeting greenhouse and pollutant gas reduction goals in the current and future transportation sector [1]. Automotive manufacturers are increasingly investing in the refinement of electric vehicles as they are becoming an increasingly popular response to the global need for reduced transportation emissions. Therefore, there is a desire to extract the most fuel economy from a vehicle as possible. Some areas that manufacturers spend much effort on include minimizing the vehicle’s mass, body drag coefficient, and drag within the powertrain. When these values are defined or unchangeable, interest is driven to …

Macronutrient Intake: A Multi-Sport Study Of Female Division I Collegiate Athletes, Ffion Price

Theses and Dissertations

Background: Macronutrients play a critical role within collegiate athletes’ performance and health, with carbohydrates providing most of the energy needs for most athletes. There is little research examining the macronutrient intake of healthy collegiate female athletes across sports. The aim of the present study was to compare macronutrient intakes of female collegiate athletes within different sports and compare their intakes to recommendations. Methods: An observational study was conducted to determine whether a sample of female collegiate athletes (n=26) consumed the IOC nutritional recommendations. Sports included within the study were soccer, basketball, volleyball, and cross-country. Athletes were asked to complete a …

A Data-Driven Approach For The Investigation Of Microstructural Effects On The Effective Piezoelectric Responses Of Additively Manufactured Triply Periodic Bi-Continuous Piezocomposite, Wenhua Yang

Theses and Dissertations

A two-scale model consisting of ceramic grain scale and composite scale are developed to systematically evaluate the effects of microstructures (e.g., residual pores, grain size, texture) and geometry on the piezoelectric responses of the polarized triply periodic bi-continuous (TPC) piezocomposites. These TPC piezocomposites were fabricated by a recently developed additive manufacturing (AM) process named suspension-enclosing projection-stereolithography (SEPS) under different process conditions. In the model, the Fourier spectral iterative perturbation method (FSIPM) and the finite element method will be adopted for the calculation at the grain and composite scale, respectively. On the grain scale, a DL approach based on stacked generative …

Synthesis And Characterization Of A Ccc-Nhc Manganese Complex And Its Catalytic Activity In Alpha-Alkylation Reactions Of Ketones Using Alcohols – Acceptorless Dehydrogenative Coupling Reaction, Thi Bao Tran Nguyen

Theses and Dissertations

N-heterocyclic carbenes are essential for the synthesis and stabilization of various metal complexes due to the tendency to act as sigma-donor of sp2 hybridized lone pair in carbene into sigma-accepting orbital of metals. Meanwhile, the electronic and steric properties of pincer complexes can be fine-tuned by modifying three sites bonded to the metals. Utilizing advantages of both NHCs and the pincer structures, NHCs-based pincer complexes have become increasingly developed in recent years. After the discovery of zirconium and rhodium complexes with CCC-NHC backbones reported in 2005, Hollis’s group has been interested in applying the CCC-NHC pincer precursor for other transition …