Digital Commons Network^™

Vibrational Dynamics In The Undercooled Liquid Of Ultra-Fragile Metallic Glasses, Hillary L. Smith, C. N. Saunders, C. Bernal-Choban, S. H. Lohaus, C. J. Stoddard, L. K. Decker, J. Y. Y. Lin, J. L. Niedziela, D. L. Abernathy, J.-H. Na, M. D. Demetriou, B. Fultz

Physics & Astronomy Faculty Works

The lattice vibrational dynamics in ultra-fragile Pt₅₇Cu₂₃P₂₀ and Pt60Cu20P20 glasses were investigated using in situ inelastic neutron scattering to measure the evolution of the phonon density of states (DOS) through the glass transition, into the undercooled liquid phase, and through crystallization. The phonon DOS curves are remarkably similar for the undercooled liquids and the amorphous solids. The vibrational entropy was obtained with these phonon DOS curves, and changes in vibrational entropy caused by the glass transition are less than 0.05k_B/atom. For these highly fragile metal/metalloid glasses, the excess vibrational entropy of the …

College Of Natural Sciences Newsletter, February 2023, College Of Natural Sciences

College of Natural Sciences Newsletters and Reports

Volume 4, Issue 1

Page 1 Dean's Message
Page 2 Awards and Recognition
Page 3-4 Nobel Recipient Visits Campus
Page 4 Adopting the Pantry
Page 5 Growing a Recruitment Mindset
Page 6 February Outreach Events
Page 7 Media Coverage of CNS
Page 8 Open PRAIRIE Data
Page 9 54th Geography Convention, and Tom Loveland EROS Geography Scholarship
Page 10 Photos of Dr. Carolyn Bertozzi's Visit

Development Of A Biaxial Apparatus For Jamming Profiles Of Photoelastic Granular Media, H. Zheng, G. Dai, Cacey Stevens Bester, M. Wang, D. Wang

Physics & Astronomy Faculty Works

We describe a two-dimensional biaxial apparatus that is used to conduct the experimental study of the jamming of granular media. The setup is designed based on the photoelastic imaging technique, which allows us to detect force-bearing contacts among particles, calculate the pressure on each particle according to the mean squared intensity gradient method, and compute contact forces on each particle [T. S. Majmudar and R. P. Behringer, Nature 435, 1079–1082 (2005)]. Particles float in a density-matched solution to avoid basal friction during experiments. We can compress (uniaxially or biaxially) or shear the granular system by an entangled comb geometry by …

First Look At Z > 1 Bars In The Rest-Frame Near-Infrared With Jwst Early Ceers Imaging, Yuchen Guo, Shardha Jogee, Steven L. Finkelstein, Zilei Chen, Eden Wise, Micaela B. Bagley, Guillermo Barro, Stijn Wuyts, Dale D. Kocevski, Jeyhan S. Kartaltepe, Elizabeth J. Mcgrath, Henry C. Ferguson, Bahram Mobasher, Mauro Giavalisco, Ray A. Lucas, Jorge A. Zavala, Jennifer M. Lotz, Norman A. Grogin, Marc Huertas-Company, Jesús Vega-Ferrero, Nimish P. Hathi, Pablo Arrabal Haro

Pacific Faculty Work

Stellar bars are key drivers of secular evolution in galaxies and can be effectively studied using rest-frame near-infrared (NIR) images, which trace the underlying stellar mass and are less impacted by dust and star formation than rest-frame UV or optical images. We leverage the power of JWST CEERS NIRCam images to present the first quantitative identification and characterization of stellar bars at z > 1 based on rest-frame NIR F444W images of high resolution (∼1.3 kpc at z ∼ 1-3). We identify stellar bars in these images using quantitative criteria based on ellipse fits. For this pilot study, we present six …

Searching For Tev Dark Matter In Irregular Dwarf Galaxies With Hawc Observatory, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, D. Avila Rojas, H. A.Ayala Solares, R. Babu, E. Belmont-Moreno, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, O. Chaparro-Amaro, U. Cotti, J. Cotzomi, E. De La Fuente, R. Diaz Hernandez, B. L. Dingus, M. A. Duvernois, M. Durocher, J. C. Diaz-Velez, C. Espinoza, K. L. Fan, N. Fraija, J. A. Garcia-Gonzalez, F. Garfias, M. M. Gonzalez, J. P. Harding, S. Hernandez-Cadena, D. Huang, F. Hueyotl-Zahuantitla, A. Iriarte, V. Joshi, S. Kaufmann, D. Kieda, J. Lee, H. Leon Vargas, J. T. Linnemann, A. L. Longinotti, G. Luis-Raya, K. Malone, O. Martinez, J. Martinez-Castro, J. A. Matthews, E. Moreno, M. Mostafa, A. Nayerhoda, L. Nellen, N. Omodei, Y. Perez Araujo, E. G. Perez-Perez, C. D. Rho, D. Rosa-Gonzalez, H. Salazar, D. Salazar-Gallegos, A. Sandoval, J. Serna-Franco, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Torres-Escobedo, R. Turner, F. Urena-Mena, L. Villasenor, Xiaojie Wang, E. Willox, H. Zhou, C. De Leon

Physics Faculty Research & Creative Works

We present the results of dark matter (DM) searches in a sample of 31 dwarf irregular (dIrr) galaxies within the field of view of the HAWC Observatory. dIrr galaxies are DM-dominated objects in which astrophysical gamma-ray emission is estimated to be negligible with respect to the secondary gamma-ray flux expected by annihilation or decay of weakly interacting massive particles (WIMPs). While we do not see any statistically significant DM signal in dIrr galaxies, we present the exclusion limits (95% C.L.) for annihilation cross section and decay lifetime for WIMP candidates with masses between 1 and 100 TeV. Exclusion limits from …

Air And Air-Steam Gasification Of Coconut Shell In A Fluidized Bed, Keynty Boy V. Magtoto, Rossana Marie C. Amongo, Sergio C. Capareda, Ronaldo B. Saludes

The Philippine Agricultural Scientist

Coconut shells’ abundance in tropical countries, along with its high volatile combustible matter (83.51%) and energy content (18.68 MJ kg^-1) make it a good biomass resource and a promising feedstock for gasification. In gasification, different mediums such as air, steam, oxygen, or their combinations can be used to react with the solid carbon and heavy hydrocarbons of biomass. Hence, the effects of using an air-steam mixture as a gasifying agent for the bench-scale fluidized bed gasification of coconut shells were studied. The steam-to-carbon ratio (SCR) was varied to evaluate its effect on the resulting syngas quality and gasification …

Effects Of Drying Temperature And Tempering Duration On Hybrid Rice Seed Germination, Thin-Layer Drying Characteristics, And Power Requirement, Rina A. Bawar, Joanne P. Foliente, Kevin F. Yaptenco, Mitchie Ann L. Cabiles

The Philippine Agricultural Scientist

This study presents the results of thin-layer drying tests for hybrid rice seeds. The independent factors were drying air temperature (45, 55, and 65 °C) and tempering duration (1, 2, and 4 h), while the dependent parameters were seed germination and drying characteristics, including drying rate, total and effective drying operation times, and power requirement. Considering one hybrid and 3 mo storage period after drying, the results showed that samples continuously dried at 45 and 55°C resulted in 91 and 86% germination percentages, respectively, which were above the acceptable Philippine national standard of at least 85%. However, when tempered for …

In-Situ Preparation Of Cofe2o4 Nanoparticles On Eggshell Membrane-Activated Carbon For Microwave Absorption, Hassan Soleimani, Jemilat Yetunde Yusuf, Lee Kean Chuan, Hojjatollah Soleimani, Mustapha Lutfi Bin Sabar, Andreas Öchsner, Zulkifly Abbas, Asmau Iyabo Balogun, Gregory Kozlowski

Physics Faculty Publications

This study explores the potential of using cobalt ferrite (CF) nanoparticles grown in situ on eggshell membranes (ESM) to mitigate the increasing problem of electromagnetic interference (EMI). A simple carbonization process was adopted to synthesize CF nanoparticles on ESM. The study further examines the composites' surface morphology and chemical composition and evaluates their microwave absorption performance (MAP) at X-band frequency. Results showed that the composite of CF and ESM - CESM@CF, exhibited a strong RL peak value of −39.03 mm with an optimal thickness of 1.5 mm. The combination of CF and ESM demonstrates excellent impedance matching and EM wave …

Superconductivity And Fermi Surface Studies Of Β″-(Bedt-Ttf)2[(H2o)(Nh4)2cr(C2o4)3]·18-Crown-6, Brett Laramee, Raju Ghimire, David Graf, Lee Martin, Toby J. Blundell, Charles Agosta

Physics

We report rf-penetration depth measurements of the quasi-2D organic superconductor (Formula presented.) -(BEDT-TTF) (Formula presented.) [(H (Formula presented.) O)(NH (Formula presented.)) (Formula presented.) Cr(C (Formula presented.) O (Formula presented.)) (Formula presented.)]·18-crown-6, which has the largest separation between consecutive conduction layers of any 2D organic metal with a single packing motif. Using a contactless tunnel diode oscillator measurement technique, we show the zero-field cooling dependence and field sweeps up to 28 T oriented at various angles with respect to the crystal conduction planes. When oriented parallel to the layers, the upper critical field, (Formula presented.) T, which is the calculated paramagnetic …

Towards An Understanding Of The Thermodynamic Properties Of Crtao4: A Computational Perspective, Tanner B. Gordon

Theses and Dissertations

Materials that can withstand higher temperatures are paramount for next-generation aircraft design. Hypersonic capabilities and jet-turbine engines operate in extreme environments. Choosing materials that have high thermal stability and oxidation resistance for these applications can increase engine efficiency, reduce size, weight and power (SWaP), and increase the maneuverability of the aircraft. The mixed oxide CrTaO₄ has been experimentally observed to significantly contribute to oxidation resistance at high temperatures. However, and despite its significance, its properties remain largely unknown. This work explores the thermal properties of this material from a multi-scale approach, by obtaining an accurate description of the thermodynamics …

Feasibility Study On The Characterization Of Mars Atmospheric And Surface Features In Spacecraft Images By Machine Learning And Similar Automated Methods, Hind Hassan Alriyami

Theses

This thesis is focused on automated detection of Mars atmospheric and surface features in spacecraft images based on machine learning and similar automated methods using crater detection algorithm (CDA) software, named DeepMars2 algorithm. The purpose of this study is to perform machine learning to detect coarse and high-resolution topography craters on mars. The algorithm is applied to two digital elevation models (DEMs) of the Mars surface with high and coarse resolution in order to identify craters using machine and deep learning methods. The DEMs are based on the satellite instruments MOLA/MGS (Mars Orbiter Laser Altimeter/Mars Global Surveyor) and HRSC/MEX (High …

Description Of Reaction And Vibrational Energetics Of Co2-Nh3interaction Using Quantum Computing Algorithms, Manh Tien Nguyen, Yueh-Lin Lee, Dominic Alfonso, Qing Shao, Yuhua Duan

Markey Cancer Center Faculty Publications

CO2 capture is critical to solving global warming. Amine-based solvents are extensively used to chemically absorb CO2. Thus, it is crucial to study the chemical absorption of CO2 by amine-based solvents to better understand and optimize CO2 capture processes. Here, we use quantum computing algorithms to quantify molecular vibrational energies and reaction pathways between CO2 and a simplified amine-based solvent model—NH3. Molecular vibrational properties are important to understanding kinetics of reactions. However, the molecule size correlates with the strength of anharmonicity effect on vibrational properties, which can be challenging to address using classical computing. Quantum computing can help enhance molecular …

Automated Additive Layering Of Vat Polymerized Plastic Organic Scintillators, Chandler J. Moore

Theses and Dissertations

The current technology for fast neutron detection imaging is limited in achieving the required high spatial resolution, strong neutron discrimination, and practical time of manufacturing. Traditional fabrication methods require days of thermal polymerization and hundreds of man-hours to produce average resolution pixelated scintillator arrays. The present work helps to eliminate this limitation by developing an additive manufacturing technique to construct such detectors for use in in dual particle imaging applications. In this work, fast-, light-curing resins are used in a prototype automated assembly machine, capable of layering of individual light-cured resin layers and optical segmentation with a self-bonded specular reflector, …

Design And Synthesis Of New Acyl Urea Analogs As Potential Σ1r Selective Ligands, R. Thapa, R. Flores, Kwan H. Cheng, Bereket Mochona, Donald Sikazwe

Physics and Astronomy Faculty Research

In search of synthetically accessible open-chain analogs of PD144418 or 5-(1-propyl-1,2,5,6-tetrahydropyridin-3-yl)-3-(p-tolyl)isoxazole, a highly potent sigma-1 receptor (σ1R) ligand, we herein report the design and synthesis of sixteen arylated acyl urea derivatives. Design aspects included modeling the target compounds for drug-likeness, docking at σ1R crystal structure 5HK1, and contrasting the lower energy molecular conformers with that of the receptor-embedded PD144418—a molecule we opined that our compounds could mimic pharmacologically. Synthesis of our acyl urea target compounds was achieved in two facile steps which involved first generating the N-(phenoxycarbonyl) benzamide intermediate and then coupling it with the appropriate amines—weakly to strongly …

Speed Of Sound For Hadronic And Quark Phases In A Magnetic Field, Efrain J. Ferrer, Aric Hackebill

Physics & Astronomy Faculty Publications

In this paper we calculate the speed of sound for three phases that may exist inside a magnetized hybrid neutron star at different density regions: A hadronic phase at low densities, quark-matter in the magnetic dual chiral density wave (MDCDW) phase at intermediate densities and a free-quark phase modeled by the MIT bag model at higher densities. It is found that the speed of sound exhibits a non-monotonic behavior, that goes from values smaller than the conformal limit ( c 2 s < 1 / 3 ) in the hadronic phase, to peak ( c 2 s > 1 / 3 ) in the MDCDW phase, to finally reach the conformal limit ( c 2 s …

Non-Hermitian Floquet-Free Analytically Solvable Time-Dependent Systems, Hamed Ghaemi-Dizicheh, Hamidreza Ramezani

Physics & Astronomy Faculty Publications

The non-Hermitian models, which are symmetric under parity (P) and time-reversal (T) operators, are the cornerstone for the fabrication of new ultra-sensitive optoelectronic devices. However, providing the gain in such systems usually demands precise control of nonlinear processes, limiting their application. In this paper, to bypass this obstacle, we introduce a class of time-dependent non-Hermitian Hamiltonians (not necessarily Floquet) that can describe a two-level system with temporally modulated on-site potential and couplings. We show that implementing an appropriate non-Unitary gauge transformation converts the original system to an effective one with a balanced gain and loss. This …

Designing Polar Textures With Ultrafast Neuromorphic Features From Atomistic Simulations, Sergey Prosandeev, Sergei Prokhorenko, Yousra Nahas, Yali Yang, Changsong Xu, Julie Grollier, Diyar Talbayev, Brahim Dkhil, L. Bellaiche

Physics Faculty Publications and Presentations

This review summarizes recent works, all using a specific atomistic approach, that predict and explain the occurrence of key features for neuromorphic computing in three archetypical dipolar materials, when they are subject to THz excitations. The main ideas behind such atomistic approach are provided, and illustration of model relaxor ferroelectrics, antiferroelectrics, and normal ferroelectrics are given, highlighting the important potential of polar materials as candidates for neuromorphic computing. Some peculiar emphases are made in this Review, such as the connection between neuromorphic features and percolation theory, local minima in energy path, topological transitions and/or anharmonic oscillator model, depending on the …

Insights Into Receptor Structure And Dynamics At The Surface Of Living Cells, Frederik Steiert, Peter Schultz, Siegfried Höfinger, Thomas D. Müller, Petra Schwille, Thomas Weidemann

Michigan Tech Publications, Part 1

Evaluating protein structures in living cells remains a challenge. Here, we investigate Interleukin-4 receptor alpha (IL-4Rα) into which the non-canonical amino acid bicyclo[6.1.0]nonyne-lysine (BCNK) is incorporated by genetic code expansion. Bioorthogonal click labeling is performed with tetrazine-conjugated dyes. To quantify the reaction yield in situ, we develop brightness-calibrated ratiometric imaging, a protocol where fluorescent signals in confocal multi-color images are ascribed to local concentrations. Screening receptor mutants bearing BCNK in the extracellular domain uncovered site-specific variations of both click efficiency and Interleukin-4 binding affinity, indicating subtle well-defined structural perturbations. Molecular dynamics and continuum electrostatics calculations suggest solvent polarization to determine …

Design And Assessment Of A Leo Gnss Miniconstellation For Positioning, Navigation, And Timing (Pnt), Mariya Abdulkhaleq Mohamad

Theses

Recently, there has been a resurgent demand in the United Arab Emirates for more accurate positioning, navigation, and timing signals, especially for some targeted applications such as autonomous vehicles and flying taxis. The existing Global Navigation Satellite Systems (GNSS) provide real-time positioning accuracy for up to several meters, while the targeted applications require fast convergence of centimeterlevel positioning accuracy. Recent studies have shown that transmitting GNSS signals from a Low Earth Orbit (LEO) instead of a Medium Earth Orbit (MEO) would enhance positioning accuracy. The main objective of this thesis is to design and simulate an optimum scenario of a …

The Three-Dimensional Visualization Of Mars Dust Storms Based On Deriving Digital Elevation Maps From Satellite Imagery, Meirah Ali Alzeyoudi

Theses

This work focuses on generating a Three-Dimensional Visualization of Mars's local dust storms utilizing satellite images from publicly available archives. The work aimed to create a Three-Dimensional Visualization of two Local Dust storms, the first local dust storm occurred on May 20, 2020, in the Chryse Planitia Region of Mars, while the second one occurred on 8 June 2021, on the northern side of the Utopia Planitia Region of Mars. The visualization will assist in providing a better understanding of the dynamics of Dust Storms on Mars by indicating and analyzing the main features of dust storms on Mars. Also, …

Generating Synthetic Satellite Images Of Mars Dust Storms Based On Radiative Transfer Models, As A Follow-On Application Of Marswrf Dust Cycle Simulations, Fatima Ali Alkaabi

Theses

Dust is a fundamental component of the Martian atmosphere; it plays a vital role in the planet's climate system and atmospheric variability. For these reasons, it is considered one of the essential keys to understanding the Martian atmosphere's behavior. The dust events on Mars range from local/regional dust storms that occur every Martian year to global dust storms that have only been observed, on average, once every 3-4 Martian years. The large regional and global dust storms have strong thermal and dynamic effects on the atmosphere. MarsWRF is a Mars version of the terrestrial numerical weather and climate model WRF …

Coupling To Quantum Topological Order In Superconducting Qubit Systems, Seth T. Hyra

Theses and Dissertations

The coupling of superconducting qubits to non-trivial topological phases offers a means of improving existing quantum computational capabilities in lieu of a fully realized topological quantum computer. I will show that although such systems do not completely avoid the necessary errors associated with an energetic qubit basis, they do provide a potential avenue for decoherence free quantum memory. Further, the physics behind such systems enables exploration of the nature of non-Abelian anyons, as well as the remaining challenges in realization of true topological quantum computation.

Microbial Motility At The Bottom Of North America: Digital Holographic Microscopy And Genomic Motility Signatures In Badwater Spring, Death Valley National Park, Carl Snyder, Jakob P. Centlvre, Shrikant Bhute, Jay Nadeau, Multiple Additional Authors

Physics Faculty Publications and Presentations

Motility is widely distributed across the tree of life and can be recognized by microscopy regardless of phylogenetic affiliation, biochemical composition, or mechanism. Microscopy has thus been proposed as a potential tool for detection of biosignatures for extraterrestrial life; however, traditional light microscopy is poorly suited for this purpose, as it requires sample preparation, involves fragile moving parts, and has a limited volume of view. In this study, we deployed a field-portable digital holographic microscope (DHM) to explore microbial motility in Badwater Spring, a saline spring in Death Valley National Park, and complemented DHM imaging with 16S rRNA gene amplicon …

A Simple In Situ Method For Optimizing Settings For The Einzel Lens Elements In A Focused Ion Beam, Rich Swinford, Erik Sanchez

Physics Faculty Publications and Presentations

Ion beams have had an incredible impact on research in the past couple of decades. One major reason for this is the continued development of systems having optimal beam currents that allows one to image more clearly at different spot sizes to include higher currents that allow for faster milling. The advancements for Focused ion beam (FIB) columns have developed rapidly due to the computational optimization of lens designs. However, once a system has been produced, the optimal column settings for these lenses may change or simply become obscure. Our work involves regaining this optimization with the newly applied values …

Characterizing Gesn Alloys By Sem/Eds And Photoluminescence Spectroscopy, Christopher M. Sutphin

Theses and Dissertations

Germanium tin (GeSn) alloys are being studied as potential transition metal (Group IV) photoelectric semiconductors or optical detectors. GeSn alloys could be employed as an optically active material within a computer. Compared to current technologies, a direct band gap GeSn alloy can be engineered to operate with higher thermal stability and efficiency. The GeSn alloy studied was composed of Ge and Si substrates with various Sn percentages grown using remote plasma-enhanced chemical vapor deposition (RPECVD). Photoluminescence spectroscopy (PL) techniques were initially used to determine the GeSn properties, including the band gap. The Ge_91.2Sn_8.8 PL spectra suggested the …

Simulation Of Neutron Generation From Laser-Driven Fusion In A Liquid D2o Sheet Using Novel Warpx Module, Colton R. Stoner

Theses and Dissertations

Using WarpX’s new nuclear fusion module, this work attempts to model an experimental system at the ELL at the AFIT with WarpX and draw conclusions about fusion products from resulting simulations. Recently, a table-top, high repetition rate, mixed radiation source was demonstrated at the ELL employing a HIL to fuse the deuterium nuclei present in a unique liquid target of heavy water. Analysis of the simulations predicted an isotropic output of neutrons from deuterium-deuterium fusion. These simulated neutrons were created in tens of femtoseconds from dense bodies of deuterons that were perturbed by the laser. However, it was found that …

Modeling Radiation Exposure On Flight Missions To Analyze Aircrew Risk, Camila V. Quintero Hilsaca

Theses and Dissertations

GCR and SPE comprise the majority of the ionizing radiation experienced in the upper atmosphere within flight-altitude environments. Although previous studies have analyzed radiation doses from single sources on civilian flight operations, there is a lack of research focused on dose received by military personnel during flight from both sources simultaneously. In-flight radiation environments are modeled through the MCNP6 for two separate aircraft, an Air Force A-10 and a Boeing 737. Particle fluence values for galactic cosmic rays and solar particle events for four separate flight paths are determined using the CARI-7A software and the SIRE2 toolkit, respectively. MCNP6 code …

Pulsed Power Neutron Production With Deuterated Polymer Accelerator Targets, Anthony O. Hagey

Theses and Dissertations

This document presents an investigation of the effect of deuterated polyethylene accelerator targets on the neutron fluence from a local mass injection dense plasma focus driven by the United States Naval Research Laboratory’s Hawk pulsed-power generator. After successful production of thin targets, the acquisition of thicker targets, and testing inside Hawk, it was found that the presence of a deuterated polyethylene target increased the neutron fluence. Results suggested that fluence can significantly increase with the presence of a deuterated target vs a nondeuterated target. Additive manufacturing printing was used as a production method in order to determine if deuterated accelerator …

Spectral Material Classification Of Orbital Objects - Applying Machine Learning To Visible And Near-Infrared Spectral Scenes, Stephen M. Stumpf

Theses and Dissertations

MSI and HSI techniques allow users to determine the material composition of an object at range. To avoid labor-intensive manual classification, ML is used to determine the most likely material contained in a given pixel of a target image. Previous work primarily focuses on terrestrial applications; this paper extends these techniques into the low-illumination space situational awareness domain, which is of critical importance to national security. HSI datacubes are preprocessed with RL deconvolution as a means of reducing the effects of the optical PSF; then, statistical ML techniques, including k-NN, LDA, QDA, and SVMs are implemented as means of assigning …

Analog Holographic Wavefront Sensor For Defocus And Spherical Aberration Measurement Recorded In A Photopolymer, Emma Branigan, Suzanne Martin, Matthew Sheehan, Kevin Murphy

Articles

An analog holographic wavefront sensor (AHWFS), for measurement of low and high order (defocus and spherical aberration) aberration modes has been developed as volume phase holograms in a photopolymer recording medium. This is the first time that high order aberrations such as spherical aberration can be sensed using a volume hologram in a photosensitive medium. Both defocus and spherical aberration were recorded in a multi-mode version of this AHWFS. Refractive elements were used to generate a maximum and minimum phase delay of each aberration which were multiplexed as a set of volume phase holograms in an acrylamide based-photopolymer layer. The …