Digital Commons Network^™

Framework Design For Weight-Average Molecular Weight Control In Semi-Batch Polymerization, S. D. Salas, N. Ghadipasha, W. Zhu, T. Mcafee, T. Zekoski, W. F. Reed, J. A. Romagnoli

Faculty Publications

A framework that embraces a state-of-the-art sensor, multi-objective dynamic optimization, nonlinear state estimation and control, is designed and implemented to achieve target weight-average molecular weight trajectories. The Automatic Continuous Online Monitoring of Polymerization reactions (ACOMP) is combined for the first time with a nonlinear state observer for full polymer characterization and signal processing. A hybrid variation of the discrete-time extended Kalman filter (h-DEKF) is formulated based on an auto-tuning procedure that uses a stochastic global optimization technique. A number of optimal policies are generated and experimentally tested. Results are provided through investigations into the free-radical aqueous polymerization of acrylamide using …

Implications Of Fault Structure Heterogeneities, Dissolution And Capillary Trapping Mechanisms For Co2 Storage Integrity, Muhammad Zulqarnain, Mehdi Zeidouni, Richard G. Hughes

Faculty Publications

Estimation of faults leakage potential is an essential component of CO2 storage integrity analysis. The selection of deep saline aquifers for CO2 storage in these settings mandates the modeling of fault-related fluid flow to estimate the most probable leakage rates. Faults usually have complex structures with heterogeneities and anisotropies over a range of scales because of which local capillary trapping becomes significantly important. We quantitatively investigate the implications of local capillary trapping for storage integrity and monitoring. Reservoir simulation results for a representative normal fault in a potential storage site in southern Louisiana with three possible damage zone configurations of …

Impacts Of Updated Design Rainfall Values On Louisiana Infrastructure, Mario Durbic

LSU Master's Theses

The Louisiana Department of Transportation and Development (LADOTD) has a Hydraulics Manual which sets forth drainage design standards and codes for projects. The Manual contains maximum annual 24-hour rainfall maps and Intensity-Duration-Frequency (IDF) curves for the return periods of 2, 5, 10, 25, 50, and 100 years. The Manual divides Louisiana into three regions and specifies that all of the cities within a given region should use the same estimated rainfall intensities and rainfall depths. NOAA Atlas 14, the Precipitation-Frequency Atlas of United States, contains the latest rainfall data and statistics for much of the United States and provides the …

Near-Infrared Photothermal Release Of Sirna From The Surface Of Colloidal Gold-Silver-Gold Core-Shell-Shell Nanoparticles Studied With Second-Harmonic Generation, Raju R. Kumal, Mohammad Abu-Laban, Prakash Hamal, Blake Kruger, Holden T. Smith, Daniel J. Hayes, Louis H. Haber

Faculty Publications

© 2018 American Chemical Society. Photothermal release of oligonucleotides from the surface of plasmonic nanoparticles represents a promising platform for spatiotemporal controlled drug delivery. Here we demonstrate the use of novel gold-silver-gold core-shell-shell (CSS) nanoparticles to study the photothermal cleaving and release of micro-RNA (miRNA) mimics or small interfering RNA (siRNA) under near-infrared (NIR) irradiation. The furan-maleimide-based Diels-Alder adduct cleaves thermally above 60 °C and is used to bind siRNA to the colloidal nanoparticle surface in water. We investigate the photothermal cleaving kinetics of siRNA under different NIR laser powers using surface-sensitive time-dependent second-harmonic generation (SHG) spectroscopy. The photothermal release …

Genetic Analysis Of Yield And Agronomic Traits Under Reproductive-Stage Drought Stress In Rice Using A High-Resolution Linkage Map, Uttam Bhattarai, Prasanta K. Subudhi

Faculty Publications

Drought stress at the reproductive stage of rice crop leads to a huge loss in grain yield. Identification and introgression of large effect drought tolerant QTLs are necessary to develop drought-tolerant rice varieties. Compared to the high-density linkage maps, widely spaced markers lead to the identification of QTLs with large confidence intervals which are difficult to incorporate in a breeding program. A previously generated genotyping-by-sequencing (GBS) based linkage map consisting of 4748 SNP markers was used to map QTLs in Cocodrie × N-22 recombinant inbred line (RIL) population. Twenty-one QTLs were discovered for days to flowering (DTF), plant height (PH), …

Evaluation Of Undrained Shear Strength And Soil Classification From Cone Penetration Test, Md Imran Hossain

LSU Master's Theses

The in-situ cone and piezocone penetration tests (CPT, PCPT) has been widely used by the geotechnical engineering community for subsurface soil characterization and classification, and for the evaluation of many engineering soil properties, such as undrained shear strength (s_u), unit weight (γ), constrained modulus (M), coefficient of consolidation (c_v), and stress history (OCR). The objective of this research study was to estimate the undrained shear strength of clayey soil using CPT/PCPT data in addition to some soil boring log data. At the same time, soil classification charts/methods based …

Development Of Long-Term Aging Factor For Asphalt Mixtures’ Cracking Resistance, Yucheng Shi

LSU Master's Theses

To characterize the cracking resistance of asphalt mixtures, semi-circular bend (SCB) test has been developed and subsequently accepted as a routine test in mixture design in Louisiana. However, SCB test requires specimens to be aged for five days in laboratory, which makes it not implementable in quality control (QC)/quality assurance (QA).

The primary project objective was to develop an aging factor to transfer the unaged SCB Jc to the aged SCB Jc. Specific objectives were to: (1) investigate the effect of laboratory aging on asphalt mixtures’ cracking resistance and asphalt binders’ rheological and chemical properties, (2) develop an aging …

Bio-Based Polyurethane Foams Made From Microwave Liquefaction Of Biomass, Xingyan Huang

LSU Doctoral Dissertations

Polyurethane (PU) foam is one of the most versatile construction insulations due to its low density, low thermal conductivity, and high mechanical performance. However, it is still highly dependent on petro-based chemicals, i.e. polyol and isocyanate. In this work, biomass, such as rape straw, switchgrass, and yaupon holly (Ilex vomitoria) were liquefied using microwave energy to produce bio-based polyol in order to substitute petro-based polyol in the production of PU foam. Cellulose nanocrystals (CNCs) were also extracted from liquefaction solid residue. They were then applied to reinforce high bio-content PU foam. Moreover, lignin was fractionated from bio-polyol by …

Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain

LSU Doctoral Dissertations

In this study we investigate displacement mechanism for oil recovered using Gas- Assisted Gravity Drainage (GAGD) method. For a typical oil recovery under gravity drainage, the recovery profile can be characterized by an initial bulk flow which occurs rapidly and a later film flow that extends for a longer duration. It is the latter period where film spreading, the ability of oil to spread above water in the presence of gas, is identified as the displacement mechanism responsible for recovering the remaining oil in gravity drainage process. Literature survey indicates that mathematical models for gravity drainage do not account for …

Integrating Climate Forecasts With The Soil And Water Assessment Tool (Swat) For High-Resolution Hydrologic Simulations And Forecasts In The Southeastern U.S., Vinit Sehgal, Venkataramana Sridhar, Luke Juran, Jactone Arogo Ogejo

Faculty Publications

This study provides high-resolution modeling of daily water budget components at Hydrologic Unit Code (HUC)-12 resolution for 50 watersheds of the South Atlantic Gulf (SAG) region in the southeastern U.S. (SEUS) by implementing the Soil and Water Assessment Tool (SWAT) model in the form of a near real-time, semi-automated framework. A near real-time hydrologic simulation framework is implemented with a lead time of nine months (March-December 2017) by integrating the calibrated SWAT model with National Centers for Environmental Prediction coupled forecast system model version 2 (CFSv2) weather data to forecast daily water balance components. The modeling exercise is conducted as …

The (B)Link Between Amotivation And Dopamine In Psychosis: What Phasic Eye Blink Rate Reveals, Jessica Elaina Mcgovern

LSU Doctoral Dissertations

Motivation deficits (i.e., avolition or amotivation) are a cardinal feature of schizophrenia spectrum disorders (SSDs) and are linked to worse functional outcomes. Accumulating evidence implicates underactive dopamine responses in reward areas of the brain (e.g., striatum) in the etiology of amotivation. Phasic dopamine firing in the striatum purportedly has a role in increasing the perceived value of a potential reward that, in effect, helps “push” the organism toward initiating and persisting in the action to pursue rewards. Previous research has suggested that eye blink rate (EBR) may be a reliable and valid index of striatal dopamine. Amotivation (clinician-rated and self-reported) …

Similarities And Differences In Western Media Portrayals Of The Greek Economic Crisis: A Qualitative Analysis Of The Guardian And The New York Times' Summer 2015 Coverage Of The Greek Economic Crisis, Tryfon Boukouvidis

LSU Master's Theses

This study examines newspaper coverage of the Greek economic crisis in the summer of 2015 by exploring attribution of responsibility to the actors involved in the crisis. I performed a qualitative content analysis on 114 news stories, 59 from The Guardian and 55 from The New York Times. Prior literature has indicated that American newspapers tend to present economic crisis from an elite perspective, which could distort public opinion to reflect elite views. Following previous studies, I analyzed the news stories in terms of how they used the responsibility frame of coverage of the Greeks and their creditors. The …

Coupled Thermo Mechanical Modeling Of Friction Stir Welding And Fatigue Life Improvement Of Friction Stir Welding Structures, Saad Bin Aziz

LSU Doctoral Dissertations

Friction- stir- welding (FSW) is comparatively a new welding process invented by The Welding Institute in 1991. Since no melting or fusion occurs during the welding process, FSW is free of high heat input and solidification defects. Two main objectives have been set forth in this work. The first object of this thesis is to develop thermomechanical models based on experimental knowledge and understanding the FSW process at a fundamental level. The quality of friction-stir-welding (FSW) joints depends on many critical weld process parameters. The main challenge for the FSW is in the selection of these critical process parameters that …

High-Dimensional Isotope Relationships, Yuyang He

LSU Doctoral Dissertations

High-dimensional isotope relationships describes the relationships of two or more element or position-specific (PS) elements in the same molecule or ion. It provides us more powerful tools to study reaction mechanisms and dynamics. Chapter 1 is about dual or multiple stable isotope relationship on δ-δ (or δ'-δ') space. While temporal data sampled from a closed-system can be treated by a Rayleigh Distillation Model (RDM), spatial data should be treated by a Reaction-Transport Model (RTM). Here we compare the results of a closed-system RDM to a RTM for systems with diffusional mass transfer by simulating the trajectories on nitrate's δ'^{18 …}

Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain

LSU Doctoral Dissertations

In this study we investigate displacement mechanism for oil recovered using Gas- Assisted Gravity Drainage (GAGD) method. For a typical oil recovery under gravity drainage, the recovery profile can be characterized by an initial bulk flow which occurs rapidly and a later film flow that extends for a longer duration. It is the latter period where film spreading, the ability of oil to spread above water in the presence of gas, is identified as the displacement mechanism responsible for recovering the remaining oil in gravity drainage process. Literature survey indicates that mathematical models for gravity drainage do not account for …

The Effect Of The Nematode Trapping Fungus Duddingtonia Flagrans Against Gastronintestinal Nematodes Of Exotic Ruminant Hoofstock At Disney's(R) Animal Kingdom Lodge, Kristen Renee Young

LSU Master's Theses

Gastrointestinal nematodes (GIN) can severely affect the performance of ruminant animals and may lead to an animal’s death in a severe, untreated infection. Zoological parks, which have used anthelmintic drugs for treatment of GIN, are now seeing evidence of drug resistant parasites (Garretson et al., 2009). Duddingtonia flagrans, a nematophagous fungus, has shown a reduction in larvae of coprocultures of exotic ruminants through feed administration at Disney's^® Animal Kingdom Lodge (DAKL) and has potential to biologically control forage larvae (Terry, 2013). This study evaluated the effectiveness of Duddingtonia flagrans, administered to exotic ruminant hoofstock at a daily …

A Study On Reduction Of Harmonic Distortion Caused By Ac Arc Furnaces, Venkata Mani Gadiraju

LSU Master's Theses

In AC arc furnaces, arc ignition is stabilized by inductors which are connected across its supply lines. They cause power factor degradation in the system. When furnaces are modelled as linear RL load, the arc nonlinearity reduces the impact of this degradation to a significant extent. Furnace Power factor is improved by the DC voltage on the arc. In this research study, power factor of AC furnaces is estimated on the assumption that DC voltage on the arc is constant and furnace operates in steady state. Primary objective of this research was to determine the power factor of the furnace …

Development Of Self-Healing Mechanisms For Asphalt Pavements, Max Abelardo Aguirre Deras

LSU Doctoral Dissertations

Self-healing mechanisms, such as microcapsules or hollow-fibers, filled with an asphalt rejuvenator present an emerging technology that would enhance an asphalt mixture’s resistance to cracking damage caused by vehicular and environmental loading. The objectives of this study were to: (a) Evaluate the effects of asphalt rejuvenators on hot-mix asphalt mixtures in order to test its effects on the fundamental engineering properties of the mixtures at high and intermediate temperatures; (b) Develop a synthesis procedure for production of microcapsules and hollow-fibers containing an asphalt rejuvenator; (c) Evaluate the self-healing efficiency of double-walled microcapsules and hollow-fibers filled with an asphalt rejuvenator, through …

Modeling The Influence Of Eutrophication And Redox Conditions On Mercury Cycling At The Sediment-Water Interface In The Berre Lagoon, Svetlana Pakhomova, Evgeniy Yakushev, Elizaveta Protsenko, Sylvain Rigaud, Daniel Cossa, Joel Knoery, Raoul Marie Couture, Olivier Radakovitch, Shamil Yakubov, Dominika Krzeminska, Alice Newton

Faculty Publications

© 2018 Pakhomova, Yakushev, Protsenko, Rigaud, Cossa, Knoery, Couture, Radakovitch, Yakubov, Krzeminska and Newton. This study presents a specifically designed Mercury module in a coupled benthic-pelagic reactive-transport model - Bottom RedOx Model (BROM) that allows to study mercury (Hg) biogeochemistry under different conditions. This module considers the transformation of elemental mercury (Hg(0)), divalent mercury (Hg(II)) and methylmercury (MeHg). The behavior of mercury species in the model is interconnected with changes of oxygen, hydrogen sulfide, iron oxides, organic matter, and biota. We simulated the transformation and transport of Hg species in the water column and upper sediment layer under five different …

The Effects Of Juvenile Exposure To Sub-Lethal Concentrations Of Pesticides On The Adult Reproductive Biology Of The Male Southern House Mosquitoe, Culex Quinquefasciatus, Shiloh Dean Judd

LSU Master's Theses

Mosquitoes transmit pathogens capable of causing significant diseases, the worst of which can permanently disfigure or kill. Mosquito control efforts can be strengthened by better understanding all aspects of mosquito biology, but there is deficient information regarding sperm production in male mosquitoes. Understanding the sperm production and capacity of vector species may reveal new control strategies.

The goal of this research was to determine if larval exposure to sub-lethal concentrations, defined as killing less than half of the sample population, of pesticides negatively impacts the adult male reproductive health of the southern house mosquito, Culex quinquefasciatus Say. This study quantified …

Identification Of Quantitative Trait Loci (Qtl) For Tolerance To Metribuzin In Soft Red Winter Wheat (Triticum Aestivum L.), Hugo Alfonso Anzueto Ponciano

LSU Master's Theses

Wheat is one of the world’s most important food crops and provides nearly 20% of the calories consumed. Wheat is the third most important crop after corn and rice on a global production scale. In Louisiana wheat harvest was about 6000 hectares in 2017. Wheat production is negatively affected by several biotic and abiotic factors including weather, diseases, and weeds. Metribuzin is a broad-spectrum herbicide commonly used in wheat because it is inexpensive and controls most of the common weeds in wheat fields. Metribuzin has benefits for the grower controlling weeds that might cause yield loss in varieties or lines …

Development Strategies For A Fractured, Heavy Oil Reservoir - Results From Numerical Simulations, German Albertovich Abzaletdinov

LSU Master's Theses

This research is focused on studying reservoir “N” in the Yarega heavy oilfield (YHOF) for development strategies and production optimization. YHOF is a naturally fractured heavy oil field where only very recently SAGD technology has been introduced. The motivation for this research is derived from the fact that SAGD employed in this field has so far resulted in early steam breakthrough leading to producer abandonment and new drilling, thus increasing costs. This study explores numerically different static and dynamic reservoir characterization models (single porosity versus dual porosity systems), and subsequent pressure-production history matched reservoir simulation for understanding heat and mass …

Evaluation Of Site Variability And Its Application In Design, Abu Hakim Muhammad Hasan Faisal

LSU Master's Theses

Geotechnical characterization has an important role in engineering geology as well as in implementation of any project. There are several variables and uncertainties involved in characterizing a project site. Four different sources of uncertainties represent the characterization of geotechnical variability, which include spatial variability, measurement error, statistical error and model bias. Spatial variability is expressed in terms of the mean, variance, and scale of fluctuation. Several statistical techniques such as the Gauge R & R, which includes X-Bar/R and ANOVA, and the Second Moment can be applied to compute site variability in terms of the coefficient of variations. Measurement error …

Direct Quantification Of Deubiquitinating Enzyme Activity In Single Intact Cells, Nora Safabakhsh

LSU Doctoral Dissertations

Challenges in drug efficacy occur during the treatment of most types of cancer due to the heterogeneity of the tumor microenvironment. This has led to the development of personalized medicine. Due to the clinical success of the proteasome inhibitors Bortezomib and Carfilzomib in treatment of multiple myeloma, interest has shifted towards molecularly-targeted chemotherapeutics for ubiquitin-proteasome system (UPS). Deubiquitinating enzymes (DUBs) are an essential part of this pathway which have been found to promote Bortezomib resistance in multiple myeloma patients. Unfortunately, there is a lack of specific, high throughput biochemical assays to characterize DUB activity in patient samples before and after …

Fermi Gbm Observations Of Grb 150101b: A Second Nearby Event With A Short Hard Spike And A Soft Tail, E. Burns, P. Veres, V. Connaughton, J. Racusin, M. S. Briggs, N. Christensen, A. Goldstein, R. Hamburg, D. Kocevski, J. Mcenery, E. Bissaldi, T. Dal Canton, W. H. Cleveland, M. H. Gibby, C. M. Hui, A. Von Kienlin, B. Mailyan, W. S. Paciesas, O. J. Roberts, K. Siellez, M. Stanbro, C. A. Wilson-Hodge

Faculty Publications

In light of the joint multimessenger detection of a binary neutron star merger as the gamma-ray burst GRB 170817A and in gravitational waves as GW170817, we reanalyze the Fermi Gamma-ray Burst Monitor data of one of the closest short gamma-ray bursts (SGRBs): GRB 150101B. We find that this burst is composed of a short hard spike followed by a comparatively long soft tail. This apparent two-component nature is phenomenologically similar to that of GRB 170817A. While GRB 170817A was distinct from the previously known population of SGRBs in terms of its prompt intrinsic energetics, GRB 150101B is not. Despite these …

Search For Gev Gamma-Ray Counterparts Of Gravitational Wave Events By Calet, O. Adriani, Y. Akaike, K. Asano, Y. Asaoka, M. G. Bagliesi, E. Berti, G. Bigongiari, W. R. Binns, S. Bonechi, M. Bongi, P. Brogi, J. H. Buckley, N. Cannady, G. Castellini, C. Checchia, M. L. Cherry, G. Collazuol, V. Di Felice, K. Ebisawa, H. Fuke, T. G. Guzik, T. Hams, M. Hareyama, N. Hasebe, K. Hibino, M. Ichimura, K. Ioka, W. Ishizaki, M. H. Israel, K. Kasahara, J. Kataoka, R. Kataoka, Y. Katayose

Faculty Publications

We present the results of searches for gamma-ray counterparts of the LIGO/Virgo gravitational wave events using CALorimetric Electron Telescope (CALET) observations. The main instrument of CALET, CALorimeter (CAL), observes gamma-rays from ∼1 GeV up to 10 TeV with a field of view (FOV) of nearly 2 sr. In addition, the CALET gamma-ray burst monitor views ∼3 sr and ∼2π sr of the sky in the 7 keV-1 MeV and the 40 keV-20 MeV bands, respectively, by using two different crystal scintillators. The CALET observations on the International Space Station started in 2015 October, and here we report analyses of events …

Fiscal Reform Scenarios And Accessibility To Food In Guatemala, Guillermo R. Fernandez

LSU Master's Theses

Since signing the peace accords in 1996, the Guatemalan government committed to increase the tax burden of 1995 by 50% to a total of 13%. This target has only been reached 4 times in more than two decades. There have been multiple attempts at tax reforms that have failed or been incomplete. Guatemala exhibits much income inequality and is one of the poorest countries in the region.

Given this background, the problem to be considered in this analysis is that there is little information regarding how different tax reforms would affect the accessibility to food in Guatemala. With information regarding …

Baldcypress And Black Willow Growth Response To Contrasting Flood Regimes, Climate, And Competition, In The Atchafalaya Basin, Louisiana, Alicia Louise Mcalhaney

LSU Master's Theses

Wetlands are dynamic ecosystems distinguished by their dependence on fluctuations of hydrologic influence. Although it is generally accepted that that flooding is a strong influence on growth, and that effects vary depending on whether water is stagnant or flowing, several aspects of flood characteristics and several tree species remain poorly investigated. One source of variability that has not been investigated is how flooding, climate, and competition among trees interact to control growth of individual trees. The objective of this study was therefore to 1) investigate effects of temporally varying hydrology and climate on growth of baldcypress and black willow trees …

The Effect Of Rest Period On Fatigue Using Electromyography During Manual Lifting, Nandakumar Prabhakar

LSU Master's Theses

Manual materials handing (MMH) is the main cause and concern for injuries in the working population which lead to musculoskeletal disorders (MSDs). MSDs significantly contribute to the cost of workers’ compensation and loss of productivity, thus impacting economy of the United States. MSDs are mainly caused due to over exertion and fatigue experienced by workers involved in manual materials handling. In addition to over-exertion and fatigue, lack of short and frequent rest intervals between tasks contributes to the risk of MSDs. The objective of this research was to study the effect of rest period on muscle fatigue using electromyography (EMG) …

Optimized Quantum F-Divergences, Mark M. Wilde

Faculty Publications

The quantum relative entropy is a measure of the distinguishability of two quantum states, and it is a unifying concept in quantum information theory: many information measures such as entropy, conditional entropy, mutual information, and entanglement measures can be realized from it. As such, there has been broad interest in generalizing the notion to further understand its most basic properties, one of which is the data processing inequality. The quantum f-divergence of Petz is one generalization of the quantum relative entropy, and it also leads to other relative entropies, such as the Petz-Renyi relative entropies. In this contribution, I introduce …