Digital Commons Network^™

The Modern Mississippi: Provenance Indicators And Human Impact, Brittney Anne Gregory

LSU Doctoral Dissertations

Given the significant degree to which the modern Mississippi River and its tributaries have been altered through dams, levees, and diversions, it is important to understand how sediment is transported from source to sink. The objective of this dissertation is to explore how the modern Mississippi River transports sediment from its tributaries to its delta using three independent proxies. Provenance indicators have traditionally been an effective way with which to characterize sediment transport in large river systems. First, detrital U-Pb zircon dating is used to investigate modern flux and possible anthropogenic influences on coarse-grained sediment within the modern Mississippi River. …

Cationic Cobalt (Ii) Hydroformylation, Drew Michael Hood

LSU Doctoral Dissertations

While investigating a bimetallic cobalt hydroformylation catalyst a new class of monometallic cationic cobalt (II) hydroformylation catalyst were discovered. These newly discovered catalyst proved to be very unique with high hydroformylation activity under mild conditions. The pre-catalyst were characterized using various methods including NMR, EPR, MS, and X-ray crystallography. Similarly the active catalyst was also investigated using NMR, EPR, FTIR, and X-ray crystallography. Various catalyst modifications were investigated for their effects on hydroformylation activity. Likewise various reaction parameters were probed to determine their effect on hydroformylation activity. Finally the best cationic cobalt (II) catalyst were directly compared to industry standards …

Aerodynamic Flutter And Buffeting Of Long-Span Bridges Under Wind Load, Shuqian Liu

LSU Doctoral Dissertations

With the continuous increase of span lengths, the aerodynamic characteristics of long-span bridges under external wind excitation have become much more complex and wind-induced vibration has always been a problem of great concern. The present research targets on the aerodynamic performance of long-span bridges under wind load with an emphasis on bridge flutter and buffeting.

For the aerodynamic flutter analysis of long-span bridges, the present research investigated the effects of the wind turbulence on flutter stability. The characterizations of the self-excited forces are presented in both the frequency-domain and in the time-domain, and the flutter analysis is conducted under both …

Optimization Of Quantum Optical Metrology Systems, Nicholas Michael Studer

LSU Doctoral Dissertations

It can be said that all of humanity's efforts can be understood as a problem of optimization. We each have a natural sense of what is ``good'' or ``bad'' and thus our actions tend towards maximizing -- or optimizing -- some notion of good and minimizing those things we perceive as bad or undesirable.

Within the sciences, the greatest form of good is knowledge. It is this pursuit of knowledge that leads to not only life-saving innovations and technology, but also to furthering our understanding of our natural world and driving our philosophical pursuits.

The principle method of obtaining knowledge …

Vulnerability Of Industrial Facilities In The Lower Mississippi River Industrial Corridor To Relative Sea Level Rise And Tropical Cyclone Storm Surge, Joseph Blake Harris

LSU Doctoral Dissertations

Relative sea level rise (RSLR) and tropical cyclone-induced storm surge are major threats to the Lower Mississippi River Industrial Corridor (LMRIC) which has approximately 120 industrial complexes located within the corridor. Spatial interpolation methods were applied to the 2004 National Oceanic and Atmospheric published Technical Report #50 subsidence dataset and cross-validation techniques were used to determine the accuracy of each method. Digital elevation models (DEMs) were created for the years 2025, 2050, and 2075, based on these predictive surface of subsidence rates. Future DEMs were utilized to model RSLR and determine the extent of storm surge on the LMRIC by …

Quantitative Evaluation Of A Lightweight Sediment For A Physical Model Of The Lower Mississippi River, Mauricio Hooper

LSU Doctoral Dissertations

The Lower Mississippi River Physical Model (LMRPM), housed at the LSU Center for River Studies on the Baton Rouge, LA Water Campus, is a distorted, movable bed model comprising the lower 195 miles of the Mississippi River from Donaldsonville through the Head of Passes into the Gulf of Mexico. Since the LMRPM was designed to replicate the hydraulics (i.e., flow and river stages) and bulk non-cohesive sediment transport, the model lightweight sediment must replicate both the incipient motion and two-dimensional dune characteristics (height and length). In addition, the model scale and distortion require that the sediment time scale be determined …

Essays On The Role Of Systematic And Idiosyncratic Volatility In Pricing Individual Equity Options, Mobina Shafaati

LSU Doctoral Dissertations

It is widely accepted that the value of an option is an increasing function of the underlying volatility. The positive relation between volatility and option price is intuitive only if we keep all other determinants of the option value constant, including the stock price. The notion that an asset price is completely unaffected by the volatility of the asset is virtually unacceptable in asset pricing theory and holds only in a stylized one-factor world in which the volatility change is completely diversifiable. In Chapter 1, I examine the role of the non-zero correlation of the underlying asset return and its …

Effective Geometric Modeling For Scientific Computing And Forensic Reconstruction, Celong Liu

LSU Doctoral Dissertations

Geometric modeling is a fundamental and critical problem for many computer graphic and computer vision problems. We usually want to build a parameterization which establishes a low-distortion one-to-one map between geometric data and canonical parametric domain, and it is a fundamental tool to support many visual data processing tasks such as mesh generation, finite element simulations, visual analytics, geometric reconstruction, etc. In this dissertation, I studied two problems. The first is to construct low- distortion canonical (polycube) parameterization of large-scale geometric regions, with which high-quality semi-structured quad meshes can be generated and used to facilitate more efficient scientific computing. The …

A Comprehensive Techno-Economic Framework For Shale Gas Exploitation And Distribution In The United States, Jorge Asis Charbel Chebeir

LSU Doctoral Dissertations

Over the past years, shale gas has turned into one of the most significant sources of energy in the United States. Technological advancements have provided the energy industry with the necessary tools to allow the economic exploitation of an enormous volume of natural gas trapped in shale formations. This has boosted the domestic gas production and generated a boom in other sectors of the economy in the country. However, major challenges are involved in the development of shale gas resources. A drastic decline of wells’ productivity, the costs involved in the gas production and distribution facets, and the volatile behavior …

Deltaic Wetland Dynamics From Seasonal To Centennial Scales, Giancarlo A. Restreppo

LSU Doctoral Dissertations

The lower plain of the Mississippi River Delta contains approximately five coastal sedimentary basins that are topographically defined, and one shelf-crossing depocenter (the Birds Foot Delta). These depositional systems receive varying quantities of sediment from fluvial and marine sources and have rates of coastal land loss that are roughly inversely proportional to fluvial sediment supply. To combat land loss along these regions, Louisiana has launched a historic campaign to sustain and regrow coastal lands using, in part, river sediment diversions. Fine sediments constitute the majority of sediment load in the Mississippi River, but are under-studied with respect to dispersal processes, …

From Rationality To Relationality: Teacher-Student Relationship As Unknowing, Shaofei Han

LSU Doctoral Dissertations

This dissertation reimagines the teacher-student relationship through a philosophical approach that draws on Laozi, Karen Barad, Deleuze & Guattari, and Emmanuel Levinas. The teacher-student relationship is normally considered a relationship of the knower (teacher) and the unknower (student) based on the modern western tradition of episteme. This dissertation interrogates the modern binary of the teacher/student, subject/object relationship by bringing ontology and ethics into educational discourse. The problematic practices of modern schooling include the reduction of teaching to knowledge transmission, and the rigid dichotomy of a subject/object relation between teacher and student. Following a Taoist Way of philosophical thinking, this work …

Can Assisted Reproductive Technologies Help Conserve 300 Million Years Of Evolution? A First Attempt At Developing These Technologies For Male Reptiles, Sean M. Perry

LSU Doctoral Dissertations

Biodiversity loss is the most critical environmental problem threatening ecosystem, animal, and human health today. Increases in extinction rates have been observed over the past 50 years, with reptile losses occurring twelve times faster than traditional extinction rates. This demonstrated biodiversity loss is secondary to climate change, habitat destruction, infectious disease, invasive species, poaching, and unsustainable trade. Approximately 20% of all reptiles are threatened with extinction and population declines are approaching rates similar to the current amphibian extinction crisis. Preventing the extinction of reptiles will require humans to acknowledge these losses and develop plans to preserve these evolutionary sentinel species. …

Determination Of Conversion Factors For Various Calibration Geometries Using Barium-133 In A Silver Zeolite Cartridge, Amin Hamideh

LSU Master's Theses

Iodine-131 (I-131) is a major fission product among other radionuclides released during a nuclear incident. This radioiodine has a half-life of 8.02 days and the primary organ of uptake through ingestion or inhalation is the thyroid gland. For these reasons, nuclear power plants must routinely monitor I-131 through air sampling. Currently, there are two adsorbing media to collect I-131: activated charcoal and silver zeolite cartridges. Silver zeolite cartridges are generally used during a post nuclear incident due to its affinity for iodine while not adsorbing noble gases such as krypton-85 and xenon-135. After an air sample is taken from a …

Investigating Cationic Metal Centers For Hydroformylation, Ryan Alexander Johnson

LSU Doctoral Dissertations

Bimetallic cooperativity can potentially increase activity of reactions. This concept is another way to increase reactivity besides simply focusing on the steric and electronic effects of a ligand. A binucleating tetrasphosphine ligand has been developed to showcase bimetallic cooperativity between two rhodium metal centers. Hydroformylation is a widely used industrial process to produce aldehydes from alkenes, H₂, and CO. The dirhodium catalyst, [Rh₂(μ-CO)(CO)₃(rac-et,ph-P4-Ph)](BF₄)₂,is highly active leading to favorable results when using a DMF/water solvent system, 1-hexene, 90 psi 1:1 H₂/CO, and 90° C: initial turnover frequency …

Entropic Energy-Time Uncertainty Relation, Patrick J. Coles, Vishal Katariya, Seth Lloyd, Iman Marvian, Mark M. Wilde

Faculty Publications

Energy-time uncertainty plays an important role in quantum foundations and technologies, and it was even discussed by the founders of quantum mechanics. However, standard approaches (e.g., Robertson's uncertainty relation) do not apply to energy-time uncertainty because, in general, there is no Hermitian operator associated with time. Following previous approaches, we quantify time uncertainty by how well one can read off the time from a quantum clock. We then use entropy to quantify the information-theoretic distinguishability of the various time states of the clock. Our main result is an entropic energy-time uncertainty relation for general time-independent Hamiltonians, stated for both the …

The Calorimetric Electron Telescope (Calet) On The International Space Station: Results From The First Two Years On Orbit, Y. Asaoka, O. Adriani, Y. Akaike, K. Asano, M. G. Bagliesi, E. Berti, G. Bigongiari, W. R. Binns, S. Bonechi, M. Bongi, A. Bruno, P. Brogi, J. H. Buckley, N. Cannady, G. Castellini, C. Checchia, M. L. Cherry, G. Collazuol, V. Di Felice, K. Ebisawa, H. Fuke, T. G. Guzik, T. Hams, N. Hasebe, K. Hibino, M. Ichimura, K. Ioka, W. Ishizaki, M. H. Israel, K. Kasahara, J. Kataoka, R. Kataoka, Y. Katayose

Faculty Publications

The CALorimetric Electron Telescope (CALET) is a high-energy astroparticle physics space experiment installed on the International Space Station (ISS), developed and operated by Japan in collaboration with Italy and the United States. The CALET mission goals include the investigation of possible nearby sources of high-energy electrons, of the details of galactic particle acceleration and propagation, and of potential signatures of dark matter. CALET measures the cosmic-ray electron+positron flux up to 20 TeV, gamma-rays up to 10 TeV, and nuclei with Z=1 to 40 up to 1, 000 TeV for the more abundant elements during a long-term observation aboard the ISS. …

Reflector Dip Trends In Seismic Sh-Wave Imaging Of A Modern Lower Mississippi River Point Bar, Adam Gostic

LSU Master's Theses

Various studies of ancient point bars have noted that a relationship can be observed between the dip angle and grain size of point bar lateral accretion deposits, with the most mud-rich deposits tending to exhibit the greatest dip. No analysis and only cursory explanations for this relationship have been provided. Additionally, buried mid-channel bars are absent from typical models of point bar architecture.

We successfully image the architecture of late-stage point bar deposits with a near surface 2D seismic SH-wave reflection survey and generate an SH-wave velocity model of the subsurface in the study area in order to interpret the …

Measurement Of The Average Shape Of Longitudinal Profiles Of Cosmic-Ray Air Showers At The Pierre Auger Observatory, A. Aab, P. Abreu, M. Aglietta, I. F.M. Albuquerque, J. M. Albury, I. Allekotte, A. Almela, J. Alvarez Castillo, J. Alvarez-Muñiz, G. A. Anastasi, L. Anchordoqui, B. Andrada, S. Andringa, C. Aramo, H. Asorey, P. Assis, G. Avila, A. M. Badescu, A. Bakalova, A. Balaceanu, F. Barbato, R. J.Barreira Luz, S. Baur, K. H. Becker, J. A. Bellido, C. Berat, M. E. Bertaina, X. Bertou, P. L. Biermann, J. Biteau, S. G. Blaess, A. Blanco, J. Blazek

Faculty Publications

The profile of the longitudinal development of showers produced by ultra-high energy cosmic rays carries information related to the interaction properties of the primary particles with atmospheric nuclei. In this work, we present the first measurement of the average shower profile in traversed atmospheric depth at the Pierre Auger Observatory. The shapes of profiles are well reproduced by the Gaisser-Hillas parametrization within the range studied, for E>10 17.8 eV . A detailed analysis of the systematic uncertainties is performed using ten years of data and a full detector simulation. The average shape is quantified using two variables related to …

Iron Mediated Organic Preservation In A River Influenced Continental Margin, Neha Ajit Ghaisas

LSU Doctoral Dissertations

Continental margins such as the Mississippi river influenced Louisiana shelf (MIS), are important land-ocean interfaces where excessive water column productivity and rapid burial results in large amounts of organic carbon (OC) being sequestered in the sediments. The preservation of OC in sediments is controlled by a number of processes among which mineral-OC interactions are considered to be more important. Specifically, the interactions between sediment iron (Fe) species and OC have been shown to promote carbon preservation. However, the exact nature of preservation mechanism is not well understood and is based on limited global data, which specifically lacks estimates from large …

Putting It All Together: Adding Value To The Global Ocean And Climate Observing Systems With Complete Self-Consistent Ocean State And Parameter Estimates, David Trossman

Faculty Publications

No abstract provided.

Evaluating Seasonal Nutrient Fluxes In Emerging And Eroding Wetlands Of The Louisiana Delta Plain, Kiran Upreti

LSU Doctoral Dissertations

Deltaic wetlands can ameliorate high NO₃^- loads via denitrification, a dominant NO₃^- reduction pathway in inland and coastal habitats. Dissimilatory Nitrate Reduction to Ammonia (DNRA), in contrast to denitrification, conserves N within the system and has been found to be favored over denitrification with increase in salinity and temperature. There are no studies in the Louisiana Deltaic plain with simultaneous estimation of denitrification and DNRA. Increased P availability has been shown to increase denitrification so it is essential to understand P biogeochemistry when studying N cycle. Here, we evaluated net denitrification using N₂:Ar and …

Phase Estimation In Linear And Nonlinear Interferometers, Sushovit Adhikari

LSU Doctoral Dissertations

Phase estimation has a wide range of applications. Over the years, several strategies have been studied to improve precision in phase estimation. These strategies include using exotic quantum states to quantum detection schemes. This dissertation summarizes my effort in improving the precision of phase estimation with a linear and nonlinear interferometer.

Chapter 1 introduces quantum optics and quantum metrology. I introduce all relevant quantum states of light used. We also look into tools and terminologies of quantum metrology such as Fisher information, shot-noise limit, Heisenberg limit, etc., along with examples of phase estimation with a Mach-Zehnder interferometer.

In Chapter 2, …

Multiplexed Paper Microfluidics For Titration And Detection Of Ingredients In Beverages, Manas Ranjan Gartia, Alisha Prasad

Faculty Publications

Food safety and access to systematic approaches for ensuring detection of food hazards is an important issue in most developing countries. With the arrival of paper-based analytical devices (mu PADs) as a promising, rapid, easy-to-use, and low-cost analytical tool, we demonstrated a simple microfluidic-based titration study for the analysis of packaged fruit juices. Similar, to the titration experiments using traditional glassware in chemistry laboratories, in this study the titration experiments were developed using paper microfluidics for the analysis of several analytes such as pH, vitamin C, sugars, and preservatives present in the packaged fruit juices. The allergen found commonly in …

On The Adjoint Markov Policies In Stochastic Differential Games, Nicolai V. Krylov

Communications on Stochastic Analysis

No abstract provided.

A Nonlocal Approach To The Quantum Kolmogorov Backward Equation And Links To Noncommutative Geometry, Will Hicks

Communications on Stochastic Analysis

No abstract provided.

Bioassay-Guided Isolation And Structure Elucidation Of Fungicidal And Herbicidal Compounds From Ambrosia Salsola (Asteraceae), Frank R. Fronczek

Faculty Publications

The discovery of potent natural and ecofriendly pesticides is one of the focuses of the agrochemical industry, and plant species are a source of many potentially active compounds. We describe the bioassay-guided isolation of antifungal and phytotoxic compounds from the ethyl acetate extract of Ambrosia salsola twigs and leaves. With this methodology, we isolated and identified twelve compounds (four chalcones, six flavonols and two pseudoguaianolide sesquiterpene lactones). Three new chalcones were elucidated as (S)-beta-Hydroxy-2,3,4,6'-tetrahydroxy-5-methoxydihydrochalcone (salsolol A), (S)-beta-Hydroxy-2',4,4',6'-tetrahydroxy-3-methoxydihydrochalcone (salsolol B), and (R)-alpha, (R)-beta-Dihydroxy-2,3,4,4,6'-pentahydroxydihydrochalcone (salsolol C) together with nine known compounds: balanochalcone, six quercetin derivatives, confertin, and neoambrosin. Chemical structures were determined …

The Effect Of Invasive Aquatic Vegetation On Odonate Diversity In An Urban Area, Sarah Thomas

Honors Capstones

No abstract provided.

Assessing Knowledge Of Coastal Land Loss In Louisiana High School Graduates, Madelyn Smith

Honors Capstones

No abstract provided.

Peerra: An Extensible And Structured Web Service For Peer-To-Peer Assistance, Drake Lambert

Honors Capstones

No abstract provided.

The Spatial Distribution Of Poverty And The Long Reach Of The Industrial Makeup Of Places: New Evidence On Spatial And Temporal Regimes, Katherine J. Curtis, Junho Lee, Heather A. O'Connell, Jun Zhu

Faculty Publications

A wealth of research identifies industrial structure as a central correlate of place-level poverty and suggests that changes in and the clustering of industry contribute to the spatial clustering of poverty over time. However, few studies have investigated the spatial and temporal dimensions simultaneously, and none have effectively examined spatiotemporal interactions. Consequently, a core tenet of theory on poverty in place has not been adequately examined. To address this limitation, we explicitly test hypotheses about systematic variation in the poverty-industry relationship over time and across space using a new method to quantify dynamic associations by simultaneously accounting for spatial and …