Digital Commons Network^™

The Ring-Closing Reaction Of Cyclopentadiene Probed With Ultrafast X‑Ray Scattering, Lisa Huang, Lauren Bertram, Lingyu Ma, Nathan Goff, Stuart W. Crane, Asami Odate, Thomas Northey, Andrés Moreno Carrascosa, Mats Simmermacher, Sri Bhavya Muvva, Joseph D. Geiser, Matthew J. Lueckheide, Zane Phelps, Mengning Liang, Xinxin Cheng, Ruaridh Forbes, Joseph S. Robinson, Matthew J. Hayes, Felix Allum, Alice E. Green, Kenneth Lopata, Artem Rudenko, Thomas J. A. Wolf, Martin Centurion, Daniel Rolles, Michael P. Minitti, Adam Kirrander, Peter M. Weber

Martin Centurion Publications

The dynamics of cyclopentadiene (CP) following optical excitation at 243 nm was investigated by time-resolved pump−probe X-ray scattering using 16.2 keV X-rays at the Linac Coherent Light Source (LCLS). We present the first ultrafast structural evidence that the reaction leads directly to the formation of bicyclo[2.1.0]pentene (BP), a strained molecule with three- and four-membered rings. The bicyclic compound decays via a thermal backreaction to the vibrationally hot CP with a time constant of 21 ± 3 ps. A minor channel leads to ring-opened structures on a subpicosecond time scale.

Current Small-Scale Cmb Constraints To Axionlike Early Dark Energy, Tristan L. Smith, V. Poulin

Physics & Astronomy Faculty Works

The south pole telescope (SPT) SPT-3G 2018 cosmic microwave background (CMB) data set (temperature and polarization) is used to place constraints on an axionlike model of early dark energy (EDE). These data do not favor axionlike EDE and place an upper limit on the maximum fraction of the total energy density 𝑓_EDE < 0.172 (at the 95% confidence level, C.L.). This is in contrast with Atacama Cosmology telescope’s (ACT) fourth data release (DR4) which gives 𝑓_EDE = 0.15⁢0 +0.050/-0.078. When combining CMB measurements with measurements of the baryon acoustic oscillations and luminosity distance to type Ia supernovae, we show that the tension with the S⁢𝐻₀ ⁡ES measurement of the Hubble parameter goes up from 2.6⁢𝜎 with 𝑃⁢𝑙⁢𝑎⁢𝑛⁢𝑐⁢𝑘 to 2.9⁢𝜎 with 𝑃⁢𝑙⁢𝑎⁢𝑛⁢𝑐⁢𝑘+SPT−3⁢G 2018. …

Nonlinear Rogue Wave Generation For All-Optical Switching In Optical Fibers And Photonic Integrated Circuits, Samuel Alexander Bechtold

Honors Program Theses and Projects

For my thesis we discuss the history of optics, electronics and photonicsproviding a framework from which I investigate the viability of engineering a Photonic Integrated Circuit (PIC) that takes advantage of the nonlinear optical process known as Rogue Wave Generation (RWG) for an all-optical switching mechanism that is capable of switching speeds in the Peta-Hertz (PHz) frequency regime. This topic is introduced through a discussion of how technological advances such as the transistor, laser and optical fiber made modern computing and telecommunications possible. This is followed by a theoretical explanation of the nonlinear optical phenomena known as supercontinuum generation (SCG) …

Cn Stretches Around 4.4 Microns Dominate The Ir Absorption Spectra Of Cyanopolycyclic Aromatic Hydrocarbons, Vincent J. Esposito, Ryan C. Fortenberry, Christiaan Boersma, Alexandros Maragkoudakis, Louis J. Allamandola

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Anharmonic quantum chemical computations reveal a strong, narrow (width = 0.075 μm) band in the 4.3–4.5 μm region of the absorption spectra of the cyano-substituted polycyclic aromatic hydrocarbons (CN-PAHs) cyanonaphthalene, cyanoanthracene, c yanophenanthrene, and c yanopyrene. This narro w windo w with intense IR lines implies that CN-PAHs of various shapes and sizes offer little variation in both wavelength and intensity in this region. Subsequently, this band can be used as a tracer for CN-PAHs. The distinct features making up the band are assigned to mixed vibrational states consisting of the CN stretch fundamental and various combination bands, including in-plane …

Multiphoton Quantum Sensing, Fatemeh Mostafavikhatam

LSU Doctoral Dissertations

While the fundamental principles of light-matter interaction are well-understood and drive countless technologies, the world of multiphoton processes remains a fascinating puzzle, holding the potential to drastically alter our understanding of how light interacts with matter at its most basic level [1–4]. This rich interplay of light and matter unveils novel phenomena that can be harnessed for sensing with exceptional precision, as exemplified by multiphoton quantum sensing. This thesis delves into the applications of multiphoton quantum protocols, particularly in imaging, communication, and plasmonic sensing, to surpass classical limitations and achieve enhanced sensitivity. We explore the potential of multiphoton quantum processes, …

A Realist Interpretation Of Unitarity In Quantum Gravity, Indrajit Sen, Stephon Alexander, Justin Dressel

Mathematics, Physics, and Computer Science Faculty Articles and Research

Unitarity is a difficult concept to implement in canonical quantum gravity because of state non-normalisability and the problem of time. We take a realist approach based on pilot-wave theory to address this issue in the Ashtekar formulation of the Wheeler–DeWitt equation. We use the postulate of a definite configuration in the theory to define a global time for the gravitational-fermionic system recently discussed in Alexander et al (2022 Phys. Rev. D 106 106012), by parameterising a variation of a Weyl-spinor that depends on the Kodama state. The total Hamiltonian constraint yields a time-dependent Schrodinger equation, without semi-classical approximations, which we …

Bioactive Glass Bead Characterization: Further Applications In Passive Drug Delivery, Marie O. Sykes

Physics and Astronomy Honors Papers

Bioactive glass beads were discovered for their bone repair properties in 1969. This properties, along with their bactericidalness, high ability to be engineered, bioactiveness and their versatile structures, mark them as excellent candidates for explorations in other biomedical applications in addition to bone repair. One alternative application includes passive drug delivery, especially when the biomaterial is in a porous, microsphere structure. In this work, we first explore various samples of bioactive glass compositions and structures in order to target the best bead for the application of drug delivery. The targeted beads are then thoroughly characterized using optical microscopy, Scanning Electron …

Quantification Of Surface Layer Turbulence Using Sensible Heat Values From Energy Balance Versus Aerodynamic Methods, Steven T. Fiorino, Yogendra Raut, Jaclyn Schmidt, Laura Slabaugh, Blaine Fourman, Jack E. Mccrae, Benjamin C. Wilson, Santasri R. Bose-Pillai

Faculty Publications

Surface layer optical turbulence values in the form of the refractive index structure function C_n^2 are often calculated from surface layer temperature, moisture, and wind characteristics and compared to measurements from sonic anemometers, differential temperature sensors, and imaging systems. A key derived component needed in the surface layer turbulence calculations is the sensible heat value. Typically, the sensible heat is calculated using the bulk aerodynamic method that assumes a certain surface roughness and a friction velocity that approximates the turbulence drag on temperature and moisture mixing from the change in the average surface layer vertical wind velocity. These assumptions/approximations generally …

Comparison Of The Fluorescence Of Bulk Cadmium Sulfide And Cadmium Sulfide Nanoparticles, Jacob Goranson

Celebrating Scholarship and Creativity Day (2018-)

The fluorescence of bulk cadmium sulfide and cadmium sulfide nanoparticles were compared. This was done using an 800-nm, unamplified Ti:sapphire laser producing 50-fs pulses. The pulses were frequency doubled using a beta barium borate (BBO) crystal. The 400-nm beam was used to induce fluorescence in the nanoparticles, while the original 800-nm beam was used to induce fluorescence in the bulk CdS by two-photon absorption. The bulk CdS showed a single fluorescent peak at 523 nm. The nanoparticles showed fluorescence at various wavelengths across the visible spectrum. In general, the nanoparticles showed a broad fluorescent spectrum between 500 nm and 750 …

Zeolitic Imidazolate Framework-8 Encapsulated With Mo-Based Polyoxometalates As Surfaces With Antibacterial Activity Against Escherichia Coli, Mariam M. Abdelkhalek, Aya M. Mohamed, Rehab Z. Abdallah, Ghada E. Khedr, Rania Siam, Nageh K. Allam

Faculty Journal Articles

Bacterial infections represent a major global health concern, causing millions of deaths and a significant economic burden. The development of antibacterial nanoporous surfaces with potential mechano-bactericidal effects can revolutionize infection control practices. In this study, a hybrid material of zeolitic imidazolate framework-8 (ZIF-8) doped with phosphomolybdic acid (PMA) was synthesized and characterized by field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and N2 sorption isotherms. PMA@ZIF-8 performance as an antibacterial agent against E. coli was superior to that of its individual constituents, suggesting a synergistic effect of PMA and ZIF-8. The …

Signal Processing Algorithms For Doppler Lidar Sensors, Samantha Grubb

Physics and Astronomy Honors Papers

Light detection and ranging (LiDAR) is a remote sensing technology that obtains relative distance and velocity measurements between a sensor and a defined target by using light transmitted and received from the target. FMCW Doppler LiDAR, a particular variant of LiDAR, functions by analyzing the frequency shift in the reflected light to determine the target's range and velocity. This technology plays a crucial role across various sectors including defense, aerospace, and automotive. This paper presents signal processing algorithms designed to optimize data obtained from Doppler LiDAR sensors. By applying various window functions to time domain data, the Signal-to-Noise Ratio (SNR) …

Near-Collapse Of The Geomagnetic Field May Have Contributed To Atmospheric Oxygenation And Animal Radiation In The Ediacaran Period, Wentao Huang, John A. Tarduno, Tinghong Zhou, Mauricio Ibañez-Mejia, Laércio Dal Olmo-Barbosa, Edinei Koester, Eric G. Blackman, Aleksey V. Smirnov, Gabriel Ahrendt, Rory D. Cottrell, Kenneth P. Kodama, Richard K. Bono, David G. Sibeck, Yong Xiang Li, Francis Nimmo, Shuhai Xiao, Michael K. Watkeys

Michigan Tech Publications

Earth’s magnetic field was in a highly unusual state when macroscopic animals of the Ediacara Fauna diversified and thrived. Any connection between these events is tantalizing but unclear. Here, we present single crystal paleointensity data from 2054 and 591 Ma pyroxenites and gabbros that define a dramatic intensity decline, from a strong Proterozoic field like that of today, to an Ediacaran value 30 times weaker. The latter is the weakest time-averaged value known to date and together with other robust paleointensity estimates indicate that Ediacaran ultra-low field strengths lasted for at least 26 million years. This interval of ultra-weak magnetic …

Measurement Of Transmission Efficiency Of Blue Light Blocking Devices, Jada Lee

Honors Theses

Technology and light sources have experienced a revolution in recent years leading to the production of light emitting diode (LED) bulbs. White-light LED bulbs undergo degradation over time, leading to a rise in color temperature and a proportional increase in the emission of blue light from these bulbs. The small size of LEDs makes them the optimal choice for electronic devices because of their limited screen size. This means that blue light now exists in red, green, and blue solid-state illumination systems that did not exist a decade ago. It is debated if blue light induces toxic effects on the …

Analyzing Atmospheric Gravity Waves Over Antarctica And Visualizing Machine Learning Data, Anastasia N. Brown

Physics Capstone Projects

In an effort to streamline the identification of "clean" windows of airglow images in all sky imager data for the ANGWIN experiment, we have developed a Light Gradient Boosted Machine (LightGBM) learning algorithm that sorts "clean" (marked as 0) wave images from "obscured" (marked as 1) images. These "clean" windows are then processed and undergo FFT-spectrum analysis. We have already successfully created LightGBM models that accurately sort through images taken at the Davis, McMurdo, and Halley research stations in Antarctica. Imager data from the Davis and McMurdo station has been fully processed from the years 2012 to 2022 with clean …

A Comprehensive Investigation Of The Influence Of Geometric Structure On The Shape Memory Performance Of Nafion, Jade Thomas

Physics Undergraduate Honors Theses

While perfluorosulfonic acid (PFSA) membranes have primarily been used in fuel cells due to their chemical, thermal, and mechanical stability, one PFSA, Nafion, boasts two unique characteristics: a broad glass transition (~55 °C to 130 °C) and a temperature-persistent electrostatic network. The combination of these two characteristics endows Nafion with exceptional shape memory properties – the ability of a material to morph and transform into pre-programmed shapes when exposed to an external stimulus – with enhanced permanent shape memorization, and a potentially near-infinite number of temporary shape memorization. This study focused on expanding the base of knowledge surrounding Nafion’s shape …

The Analysis Of Mechanical Exfoliation Of Graphene For Various Fabrication And Automation Techniques, Lance Yarbrough

Physics Undergraduate Honors Theses

Mechanical Exfoliation

An Educational Resource For Particle Identification (Pid) In Experimental Particle Physics Data, Richard Dube

University Scholar Projects

Although particle physics research is typically reserved for advanced undergraduates, algebra-based physics students can readily develop the foundational skills necessary to conduct particle physics research. Despite this, there is a shortage of educational resources that introduce particle physics to algebra-based physics students. This project, Particle Identification Playground, is a collection of Python-based activities that teach students about several fundamental topics in experimental particle physics research. Through these activities, students will learn about the common detectors used in particle physics, how they work, and how we can use these detectors to identify particles. Students are able to interact with 3D models …

The Search For Photonuclear Interactions Of Muons Utilizing Test Beam Data At The Large Hadron Collider, Miranda M. Williams

2024 Spring Honors Capstone Projects - Archive

The ATLAS Detector is one of four different types of detectors within the Large Hadron Collider and is used to study the fundamental theories of the universe. Within the ATLAS experiment, beams of known composition and energies – otherwise known as “test beams” – are one of the many methods used to study specific physical phenomena. In this study, a test beam of muons with an energy of 160 GeV was analyzed to search for evidence of photonuclear interactions. This necessitated analyzing and filtering over 50,000 total events using specific parameters that would indicate such an event had occurred. To …

Electrochemical Modulation Of Surface Plasmon Wave To Investigate Dna-Based Sensing Platforms And Detection Of Sars-Cov2., Anil Sharma

Electronic Theses and Dissertations

This study offers a thorough comparative analysis of optical and electrical signaling strategies for assessing the electrochemical properties of different redox-labeled DNA-based biosensing platforms. In addition, it illustrates the development of an optical interrogation technique with electrochemical modulation of surface plasmon waves (ECM-SPW) as a route for analyzing and implementing DNA-based hybridization sensors. For those quantitative analyses, we chose a model sensing platform composed of a methylene blue (MB)-modified single-stranded DNA (ssDNA) signaling probe and an unlabeled capture ssDNA probe that complements the signaling probe. Two types of signaling probes were employed in this work: one with MB attached to …

Investigations Of Physical Properties Of Novel Magnetic And Non- Magnetic Two-Dimensional (2d) Alloys., Mohammed Ameen Irziqat

Electronic Theses and Dissertations

This research work reports investigations of structural and physical properties of novel magnetic and non-magnetic 2D alloys. Three techniques were utilized in this investigation: Angle-resolved polarized Raman spectroscopy (ARPRS), Electrical &Thermoelectric power measurements, Magneto-optic Kerr effect (MOKE) spectroscopy. ARPRS and MOKE experiments were constructed during the course of this work. ARPRS was used to study the anisotropy of 2-dimensional black-arsenic phosphors (b-AsxP1-x) as a function of arsenic concentration (x). It was observed experimentally that all Raman modes of the studied samples with x=0, 0.4, 0.8 exhibit polarization dependence. More interestingly, the polarization dependence of Raman modes due to the vibrations …

Proof-Of-Concept For Converging Beam Small Animal Irradiator, Benjamin Insley

Dissertations and Theses (Open Access)

The Monte Carlo particle simulator TOPAS, the multiphysics solver COMSOL., and

several analytical radiation transport methods were employed to perform an in-depth proof-ofconcept

for a high dose rate, high precision converging beam small animal irradiation platform.

In the first aim of this work, a novel carbon nanotube-based compact X-ray tube optimized for

high output and high directionality was designed and characterized. In the second aim, an

optimization algorithm was developed to customize a collimator geometry for this unique Xray

source to simultaneously maximize the irradiator’s intensity and precision. Then, a full

converging beam irradiator apparatus was fit with a multitude …

Impact Of Property Covariance On Cluster Weak Lensing Scaling Relations, Zhuowen Zhang, Arya Farahi, Daisuke Nagai, Erwin T. Lau, Joshua Frieman, Marina Ricci, Anja Von Der Linden, Hao-Yi Wu, Lsst Dark Energy Science Collaboration

Physics Faculty Publications and Presentations

We present an investigation into a hitherto unexplored systematic that affects the accuracy of galaxy cluster mass estimates with weak gravitational lensing. Specifically, we study the covariance between the weak lensing signal, ΔΣ, and the ‘true’ cluster galaxy number count, N_gal, as measured within a spherical volume that is void of projection effects. By quantifying the impact of this covariance on mass calibration, this work reveals a significant source of systematic uncertainty. Using the MDPL2 simulation with galaxies traced by the SAGE semi-analytic model, we measure the intrinsic property covariance between these observables within the three-dimensional vicinity of …

Learning, Optimizing, And Simulating Fermions With Quantum Computers, Andrew Zhao

Physics & Astronomy ETDs

Fermions are fundamental particles which obey seemingly bizarre quantum-mechanical principles, yet constitute all the ordinary matter that we inhabit. As such, their study is heavily motivated from both fundamental and practical incentives. In this dissertation, we will explore how the tools of quantum information and computation can assist us on both of these fronts. We primarily do so through the task of partial state learning: tomographic protocols for acquiring a reduced, but sufficient, classical description of a quantum system. Developing fast methods for partial tomography addresses a critical bottleneck in quantum simulation algorithms, which is a particularly pressing issue for …

Encapsulated 2d Materials And The Potential For 1d Electrical Contacts, Sarah Wittenburg

Physics Undergraduate Honors Theses

The utilization of two-dimensional materials and heterostructures, particularly graphene and hexagonal boron nitride, have garnered significant attention in the realm of nanoelectronics due to their unique properties and versatile functionalities. This study focuses on the synthesis and fabrication processes of monolayer graphene encapsulated between layers of hBN, aiming to explore the potential of these heterostructures for various electronic applications. The encapsulation of graphene within hBN layers not only enhances device performance but also shields graphene from environmental contaminants, ensuring long-term stability. Experimental techniques, including mechanical exfoliation and stamp-assisted transfer, are employed to construct three-layer stacks comprising hBN-graphene-hBN. The fabrication process …

Redesign Of X-Ray Irradiator To Expand Research Of Low-Dose X-Ray Radiation, Lauren Ulbrich

All Theses

The effects of high-dose radiation are well-documented, and are understood to be harmful to the human body. On the other hand, the effects of low-dose radiation are much less understood. There is debate over whether or not there are negative, positive, or no effects at all from low-dose radiation. One of the reasons why these effects are not well known is because there aren't as many studies done on this type of radiation. It is a lot harder to classify the effects of radiation at low doses due to many external factors. However, the Clemson Medical Physics lab has been …

The Potential For Enhancing Tumour Detection In Medical Imaging With Coherent Scatter, Aastha Boora

Legacy Theses & Dissertations (2009 - 2024)

A number of medical disorders may only be diagnosed with the use of medical imaging, and X-rays are commonly used to detect fractures, abnormal masses, and cavities. The penetration power of X-rays enables them to effectively see these structures inside the body. However, since background structures like fat or fibrous glandular tissue have similar absorption coefficients, X-ray radiography often face challenges when imaging soft tissues for cancer/tumour diagnosis. Research has shown the theoretical potential for X-ray phase imaging to increase contrast factors by a factor of 100 or more, which theoretically could result in enhanced visualization of tumours. In addition …

Deterministic Global 3d Fractal Cloud Model For Synthetic Scene Generation, Aaron M. Schinder, Shannon R. Young, Bryan J. Steward, Michael L. Dexter, Andrew Kondrath, Stephen Hinton, Ricardo Davila

Faculty Publications

This paper describes the creation of a fast, deterministic, 3D fractal cloud renderer for the AFIT Sensor and Scene Emulation Tool (ASSET). The renderer generates 3D clouds by ray marching through a volume and sampling the level-set of a fractal function. The fractal function is distorted by a displacement map, which is generated using horizontal wind data from a Global Forecast System (GFS) weather file. The vertical windspeed and relative humidity are used to mask the creation of clouds to match realistic large-scale weather patterns over the Earth. Small-scale detail is provided by the fractal functions which are tuned to …

Engineering Silicon Metalenses In Wide Field Revers-Telephoto Optical Systems For Long-Wave Infrared Thermal Imaging, Alfred Anson Moore

Graduate Theses - Physics and Optical Engineering

A novel optical system designed to image light emitted from a CO 2 laser (10.6 μm) is presented here. This system utilizes a positive conventional lens and a negative all silicon metalens. Demonstrated here is the ability of metalenses to replace a combination of optical elements to produce more compact and light-weight optical systems. It also shows how metalenses can replace comparatively expensive custom-manufactured lenses. Several systems that utilize meta-surfaces are explored, including positive and negative metalenses, a meta-corrector, a metalens doublet imaging system that corrects for 0 th -order images overlapping 1 st -order images, and several telephoto optical …

Studying Superconducting Thin Films For Quantum Computing Applications, Bernardo Jaime Langa Junior

All Theses

Superconducting qubits have emerged as a promising platform for realizing error-corrected quantum computing. Reaching the minimum threshold for error correction requires scaling the number of qubits well beyond the current numbers while improving their coherence and minimizing their crosstalk. Such daunting demands require groundbreaking innovations in the design of superconducting quantum circuits as well as in engineering the materials integrated into the devices. This thesis explores materials solutions for two different scalability problems: 1) crosstalk and 2) loss due to surface oxidation. The crosstalk is addressed by making voltage-tunable superconductor-semiconductor Josephson junctions (JJs). For the loss due to surface oxidation, …

Investigation Of Domain Formation During Phase Separation In A Mixture Of Flexible And Rigid Biopolymers, Steven Huntley

All Theses

Complex fluids and heterogenous mixtures composed of multiple types of polymers are found throughout industrial and biological fluid systems. For example, extrusion based additive manufacturing systems pass dense mixtures of polymers through the extrusion heads to deposit composite polymeric materials. In cells, active and complex mixtures of biopolymers self-organize into assemblies that perform critical physiological functions.

Polymers in dense solutions undergo phase separation as a result of differences in physiochemical properties. A few examples of these properties include charge, structure, rigidity, and hydrophobicity. We observe the formation of polymer domains composed of rigid and a flexible biopolymer species that phase …