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Homogeneous Nucleation Of Water Vapor In Inert Gas Atmospheres, Arthur Henry Biermann

Doctoral Dissertations

"The homogeneous nucleation of water vapor in atmospheres of helium, neon, argon, krypton, and xenon was studied using an expansion type cloud chamber. A strong dependence of the nucleation rate on the particular inert carrier gas was observed. At present the only dependence upon the nature of the carrier gas included in classical nucleation theories is a small factor arising from kinetic considerations which is in the wrong direction to explain the observations. To explain the dependence of the rate on the nature of the carrier gas, a molecular cluster model is assumed allowing inert gas atoms to occupy the …

Surface Plasmon-Longitudinal Optical Phonon Contribution To The Reflectivity Of N-Type Insb, William Eugene Anderson

Doctoral Dissertations

"The reflectivity of n-type InSb has been measured in the far infrared. The doping of the samples was such that the free-carrier plasma frequency was near the longitudinal optical phonon frequency. The results suggest that samples with a sufficiently thick damage layer show effects due to surface plasmons. The results also indicate that the surface plasma excitations are coupled to the phonons. A simple model of this coupling is presented which agrees qualitatively with the observed reflectivity. A somewhat more rigorous theory of the coupling is also presented"--Abstract, page ii.

Absolute Cross Sections For Excitation Of Neon By Impact Of 20-180 Kev H , H₂ And He Ions, George William York

Doctoral Dissertations

"The technique of heavy-ion energy-loss spectrometry has been used to measure excitation cross sections for the (2p⁵)3s and (2p⁵)3p electronic configurations of Neon. The incident particles used were H⁺ , H⁺₂ and He⁺ at impact energies from 20-180 keV. The results are compared with previous optical measurements of the emission cross sections of lines from these levels as excited by H⁺ and He⁺ impact. Agreement is not good, either in shape or in absolute magnitude for excitation of the (2p⁵)3s configuration. However, agreement is surprisingly good for excitation of the (2p⁵)3p configuration. A curve fitting technique has been applied to …

Mössbauer Studies Of Bifeo₃-Pbtio₃ Perovskite-Type Solid Solutions, C. M. Yagnik, Robert Gerson, William Joseph James

Physics Faculty Research & Creative Works

The Mössbauer spectra of the ferroelectric solid solutions (BiFeO₃)_x(PbTiO)1-x have been studied as a function of temperature, mainly between room temperature and 600°C, using ⁵⁷Fe in the solutions as an absorber. The quadrupole splitting increased and the isomer shift decreased between x = 0.05 and x = 0.70, a range in which the solutions are tetragonal and paramagnetic, and in which the unit cell volume increases with increasing x. The isomer shift, in particular, was primarily determined by the unit cell volume. Data are presented on the internal magnetic field of the antiferromagnetic …

MöSsbauer Studies Of Stable Interstitial And Substitutional Sites Of Cobalt In Gold, Charles Freeland Steen

Dissertations and Theses

Precision measurements of the Debye-Waller factor of Fe⁵⁷ in Au using the wide black absorber technique have been made in the temperature range from room temperature to 830 K. The major source of error arises from Au L_y x-rays which are unresolved by the radiation detection system from the 14.4 KeV gamma ray. The K absorption edge of Br has been used to correct for the presence of x-rays.

These measurements have revealed the existence of two nonequivalent lattice sites which the Co⁵⁷ impurity (parent of Fe⁵⁷) may occupy. One of the sites has been …

Local Magnetic Moments And The Mossbauer Effect, Richard B. Frankel, Brian B. Schwartz

Physics

No abstract provided.

Thermal Expansivity And Refractive Index Determinations For Some Hydrosol Systems And Their Similarity To Properties Ascribed To "Anomalous" Water, Gerald Wayne Chappue

Masters Theses

"The characteristic thermal expansion and refractive index of aqueous dispersions of SiO₂ and NaOH were determined for samples contained in quartz micro-capillaries. Comparison is made with the expansivity and refractive properties of anomalous water or polywater as reported by other investigators. The similarity between the properties and behavior of various hydrosol systems and those ascribed to anomalous water is cited as a serious challenge to the hypothesized existence of an allotropic modification of water"--Abstract, page ii.

Interplanar Force Constants Of Symmetry Planes In Close-Packed Structures, Paul G Khoury

Archived Theses and Dissertations

No abstract provided.

Surface Plasmons And The Reflectivity Of N-Type Insb, William E. Anderson, Ralph William Alexander, Robert John Bell

Physics Faculty Research & Creative Works

The Reflectivity of N-Type InSb Has Been Measured in the Far Infrared. the Doping of the Samples Was Such that the Free-Carrier Plasma Frequency Was Near the LO Mode Frequency. the Results Suggest that Samples with a Sufficiently Thick Damage Layer Show Effects Due to Surface Plasmons. Use of a Simple Model Indicates that the Surface-Plasma Excitations Are Coupled to the Phonons. © 1971 the American Physical Society.

Comparison Of Experimental And Theoretical Values Of Cross Sections For Electron Production By Proton Impact, M. Eugene Rudd, D. Gregoire, J. B. Crooks

M. Eugene Rudd Publications

Angle and energy distributions of electrons ejected from single- and multishell atoms by 50-to 300-keV protons are compared with various theoretical treatments. Partial cross sections for each subshell are calculated by scaling according to the number of electrons and the binding energy and then are added. The Born approximation fails at large and at small angles but yields fair agreement at intermediate angles. The treatments of Salin and of Macek, which take account of the influence of the projectile after the collision, yield much improved agreement at small angles. The binary-encounter model is used to calculate cross sections which are …

X-Ray And Mössbauer Spectroscopy Studies Of The Silicon-Antimony And Bismuth-Antimony Alloys, James Ralph Teague

Doctoral Dissertations

"X-ray and Mossbauer spectroscopy were used to investigate two antimony alloys, Bi-Sb and Si-Sb, showing semiconductorsemimetallic transitions or vice versa, depending on the antimony concentration in the host lattice. Resistivity and density measurements were found to be helpful in the analysis of the results. X-ray studies for dislocation-free antimony-doped silicon showed that the lattice constant of the alloy increased as the antimony concentration increased from 10¹⁸ to 10¹⁹ Sb atoms/cc. Rather good agreement was found between theoretical and experimental changes in lattice constant for dislocation-free silicon. Mössbauer studies showed that the isomer shift decreased linearly with increasing antimony concentration, which …

Theory Of Nucleation Of Water Properties Of Some Clathrate Like Cluster Structures, Mehdi Daee

Doctoral Dissertations

"The tranquility of classical homogeneous nucleation theory has been disturbed by the introduction of statistical mechanical correction factors to a basically thermodynamic theory. These factors, which appear to be essential, destroy much of the agreement with experiment in the case of water vapor. A molecular model for the pre-nucleation water clusters is proposed with a view toward resolving some of these difficulties. As a first step, the Properties of a few specific cluster configurations have been examined. Clathrate-like structures containing 16 to 57 water molecules are discussed. The hydrogen bonds were treated as simple harmonic oscillators for the purpose of …

Photoionization Of Photoexcited Cesium, Robert E. Hebner

Doctoral Dissertations

"A new method for obtaining the cross section for photoionization of photoexcited cesium is presented. The salient feature of this experiment is to use three crossed beams, i.e., two light beams intersecting a beam of cesium atoms. The cross section is determined by counting the ions produced by the two step process: Cs (6S) + h[upsilon]₁ --> Cs (6P) ; Cs (6P) + [upsilon]₂ --> Cs⁺ + e⁻ The relative cross section for the second step has been obtained from threshold (5060 Å) to 2500 Å. The excitation light source used in obtaining this cross section was a rf resonance …

Mossbauer Study Of An Intramolecular Antiferromagnet, R. Lechan, C. R. Abeledo, R. B. Frankel

Physics

Mossbauer measurements at 4.2 ≤T ≤ 22 K and OsHosBO kOe are + reported in (Fe Salen Cl)₂, a molecular complex containing two coupled Fe³⁺ ions bridged by oxygen atoms. At 4.2 K only the ground state with effective spin S = 0 is appreciably populated. Analysis of the magnetic field and temperature dependence of the magnetic hyperfine field yields an exchange constant J= -6.7 cm>sup>-1 and a hyperfine field of -192 kOe per unit spin at each Fe³⁺ nucleus.

Calculation Of Anisotropic Hyperfine Constants For Lattice Nuclei Near A Shallow Donor, Edward B. (Boyd) Hale, Robert Lee Mieher

Physics Faculty Research & Creative Works

A method is presented for calculating the magnetic anisotropic (dipolar) hyperfine constants for lattice nuclei near a shallow-donor impurity. The method assumes that the wave function of the donor electron can be expressed in an effective-mass form, i.e., a slowly varying envelope function times conduction-band Bloch functions. For each dipolar hyperfine constant, two separate calculations are performed. One calculation is for a local region about the lattice nucleus of interest. The greatest part of the interaction occurs in this region (about 85 ± 10%). The second calculation is for the more distant region. The dipolar constants in the distant region …

Second- And Third-Order Elastic Constants Of Aluminum And Lead, Tetsuro Suzuki

Physics Faculty Research & Creative Works

The second- and third-order elastic constants of Al and Pb are calculated as the second and third derivatives of the binding energy with respect to the finite deformation parameter. The binding energy is derived from a local pseudopotential by use of second-order perturbation theory. It is shown that the binding energy satisfied not only the diagonal equilibrium condition, but also the off-diagonal equilibrium condition, i.e., the first derivative of the binding energy with respect to a volume change as well as with respect to shear deformations is zero. Accordingly, the present method of calculation is based on a stable lattice …

Magnetostriction And Magnetic Breakdown In Cadmium, J. M. Carter, Don M. Sparlin

Physics Faculty Research & Creative Works

Studies of the monotonic magnetostriction of cadmium at 4.2 °K in applied magnetic fields to 70 kG have shown that the angular variation of an extremal point Hm is proportional to secθ. The magnitude of Hm is in close agreement with the onset of a breakdown orbit γ13 observed for the applied field within 35 °of the c axis. The range of observation of Hm coincides with the range of the orbit γ. © 1971 The American Physical Society.

Absolute Excitation Cross Sections Of He+ In 20-100-Kev He+-He Collisions Using Energy-Loss Spectrometry, D. R. Schoonover, John T. Park

Physics Faculty Research & Creative Works

Application of positive-ion energy-loss spectrometry has been extended to include experimental determination of absolute excitation cross sections of ground-state helium ions. Helium ion-atom collisions were studied for impact energies ranging between 20-100 keV, in 10-keV intervals. The data were taken with an apparatus resolution between 0.6-0.8 eV full width at half-maximum (FWHM). Cross sections for transitions from ground state to the second and third principal quantum levels of the ion plotted as a function of impact energy were still rapidly increasing at 100 keV. The cross sections at this energy were (1.64 ± 0.28) x 10-18 cm2 for He+(1s122)→He+ (n=2) …

Collision Cross Sections For The Excitation Of The Schumann-Runge Dissociation Continuum In Molecular Oxygen By 20-110-Kev Protons, John T. Park, F. D. Schowengerdt, D. R. Schoonover

Physics Faculty Research & Creative Works

Absolute cross sections for the excitation of the Schumann-Runge dissociation continuum of molecular oxygen have been obtained from inelastic energy-loss spectra induced by 20-110-keV protons incident on gaseous targets of molecular oxygen. Apparent differential energy loss cross sections, ionization cross sections, and total inelastic cross sections are also obtained from the energy-loss spectra. The proton energy-loss spectra have an energy resolution of about 2 eV. The energy location of the first peak in the energy-loss spectra of O2 is in general agreement with the findings of photo absorption and electron energy-loss-spectra measurements. The cross section for the Schumann-Runge dissociation continuum …

Nuclear Magnetic Resonance Investigation Of The Metal-To-Semiconductor Transition In Crystalline Cdo, R. P. Benedict, David C. Look

Physics Faculty Publications

Measurements of the Cd¹¹³ nuclear-spin-lattice relaxation time (T₁) and resonance frequency shift (K) were carried out in several samples of polycrystalline n-type CdO over the temperature (T) range 1.4-300°K, frequency (ν) range 2-10 MHz, and carrier concentration (N_e) range 3.3-44×10¹⁸ cm^-3. For N_e>10¹⁹ cm^-3, we find that T₁∝N_e^-2/3T^-1 and K∝N_e^1/3, showing that the nuclei are interacting with degenerate conduction electrons. Furthermore, the Korringa relationship holds and the calculated electron density at a nucleus is almost the same as …

Nuclear Orientation Of 253Es In Neodymium Ethylsulfate, A. J. Soinski, Richard B. Frankel, Q. O. Navarro, D. A. Shirley

Physics

Einsteinium-253 nuclei were oriented at low temperatures in a neodymium ethylsulfate lattice. From the temperature-dependent α-particle angular distribution a nuclear magnetic moment |μ|=(2.7±1.3)μ_N was deduced. From the values for the angular distribution function at the lowest temperatures it was possible to test the predictions of the Mang shell-model theory for the relative phases and amplitudes of the α-partial waves. As predicted, the waves of angular momentum L=0 and 2 are in phase, and the L=0 and 4 waves are out of phase. The predicted wave amplitudes are in error, especially that of the L …

Perturbation Theory Of The Hooke's Law Model For The Two‐Electron Atom, Ronald White, W. Byers Brown

Center for Advanced Mineral and Metallurgical Processing (CAMP)

The Hooke model for the two‐electron atom replaces the electron–nuclear interaction by a harmonic oscillator potential, but retains the Coulomb repulsion of the electrons. The first‐order perturbation equation for the electron repulsion is solved analytically, and the exact first‐, second‐, and third‐order perturbation energies are obtained. A similar Z^-1 perturbation treatment is carried out for the Hartree–Fock equation and other variational approximations. The Z^-1 of the correlation energy is compared with that for helium-like atoms and found to be similar.

Excitation Of The (2P2)3P State Of Helium Near Threshold, Paul Burrow

Paul Burrow Publications

The trapped-electron method is applied to the excitation by electron impact of the (2p²)³P state, the lowest doubly excited state of helium which is stable against auto-ionization. The energy of this state, 59.64±0.08 eV, is in good agreement with theory. An estimate of the slope of the total cross section for excitation of the (2p²)³P state at threshold gives a value of 4 × 10^-20 cm²/eV.

Doppler Shift In Frequency In The Transport Of Electromagnetic Waves Through An Underdense Plasma, Jerry Peacher, Kenneth M. Watson

Physics Faculty Research & Creative Works

In an earlier publication, the validity of the radiation transport theory was studied for the calculation of multiple scattering of electromagnetic waves by a turbulent plasma. In the present paper, we extend the transport theory to include a description of the Doppler shift in frequency caused by electron motion.

Are There Magnetic Moments At The Transition Metal Sites In Feal, Coal, And Nial?, Richard B. Frankel, D. J. Sellmeyer, N. A. Blum

Physics

Measurements of the hyperfine interactions in ⁵⁷Fe in the CsCl structure intermetallic compounds FeAl, CoAl and NiAl are reported.

Investigation Of The Alpha-Sub-Gamma Phase In Alnico 6, Cortez Samuel

Dissertations and Theses

The purpose of this research project was to study the αᵧ phase in Alnico 6. Other phases were studies for comparison. Also the effect of an applied magnetic field on the formation of the αᵧ phase was investigated.

Three single crystals of Alnico 6 were heat treated for one hour--one at 1250°C, one at 1000°C, and one at 800°C--and water-quenched. The microstructure of each sample was observed with the optical microscope, and X-ray diffraction patterns were taken to determine the crystal structure of the phases present.

Several single crystal samples of Alnico 6 were heat treated at 1000°C and furnace-cooled. …

De Haas-Van Alphen Effect In Dilute Beryllium-Copper Alloys , I.S. Goldstein, David J. Sellmyer, B.L. Averbach

David Sellmyer Publications

The de Haas-van Alphen effect was investigated in pure beryllium and in Be-Cu alloys containing up to 0.34 at.% Cu. The extremal cross-sectional areas of the cigar-shaped third-band electron pieces of Fermi surface decreased with alloying. The areas of the coronet-shaped second-band hole piece increased with alloying. The magnitude of the area changes were compared with rigid-band-theory predictions. Corrections for lattice-parameter changes were included when possible. In the low-concentration limit, the theory is able to account for the observed area changes. For the highest-concentration alloy, there are deviations, for all areas measured, to greater changes than are predicted by the …

Transient Optical Absorption By Self-Trapped Excitons In Alkali Halide Crystals, Robert Fuller, R.T. Williams, M.N. Kabler

Robert G. Fuller Publications

Transient absorption spectra produced by pulsed electron excitation at low temperature have been identified as due to transitions originating in the lowest triplet states of the self-trapped exciton. The current model, comprising an electron plus a self-trapped hole, is shown to provide electronic configurations for the higher excited states which give a good account of the principal features of the spectra.

12th Annual Rocky Mountain Spectroscopy Conference

Rocky Mountain Conference on Magnetic Resonance

Program and abstracts from the 12th annual meeting of the Rocky Mountain Spectroscopy Conference, sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 3-4, 1970.

X-Ray Induced Luminescence Of Sapphire And Ruby, Ivan Collier Jr.

Masters Theses & Specialist Projects

Over the past decade the luminescence properties of sapphire (∝-AL₂O₃) and ruby (Al₂O₃:Cr₂O₃) have been the subject of many investigations because of their importance in materials technology. Sapphire and ruby are at present used as lasing materials, radiation dosimeters, and as optical windows. In order that these operations may be made more efficient, and that other useful luminescent properties may be systematically explored and developed, much attention has been given to understanding the luminescent mechanisms from the standpoint of the physics of the solid state. However, mechanisms have …