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Point Of Sale Assessment, 2009 December, Holley Hewitt Ulbrich Dec 2009

Point Of Sale Assessment, 2009 December, Holley Hewitt Ulbrich

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Observations Of Very High Energy Gamma-Ray Emission From Supernova Remnants With Veritas, Mark Theiling Dec 2009

Observations Of Very High Energy Gamma-Ray Emission From Supernova Remnants With Veritas, Mark Theiling

All Dissertations

The nature and source of cosmic rays has been at the core of particle astrophysics since their discovery almost a century ago. The cosmic ray spectrum is best described by a broken power law, and can be better understood as three distinct parts. Theory holds that cosmic rays up to ∼1015 eV – those below the “knee” or steepening in the spectrum – are produced in the shocks of supernova remnants. Direct detection of cosmic rays produced in supernova remnant shocks is impossible, however, as cosmic rays below ∼1018 eV are deflected by the Galactic magnetic field and cannot be …


A Cognitive Model For Problem Solving In Computer Science, Jennifer Parham Dec 2009

A Cognitive Model For Problem Solving In Computer Science, Jennifer Parham

All Dissertations

According to industry representatives, computer science education needs to emphasize the processes involved in solving computing problems rather than their solutions. Most of the current assessment tools used by universities and computer science departments analyze student answers to problems rather than investigating the processes involved in solving them. Approaching assessment from this perspective would reveal potential errors leading to incorrect solutions.
This dissertation proposes a model describing how people solve computational problems by storing, retrieving, and manipulating information and knowledge. It describes how metacognition interacts with schemata representing conceptual and procedural knowledge, as well as with the external sources of …


Synthesis And Development Of Novel Fullerene-Based Structures For Photovoltaics, Electronic Applications And Mri Contrast Agents, Manuel Chaur Dec 2009

Synthesis And Development Of Novel Fullerene-Based Structures For Photovoltaics, Electronic Applications And Mri Contrast Agents, Manuel Chaur

All Dissertations

Metallic nitride endohedral metallofullerenes (EMFs) are one of the most interesting types of metallofullerenes due to their high yields and interesting electronic properties. The synthesis of these compounds allows the encapsulation of different metals inside fullerenes making it possible to combine the properties of the metal with those of the fullerene. Their interesting electrochemical and optical features make them potential candidates for several applications such as molecular electronics, biomedical imaging, non-linear optical devices, and magnetic resonance imaging (MRI) agents. This thesis reports the synthesis of novel metallic nitride EMFs based on Gd, Nd, Pr, Ce and La. These families of …


Functional Characterization Of Calcium Dependent Protein Kinase 32 From Arabidopsis, Rucha Karve Dec 2009

Functional Characterization Of Calcium Dependent Protein Kinase 32 From Arabidopsis, Rucha Karve

All Dissertations

Calcium-dependent protein kinases (CPKs) are major plant Ca2+ sensors, many of which have roles in plant stress responses. The Arabidopsis genome encodes 34 CPK isoforms. Here we report characterization of AtCPK32 gene function. Analysis of transgenic plants expressing pCPK32-GUS shows that CPK32 is highly expressed in roots, pollen and embryo, as well as leaf hydathodes, and the abscission zone of mature siliques. Real time RT-PCR and promoter expression patterns show that CPK32 is responsive to abiotic and biotic stresses. Plants treated with salt, ABA, osmotic stress (PEG), wounding, and flagellin 22 peptide show up-regulation of CPK32 upon these stress treatments. …


An Investigation On The Use And Flexibility Of Genetic Algorithms For Logistic Regression, Sara Yoder Dec 2009

An Investigation On The Use And Flexibility Of Genetic Algorithms For Logistic Regression, Sara Yoder

All Dissertations

Social scientists and other users of large data sets often desire a model to predict the probability that some condition exists, such as the probability that a person has diabetes or that a credit card transaction will be fraudulent. In general, this can be done by data mining techniques, which allow multiple records of data composed of numerous independent variables and one dependent variable to be examined in a statistical fashion to make a predictive model. One particular technique used is logistic regression. Logistic regression forms a predictive model based on a set of independent variables by assigning coefficients to …


Preservice Teacher Attitudes And Intentions Toward An Inclusive Educational Environment: An Application Of The Theory Of Planned Behavior, Julie Jones Dec 2009

Preservice Teacher Attitudes And Intentions Toward An Inclusive Educational Environment: An Application Of The Theory Of Planned Behavior, Julie Jones

All Dissertations

The purpose of this research project was to identify preservice teacher beliefs, attitudes, and intentions toward the inclusion of students with disabilities in a predominately general education environment. A survey instrument was created based on Ajzen and Fishbein's theory of planned behavior and disseminated to three universities in South Carolina. This study improves upon existing studies of preservice teacher attitudes because it takes place at more than one institution and is grounded in a theory that explores the many- layered aspects of attitude.
Preservice teacher attitudes were moderately positive on all measures: behavioral beliefs, subjective norms, and perceived behavioral control. …


Exploring Formation And Distribution Of Halonitromethanes In Drinking Waters, Jia Hu Dec 2009

Exploring Formation And Distribution Of Halonitromethanes In Drinking Waters, Jia Hu

All Dissertations

ABSTRACT
Nine halonitromethanes (HNMs) were among the more than fifty unregulated high-priority disinfection by-products (DBPs) that were monitored for and detected in drinking waters in a 2000-2002 nationwide occurrence study funded by the US Environmental Protection Agency (USEPA). The toxicology studies conducted in recent years have shown that HNMs are one of the most cytotoxic and genotoxic classes among the emerging DBPs, with orders of magnitude higher cytotoxicity and genotoxicity than any of the regulated organic DBPs. Furthermore, brominated HNMs were found to be more toxic than their chlorinated analogs, with dibromonitromethane being the most cyto- and genotoxic. Today, our …


Probabilistic Remediation Evaluation Model For Chlorinated Solvents Considering Uncertainty, Hailian Liang Dec 2009

Probabilistic Remediation Evaluation Model For Chlorinated Solvents Considering Uncertainty, Hailian Liang

All Dissertations

The complex processes and expensive costs of source and plume remediation of dense, non-aqueous phase liquid (DNAPL) complicate the decision-making process for site remediation. Selection of remediation alternatives has been a big challenge due to the lack of tools that simultaneously evaluate the effectiveness of source and plume remediation and access the uncertainties in all major parameters. In this research, a new probabilistic remediation model, Probabilistic Remediation Evaluation Model for Chlorinated solvents sites (PREMChlor), has been developed. This is achieved through linking the analytical model REMChlor to a Monte Carlo modeling simulation package GoldSim via a FORTRAN Dynamic Link Library …


A Scanpath Comparison Of The Salient Features Of Weather Among General Aviation Pilots Based On Training And Experience, Michael Sawyer Dec 2009

A Scanpath Comparison Of The Salient Features Of Weather Among General Aviation Pilots Based On Training And Experience, Michael Sawyer

All Dissertations

Over the last 20 years the number of annual accidents in general aviation has seen a steady decline. The annual number of fatal accidents, however, has remained relatively stable. Adverse weather is consistently cited as a leading cause of fatal accidents in general aviation; weather accidents have a fatality rate nearly four times that of other general aviation accidents. Reviews of accident data reveal that often these accidents occur when inexperienced pilots who are certified only for visual flight rules flight continue into adverse weather. The Situation Assessment Hypothesis suggests these accidents occur when pilots fail to accurately recognize weather …


Visuohaptic Simulation Of A Borescope For Aircraft Engine Inspection, Deepak Vembar Dec 2009

Visuohaptic Simulation Of A Borescope For Aircraft Engine Inspection, Deepak Vembar

All Dissertations

Consisting of a long, fiber optic probe containing a small CCD camera controlled by hand-held articulation interface, a video borescope is used for remote visual inspection of hard to reach components in an aircraft. The knowledge and psychomotor skills, specifically the hand-eye coordination, required for effective inspection are hard to acquire through limited exposure to the borescope in aviation maintenance schools. Inexperienced aircraft maintenance technicians gain proficiency through repeated hands-on learning in the workplace along a steep learning curve while transitioning from the classroom to the workforce.
Using an iterative process combined with focused user evaluations, this dissertation details the …


Ninth Grade Academies In South Carolina: Early Adopters Versus Late Adopters, Daniel Mullis Dec 2009

Ninth Grade Academies In South Carolina: Early Adopters Versus Late Adopters, Daniel Mullis

All Dissertations

The addition of ninth graders to the high school level brought administrative challenges: increased failure rate, truancy, and disciplinary infractions; as a solution, the Ninth Grade Academy concept evolved. This study's purpose was to examine South Carolina schools' academies to determine if early adopters were more effective than late adopters. The study's research was based on Institutional Theory with its main focus as Institutional Isomorphism. This qualitative study used survey results to determine how much administrators used data from existing academies before beginning their own implementation process. The study used institutional theory to assess whether new academies were a form …


Field Evaluation Of The Immunocontraceptive Gonacontm In Reducing Eastern Gray Squirrel Fecundity In Urban Areas, Murali Pai Dec 2009

Field Evaluation Of The Immunocontraceptive Gonacontm In Reducing Eastern Gray Squirrel Fecundity In Urban Areas, Murali Pai

All Dissertations

The purpose of this study was to evaluate the immunocontraceptive GonaConTM in reducing fecundity in Eastern gray squirrel (EGS) (Sciurus carolinensis) in urban areas. Using a modified box trap design, 317 EGS were captured during four trapping sessions on a 5.66 ha site on Clemson University's main campus. EGS were handled using a restraint cone and sexed, weighed, ear-tagged and implanted with a microchip at the nape of the neck on all 'original' captures and later identified in subsequent captures as 'recaptures.' Blood samples and morphometric data were obtained on EGS before the immunocontraceptive GonaConTM was administered by …


Synthesis, Modification Of Mesoporous Carbons And Their Application In Polymer Electrolyte Membrane Fuel Cells, Bing Liu Dec 2009

Synthesis, Modification Of Mesoporous Carbons And Their Application In Polymer Electrolyte Membrane Fuel Cells, Bing Liu

All Dissertations

Mesoporous carbon materials of carbon xerogel (CX) and silica-templated carbon (MC) were synthesized and explored as catalyst supports alternative to the most-commonly-used carbon black (CB) support, for polymer-electrolyte-membrane fuel cell (PEMFC) application. Pt catalyst was loaded on these carbons and electrodes were fabricated from them. These Pt-loaded carbon supports were characterized with XRD, TEM, ex-situ and in-situ cyclic voltammetry, etc. The fabricated electrodes were evaluated in single-cell testing in comparison with commercial CB-supported Pt catalyst fabricated electrodes. The experimental results showed that CX-supported Pt catalyst had close or better performance than that of CB-supported Pt, possibly due to CX's 3-D …


Examining The Dynamics Of Managing Information Systems Development Projects: A Control Loss Perspective, Ravi Narayanaswamy Dec 2009

Examining The Dynamics Of Managing Information Systems Development Projects: A Control Loss Perspective, Ravi Narayanaswamy

All Dissertations

The failure rate of information systems development (ISD) projects continues to pose a big challenge for organizations. The success rate of ISD projects is less then forty percent. Factors such as disagreements and miscommunications among project manager and team members, poor monitoring and intermediary problems contribute to project failure.
Agency theory and leader member exchange (LMX) theories offer potential explanations for project failure. In particular, three monitoring strategies - control strategy, decision rights, and influence tactics were found to be effective in promoting project success. LMX theorists suggest that achieving congruence between the manager and subordinate regarding each other actions …


Branchings And Time Evolution Of Reaction Networks, Changyuan Wang Dec 2009

Branchings And Time Evolution Of Reaction Networks, Changyuan Wang

All Dissertations

In this thesis I analyze flows in reaction networks in terms of branchings
in a digraph. If the coupled differential equations governing the rate
of change of probabilities X of a state or species are finite-differenced in time, a matrix equation (I + Adt)X(t+dt) = X(t) results, where X(t) is a vector giving the probabilities at time t and X(t+dt) is a vector giving the probabilities at time t + dt. I demonstrate that the matrix (I + Adt) may be written as the product of an incidence matrix and a weight matrix for a directed graph (digraph) representing the …


Some New Problems In Changepoint Analysis, Jonathan Woody Dec 2009

Some New Problems In Changepoint Analysis, Jonathan Woody

All Dissertations

Climatological studies have often neglected changepoint effects when modeling
various physical phenomena. Here, changepoints are plausible whenever a station location moves or its instruments are changed. There is frequently meta-data to
perform sound statistical inferences that account for changepoint
information. This dissertation focuses on two such problems in changepoint analysis.
The first problem we investigate involves assessing trends
in daily snow depth series. Here, we introduce a stochastic storage model. The model allows for seasonal features, which permits the
analysis of daily data. Changepoint times are shown to greatly influence estimated trends in one snow depth series and are accounted …


On The Testing And Estimation Of High-Dimensional Covariance Matrices, Thomas Fisher Dec 2009

On The Testing And Estimation Of High-Dimensional Covariance Matrices, Thomas Fisher

All Dissertations

Many applications of modern science involve a large number of parameters. In
many cases, the number of parameters, p, exceeds the number of observations,
N. Classical multivariate statistics are based on the assumption that the
number of parameters is fixed and the number of observations is large. Many of
the classical techniques perform poorly, or are degenerate, in high-dimensional
situations.
In this work, we discuss and develop statistical methods for inference of
data in which the number of parameters exceeds the number of observations.
Specifically we look at the problems of hypothesis testing regarding and the
estimation of the covariance …


Metal Oxide And Mercuric Sulfide Nanoparticles Synthesis And Characterization, Xin Xu Dec 2009

Metal Oxide And Mercuric Sulfide Nanoparticles Synthesis And Characterization, Xin Xu

All Dissertations

Increasing applications of nanoparticles (NPs), such as metal oxide and mercuric sulfide NPs, lead to heightened environmental concern. Challenges to the study of natural and engineered NPs include the physical and chemical characterizations.
Commercially available and laboratory-synthesized metal based NPs, iron oxide (Fe2O3), copper oxide (CuO), titanium dioxide (TiO2), zinc oxide (ZnO) and mercuric sulfide (HgS) were studied by comprehensive characterizations methods. The general synthesis process was modified sol-gel method. The size and morphology of NPs could be influenced by temperature, sonication, calcination, precursor concentration, pH and types of reaction media. In the synthesis of nZnO in ethanol, the essential …


Decoding Of Multipoint Algebraic Geometry Codes Via Lists, Nathan Drake Dec 2009

Decoding Of Multipoint Algebraic Geometry Codes Via Lists, Nathan Drake

All Dissertations

Algebraic geometry codes have been studied greatly since their introduction by Goppa . Early study had focused on algebraic geometry codes CL(D;G) where G was taken to be a multiple of a single point. However, it has been shown that if we allow G to be supported by more points, then the associated code may have better parameters. We call such a code a multipoint code and if G is supported by m points, then we call it an m-point code. In this dissertation, we wish to develop a decoding algorithm for multipoint codes. We show how we can embed …


Atom Scattering From Metals, William Hayes Dec 2009

Atom Scattering From Metals, William Hayes

All Dissertations

In the initial portion of this dissertation studies of Ar
scattering from Ru(0001) at thermal and hyperthermal energies are
compared to calculations with classical scattering theory. These
data exhibited a number of characteristics that are unusual in
comparison to other systems for which atomic beam experiments have
been carried out under similar conditions. The measured energy
losses were unusually small. Some of the angular distributions
exhibited an anomalous shoulder feature in addition to a broad
peak near the specular direction and quantum mechanical
diffraction was observed under conditions for which it was not
expected. Many of the unusual features observed …


Characterization Of Escherichia Coli Related To Construction Site Sediment Basins, Calvin Sawyer Dec 2009

Characterization Of Escherichia Coli Related To Construction Site Sediment Basins, Calvin Sawyer

All Dissertations

Large construction sites can have significant temporary and permanent impacts on the physical landscape. Excess sediment is frequently deposited into nearby surface waters, altering benthic habitat, reducing water clarity and transporting other pollutants such as enteric bacteria. To capture eroded soil and attenuate storm discharge peaks, many permitted construction projects larger than 10 acres in South Carolina require the installation of a sediment basin. Sediment-laden runoff is routed to a newly excavated impoundment, where larger particles settle out of suspension. Thus an entirely new hydrologic feature designed to concentrate eroded sediment and water is introduced into the landscape.
Eight construction …


Synthesis And Characterization Of Metallic, Core-Shell And Composite Nanoparticles, Amar Kumbhar Dec 2009

Synthesis And Characterization Of Metallic, Core-Shell And Composite Nanoparticles, Amar Kumbhar

All Dissertations

ABSTRACT
Silver nanoparticles exhibit size, shape and the surrounding dielectric medium dependent optical properties (scattering and absorption) in the visible spectral region. These optical properties can be explained in terms of the collective oscillation of the 'free conduction band electrons' or 'surface plasmons' induced by an external electromagnetic field. Dipole and Quadrupole Plasmon resonances have been observed for silver particles less than 100nm in diameter prepared using various synthetic techniques. However higher order resonances have been elusive due to lack of experimental techniques to prepare colloidal solutions of large silver nanoparticles in the size range above 100nm. Controlled hydrogen reduction …


Development Of A Fluorescent Probe For Determination Of Water Transport In Subcellular Organelles, Adriana Chaurra-Arboleda Dec 2009

Development Of A Fluorescent Probe For Determination Of Water Transport In Subcellular Organelles, Adriana Chaurra-Arboleda

All Dissertations

Water transport has been widely studied in a variety of cells and isolated membranes. However, the intrinsic complexity related with the study of intracellular processes has delayed the development of an analytical technique for the study of water transport in subcellular compartments of living cells. This study represents the development and application of a ratiometric fluorescent probe to study water transport in endocytic organelles of intact living cells. The probe is based on the use of a D2O-sensitive fluorophore, Lucifer yellow dextran (LY-dex), together with a D2O-insensitive fluorophore, Alexa fluor 546 dextran (AF546-dex), used as an …


An Approach Designed For Reginal Prospective Human Health And Ecological Risk Assessment And Its Application To Mercury Risks From A Coal-Fired Power Plant, Pathratipa Sansayavichai Dec 2009

An Approach Designed For Reginal Prospective Human Health And Ecological Risk Assessment And Its Application To Mercury Risks From A Coal-Fired Power Plant, Pathratipa Sansayavichai

All Dissertations

A large and/or long-term released source of a toxic chemical(s) can cause adverse effects to humans and non–human species inhabiting all over the region. The overall goal of this dissertation was to improve practices in risk assessment concerning a regional risk posed by a prospective source. A generic conceptual framework for performing regional prospective human health and ecological risk assessment was developed. The formulation of a priori considerations was used to identify the possible sources of uncertainties in the prospective risk assessment. Physiologically based pharmacokinetic (PBPK) modeling was utilized to reduce uncertainty in a toxicologically safe dose used in risk …


Exploring T. Brucei Hexokinase Biology: Localization And Inhibition Studies, Todd Lyda Dec 2009

Exploring T. Brucei Hexokinase Biology: Localization And Inhibition Studies, Todd Lyda

All Dissertations

Trypanosoma brucei, the causative agent of the disease African sleeping sickness
in humans and nagana in animals, is a scourge of sub-Saharan Africa. There is a
desperate need for more efficacious therapies for the disease; here we describe research
validating T. brucei hexokinase 1 (TbHK1) as a drug therapeutic target for T. brucei
infection and the identification and characterization of novel inhibitors of the enzyme by
both low throughput and high throughput means. Additionally this thesis introduces
efforts at characterizing a second T. brucei hexokinase, focusing mostly on cell biology
and the determination of localization.
The small molecule quercetin (QCN) …


Polymeric Carbon Nanocomposites - Preparation, Characterization, And Properties, Lucia Veca Dec 2009

Polymeric Carbon Nanocomposites - Preparation, Characterization, And Properties, Lucia Veca

All Dissertations

Excellent thermal properties of carbon nanomaterials such as carbon nanotubes and newly discovered graphene make them the filler of choice for the development of thermal management materials. Graphene has been viewed as “ unrolled single-walled carbon nanotube and as a wonder material with many superlatives to its name ” thus there is an excessive interest in developing new synthetic routes towards large scale production of high quality graphene nanosheets.
In this dissertation, we report different methods that could further exfoliate the commercially available expanded graphite to nanometer sized carbon structures, “carbon nanosheets ”, for their use in highly thermal conductive …


Wide Area Monitoring And Control, Manish Patel Dec 2009

Wide Area Monitoring And Control, Manish Patel

All Dissertations

Today's interconnected power system is deregulated for wholesale power transfers. In 1996 Federal Energy Regulatory Commission provided open access of the transmission network to utilities. Since then utilities are transferring power over long distances to bring reliable and economical electric supply to their customers. As the number of wholesale power transactions taking place over an interconnected system are increasing, system operators in control areas are forced to monitor the grid on a large scale to operate it reliably. Before scheduling such a large scale power transactions, it is necessary to make sure that such transaction will not violate system operating …


User Study Of Information Extracted From Engineering Representations, Rachel Hannah Dec 2009

User Study Of Information Extracted From Engineering Representations, Rachel Hannah

All Theses

It is important for designers to understand the usefulness of different engineering representations in order to save time and money throughout a project. Designers often rely on past experience to decide which model to construct; yet students without this experience have no help. Interestingly there are noticeable gaps in the research literature with respect to how and when to select representations and modeling approaches for engineering designs. This thesis examines the differences between three types of engineering representations, specifically sketches, drawing packages, and physical prototypes. The amount of information designers can extract from these representations and also the correctness and …


A Particle Swarm Optimization Using Random Keys For Flexible Flow Shop Scheduling Problem With Sequence Dependent Setup Times, Vinodh Sankaran Dec 2009

A Particle Swarm Optimization Using Random Keys For Flexible Flow Shop Scheduling Problem With Sequence Dependent Setup Times, Vinodh Sankaran

All Theses

In this research, a particle swarm optimization algorithm (PSO) using random keys is developed to schedule flexible flow lines with sequence dependent setup times to minimize makespan. The flexible flow line scheduling problem is a branch of production scheduling and is found in industries such as printed circuit board and automobile manufacturing. It is well known that this problem is NP-hard. For this reason, we approach the problem by implementing a particle swarm optimization (PSO), a metaheuristic which is inspired by the motion of a flock of birds or a school of fish searching for food. The proposed PSO has …