Digital Commons Network^™

Spectroscopic And Kinetic Studies Of Bismuth Dimers, Robert Eugene Frankin

Theses and Dissertations

The spectroscopy of high rotational levels (J ≤ 211) in Bi₂ X(O_g⁺) and A(O_u⁺) was investigated for 2≤v"≤5 and 0≤v'≤4 by observing total fluorescence from laser excitation. Dunham coefficients were derived that fit all observed rotational lines to within 0.01 cm^-1. Franck-Condon factors were calculated and experimentally verified for transitions originating from the initially populated levels 0≤v'≤5. Vibrational energy transfer upon collision with rare gas collision partners was investigated for the low-lying vibrational levels of the A-state using spectrally resolved, continuous wave laser induced fluorescence. Vibrational transfer was adequately modeled by …

Characterization Of Iron Oxides And Atmospheric Corrosion Of Steel, Sei Jin Oh

Physics Theses & Dissertations

The study of corrosion behavior was performed using three different analytical techniques, which provided information on the formation, development and layering of iron oxides on the corrosion products as a function of atmospheric conditions, exposure time and type of steel. In particular, the protective layer formed on weathering steel was investigated as a function of different amounts of alloying elements in the steel, atmospheric conditions and exposure times. Combined together, the results provided a better understanding of the atmospheric corrosion behavior of steel, and formed a part of database of the atmospheric corrosion characteristics.

Accurate characterization of the iron oxides …

Inner-Shell Excitation Spectroscopy Of Closo-Carboranes, Adam P. Hitchcock, Stephen G. Urquhart, Alex T. Wen, A. L. David Kilcoyne, Tolek Tyliszczak, Eckart Rühl, Nobuhiro Kosugi, John D. Bozek, James T. Spencer, David N. Mcilroy, Peter A. Dowben

Peter Dowben Publications

Oscillator strength spectra in the region of B 1s and C 1s excitation of three isomeric carborane cage compounds [closo-1,2-orthocarborane, closo-1,7-metacarborane, closo-1,12-paracarborane (C₂B₁₀H₁₂)] have been derived from inner-shell electron energy loss spectra (ISEELS) recorded under electric dipole-scattering conditions. Total ion yield spectra recorded at high resolution with synchrotron radiation are also reported. The spectral features are assigned on the basis of comparisons with spectral predictions derived from the results of ab initio and semiempirical (extended Hückel) molecular orbital calculations. The isomeric and core level variations in the discrete core excitations …

Radial Dose Model Of Ssb, Dsb, Deletions And Comparisons To Montecarlo Track Structure Simulations, Francis A. Cucinotta, H. Nikjoo, J. W. Wilson, Robert Katz, D. T. Goodhead

Robert Katz Publications

The initial lesions formed in DNA by ionizing radiation include base damage, single strand breaks (SSB), double strand breaks (DSB), DNA cross links, and deletions. Deletions occur through energy deposition and perhaps more importantly through recombination repair of DSB's. Several mechanisms for the formation of DSB's and deletions related to energy deposition can be considered. Track simulation codes have indicated the importance of clusters of ionizations in small volumes similar to the size of a nucleosome. These clusters have been related to several types of damage to DNA, including DSB and deletions resulting from multiple DSB's formed by single electron …

Electron-Impact Ionization Cross Sections Of Atmospheric Molecules, Y.-K. Kim, W. Hwang, N. M. Weinberger, M. A. Ali, M. Eugene Rudd

M. Eugene Rudd Publications

A theoretical model for electron-impact total ionization cross sections, which has been found to be reliable for a wide range of molecules, is applied to molecules of interest to atmospheric science. The new theory, the binary-encounter-Bethe (BEB) model, combines the binary encounter theory and the Bethe theory for electron-impact ionization, and uses simple theoretical data for the ground state of the target molecule, which are readily available from molecular structure codes. Total ionization cross sections of 11 molecules, CS, CS₂, COS, CH₄, H₂S, NH₃, NO₂, N₂O, O_{3 …}

Lithium Bonding Interaction In H2Cy⋯Lif (Y=O,S) Complexes: A Theoretical Probe, Salai Cheettu Ammal, P. Venuvanalingam, S. Pal

Faculty Publications

Ab initio calculations at 6-31++G(d,p) level have been done on H2CY⋯LiF (Y=O,S) complexes choosing ten possible orientations in each complex. The effect of correlation on complex binding energies has been studied via single point MP2 (full) calculations done on 6-31++G(d,p) geometry. Binding energies have been corrected for basis set superposition error. Frequency calculations confirm that H2CO⋯LiF and H2CS⋯LiF complexes have three and two stable forms, respectively. The most stable form in each complex has been found to have a strong lithium bonding interaction and a secondary hydrogen bondinginteraction. NBO analysis has revealed that in this form oxygen donates nσ lone …

A System For Collecting Milligram Quantities Of Cloud Condensation Nuclei, Darryl J. Alofs, Donald E. Hagen, Steven D. Medley, Daniel R. White, John L. Schmitt, Allen L. Williams

Mechanical and Aerospace Engineering Faculty Research & Creative Works

An Experimental System to Collect Cloud Condensation Nuclei (CCN) Onto Filters in Amounts Sufficient for Chemical Analysis is Described. This Experimental Apparatus is Designed to Process Ambient Air at a Rate of More Than 1 M3/min. Two Identical Systems Have Been Built. One is Installed in a Laboratory at Rolla, MO. the Other is Installed on an 11 M Long Trailer. the System Isolates Three Size Classes of CCN, Having Mass Median Diameters of 0.27, 0.12, and 0.075 Μm, Respectively, and Mass Collection Rates of 11.5, 1.28, and 0.13 Mg/day, Respectively. the above Sizes and Collection Rates Are Obtained from …

The Zeus Leading Proton Spectrometer And Its Use In The Measurement Of Elastic Ρ0 Photoproduction At Hera, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. R. Okrasiński, J. Repond, R. Stanek, R. L. Talaga, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, P. Bruni, G. Cara Romeo, G. Castellini, M. Chiarini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti

Faculty Publications

The differential cross section dσ/dt for elastic ρ0 photoproduction, γp → ρ0ρ (ρ0 → π+π-), has been measured in ep interactions at HERA. The squared four-momentum exchanged at the proton vertex, t, has been determined directly by measuring the momentum of the scattered proton using the ZEUS Leading Proton Spectrometer (LPS), a large scale system of silicon micro-strip detectors operating close to the HERA proton beam. The LPS allows the measurement of the momentum of high energy protons scattered at small angles with accuracies of 0.4% for the longitudinal momentum and 5 MeV for the transverse momentum. Photoproduction of ρ0 …

Measurement Of Inelastic J/Ψ Photoproduction At Hera, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti

Faculty Publications

No abstract provided.

Study Of Photon Dissociation In Diffractive Photoproduction At Hera, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti

Faculty Publications

Diffractive dissociation of quasi-real photons at a photon-proton centre of mass energy of W ≈ 200 GeV is studied with the ZEUS detector at HERA. The process under consideration is γp → XN, where X is the diffractively dissociated photon system of mass MX and N is either a proton or a nucleonic system with mass MN < 2 GeV. The cross section for this process in the interval 3 < MX < 24 GeV relative to the total photoproduction cross section was measured to be σDpartial/σtot = 6.2 ± 0.2(stat) ± 1.4(syst)%. After extrapolating this result to the mass interval of mφ2 < MX2 < 0.05W2 and correcting it for proton dissociation, the fraction of the total cross section attributed to single diffractive photon dissociation, γp → Xp, is found to be σSD/σtot = 13.3 ± 0.5(stat) ± 3.6(syst)%. The mass spectrum of the dissociated photon system in the interval 8 < MX < 24 GeV can be described by the triple pomeron (IP IP IP) diagram with an effective pomeron intercept of αIP(0) = 1.12 ± 0.04(stat) ± 0.08(syst). The cross section for photon dissociation in the range 3 < MX < 8 GeV is significantly higher than that expected from the triple pomeron amplitude describing the region 8 < MX < 24 GeV. Assuming that this discrepancy is due to a pomeron-pomeron-reggeon (IP IP IR) term, its contribution to the diffractive cross section in the interval 3 < MX < 24 GeV is estimated to be fIP IP IR = 26 ± 3(stat) ± 12(syst)%. © Springer-Verlag 1997.

Comparison Of Zeus Data With Standard Model Predictions For E+P → E+X Scattering At High X And Q2, J. Breitweg, M. Derrick, D. Krakauer, S. Magill, D. Mikunas, B. Musgrave, J. Repond, R. Stanek, R. L. Talaga, R. Yoshida, H. Zhang, Margarita C. K. Mattingly, F. Anselmo, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, G. Castellini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, I. Gialas, P. Giusti, G. Iacobucci, G. Laurenti

Faculty Publications

Using the ZEUS detector at HERA, we have studied the reaction e+p → e+X for Q2 > 5000 GeV2 with a 20.1 pb-1 data sample collected during the years 1994 to 1996. For Q2 below 15000 GeV2, the data are in good agreement with Standard Model expectations. For Q2 > 35000 GeV2, two events are observed while 0.145 ± 0.013 events are expected. A statistical analysis of a large ensemble of simulated Standard Model experiments indicates that with probability 6.0%, an excess at least as unlikely as that observed would occur above some Q2 cut. For x > 0.55 and y > 0.25, four …

Reflections On The Gao Report On The Nuclear Triad, David W. Hafemeister

Physics

Senate Hearings on the GAO report on the nuclear triad and on the START treaty showed that vulnerabilities of the U.S. triad were vastly over‐stated, that the performance of new projected strategic systems was over‐estimated, and that the performance of existing U.S. strategic systems was under‐estimated. These exaggerations enhanced the psychological (Freud) aspects of the Cold War and compromised logic (Newton).

With the end of the Cold War it is imperative that we re‐examine the basic premises that guided the choices of the strategic nuclear systems. The initial bottom line is that these systems were successful in that they did …

Review Of The Nuclear Black Market, Global Organized Crime Project, David W. Hafemeister

Physics

No abstract provided.

Three-Dimensional Direct Simulation Monte Carlo Method For Slider Air Bearings, Alejandro Garcia, W. Huang, D. B. Bogy

Faculty Publications

The direct simulation Monte Carlo (DSMC) method is used to solve the three-dimensional nano-scale gas film lubrication problem between a gas bearing slider and a rotating disk, and this solution is compared to the numerical solution of the compressible Reynolds equations with the slip flow correction based on the linearized Boltzmann equation as presented by Fukui and Kaneko [molecular gas film lubrication (MGL) method] [ASME J. Tribol. 110, 253 (1988)]. In the DSMC method, hundreds of thousands of simulated particles are used and their three velocity components and three spatial coordinates are calculated and recorded by using a hard-sphere collision …

Summing Up: Questions And Answers On The Comprehensive Test Ban Treaty, David W. Hafemeister

Physics

My experiences with the ratification of the Strategic Arms Reduction Treaty, the Threshold Test Ban Treaty, and the Conventional Armed Forces in Europe Treaty have led me to conclude that presenting technical issues early in the process greatly reduces their politicization during the ratification end game. This chapter summarizes the important issues that will be raised during the debate on ratification of the Comprehensive Test Ban Treaty. It uses a compact question and answer format to cover the following topics: I. Nuclear Proliferation, II. Nuclear Arms Control, III. Warhead Reliability and Yield for National Security, IV. Warhead Safety, V. Verification, …

A Child's Flashlight And Rc Circuit Concepts, Matthew J. Moelter, Rand S. Worland

Physics

No abstract provided.

Effect Of Diurnal Convection On Trapped Thermal Plasma In The Outer Plasmasphere, Mark Anthony Reynolds, G. Ganguli, J.A. Fedder, D.J. Melendez-Alvira

Publications

A kinetic, multi‐species model of the plasmasphere is constructed that includes the effect of convection and corotation electric fields on trapped particles in drifting flux tubes. The resulting morphology of the outer plasmasphere is significantly different from the morphology obtained using the assumption of diffusive equilibrium. The difference is due primarily to the contraction and expansion of the region of velocity space accessible to the trapped particles, and has implications for the interpretation of remote sensing experiments.

Harmonic Oscillation In The Presence Of Multiple Damping Forces, Chris Pelto '97

Honors Projects

The relatively mundane damped harmonic oscillator is found to exhibit interesting motion once under the influence of both a velocity dependent and a Coulombic frictional damping force. Data for the decay of the amplitude as a function of time were collected on a specially prepared torsional oscillator. with a variable electromagnetic damping mechanism. An analytical solution of the appropriate equation of motion was obtained by the method of Laplace transforms. In both the limits of zero Coulombic friction and zero velocity damping, the solution reduces to the well-known answers to the problem. the solution, when plotted with the correct parameters, …

Droplet Concentration And Size Distribution In Haze And Fog, Josef Podzimek

Physics Faculty Research & Creative Works

Fog (haze) droplet concentrations and size distributions were measured at five sampling sites representing rural and urban regions and a highly polluted marine-urban environment. Droplet imprints in a thin gelatine layer were evaluated and compared to the measurement by light scattering instruments. This enabled conditions for the application of the logarithmic-normal size distribution and for the classification of typical fog droplet size distributions to be established. In particular, the parameters featuring the width and asymmetry of a size distribution were suggested and calculated. Advantages and drawbacks of the applied droplet sampling and evaluation technique are discussed in more detail. © …

Velocity Space "Snapshots" Of Continuum Electrons Produced By Slow, Bare, Highly Charged Ions: Saddle-Point Electrons?, M. Abdallah, S. Kravis, C. L. Cocke, Y. D. Wang, M. Stöckli, Ronald E. Olson

Physics Faculty Research & Creative Works

Comprehensive velocity-space "snapshots" of the electron continua produced by the impact of ions on He at a projectile velocity of 1.63 a.u. have been measured for the bare projectiles of p, He, C, O and Ne. For the three highly charged ions, this velocity lies in the "ionization threshold" region where electron capture dominates the reaction. The experimental technique projects the distribution of soft continuum electrons onto a two-dimensional detector in such a way that the velocity-space distribution for all electrons with laboratory energies in the range from 0-30eV is accurately imaged. The data show no evidence for a saddle-point …

The Effect Of Three-Dimensional Freestream Disturbances On The Supersonic Flow Past A Wedge, Peter W. Duck, D. Glenn Lasseigne, M. Y. Hussaini

Mathematics & Statistics Faculty Publications

The interaction between a shock wave (attached to a wedge) and small amplitude, three-dimensional disturbances of a uniform, supersonic, freestream flow are investigated. The paper extends the two-dimensional study of Duck et al. [P W. Duck, D. G. Lasseigne, and M. Y. Hussaini, ''On the interaction between the shock wave attached to a wedge and freestream disturbances,'' Theor. Comput. Fluid Dyn. 7, 119 (1995) (also ICASE Report No. 93-61)] through the use of vector potentials, which render the problem tractable by the same techniques as in the two-dimensional case, in particular by expansion of the solution by means of …

Electromagnetic Reaction Cross Sections In Relativistic Heavy Ion Collisions, Jack Dostal

Presidential Scholars Theses (1990 – 2006)

The goal of this project was to produce a computer program to predict the cross section of relativistic heavy ion collisions between given projectile and target nuclei. An explanation of the usefulness of relativistic heavy ion collision analysis is presented. The use of the Weiszacker-Williams method of virtual quanta for enhancing reaction cross sections of this type is discussed. Quantum-mechanical corrections to the semiclassical Weiszacker-Williams method are introduced. C++ computer code has been developed to calculate both semiclassical (as a check) and quantum-mechanical cross sections for these types of reactions. Preliminary results are given for the heavy ion reaction ( …

The Interaction Of Naphthoquinones With The Calcium Release Channel Of Skeletal Muscle Sarcoplasmic Reticulum, Ruohong Xia

Dissertations and Theses

The sarcoplasmic reticulum (SR) is an intracellular membrane system which regulates cytoplasmic calcium concentration in muscle and controls the contractile state of muscle. In this thesis, the interaction between naphthoquinone and the Ca²⁺ release mechanism of SR is described. 1,4-naphthoquinone (1,4NQ) is shown to stimulate Ca²⁺ release and to modify high-affinity ryanodine binding to skeletal muscle sarcoplasmic reticulum. The interaction between 1,4NQ and the SR involves the oxidation ofcritical sulfhydryl groups associated with the Ca²⁺ release mechanism. The modulation of ryanodine binding by 1,4NQ is biphasic. At low concentrations of 1,4NQ (<10 >μM) ryanodine binding is stimulated, …

Voltage Responses To Optical Pulses Of Unbiased Normal And Superconducting Samples, D. Van Vechten, K. S. Wood, G. G. Fritz, J. S. Horitz, G. M. Daly, J. B. Thrasher, D. M. Photiadis, J. Ding, J. F. Pinto, M. G. Blamire, G. Burnell, A. L. Gyulamiryan, V. H. Vartanyan, R. B. Akopyan, Armen Gulian

Mathematics, Physics, and Computer Science Faculty Articles and Research

The direct transformation of the energy of an incident high-energy photon into a measurable potential difference within an absorbing metal is investigated. Experimental evidence is presented that the effect arises from the inherent energy dependence of the electronic density of states, rather than from a simple temperature excursion. The similarities between the results on Al and YBa₂Cu₃O₇ samples indicate that the effect is universal in nature. We assert it may be used as the basis of a fast, energy resolving, individual photon detector for the ultraviolet radiation and x-rays.

Turbulence Modeling Of The Toroidal Wall Heat Load Due To Shear Flows Over Cavities In The Neutral Gas Blanket Divertor Regime, George Vahala, Linda L. Vahala, Joseph Morrison

Electrical & Computer Engineering Faculty Publications

Heat loads to the target plate in reactor tokamaks are estimated to be orders of magnitude higher than those that can be withstood by known materials. In regimes of plasma detachment, there is strong evidence that plasma recombination occurs near the divertor plate, leading to a cold neutral gas blanket. Because of the strong coupling between the plasma and the neutrals within the divertor region, there is significant neutral flows along field lines up to Mach 1.2 and Reynolds numbers over 1000. The effects of three dimensional (3D) neutral turbulence within the gas blanket on heat deposition to the toroidal …

Reflection High-Energy Electron-Diffraction Study Of Melting And Solidification Of Pb On Graphite, Z. H. Zhang, P. Kulatunga, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The melting and solidification of Pb thin films on pyrolytic graphite are investigated in situ by reflection high-energy electron diffraction. Thin films with thicknesses of 4-150 monolayers are investigated. The surface morphology of the thin films were studied by scanning electron microscopy. Superheating of the Pb thin films by 4±2 to 12±2 K is observed from diffraction intensity measurements. Upon cooling the substrate, the Pb on graphite is seen to supercool by ∼69±4 K.

Femtosecond Photoemission Study Of Ultrafast Electron Dynamics On Cu(100), J. Cao, Y. Gao, R. J. D. Miller, Hani E. Elsayed-Ali, D. A. Mantell

Electrical & Computer Engineering Faculty Publications

The energy dependence of the relaxation of photoexcited electrons in copper was measured using femtosecond time-resolved photoemission spectroscopy to within 0.3 eV above the Fermi level. By performing lifetime measurements under different surface conditions, several surface dynamical processes were investigated. In particular, an anomalous long lifetime feature, which cannot be explained with Fermi-liquid theory, was observed in the lifetime-energy curve. This feature was found originating from the photoexcitation of the strongly localized Cu 3d electrons. ©1997 American Physical Society

Velocity–Space Drag And Diffusion In A Model, Two-Dimensional Plasma, Mark Anthony Reynolds, B.D. Fried, G.J. Morales

Publications

The quasilinear fluctuation integral is calculated for a two-dimensional, unmagnetized plasma ~composed of charged rods!, and is expressed in terms of Fokker–Planck coefficients. It is found that in two dimensions, the enhanced fluctuations generated by fast electrons lead to anomalously large transport coefficients. In particular, the effect of a small population of fast electrons is only weakly dependent on their density. In three dimensions, the effect of fast electrons is masked by the dominant approximation, but higher-order terms describe processes similar to those in two dimensions, and these terms can become significant for weakly stable plasmas. The differences between two …

How Much Of The Nucleon Spin Is Carried By Glue?, Ian Balitsky, Xiangdong Ji

Physics Faculty Publications

We estimate in the QCD sum rule approach the amount of the nucleon spin carried by the gluon angular momentum: the sum of the gluon spin and orbital angular momenta. The result indicates that gluons contribute at least one half of the nucleon spin at the scale of 1GeV².

Ionization Of Helium In The Attosecond Equivalent Light Pulse Of 1 Gev/Nucleon U⁹²⁺ Projectiles, R. Moshammer, W. Schmitt, J. Ullrich, H. Kollmus, A. Cassimi, R. Dörner, O. Jagutzki, R. Mann, Ronald E. Olson, H. T. Prinz, H. Schmidt-Böcking, L. Spielberger

Physics Faculty Research & Creative Works

Single and double ionization of helium by 1 GeV/nucleon U92+ impact was explored in a kinematically complete experiment. The relativistic ion generates a subattosecond (10−18s) superintense (I > 1019W/cm2) electromagnetic pulse, which is interpreted as a field of equivalent photons (Weizsäcker-Williams method). Cross sections, the emission characteristics of ions and electrons as well as momentum balances, are quantitatively discussed in terms of photoionization of the atom in this broadband, ultrashort virtual photon field. © 1997 The American Physical Society.