Digital Commons Network^™

Reactive Thin Film Polymers And Thin Film Composite Membranes For The Rapid Screening Of Uranium Isotopes, Abenazer W. Darge

All Dissertations

Traditional radiochemistry approaches for the detection of trace-level alpha-emitting radioisotopes in water require lengthy offsite sample preparations and do not lend themselves to rapid quantification. Therefore, a novel platform is needed that combines onsite purification, concentration, and isotopic screening with a fieldable detection system. My dissertation research objective was to develop novel reactive thin polymer films and thin film composite membranes for the selective separation of uranium from environmental water followed by direct isotopic analysis by alpha spectroscopy. Chapter 1 reviews progress made on uranium separation from aqueous matrices and discusses methods used for the determination of isotopic composition.

Chapter …

Light Harvesting And Electrically Conducting Metal-Organic Frameworks, Monica Gordillo Varela

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Composed of metal clusters nodes and organic linkers, metal-organic frameworks (MOFs) have emerged as versatile platforms with unparalleled chemical and structural tunability, synthetic facility, permanent porosity, and size-selective guest encapsulation capability. These features make them potential candidates for a variety of applications such as gas storage,drug delivery, catalysis,and sensing. In recent years, the introduction of redox- and photoactive components have yielded stimuli-responsive electronic and photonic MOFs and expanded their utility in molecular electronics and energy storage devices/technologies.

Chapter one describes the light-harvesting ability of a porphyrin-based MOF. Herein, we have demonstrated spontaneous solvothermal growth of [100]-oriented uniform pillared-porphyrin framework-11 (PPF-11) …

Design And Analysis Of Efficient Freight Transportation Networks In A Collaborative Logistics Environment, Vishal Badyal

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The increase in total freight volumes, reducing volume per freight unit, and delivery deadlines have increased the burden on freight transportation systems of today. With the evolution of freight demand trends, there also needs to be an evolution in the freight distribution processes. Today's freight transportation processes have a lot of inefficiencies that could be streamlined, thus preventing concerns like increased operational costs, road congestion, and environmental degradation. Collaborative logistics is one of the approaches where supply chain partners collaborate horizontally or/and vertically to create a centralized network that is more efficient and serves towards a common goal or objective. …

Examining The Different Snap-Through Characteristics Of Bistable Cfrp Composite Laminates, Vishrut Deshpande

All Theses

Bistable carbon fiber composites, whose bistability arises from having asymmetric fiber layouts in different layers, have shown immense potential for use in shape morphing and adaptive structure applications. While many studies in this field focus on these composite laminates’ external shapes at the two stable states, their snap-through behavior of shifting from one stable shape to the other remains a critical aspect to be investigated in complete detail. Moreover, symmetric loading conditions have been extensively studied based on the classical lamination theory, but the asymmetric loading conditions received far less attention. Therefore, this study examines an asymmetric, localized point load …

Age-Specific Effects Of An Early Grade Literacy Intervention In Asia And Africa, Doris Suzuki Esmerio

All Theses

Education has been widely recognized in the economic literature as a fundamental element in the economic development of nations and individuals. In this study, I focus on literacy acquisition for young children in poor communities in South Asia and Sub- saharan Africa. Literature on cognitive skill formation, neurobiology and psychology have found converging evidence that returns to investments in education differ by age. This is explained by the fact that neural circuits are more receptive to environmental influences at sensitive periods of brain development. Using data from a RCT experiment conducted between 2012-2016 in Bangladesh, Burundi, Ethiopia, Eswatini, Ghana, India, …

Effects Of Invasive Wild Pigs And Supplemental Feeding On Wildlife In The Piedmont Region Of South Carolina, Elizabeth A. Saldo

All Theses

Wild pigs (Sus scrofa), which are invasive in much of the world, can alter ecosystems and compete with native species through interference competition and resource exploitation. We assessed the potential for interspecific interactions between invasive wild pigs and other wildlife in the Piedmont region of South Carolina by examining their spatiotemporal overlap in a correlational field study and an experimental field study. Our correlational study used data from wildlife cameras in seasonal occupancy, N-mixture, and temporal overlap analyses. Both deer (Odocoileus virginianus) and coyote (Canis latrans) site use were negatively associated with wild pig …

Creating A Printed Electronic Tangible User Interface Suitable For Primary Education Settings, Lauren Toler

All Theses

With the growing popularity of interactive learning, an experiment developing a tangible user interface made of paper was performed. Screen printing was utilized to print conductive traces that would connect to a device that has capacitive touch capabilities. A color mixing program was coded to accompany the tangible interface. It was found that a tangible user interface can be successfully made of paper. Further research with development, construction, and testing of this paper tangible interface was proposed.

Pasture Biomass Estimation Using Crop Surface Modeling And Vegetation Indices, Brendan Macinnis

All Theses

Biomass estimations are a critical function of any grazing or haylage system. Determination of ideal harvesting or grazing times help optimize the quality and quantity of above-ground biomass (AGB). The objective of this study was to evaluate the use of unmanned aerial vehicles (UAVs) for Alfalfa and Tall Fescue biomass estimations. Using a DJI Mavic Pro, RGB and NDVI images were taken and used to create orthomosaic images. Structure-from-motion (SfM) techniques were used to developed digital elevation models to evaluate the change in canopy height (∆H) between pre- and post-harvests. Change in canopy height (∆H) was shown to provide the …

Effects Of Forest Management On Early-Successional Avian Species In The Southern Blue Ridge Ecoregion, Michael J. Adams

All Theses

Early-successional habitats are a critical habitat type for Ruffed Grouse (Bonasa umbellus) and Golden-winged Warblers (Vermivora chrysoptera). In the Southern Blue Ridge Ecoregion, early-successional habitats have declined over the last 70 years, and the extent of which Ruffed Grouse and Golden-winged Warblers occupy these habitats at the edge of their ranges is unknown. Understanding the factors that drive the presence or absence of these species in this region is critical to inform quality management of early-successional forests. Additionally, increased knowledge of these species will likely benefit other species of conservation concern that rely on early-successional forests, …

A Performance Evaluation Of Architectural Coatings To Preserve Aerosol Paint On Concrete, Riley Morris

All Theses

The growing movement of assigning cultural and heritage value to graffiti and street art is one without a preservation solution to ensure the longevity of these works in-situ in an outdoor environment. The goal of this thesis was to provide a comprehensive evaluation of six architectural topcoats’ performance when applied as a conservation treatment to outdoor aerosol graffiti and street art on concrete substrate. An artist’s quality, durable, color-fast spray-paint was applied to twenty-eight concrete test panels to mimic the application of graffiti or street art. Six topcoats, Prosoco SC-1, Prosoco Gloss n’ Guard WB, Keim Faceal Oleo HD®, Keim …

The Ivory Tower: An Intersectional View On Gender And Ethnicity In Academia Before And After The Transition To Online Work, Chelsea Robbins

All Theses

A substantial body of research shows that female academics have faced lower salaries, fewer promotions, and lower rates of tenure than male academics. Proposed mechanisms include higher demands for unrewarded service in the teaching-research-service ratio and significant obstacles in balancing work and family. This study proposed the ‘Academic Tetrad,’ which includes the additional facet of home life, as an alternative to the traditional ‘Academic Trinity’ perspective. The present study utilized an intersectional perspective to examine the academic tetrad, key workplace variables, and work-life balance across the COVID-19 transition to online work. The findings countered previous research by showing equality on …

The Social Network Of Early American Architecture: A Network Analysis Of Early Architectural Training In And Out Of The Lowcountry, James Mcenerney

All Theses

The contents of this thesis contain research conducted over a 9-month span surrounding the nature of architectural education in the late American Colonial Period, progressing into the Early Republic. Themes such as early European influences, 17^th and 18^th century art and architecture schools of Dublin, Ireland and Paris, France, and early American drafting schools/apprenticeship societies are analyzed. This paper, first, seeks to document the scholarly dialogue surrounding the ways in which early American architectural practitioners were educated, and in what ways this training was manifest in their physical designs. With a timeframe of approximately 1770 to 1830, 23 …

The Influence Of Classroom Design On Problem Behaviors And Educational Growth Indicators For Children With Autism Spectrum Disorder (Asd), Anthony D. Asher

All Theses

This qualitative comparative case study reports on findings from a pre-and post-occupancy evaluation using multiple data collection methods to explore how classroom design features contribute to behavioral outcomes for children with ASD. Ten children, ages three to five years older with ASD, were observed over four months as they transitioned from their current classrooms into their newly built classrooms based on evidence-based design for children with ASD. For a two-month period in each setting, environmental conditions were tracked continuously in both classrooms. In addition, interviews were conducted with the special education teachers in both settings to gain insight into the …

Use Of 14c-Pfoa To Study Uptake And Biological Effects Of Pfoa In Brassica Juncea, Bryanna Dawn Wattier

All Theses

Perfluorooctanoic acid (PFOA), a surfactant, is a member of the perfluoroalkyl acids (PFAAs) family and is a contaminant of emerging concern for human and environmental health. PFOA is a persistent organic pollutant but currently little is known about (1) the potential ecological and toxicological effects of PFOA and (2) how PFOA moves in the environment. This study employs a radiotracer (¹⁴C-PFOA) to study the uptake and effects of PFOA in hydroponically grown Brassica juncea, a representative crop species. Plants were exposed in quadruplicate over the course of seven days (with plants sampled on day 4 and day 7) …

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

All Theses

Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …

Cladding By Another Name: A Comparative Analysis Of The Environmental And Economic Costs Of Traditional Wood Clapboards, Composite Fiber-Cement Siding, And Vinyl Siding, Nicole Larochelle

All Theses

Using the tools provides by the scientific community, namely the products of lifecycle cost assessments (LCA) – which are synthesized in environmental product declarations (EPD) – and life cycle cost assessments (LCCA), the overall environmental and economic impacts of historic, traditional, and simulated materials are established and compared. This informs the historic preservation community of the quantifiable sustainability of historic materials in relation to alternatives. Through these two different methods of environmental and economic life cycle costing, this research demonstrates that retaining in-situ siding incurs the least impact on the environment and is the second most economic option. While the …

Effects Of Tannin-Free Grain Sorghum Varieties On The Metabolizable Energy, Performance, And Intestinal Health Of Poultry, Alissa Moritz

All Dissertations

The single largest cost of poultry production is the cost of feed, and it is favorable to seek more sustainable, alternative feed ingredients to reduce the competition between human, animal, and industrial users. Grain sorghum is a potential alternative feedstuff to minimize the dependence of corn by the poultry industry. Not only is it nutritionally similar to corn, but it is tolerant to dry, sandy soils, which allows it to grow successfully in arid climates. This is highly desirable because of its potential to alleviate the production pressure of growing other cereal grains like corn that are less tolerant to …

Designing And Evaluating Accessible E-Learning For Students With Visual Impairments In K-12 Computing Education, Earl W. Huff Jr

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This dissertation explores the pathways for making K-12 computing education more accessible for blind or visually impaired (BVI) learners. As computer science (CS) expands into K-12 education, more concerted efforts are required to ensure all students have equitable access to opportunities to pursue a career in computing. To determine their viability with BVI learners, I conducted three studies to assess current accessibility in CS curricula, materials, and learning environments. Study one was interviews with visually impaired developers; study two was interviews with K-12 teachers of visually impaired students; study three was a remote observation within a computer science course. My …

Penalized Estimation Of Autocorrelation, Xiyan Tan

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This dissertation explored the idea of penalized method in estimating the autocorrelation (ACF) and partial autocorrelation (PACF) in order to solve the problem that the sample (partial) autocorrelation underestimates the magnitude of (partial) autocorrelation in stationary time series. Although finite sample bias corrections can be found under specific assumed models, no general formulae are available. We introduce a novel penalized M-estimator for (partial) autocorrelation, with the penalty pushing the estimator toward a target selected from the data. This both encapsulates and differs from previous attempts at penalized estimation for autocorrelation, which shrink the estimator toward the target value of zero. …

Porous Silicon Photonics For Label-Free Interferometric Biosensing And Flat Optics, Tahmid Hassan Talukdar

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This dissertation uses porous silicon as a material platform to explore novel optical effects in three domains: (i) It studies dispersion engineering in integrated waveguides to achieve high performance group index sensing. With proper design parameters, the sensor waveguides can theoretically achieve 6 times larger group index shift compared to the actual bulk effective refractive index shift. We demonstrate the guided mode confinement factor to be a key parameter in design and implementation of these waveguides. (ii) It explores multicolor laser illumination to experimentally demonstrate perceptually enhanced colorimetric sensing, overcoming the limitations faced by many contemporary colorimetric sensors. Our technique …

Floating Treatment Wetlands For Brackish Waters: Plant Selection And Nutrient Uptake Potential., Andrea Landaverde

All Theses

Brackish water bodies in coastal regions provide critical ecosystem services that support human and environmental health. Anthropogenic activities such as agricultural and industrial activities, construction, urban settlements, and tourism contribute to increased inputs of nitrogen (N) and phosphorus (P) in brackish coastal ecosystems. Excess nutrients can lead to impaired water quality and affect marine organisms. Floating treatment wetlands (FTWs) are a vegetated-base technology used to remove contaminants from water column, that has been mainly studied and applied in freshwater systems. Application of FTWs in brackish systems requires further investigation, as high salinity in brackish waters could result in toxicity to …

Understanding User Perceptions Of Voice Personal Assistants, Ha Young Kim

All Theses

As the artificial intelligence (AI) technique improves, voice assistant (smart speaker) such as Amazon Alexa and Google Assistant are quickly, surely permeating into people's daily lives. With its powerful and convenient benefits and the circumstances that people started to stay at their home longer due to the pandemic, reliance on smart speakers has increased rapidly. But at the same time, concerns of security on smart speakers have increased.

In this thesis, we conducted an online user survey of smart speaker users with five different perspectives – 1) Users’ engagement with privacy policy; 2) Awareness of different policy requirements defined by …

Prediction Of Pathogenic Mutations In Spermine/Spermidine Synthases, Shannon Bonomi

All Theses

As genetic technology and information become continuously more sophisticated and applied to the prevention and treatment of diseases, the need to understand the effects of genetic variants becomes an important task with regards to assessing disease risk. In the specific case of intellectual disabilities, prenatal screenings is an important diagnostic tool that prepares families and health professionals for the arrival of a child who may need immediate, specialized care. Cell Free DNA screenings are routine for determining sex and provide the opportunity to discover genetic anomalies. However, this has little value unless mutations can be recognized as pathogenic and are …

A Contribution To The Statistical Analysis Of Climate-Wildfire Interaction In Northern California, Adam Diaz

All Theses

Wildfires are extreme weather events that exist at the interface of atmospheric, ecological, and human processes. Ongoing anthropogenic climate change is expected to impact the distribution, frequency, and behavior of wildfires on a grand scale, however the exact nature of this change remains shrouded in a great deal of uncertainty. This study takes a statistical approach to the question over the fire-prone Northern California region of the western United states. Climate model projections are analyzed to investigate changes in a major driver of fire weather in the region. The relationship between wildfire severity and climate factors is then explored separately, …

Advancing Hymenocallis Coronaria Conservation And Restoration For Improved Habitat Management In Fall Line Streams Of The Southeast, Andrew Paul Grunwald

All Theses

The rocky shoals spider lily (Hymenocallis coronaria) is a culturally and ecologically important emergent macrophyte endemic to the biodiverse shoals of fall line streams in the southeastern United States. H. coronaria has declined throughout its range as shoal habitat has become increasingly threatened by flow modification and other anthropogenic stressors. The genetics and botany of H. coronaria have been given considerable attention, but quantitative habitat research has been lacking. Furthermore, despite substantial need, public interest, and its status as an indicator species for fall line streams, no research has been conducted on H. coronaria restoration. Our main objectives …

Physical And Microbiological Characteristics Of Pickled Eggs From Japanese Quail (Coturnix Coturnix Japonica) Of The Pharaoh Variety, Adair Hoover

All Theses

The quality and microbiological characteristics of quail eggs were evaluated after eggs were pickled in different vinegar brine solutions. Pickling food in vinegar is one of the oldest preservation methods; however, little research has been conducted on pickled quail eggs. Commercial quail eggs obtained from a local producer were boiled, peeled, and placed into various pickling solutions and held for 24 or 48 hours at room temperature. After the holding period, eggs were removed from the solutions, weighed, and tested for pH, water activity, texture, and color. A second experiment was conducted to determine the effects of various pickling solutions …

Enabling Breeding For Targeted Heat Requirement In Peach, Omer Atagul

All Theses

Peach [Prunus persica (L.) Batsch] germplasm varies in heat requirement and bloom time. This variability can be utilized in breeding for targeted environment or overall climate resilience. Development of molecular tools to aid in targeted selection of dormancy related traits is needed to support breeding for these traits. This project furthers our understanding of heat requirement accumulation diversity and genetic control in peach.

Peach bloom date (BD) is determined by the dynamic relationship of temperature requirements, from the sequential fulfillment of chill requirement (CR) and heat requirement (HR). Knowledge of HR and its influence on BD would provide deeper …

Predictive Performance And Teaming Via The Mist-C Ocean Hierarchy Utilizing Personality And Skills, Brighton H. Owen

All Theses

This thesis seeks to establish and define the individual, the team as an entity, and qualify various metrics to predict team performance. When several individuals come together, they form a team that is often capable of designing and developing concepts beyond the individual on their own by methods of task dispersion, goal orientation, communication, and more. With these teams comes growth and increased performance leading to more efficient processes and better metrics by which performance may be measured. To achieve this, 34 engineering students in the AerosPACE senior design program, which lasted two semesters, were asked to complete surveys in …

Analysis Of The Self-Heating Effect On Unfilled Poly(Methyl Methacrylate) Due To Cyclic Behavior, Muhammed R. Kose

All Theses

Poly(methyl methacrylate, (PMMA) has been implemented as part of the supporting structure in complete hip and knee replacements since the 1950s. Known as bone cement while in the body, PMMA is known to undergo compressive and tensile stresses that wear down the bio-compatible barrier and cause pieces to come loose inside the human body. These pieces are then attacked by the body’s own nervous system, leading to inflammation, and eventually necessitating replacement. It has been documented that under cyclic loading PMMA can reach temperatures that start to degrade its tensile capabilities. In this study the potential cause of self-heating was …

A Conservative Numerical Scheme For The Multilayer Shallow Water Equations, Evan Butterworth

All Theses

An energy-conserving numerical scheme is developed for the multilayer shallow water equations (SWE’s). The scheme is derived through the Hamiltonian formulation of the inviscid shallow water flows related to the vorticity-divergence variables. Through the employment of the skew-symmetric Poisson bracket, the continuous system for the multilayer SWE’s is shown to preserve an infinite number of quantities, most notably the energy and enstrophy. An energy-preserving numerical scheme is then developed through the careful discretization of the Hamiltonian and the Poisson bracket, ensuring the skew-symmetry of the latter. This serves as the groundwork for developing additional schemes that preserve other conservation properties …