Digital Commons Network^™

Adherence To A Gluten-Free Diet And Depression, And Nutrient Distribution In Participants With Celiac Disease, Mohammad K. Shushari

Theses and Dissertations

Celiac disease (CD), an autoimmune disorder affecting millions of Americans, poses significant obstacles leading to a normal life. With no known cure, adherence to a strict glutenfree diet (GFD) is essential. However, the cost and limited availability of gluten-free alternatives can burden individuals with CD. Additionally, factors such as socioeconomic status, nutrient deficiencies, and the nature of the disease may contribute to mental health issues. This study aimed to investigate the influence of adherence to a GFD on depression in CD patients. The prevalence of depression among individuals with CD from diverse backgrounds was examined, along with the analysis of …

Soil Health As Influenced By The Integration Of Cover Crops And Poultry Litter In North-Central Mississippi, Nikitha Reddy Kovvuri

Theses and Dissertations

Soil health-based agricultural management practices are widely promoted to improve soil structure, infiltration and reduce erosion. This study was conducted at two locations in North-Central Mississippi to evaluate the influence of different cover crop species and poultry litter on soil health that can impact crop production, climate change, and resilience. The results indicated that the cover crops showed a little effect on some soil health indicators compared to control treatment. However, in one location, rye, and a mixture of cover crops decreased bulk density and increased available water content and organic matter. The poultry litter had a positive effect on …

The Cosolvent And Association Effect On Polymer Behaviors, Xiangyu Zhang

Theses and Dissertations

The blending or mixing is extensively utilized in diverse processes of polymers to bring about advantageous properties, but the behavior becomes intriguing when associations are involved and multi-solvents are used. Explanations based on chemistry-specific arguments are less than satisfactory in abstracting essential features, and lack the general applicability across various systems. So, this work focuses on capturing the physical force governing the phenomenon of interest by using a generic model. Highly non-trivial behaviors of polymers are often observed in multi-solvent solutions. It is known that polymers swell and dissolve in good solvents, while they tend to collapse and aggregate in …

Transition Metal-Catalyzed Functionalization Of Carbon-Hydrogen Bonds In Alkenes, Xiaolin Qian

Theses and Dissertations

Alkenes can undergo a variety of chemical reactions to form more complex molecules with a range of functional groups. This makes them useful starting materials for synthesizing a wide range of organic compounds. Chapter I provided an overview of the development history of alkenyl C−H bond activation. The early reactions of C−H compounds with metal complexes, as well as stoichiometric activation of the transition metal-activated C–H bond, were discussed. Then the first successful and efficient organometallic-catalyzed transformations of a C−H bond, the first transition metal-catalyzed vinylic C–H functionalization, and the first transition metal-catalyzed olefinic C–H functionalization under mild conditions were …

Exponential Runge–Kutta Time Integration For Pdes, Trky Alhsmy

Theses and Dissertations

This dissertation focuses on the development of adaptive time-stepping and high-order parallel stages exponential Runge–Kutta methods for discretizing stiff partial differential equations (PDEs). The design of exponential Runge–Kutta methods relies heavily on the existing stiff order conditions available in the literature, primarily up to order 5. It is well-known that constructing higher-order efficient methods that strictly satisfy all the stiff order conditions is challenging. Typically, methods up to order 5 have been derived by relaxing one or more order conditions, depending on the desired accuracy level. Our approach will be based on a comprehensive investigation of these conditions. We will …

Effectiveness Of Intervention Studies Based On Diet And/Or Physical Activity In Treatment, Prevention, And Management Of Diabetes Among South Asians: A Systematic Review, Ishaan Arora

Theses and Dissertations

The purpose of this study was to describe diet and/or physical activity-based interventions and their control in cardiometabolic risk factors of diabetes for the South Asian (SA) population. A systematic review was conducted in accordance with the PRISMA guidelines. Seventeen randomized control trials meeting the inclusion criteria were included for analysis. Interventions with type-2 diabetic SA showed significant improvements in HbA1c% (4/5 studies), fasting blood glucose (3/4 studies), and postprandial glucose (2/2 studies). Interventions with at-risk/prediabetic and non-diabetic SA showed a modest change in overall outcomes, with significant change reported for post-prandial insulin (3/4 studies), BMI and weight (2/4 studies), …

Assessing The Effectiveness Of Agricultural Extension Advice On Household Food Consumption And Food Security Outcomes In Malawi, Mphatso Chinsinga

Theses and Dissertations

My study examined the influence of agricultural extension advice on household food consumption and food security outcomes in Malawi. I utilized a pooled cross-sectional dataset from the Malawi Integrated Household Survey (IHS) and Integrated Household Panel Survey (IHPS) conducted in 2010, 2013, 2016, and 2019. To identify the effects, multivariate linear and logistic regression models were employed, considering various factors and incorporating fixed effects for survey wave, district, and data collection month. My findings revealed heterogeneity in the impacts of agricultural extension advice on food consumption and food security outcomes. Specifically, the results showed a positive correlation between agricultural extension …

Direct Measurement Of The 114cd(N, Gamma)115cd Cross Section In The 1 Ev To 300 Kev Energy Range, Kofi Tutu Addo Assumin-Gyimah

Theses and Dissertations

The large thermal cross section of cadmium makes it ideal for many practical applications where screening of thermal neutrons is desired. For example, in non-destructive assay techniques, or for astrophysical studies of the s-process. All such applications require precise knowledge of the neutron-capture cross section on cadmium. Although there are some data on neutron-capture cross sections particularly at thermal energies and at energies relevant for astrophysics, there is very little data at most other energies. Further, the evaluated cross sections from the ENDF and JENDL databases disagree at high energies. Therefore, there is a critical need for precise knowledge of …

Effects Of Adding Graphene-Based Nano Materials On Cure Time And Bond Strength Of Adhesives, Bradia T. Henfield

Theses and Dissertations

This research took place in 3 stages. In the first stage, lignin graphene (LG) was synthesized using a catalytic thermal conversion process. In stage 2, the time and temperature correlations for polyvinyl acetate (PVAc) and phenol resorcinol formaldehyde (PRF) adhesives were found and PRF showed stronger correlation when doped with carbon nanomaterials. Stage 3 evaluated the effect of the nanomaterials on radio frequency (RF) heating time and adhesive strength. It was found that all versions of the PRF adhesive resulted in higher shear strength values when cured in room temperature for 24 hours or in an oven at 170 °F …

Advancing Poultry Nutrition Through Statistical Strategies To Reduce Experimental Variation And Novel Protease Enzyme Research, Caleb Morgan Marshall

Theses and Dissertations

Increasingly, nutritionists are challenged to optimize broiler genetic capacity, while considering varying ingredient qualities and pricing, to meet production goals and profitability. Due to scale and cost, university and private research is often used by nutritionists to help make these decisions; thus, requiring these facilities to detect small, incremental improvements. In Chapters 1 and 2, processing data from several nutrition research trials were utilized to evaluate the impact of processing personnel, sample size, and unit of analysis on the detection of dietary differences. By accounting for potential variability between personnel (as a covariant) and selecting an adequate sample size for …

Using Dynamic Task Allocation To Evaluate Driving Performance, Situation Awareness, And Cognitive Load At Different Levels Of Partial Autonomy, Viraj R. Patel

Theses and Dissertations

The state of the art of autonomous vehicles requires operators to remain vigilant while performing secondary tasks. The goal of this research was to investigate how dynamically allocated secondary tasks affected driving performance, cognitive load, and situation awareness. Secondary tasks were presented at rates based on the autonomy level present and whether the autonomous system was engaged. A rapid secondary task rate was also presented for two short periods regardless of whether autonomy was engaged. There was a three-minute familiarization phase followed by a data collection phase where participants responded to secondary tasks while preventing the vehicle from colliding into …

Utilizing Soil Quality Data For Premium Rate Making In The Federal Crop Insurance Program, Rylan Moore

Theses and Dissertations

The federal crop insurance program provides crop insurance for millions of acres and many commodities every year. The Risk Management Agency of the USDA is responsible for determining the premium rates for these covered commodities. Currently, the quality of soil is not considered when determining baseline yields and expected premium rates. This study utilizes the moment-based maximum entropy method to assess the effect of incorporating soil in the rate making methodology. Several moments of upland cotton yield in Arkansas, Mississippi, and Texas are conditioned on weather, irrigation, and soil control variables. Ultimately, I find evidence of mispriced premium rates for …

Ruggedness Test Of A New Standardized Test Method For Abrasion Resistance Of E-Textiles, Erin Parker

Theses and Dissertations

Standard test methods provide product developers with information regarding materials' suitability for different purposes. Typically, current standards are suitable for determining the mechanical properties of new materials. However, in the case of electronic textiles (E-Textiles) and wearable technology (wearables), adding conductive components with added functionality makes utilizing textile standards difficult, and these standards will not provide information on mechanical and electrical properties of conductive elements. New standards for E-Textile and wearables testing are needed to ensure product developers can obtain the information necessary to make informed decisions about new products. Standards organizations such as the American Society for Testing and …

Re(Engineering) Student Success: Constructing Knowledge On Students’ Experiences In Engineering Education Programs To Encourage Holistic Student Success, Shaylin Williams

Theses and Dissertations

If a group of engineering deans were asked whether students at their institutions were successful and why, what information might they immediately or subconsciously use to measure or gauge the engineering students’ success? If only academic performance outcomes like GPA, individual course grades, or graduation rate race to their minds, then their rationale aligns with the majority of researchers. My research seeks to shift the mindset that frames engineering student success mainly within the boundaries of academic performance measures. By measuring students’ perceived autonomy, competence, social integration and relatedness within their programs, and aspirations after graduation, one can more accurately …

Assessment Of Light Weight Deflectometer For Low Volume Roads Experiencing Rapidly Increased Traffic Levels, Margarita Ordaz

Theses and Dissertations

When evaluating low volume roads (LVRs), structural capacity emphasis is minimal since deterioration typically results from environmental factors. However, in cases where LVR’s experience rapidly increased traffic loading, structural condition becomes important. The research objective was to determine whether the Light Weight Deflectometer (LWD) can be used as a structural evaluation tool for LVRs in the aforementioned conditions. This study explored the capability of LWD equipment in evaluating major factors that influence flexible pavement structural capacity: load induced deterioration, soil moisture, and asphalt temperature. Falling Weight Deflectometer (FWD) and LWD tests were performed to measure pavement structural condition. LWD was …

A New Saturation-Based Framework For Compaction Quality Control, Kevin Clark Miller

Theses and Dissertations

Field compaction control is arguably the most common yet critical quality control procedure in geotechnical engineering. Since the early 1930s, the systematic process for performing quality control of compacted soils has often been performed by measuring the in-place dry unit weight (or density) and as-compacted soil moisture content after placement in a fill. However, the current practice overlooks several facts resulting from comparing soil prepared and compacted in the laboratory to soils placed and compacted in the field. These issues include comparing the compaction energy in the lab versus what is applied in the field, and the behavior of saturated …

Development Of Hydrophobic Paper And Wood Products Via Metal Ion Modification, Oshani Nayanathara Rathnayaka Mudiyanselage

Theses and Dissertations

Renewable lignocellulosic materials are promising green plastic alternatives to fossil fuel-based plastics. However, the hydrophilic nature and poor water resistance of lignocellulosic materials have hindered their practical applications. This study reports a facile metal-ion-modification (MIM) route, swelling with aqueous metal ion solutions, and drying to convert conventional hydrophilic paper and wood pulp into biodegradable hydrophobic paper and tableware without the addition of hydrophobic sizing chemicals/materials. Metal ions such as Fe3+ and Zr4+ can coordinate with pulp fibers’ polar groups (i.e., O.H., C=O, and COOH) that induce self-assembly of their surface fibrillated “hairy” cellulose nanofibrils to form a more compact structure …

Determining Student Attentiveness By Use Of Heart Rate Measurement Using A Wearable Device, Erik Rhodes Brown

Theses and Dissertations

Distraction from personal technology is a widely recognized problem in the modern classroom. Further, instructors have limited abilities to determine when students are waxing or waning in attentiveness. This evaluative experiment leverages the Apple Watch’s heart rate sensors to capture signs of attentiveness in participants simulating remote university lectures of differing interest levels as determined by YouTube commenters. Once captured, the heart rate data separated and analyzed to determine the effect of the lecture treatment on the participants’ heart rates. Twenty-seven students from Mississippi State University’s Electrical and Computer Engineering and Computer Science and Engineering departments elected to participate in …

Assessing Drivers Of Overwintering Survival And Annual Range Shifts By The Redbanded Stink Bug, Piezodorus Guildinii (Westwood), Thomas Gustavus Paul

Theses and Dissertations

The redbanded stink bug, Piezodorus guildinii (Westwood) (Hemiptera: Pentatomidae), is a non-native pest of soybeans in the Americas outside of the Carribean. Mortality of overwintering adults due to cold exposure has been implicated as a major driver of interannual fluctuations in the occurrence of P. guildinii in the southeastern United States, but formal investigations of drivers, including factors other than cold temperatures, are rare. We conducted overwintering assays with field-collected P. guildinii to quantify survival and coupled historical occurrence with climatic data to develop a species distribution model. We found that leaf litter provides substantial insulation from lethal temperatures and …

Changes In Paleobiodiversity Across The K-Pg Boundary In Oktibbeha County, Mississippi, Joshua Broussard

Theses and Dissertations

Evidence of the Cretaceous-Paleogene (K-Pg) extinction can be seen across the Mississippi Embayment, however research examining the K-Pg boundary in the state of Mississippi is lacking. The objective of this study addresses how macrofauna changed across the K-Pg boundary in Oktibbeha County, Mississippi and subsequent comparison to other Early Paleogene and Late Cretaceous benthic marine macrofaunal localities. Comparison included previously collected material as well as specimens collected during this study in order to reconstruct the biological community living on the seafloor in the earliest Paleocene Mississippi Embayment. The primary fauna present after the K-Pg extinction was mainly composed of small …

Designing Bioinspired Materials With Tunable Structures And Properties From Natural And Synthetic Polymers, Anandavalli Varadarajan

Theses and Dissertations

Biological systems are composed of complex materials which are responsible for performing various functions, such as providing structural support, mobility, functional adaptation to the environment, damage repair, and self-healing. These complex materials display excellent mechanical properties and can rapidly adapt to external stimuli. Thus, nature inspires in terms of source materials, functions, and designs to develop new-generation structural and functional materials. Polymers (natural or synthetic) are excellent sources of developing materials to mimic the functions of soft segments in biological systems. This dissertation focuses on synthesizing and characterizing two different materials with tunable structures and properties: complexes from natural polysaccharides …

Applying Push-Pull-Mooring Model To Investigate Non-Malicious Workarounds Behavior, Nawaf Rasheed Aljohani

Theses and Dissertations

More than half of the violations of information systems security policies are initiated by non-malicious activities of insiders. To investigate these non-malicious activities, we utilized the theory of workaround and argued that the application of neutralization techniques impacts the use of workarounds. We built our model using three theories: the theory of workaround, push-pull-mooring theory, and techniques of neutralization. We identified the elements of workarounds related to non-malicious violations and proposed a theoretical perspective using the push-pull-mooring theory to investigate non-malicious workarounds empirically. We propose that non-malicious activities of insiders can be seen as a switching behavior, with push factors …

Heat And Mass Transfer Modeling Of High-Temperature Moving-Bed Thermochemical Reactors, David Korba

Theses and Dissertations

With the global deployment of renewable energy generation at record rates, clean energy is steadily becoming competitive with its fossil-fuel counterparts. However, further expansion is limited by the inherent intermittency of renewable energy sources (solar, wind, wave, etc.), which typically do not match with daily and seasonal variations of global (and local) energy demand. Thermochemical energy storage (TCES) has demonstrated strong potential in being a technological pathway to provide on-demand process heat and handle the intrinsic variations in renewable energy generation and energy demand. TCES works on the premise of excess renewable heat driving an endothermic reduction reaction, in which …

Development Of Preservative-Treated Cross-Laminated Timber And Lignin-Reinforced Polyurethane-Adhesive For Glued Laminated Timber, Samuel Oluwafemi Ayanleye

Theses and Dissertations

Interest in the use of mass timber in building and construction is growing worldwide, this is due to the structural integrity and reduced environmental footprint of timber-based structures. Concerns associated with the biological and environmental degradation of mass timber necessitate the development of adequate protection strategies to ensure the durability of these products. Preservative treatment is a proven technique that increases the durability and performance of wood in-service and can also be applied to large-sized timber panels such as cross-laminated timber (CLT). Therefore, this study focused on investigating the feasibility of treating prefabricated 3- and 5-layer CLT panels with Copper-azole …

Ide-Based Learning Analytics For Assessing Introductory Programming Skill, Phyllis J. Beck

Theses and Dissertations

Providing a sufficient level of personalized feedback on students' current level of strategic knowledge within the context of the natural programming environment through IDE-based learning analytics would transform learning outcomes for introductory programming students. However, providing sufficient insight into the programming process was previously inaccessible due to the need for more complex and scalable data collection methods and metrics with a wider variety for understanding programming metacognition and the full programming process.

This research developed a custom-built web-based IDE and event compression system to investigate two of the five components of a five-dimensional model of cognition for programming skill estimation …

Self-Referential Processing And Depression: A Systematic Review And Meta-Analysis, Amanda Collins

Theses and Dissertations

Cognitive theories of depression, including Beck’s Cognitive Theory, suggest that depressed individuals hold negative schemas about themselves and their environment. These negative schemas may influence the extent to which depressed individuals process positivity. Reward Devaluation Theory posits that depressed individuals avoid and devalue positivity. This suggests that depressed individuals may be less likely to hold positive schemas, or may be more likely to associate positivity with negativity. Previous meta-analytic reviews suggest that this is potentially the case, but have not assessed for self-referential stimuli. Self-referential encoding and recall tasks assess for self-schemas and may give further insight into how depressed …

Fabrication And Imaging Of Highly Ordered Plasmonic Au Nano-Prism And Self-Assembled Supramolecular Nanostructure, Ridwan Tobi Ayinla

Theses and Dissertations

The precise control of the resonance frequency of plasmonic nanostructures is critical and depends on the size, composition, shape, and dielectric nature of the environment. The ability to control the shape and size of nanomaterials acutely depends on the fabrication technique and material design. We used a cheap and scalable method known as nanosphere lithography (NSL) to fabricate plasmonic nano-prism (NP) on glass and indium tin oxide substrate (ITO). The methods involve substrate hydrophilicity treatment, polystyrene nanosphere masking, metal deposition, and mask removal. The array and specific morphology of the fabricated NP was established using scanning electron microscope (SEM) and …

Vaccination And Immune Response Of Channel Catfish (Ictalurus Punctatus) Against Virulent Aeromonas Hydrophila, Basant Mahmoud Ali Gomaa

Theses and Dissertations

Virulent Aeromonas hydrophila (vAh) is a causative agent of motile Aeromonas septicemia (MAS) in catfish. There are limitations in the current therapeutic and preventative strategies against vAh. The pathogenesis of MAS as well as the immune response of catfish to vAh infection are poorly understood. The aim of this study is to: 1) develop a dual live attenuated vaccine against MAS and enteric septicemia of catfish caused by Edwardsiella ictaluri; and 2) evaluate the vAh bacterial load and gene expression patterns in catfish tissues following vAh infection. Previously, six recombinant vAh …

Investigating Specialty Crop Farmers’ Preferences For Contract Design And Attitudes Towards Blockchain-Based Smart Contracts, Esther Mmenaa Agyemang-Duah

Theses and Dissertations

This study examines small and medium scale specialty crop growers’ preferences for marketing contract attributes and willingness to adopt blockchain-based smart contracts. The data used were collected using an online survey and discrete choice experiment. Findings indicate that farmers prefer higher average prices, cash, check or electronic bank payment over cryptocurrency, and immediate payment upon product delivery over delayed payment. When choosing a contract, farmers viewed traditional text-based contracts and digital platforms with automated smart contracts equivalently, on average. On average, farmers showed no preference for providing and not providing traceability lot codes to buyers, and between choosing a contract …

Improved Stoichiometric Synthesis Of Ccc-Nhc Pincer Rh Complexes And Catalytic Activity Towards Dehydrogenative Silylation And Hydrosilylation Of Alkenes, Enock Amoateng

Theses and Dissertations

N-Heterocyclic carbenes (NHCs) have attracted growing interest not only as successful ancillary ligands in a wide variety of transition-metal-catalyzed reactions but have also shown to offer photophysical and electrochemical properties. The metalation/transmetalation strategy using [Zr(NMe₂)₄] as initial metalating reagent offers an efficient approach to the preparation of CCC-NHC pincer complexes of the late transition metals such as Rh and Ir. In the process of investigating an intermediate and the mechanism of the metalation/transmetalation to Rh sequence, a mixed valent bimetallic CCC-NHC pincer Rh complex with two chloro ligands bridged between a [(CCC-NHC)Rh(III)] and a [Rh(I)(COD)] fragment …