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The Kauffman Bracket Skein Module Of The Quaternionic Manifold, John Michael Harris

LSU Doctoral Dissertations

In this work, we study the structure of the Kauffman bracket skein module of the quaternionic manifold over the field of rational functions. We begin with a brief survey of manifolds whose Kauffman bracket skein modules are known, and proceed in Chapter 2 by recalling the facts from Temperley-Lieb recoupling theory that we use in the proofs. In Chapter 3, using recoupling theory and with Mathematica's assistance, we index an infinite presentation of the skein module, and conjecture that it is five-dimensional. In Chapter 4, using a new set of relations, we prove that the skein module is indeed spanned …

Wood Laminated Composite Poles, Cheng Piao

LSU Doctoral Dissertations

Wood composite poles are new engineered products with polygonal shapes and bonded with synthetic resins. The poles have multiple advantages over the solid wood poles and are a promising solid pole substitute in power transmission, telecommunication, and cable TV services. The use of composite poles may reduce the cost both in materials and manipulation, and facilitate installation and treatment. It is necessary to evaluate the factors that affect their properties and construct theoretical and analytical models to analyze these properties. Experiments were conducted to investigate strip thickness and number of strips’ (NOS) effects on the flexural properties and shear stress …

Toward A Global Microscopic Theory For Nuclear Structure: Mean Field Plus Random Phase Approximation Vs. Shell Model, Ionel Stetcu

LSU Doctoral Dissertations

Our understanding of nuclear structure is built upon mean-field theories such as Hartree-Fock and time-dependent Hartree-Fock. The small-amplitude limit of the latter is the random phase approximation (RPA), which is widely used to model giant resonances in nuclei. Despite this popularity, RPA has been mostly validated against toy models; tests against complex models are scarce in the literature. We perform a thorough test of the RPA against full 0hw shell model (SM) calculations, including in our investigation binding energies, scalar ground-state observables, for which we develop a new method, and transition strengths. We allow deformed Hartree-Fock solutions and compare results …

Progressive Fatigue Effects On Manual Lifting Factors, Anthony D'Wayne Banks

LSU Doctoral Dissertations

Much evidence suggests that the cause of lower back pain (LBP) and injury is frequently related to the posture of lifting, the load, muscle fatigue, and other factors. The purpose of this study was to evaluate the effect of progressive fatigue on factors that have previously been associated with increased risk of LBP in various occupational settings, during a repetitive lifting task where freestyle lifting technique was utilized. A laboratory experiment was conducted to evaluate several fatigue analysis, electromyography amplitude, kinematic, and kinetic parameters of repetitive freestyle lifting during a 2-hour lifting period. Each of ten (10) young adult male …

Parallel Molecular Dynamics Simulations Of Dynamics Of Oxidation And Reactive Wetting In Metal/Ceramic Systems, Gurcan Aral

LSU Doctoral Dissertations

Oxidation of a flat aluminum (111) surface and the reactive wetting of the aluminum (Al) droplet on a flat alumina (α-Al₂O₃) surface are investigated by using parallel molecular-dynamics simulations with dynamic charge transfer among atoms on a microscopic length scale. The interatomic potential, based on the formalism of Streitz and Mintmire, allows atoms to vary their charges dynamically between anions and cations, when atoms move and their local environment is altered. We investigate the oxidation thickness as a function of time and the oxygen density which is 10-40 times that of the normal state (1 atm …

Translating "Hebrew" Into "Greek": The Discursive Hermeneutics Of Emmanuel Levinas's Talmudic Readings, Matthew Wayne Guy

LSU Doctoral Dissertations

This dissertation examines Emmanuel Levinas’s Talmudic readings and the hermeneutics employed to translate the Talmud into modern language. Levinas claims to be translating “Hebrew” into “Greek” by rendering into a universal, philosophical language (“Greek”) the ethical structure of subjectivity (“Hebrew”) within the Talmud. Since they investigate the structure of subjectivity, extensive use of his philosophical works and the influential works of others are used to analyze his Talmudic readings. Chapter One places Levinas’s project against the background of the Talmud, Judaic tradition, and projects like Rudolf Bultmann’s New Testament readings and Thorleif Boman’s comparative study of Greek and Hebrew. A …

Language, Identity And The Achievement Gap: Comparing Experiences Of African-American Students In A French Immersion And A Regular Education Context, Michelle Georgette Haj-Broussard

LSU Doctoral Dissertations

The Black/White Achievement gap has been a persistent problem in education. Previous research attributed this gap to students' culture (Jenks & Phillips, 1998; Ogbu, 1995a.b) or teachers' expectancy (Rist, 1970). Post-colonial literature suggests that this research itself is oppressive, and that learning is negotiating the "spaces" between students and teachers (Ellsworth, 1997); creating a hybrid "mestiza" space (Anzaldúa, 1987). The openness of immersion to diversity, and its subsequent educational benefits for African-American students (Caldas & Boudreaux, 1999) conforms to this post-colonial perspective. This mixed-methodology study examined both academic achievement and the experiences of Louisiana fourth grade students/teachers in both the …

Dynamic Modeling And Parameter Estimation For An Ethlyene-Propylene-Diene Polymerization Process, Rujun Li

LSU Doctoral Dissertations

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A general dynamic model for continuous EPDM polymerization in which crosslinking and gel formation are attributable to reactions between pendant double bonds has been developed. A pseudo-kinetic rate constant method is introduced to construct a moment model for a pseudo-homopolymer that approximates the behavior of the actual terpolymer under long chain and quasi-steady state assumptions. The pseudo-homopolymer model is then used as the basis for application of the numerical fractionation method. The proposed dynamic model is capable of predicting polydispersities and molecular weight distributions near the gel point with as few as eleven generations, and in the …

Biomechanical Reconstruction Of The Appendicular Skeleton In Three North American Jurassic Sauropods, Ray Wilhite

LSU Doctoral Dissertations

Forelimb and hindlimb articulation, reconstructed musculature, and function were examined in Apatosaurus, Diplodocus, and Camarasaurus. A technique was developed using a Microscribe three-dimensional digitizer to capture external morphological data for skeletal reconstruction and determination of taxonomically useful features. The appendicular musculature of Alligator mississippiensis was dissected to determine form, function, origin, and insertion of muscles to aid in reconstruction of sauropod musculature. Contrary to the literature, M. caudofemoralis longus was found to originate primarily from the lateral surfaces of the proximal chevrons instead of the bodies and transverse processes of the caudals, demonstrating that chevron morphology is indicative of the …

Molecular-Dynamics Simulations Of Self-Assembled Monolayers (Sam) On Parallel Computers, Satyavani Vemparala

LSU Doctoral Dissertations

The purpose of this dissertation is to investigate the properties of self-assembled monolayers, particularly alkanethiols and Poly (ethylene glycol) terminated alkanethiols. These simulations are based on realistic interatomic potentials and require scalable and portable multiresolution algorithms implemented on parallel computers. Large-scale molecular dynamics simulations of self-assembled alkanethiol monolayer systems have been carried out using an all-atom model involving a million atoms to investigate their structural properties as a function of temperature, lattice spacing and molecular chain-length. Results show that the alkanethiol chains tilt from the surface normal by a collective angle of 25o along next-nearest neighbor direction at 300K. At …

A Comparison Of Life Histories And Ecological Aspects Among Snappers (Pisces: Lutjanidae), Fernando Martinez-Andrade

LSU Doctoral Dissertations

An extensive search for data on life-history and ecological variables was conducted for a representative number of the species within the family Lutjanidae. After creating different databases and standardizing all data, these variables were examined in statistical, correlation and graphic analyses. Additionally, a series of Principal Component Analyses were used to examine patterns among variables. Life-history variables included age at length zero, asymptotic length, maximum length, longevity, asymptotic weight, length at maturity, age at maturity, reproductive life span, growth rate and mortality rate. Ecological variables included latitudinal and vertical distribution, habitat selection (represented by substrate type), and spawning seasons. The …

Where Have All The Flowers Gone?: A Modular Systems Perspective Of It Infrastructure Design And Productivity, Pratim Datta

LSU Doctoral Dissertations

Assessing value of IT infrastructure investments has been both difficult and ambiguous. This research develops and tests a conceptual framework to understand the productivity process. A lagged and recursive framework is used to trace the relationship between IT infrastructure investments, infrastructure design, and organizational productivity along with contingencies of IT management and the environment. A major contribution of this study is the use of the systems perspective to disaggregate the concepts of IT infrastructure and productivity into collectively exhaustive types. Findings reveal that IT investments do not significant affect productivity but do so when used to develop an IT infrastructure …

Analytical Study On Flood Induced Seepage Under River Levees, Senda Ozkan

LSU Doctoral Dissertations

A common and potentially dangerous phenomenon associated with flooding is seepage under levees and the formation of sand boils. Seepage flow due to hydrostatic head gradients of floods may cause deformation of pervious layers leading to heave, piping and sand boils. Underseepage may also cause irreversible changes in the characteristics of the porous medium. A series of independent flood events may have cumulative effects on pervious layers causing sand boils to grow. Current underseepage analyses for levees are based on steady-state flow. Transient seepage flow due to rapid changes in river head may contribute to cumulative effects and cause critical …

The Transcendental Eigenvalue Problem And Its Application In System Identification, Kumar Vikram Singh

LSU Doctoral Dissertations

An accurate mathematical model is needed to solve direct and inverse problems related to engineering analysis and design. Inverse problems of identifying the physical parameters of a non-uniform continuous system based on the spectral data are still unsolved. Traditional methods, for the system identification purpose, describe the continuous structure by a certain discrete model. In dynamic analysis, finite element or finite difference approximation methods are frequently used and they lead to an algebraic eigenvalue problem. The characteristic equation associated with the algebraic eigenvalue problem is a polynomial. Whereas, the spectral characteristic of a continuous system is represented by certain transcendental …

Design And Synthesis Of Constrained Dipeptide Units For Use As Β-Sheet Promoters, Umut Oguz

LSU Doctoral Dissertations

The study of factors promoting beta-sheet formation has recently gained interest due to the suspected involvement of beta-sheets in brain degenerative diseases such as Alzheimer's disease (AD), Creutzfeldt-Jacob disease (CJD) and bovine spongiform encephalopathy. Understanding beta-sheet formation and the factors that stabilize beta-sheet structure may serve as a basis for future drug design. The extended structure of a beta-sheet can be stabilized by constrained amino acid analogs that are pre-organized to adopt the extended conformation. In this dissertation using innovative synthetic organic chemistry methods, two dipeptide units are designed and synthesized that are constrained to form the extended conformation and …

Rotary Kiln Incineration Of Hazardous Wastes: Pilot-Scale Studies At Louisiana State University, John Sutherland Earle

LSU Doctoral Dissertations

Studies of incineration of surrogates for hazardous wastes are conducted in the pilot-scale rotary kiln incinerator (RKI) at Louisiana State University (LSU) in Baton Rouge, Louisiana. The purpose of the research is to investigate methods of treating and destroying hazardous wastes in a cost-effective and environmentally sound way. The objective is to provide process data that will contribute to increased knowledge for RKI design and operation. The LSU facility is a College of Engineering Combustion Laboratory that is unique in its large size as a university laboratory. It is equipped with individual instruments for analysis of O₂, CO, …

The Impact Of Louisiana's School And District Accountability System On Students' Performance On The State Mandated Criterion Referenced Test, Linda B. Tolbert

LSU Doctoral Dissertations

This study is aimed at determining the impact of Louisiana’s School and District Accountability System on students’ performance on the state mandated criterion-referenced test (LEAP 21). The study was designed to determine the extent to which teachers in Title I schools in a large urban district in southwest Louisiana have turned to instructionally unsound practices in response to a high-stakes accountability system. The specific objectives addressed in this study were to: 1) Explore if test scores have changed beyond what would be expected given the cohort design of the accountability model. 2) Explore if test scores have changed and determine …

Design And Synthesis Of Handles For Solid-Phase Peptide Synthesis And Convergent Peptide Synthesis, Jose Giraldes

LSU Doctoral Dissertations

The recent popularity of methods for solid-phase peptide synthesis that use the 9-fluorenylmethyloxycarbonyl (Fmoc) group for N^α-amino protection has created a need for compatible anchoring linkages and handles. In an effort to develop mild new methods for use in solid-phase peptide synthesis (SPPS), a new ferrocene containing linker or “handle”, the 1’1-ferrocenyl carboxaldehyde handle was designed, synthesized, characterized and tested. This linker is analogous to those commercially available and developed by Barany. The ferrocenyl amine linker(FAL) releases C-terminal peptide amides upon acidolysis. Since the FAL handle is acid labile it is compatible with Fmoc and N^α-dithiasuccinoyl …

Characterization Of Native And Bypass Human Coronary Artery Plaque Deposits From The Same Heart: Investigation Of The Chemical Form Of Calcium In Human Coronary Artery Plaque Deposits, Serigne Thiam

LSU Doctoral Dissertations

Gradual deposits of lipids, proteins, and calcium on the coronary arterial walls cause atherosclerosis, leading to blockage of the blood flow and possible heart attack. Despite many studies, the mechanism underlying these processes remains unclear. In this research, differences between native and bypass plaque deposits from the same heart were examined. In addition, the crystalline and the amorphous plaques within these native and bypass vessels were characterized. The techniques used to characterize the deposits included inductively coupled plasma mass spectrometry (ICPMS), solid-state nuclear magnetic resonance (NMR), high performance liquid chromatography (HPLC), etc. The results from the ICPMS technique showed that …

Synchrotron Radiation As A Probe Of Chemical Information Using Novel Experimental Configurations, George Farquar

LSU Doctoral Dissertations

Determination of chemical information with synchrotron radiation is an area of great scientific interest, and expanding the range of available techniques is the topic of this dissertation. The experimental methods described herein allows for a significant advancement of the availability of subtle chemical information. This dissertation uses ionizing radiation to study three chemical systems. First, the l=3 shape resonance in CO is investigated using a cryogenically cooled gas jet. Shape resonant effects have been studied for many years. Previously, this was accomplished on the vibrational structure of molecules with a limited ability to determine the rotational substructure effects. A dramatic …

Uncovering Strata: An Investigation Into The Graphic Innovations Of Geologist Henry T. De La Beche, Renee M. Clary

LSU Doctoral Dissertations

An historical investigation into the types of illustrations in the Golden Age of Geology (1788-1840) revealed the nature and progression of graphic representation at the dawning of geology as a science. Exhaustive sampling of geology texts published in the period of focus proceeded until saturation was achieved. Qualitative analysis and evaluation of early illustrations were accomplished with Edward R. Tufte's theory of graphic design. Hypothesis testing around a correlation coefficient revealed significance at the 99% confidence level for relationships between publication year and number of included graphics, and publication year and the graphic density of texts. Henry T. De la …

Atomic And Electronic Structure Of Bulk Intermetallic And Heteroepitaxially Grown Surface Alloys, Orhan Kizilkaya

LSU Doctoral Dissertations

It has been well documented that the surfaces of solids may differ from their bulk counterpart. The symmetry that a bulk possesses is broken at the surface. Due to this broken symmetry in the reduced dimension of the surface, the energetic of the surface also differs from the bulk counterpart. Reconstruction, charge redistribution, and surface alloying are phenomena that minimize the surface free energy. Surface properties of scientifically and technologically important bimetallic systems are the main focus of this dissertation. Specifically, surfaces of bulk alloy or heteroepitaxially grown metal-on-metal systems have been investigated primarily with two indispensable surface techniques, scanning …

Self-Efficacy, Motivation, And Outcome Expectation Correlates Of College Students' Intention Certainty, Carol Couvillion Landry

LSU Doctoral Dissertations

This study explored relationships between Self-Efficacy, Motivation, and Outcome Expectations and Intention Certainty. Intention Certainty is a new variable created for this study and comprised of existing conceptions of intention and decision certainty. The purpose of this study was fourfold. This study attempted to expand our understanding of the college retention dropout issue by exploring relationships between psychologically rich variables. Second, this study provided information considered useful for framing future research on retention from a different perspective that focuses on characteristics of individuals who stay, rather than those who leave higher education with the consideration of psychological constructs. Further, this …

Diffusion Of A Rodlike Virus In Complex Solutions, Randall Charles Cush

LSU Doctoral Dissertations

Entanglement phenomena in concentrated polymer solutions remain an interesting and challenging problem. It is still unclear how entanglement onset affects polymer chain motion at small distance scales. One way to study such motion is to follow the diffusion of a probe particle while increasing the concentration of the polymer. Many such studies have been done using probes ranging from linear and star polymers to various colloidal particles; however, relatively few studies have used rodlike probes. Rodlike probes are potentially more interesting due to the added information that may be gained by following rotational as well as translational diffusion. The anisotropic …

Design Of Optimal Equalizers And Precoders For Mimo Channels, Lijuan Li

LSU Doctoral Dissertations

Channel equalization has been extensively studied as a method of combating ISI and ICI for high speed MIMO data communication systems. This dissertation focuses on optimal channel equalization in the presence of non-white observation noises with unknown PSD but bounded power-norm. A worst-case approach to optimal design of channel equalizers leads to an equivalent optimal H-infinity filtering problem for the MIMO communication systems. An explicit design algorithm is derived which not only achieves the zero-forcing (ZF) condition, but also minimizes the RMS error between the transmitted symbols and the received symbols. The second part of this dissertation investigates the design …

Massively Parallel Molecular Dynamics Simulations Of Crack-Front Dynamics And Morphology In Amorphous Nanostructured Silica, Cindy Lynn Rountree

LSU Doctoral Dissertations

Atomistic aspects of dynamic fracture in amorphous and nanostructured silica are herein studied via Molecular dynamics (MD) simulations, ranging from a million to 113 million atom system. The MD simulations were performed on massivelly parallel computers using highly efficient multi-resolution algorithms. Crack propagation in these systems is accompanied by nucleation and growth of nanometer scale cavities up to 20 nm ahead of the crack front. Cavities coalesce and merge with the advancing crack to cause mechanical failure. Recent AFM studies in silica glasses confirm this scenario of fracture [1]. The morphology of the fracture surfaces is studied by calculating the …

The Extinction Properties Of Reddened Galactic Ob Sightlines, Lynne Angela Valencic

LSU Doctoral Dissertations

A solid understanding of dust grains and their extinction properties is needed to better remove the effects of extinction from data and to comprehend the nature of the processes which modify grains. This requires a large sample of Galactic sightlines, extending far beyond the solar neighborhood, sampling not only a large volume of space but also a wide variety of environments. To fulfill this requirement, a database of sightlines toward 426 young, reddened stars was constructed using extinction curves based on IUE spectra. The curves were fit and the Fitzpatrick-Massa (FM) parameters were found. FM parameters allow for a quantitative …

The Influence Of Selected Factors On Burnout Among Faculty In Higher Education, Ronald R. Rush

LSU Doctoral Dissertations

The purpose of this study was to explore demographic variables and job satisfaction and the relationship with burnout among higher education faculty. The sample included 248 tenured professors selected through simple random sampling techniques. A three-part instrument was used: the Maslach Burnout Inventory (MBI-ES), which measured levels of burnout based on subscales of Emotional Exhaustion, Depersonalization, and Personal Accomplishment; the Job Descriptive Index (JDI) and Job in General (JIG) scales, which indicated job satisfaction in areas of: Work on Present Job, Present Pay, Opportunities for Promotion, Supervision on Present Job, People in Present Job, and Job in General; and, a …

Block-Level Discrete Cosine Transform Coefficients For Autonomic Face Recognition, Willie L. Scott, Ii

LSU Doctoral Dissertations

This dissertation presents a novel method of autonomic face recognition based on the recently proposed biologically plausible network of networks (NoN) model of information processing. The NoN model is based on locally parallel and globally coordinated transformations. In the NoN architecture, the neurons or computational units form distributed networks, which themselves link to form larger networks. In the general case, an n-level hierarchy of nested distributed networks is constructed. This models the structures in the cerebral cortex described by Mountcastle and the architecture based on that proposed for information processing by Sutton. In the implementation proposed in the dissertation, the …

Electrodeposition Of Nickel-Copper Alloys And Nickel-Copper-Alumina Nanocomposites Into Deep Recesses For Mems, Amrit Panda

LSU Doctoral Dissertations

Electrodeposition is an important component in the fabrication of micro electro mechanical systems (MEMS). Nickel is the most commonly used material to produce three dimensional microstructures and few material alternatives have been demonstrated. In this dissertation, electrodeposited Ni-Cu alloys and nanocomposites are investigated as possible replacements for nickel in microsystems. Ni-Cu alloys are attractive for their corrosion resistance, magnetic and thermophysical properties. Alumina nanoparticulates included into metal matrices improve hardness and tribology of deposits. The Ni-Cu alloys and Ni-Cu-g-Al2O3 nanocomposites were electrodeposited from a citrate electrolyte, both at low and high pH. Electrodeposition experiments were performed in recessed microelectrodes 500 …